• Title/Summary/Keyword: Physical absorption

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Modeling of Wet Flue Gas Desulfurization Process for Utilization of Low-Grade Limestone (저품위 석회석 활용을 위한 습식 배연탈황 공정 모델링 연구)

  • Lim, Jonghun;Choi, Yeongryeol;Kim, Geonyeol;Song, Hojun;Kim, Junghwan
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.743-748
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    • 2019
  • This study focuses on the simulation of wet flue gas desulfurization process for improving the production of gypsum by the utilization of low-grade limestone. At present, high-grade limestone with a $CaCO_3$ content of 94% is used for producing merchantable gypsum. In modeling process, a lot of reactions are considered to develop model. First, the limestone dissolution is simulated by RSTOIC model. Second, SOx absorption and crystallization is used by RCSTR model. Finally the gypsum is separated by using SEPERATORS model. Modeling steps make it easy to reflect further side reactions and physical disturbances. In optimization condition, constraints are set to 93% purity of gypsum, 94% desulfurization efficiency, and total use of limestone at 3710 kg/hr. Under these constraints, the mass flow of low-grade limestone was maximized. As a result, the maximum blending quantity of low-grade limestone for 2,100 kg of high-grade limestone that satisfies constraints is about 1,610 kg.

Analysis the Use of Concrete Fine Aggregates of Coal Gasification Slag (콘크리트용 잔골재로서 석탄가스화 용융슬래그(CGS)의 활용성 분석)

  • Park, Kyung-Taek;Han, Min-Cheol;Hyun, Seung-Yong
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.2
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    • pp.101-108
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    • 2019
  • This study is analysis of the utilization as a concrete fine aggregate on CGS, a by-product of Integrated coal gasification combined cycle(IGCC). That is, in KS F 2527 "Concrete aggregate," properties of 1~12times to CGS were evaluated, focusing on quality items corresponding to natural aggregate sand(NS) and melted slag aggregate sand(MS). As a result, the distribution of grain shape, safety and expansion were all satisfied with KS standards by physical properties, but the quality was unstable at 7~12times of water absorption ratio and absolute dry density. The particle size distribution was unstable due to asymmetry distribution of coarse particles, and particles were too thick for 7~12times. The passing ratio of 0.08mm sieve was also out of the KS standard at part factor of 7~12times, but chloride content, clay contents, coal and lignite were all satisfactory. Meanwhile, chemical composition was satisfactory except for $SO_3$ in 1~6times, and content and amount of harmful substances were all within the specified value except for F in 7~12times. As a result of SEM analysis, the surface quality and porosity were 7~12times more than 1~6times, and it was the quality was degraded. Therefore, it is necessary to reduce the quality deviation by using separate measures in order to utilize it as concrete aggregate in the future, and if it is premixed with fine quality aggregate, it will contribute positively to solve aggregate supply shortage and utilize circulation resources.

Rheological properties of flour dough containing roasted rice bran (볶은 쌀겨를 첨가한 밀가루 반죽의 rheology 특성)

  • Shin, Hyun-Kwang;Lee, Jeong-Hoon;Chung, Koo-Chun;Lee, Si-Kyung
    • Korean Journal of Food Science and Technology
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    • v.50 no.6
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    • pp.587-593
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    • 2018
  • This study was carried out to investigate the effect of roasted rice bran (RRB) on the rheological properties of bread dough. According to farinograph analysis, the consistency of the control sample was greatest. There were no significant differences in water absorption (p<0.05). Lower values of development time, stability, and time to breakdown, which were affected, by the addition of RRB, were observed for RRB-containing dough samples, compared to the control dough sample. Addition of RRB significantly increased the mixing tolerance index (MTI). According to rheofermentometer analysis, the values of H'm, $T^{\prime}_1$, and retention volume decreased with increase in the amount of RRB added. According to the rapid visco analyzer (RVA) analysis, peak viscosity, holding strength, and setback values were greater in the control than in the RRB-containing samples. The addition of RRB to the flour influenced rheological properties like fermentation volume and acidity. The total acidity increased with the increase in the amount of RRB added. The present study has indicated that there was no significant difference between the rheological properties of the control and 5% RRB-containing dough samples. Therefore, the addition of 5% RRB could be an effective way to produce functional flour bread without affecting its desirable physical properties.

The Effects of Diet-Gel and Electric Muscle Stimulator on Waist Circumference Reduction (다이어트젤과 전기근육자극기가 허리둘레 감소에 미치는 영향)

  • Lee, Gwang-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.2
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    • pp.453-464
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    • 2021
  • Abdominal obesity is increasing due to a decrease in physical activity and westernization of diet in busy daily life. Therefore, in order to satisfy the desire for body shape management, a management program with high efficiency versus time is needed. In this study, the diet-gel (i.e., slimming cosmetics) with the electrical muscle stimulation therapy was used to promote the effect of reducing waist circumference and body fat mass (or abdominal fat). For men and women in their twenties, the subjects simply applied diet-gel to their waist, wore EMS, and massaged for 20 minutes twice a day after waking up and before going to sleep. The experiment period was carried out for 2 weeks. The reduction of subcutaneous fat was observed using non-contrast CT, and it was confirmed by measuring waist circumference and body fat mass. In conclusion, the developed EMS and diet-gel combination program showed excellent waist management effects by reducing waist circumference by about 3 cm (p<0.001) and body fat mass by about 1 kg (p<0.01). This result suggests that the use of EMS shows a massage effect by muscle stimulation, and plays a role in promoting fat decomposition by helping the absorption of diet gel.

Preparation and characterization of Mn doped copper nitride films with high photocurrent response

  • Yu, Aiai;Hu, Ruiyuan;Liu, Wei;Zhang, Rui;Zhang, Jian;Pu, Yong;Chu, Liang;Yang, Jianping;Li, Xing'ao
    • Current Applied Physics
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    • v.18 no.11
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    • pp.1306-1312
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    • 2018
  • The Mn-doped copper nitride ($Cu_3N$) films with Mn concentration of 2.0 at. % have high crystallinity and uniform surface morphology. We found that the as-synthesized Mn-doped $Cu_3N$ films show suitable optical absorption in the visible region and the band gap is ~1.48 eV. A simple photodetector based on Mn doped $Cu_3N$ films was firstly fabricated via magnetron sputtering method. The fabricated device with doping of Mn demonstrated high photocurrent response and fast response shorter than 0.1 s both for rise and decay time superior to the pure $Cu_3N$. Furthermore, the energy levels of Mn-doped Cu3N matched well with ITO and Ag electrode. The excellent photoelectric properties reflect a good balance between sensitivities and response rate. Our investigation reveals the excellent potential of Mn-doped $Cu_3N$ films for application of photodetectors.

Measurement of Thermal Diffusivity and the Optical Properties of a Carbon Nanotube Dispersion by Using the Thermal Lens Effect (열렌즈 효과를 이용한 탄소 나노 튜브 분산액의 열확산도와 광학적 특성 측정)

  • Park, Hyunwoo;Kim, Hyunki;Kim, Sok Won;Lee, Joohyun
    • New Physics: Sae Mulli
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    • v.68 no.11
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    • pp.1167-1172
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    • 2018
  • Carbon nanotubes (CNTs) are structures of carbon atoms bonded together in hexagonal honeycomb shapes, with multi-walled CNTs having a very high thermal conductivity of $3000W/m{\cdot}K$ and single-walled CNTs having a conductivity of $6000W/m{\cdot}K$. In this work, the transmittance and the thermal diffusivity of a multi-walled carbon nanotube dispersion with a concentration of 1.5 M were measured using a single beam method, a dual beam method, and the thermal lens effect. The nonlinear optical coefficients were obtained by using the z-scan method, which moved the sample in the direction of propagation of the single laser beam, propagation and the thermal diffusivity was measured using a double laser beam. As a pump beam, a diode-pumped solid state (DPSS) laser with a wavelength of 532 nm and an intensity of 100 mW was used. As the probe beam, a He-Ne laser having a wavelength of 633 nm and an intensity of 5 mW was used. The experimental result shows that when the concentrations of the sample were 9.99, 11.10, 16.65, and 19.98 mM, the nonlinear absorption coefficients were 0.046, 0.051, 0.136 and 0.169 m/W, respectively. Also, the nonlinear refractive indices were 0.20, 0.51, 1.25 and $1.32{\times}10^{-11}m^2/W$, respectively, and the average thermal diffusivity was $1.33{\times}10^{-6}m^2/s$.

The Mechanical Properties of SMA Concrete Mixture Using Steel Slag Aggregate (제철 슬래그 골재를 이용한 SMA 혼합물의 역학적 특성)

  • Kim, Hyeok-Jung;Na, Il-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.1
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    • pp.109-116
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    • 2021
  • In order to replace mineral aggregate used as road pavement materials with steel slag aggregate, this present study evaluated mechanical properties of SMA Concrete mixtures using steel slag aggregate as oxidized slag from electric furnace in iron works. The variables of this experiment are the aggregate type of mineral and steel slag and the sieve sized of 10mm and 13mm. The physical properties inclu ding the specific gravity and absorption rate etc. of the slag aggregate mixtu res satisfied the KS standard as asphalt mixtu re. As a resu lt of evalu ating the mechanical properties of the asphalt mixtures, the optimum asphalt content of the slag aggregate mixtures were lower than that of the mineral aggregate mixtures, but other quality standards were all satisfied. In the deformation strength evaluation, the slag aggregate mixtures were measu red slightly higher than that of the mineral aggregate mixtu res, and the dynamic stability test satisfied the 2,000pass/mm standard value in all specimens. And, the moduli of resilient of the slag aggregate mixtures showed an improved value compared with the mineral aggregate mixtures. Therefore, as the resilient rate of the slag aggregate mixtures improved, it is speculated that there will be an effect of improving public performance according to the repeated traffic load of the vehicle.

Material Properties Evaluation of Cement Mortar Mixed with Organic/Inorganic Combined Water-repellent (유/무기 복합 발수제를 혼입한 모르타르의 재료특성 평가)

  • Kim, Wan-Su;Yoon, Chang-Bok;Cho, In-Sung;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.6
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    • pp.50-58
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    • 2020
  • When the concrete surface layer is damaged, The method of impregnating the concrete surface with a water repellent cannot secure the expected durability. Recently, various waterproofing and water-repellent materials were mixed into concrete or mortar to secure water repellency even inside cracks, but compressive strength was greatly reduced. In order to overcome the decrease in compressive strength, there has not yet been a study using the merits of organic and inorganic materials at the same time, so in this study, the physical properties and water repellency performance were evaluated by mixing an organic/inorganic composite water repellent appropriately mixed with an organic and inorganic material into the mortar. When mixed with organic/inorganic water repellent, the flow and air content were reduced by about 10% and 50% compared to the Liquid specimen. In the case of the P6L1 specimen, it was confirmed that the compressive strength decreased by about 3.5% compared to the non-mixed mortar at 39.5 MPa, the same as the existing water repellent, Powder. Water-repellent performance The organic-inorganic composite water repellent mixture specimen confirmed higher water repellency than the existing water repellent mixture powder, and the chloride penetration resistance evaluation result showed that the organic-inorganic composite water repellent mixture specimen reduced the passing charge by about 45% compared to the non-mixed mortar. In summary, it is judged that the P5L1 organic/inorganic composite water repellent mixed with a powder water repellent and a liquid water repellent in a ratio of 5:1 is the most reasonable to prevent the decrease in compressive strength and secure water repellency.

Development of CNT Coating Process using Argon Atmospheric Plasma (아르곤 상압플라즈마를 이용한 CNT 코팅 공정 기술 개발)

  • Kim, Kyoung-Bo;Lee, Jongpil;Kim, Moojin
    • Journal of Industrial Convergence
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    • v.20 no.10
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    • pp.33-38
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    • 2022
  • In this paper, a simple method of forming a solution-based carbon nanotube (CNT) for use as a conductive material for electronic devices was studied. The CNT thin film coating was performed on the glass by applying the spin coating method and the argon atmospheric pressure plasma process. In order to observe changes in electrical and physical properties according to the number of coatings, samples formed in the same manner from times 1 to 5 were prepared, and surface shape, reflectance, transmittance, absorbance, and sheet resistance were measured for each sample. As the number of coatings increased, the transmittance decreased, and the reflectance and absorptivity increased in the entire measurement wavelength range. Also, as the wavelength decreases, the transmittance decreases, and the reflectance and absorption increase. In the case of electrical properties, it was confirmed that the conductivity was significantly improved when the second coating was applied. In conclusion, in order to replace CNT with a transparent electrode, it is necessary to consider the number of coatings in consideration of reflectivity and electrical conductivity together, and it can be seen that 2 times is optimal.

Analysis on Characteristics of Pigments Manufactured with Various Neorok Produced from Mt. Gwangjeongsan, Pohang (포항 광정산 일대 산출 뇌록으로 제조한 안료의 특성 분석)

  • Mun, Seong Woo;Kang, Young Seok;Kim, Ji Sun;Hwang, Ga-Hyun;Park, Ju Hyun;Lee, Sun Myung;Jeong, Hye Young
    • Journal of Conservation Science
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    • v.36 no.6
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    • pp.533-540
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    • 2020
  • Mt. Neoseongsan (NSS) is the only natural Neorok source in Korea. The geological, historical, and cultural values of NSS were recognized in 2013, and NSS has since been designated and maintained as a natural monument (No. 547), which has restricted the research and utilization of NSS Neorok. The limited NSS Neorok supply has hindered the restoration research of traditional pigments. Recently, a large amount of Neorok has been mined from Mt. Gwangeongsan (GJS) and is expected to be the main supply source of Neorok for restoring traditional pigments. Therefore, this study analyzed the characteristics of NSS- and GJS-Neorok-based pigments to evaluate the feasibility of substituting GJS Neorok for NSS Neorok in pigments. The NSS Neorok was mostly comprised of celadonite, whereas the GJS Neorok included minerals containing glassy phases such as celadonite, cristobalite, tridymite, etc. Because both Neorok samples were vitrified under identical conditions, the GJS Neorok grains were larger than the NSS Neorok ones. The GJS Neorok pigment showed that the chromaticity, grain size, oil absorption, and stability varied depending on the mineral types and contents. In particular, GJS-2 and NSS Neorok showed similar mineral compositions, physical properties, and stabilities, suggesting that GJS-2 can be substituted for NSS Neorok, which has been difficult to source and utilize ever since NSS was designated as a natural monument.