• 제목/요약/키워드: Photothermal Deflection

검색결과 10건 처리시간 0.027초

광열편향법을 이용한 이방성 재료의 열전도계수 측정에 관한 이론적 연구 (A Theoretical Study for the Thermal Conductivity Measurement of Anisotropic Material using Photothermal Deflection Spectroscopy)

  • 전필수;김현정;유재석
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회B
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    • pp.2465-2470
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    • 2007
  • We have analyzed the three-dimensional thermal conduction in anisotropic materials using nonsymmetric-Fourier transforms. And a complete theoretical treatment of the photothermal deflection spectroscopy has been performed for thermal conductivity measurement in anisotropic medium. Thermal conductivity tensor was determined by the deflection angle and phase angle with the relative position between the heating and probe beams. The influence of the parameters, such as modulation frequency of the heating beam, the thermal conductivity tensor, was investigated.

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광열/광음 기법에 의한 나노초 폭발적 기화 과정 분석 (Analysis of Nanosecond Explosive Vaporization Process by Photothermal/Photoacoustic Methods)

  • 박희권;;최선락;김동식
    • 대한기계학회논문집B
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    • 제27권6호
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    • pp.804-812
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    • 2003
  • This paper introduces optical methods for in-situ measurement of surface temperature and pressure transient in thermal processes having nanosecond time scales. In the temperature measurement, a p -Si thin film whose refractive index is calibrated as a function of temperature is embedded beneath the sample surface and the photothermal reflectance is monitored for estimating the surface temperature. The pressure transients are measured using the photoacoustic optical deflection method. The experimental technique is used to analyze the nanosecond laser induced vaporization process that is central to numerous engineering and bio-medical applications. Based on the experimental results, discussions are made on the experimental technique and the physical mechanisms of laser-driven explosive vaporization phenomena.

사파이어 기판 위에 성장된 AlGaN 에피층의 광 흡수 특성 (Characteristic absorbance of AlGaN epilayers grown on sapphire substrate)

  • 김제원;박영균;김용태;최인훈
    • 한국진공학회지
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    • 제8권2호
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    • pp.153-157
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    • 1999
  • The dependence of the absorption edge of wurtzite $Al_xGa_{1-x}N$ on alN mole fraction has been studied. The AlN mole fraction was varied from 0 to 1. The absorption coefficients at room temperature were determined by transmission and photothermal deflection spectroscopy. Photothermal deflection spectroscopy can be applied to determine the low absorbance values. From the results, the effective bandgaps of $Al_xGa_{1-x}N$ alloys were determined by choosing corresponding photon energies of the positions of the absorption coefficient of $6.3\times10^4\textrm{cm}^{-1}$ at the absorption curves of the $Al_xGa_{1-x}N$ alloys. From the energy position of the absorption coefficient versus AlN mole fraction, a bowing parameter of 1.3eV was determined. The bowing parameter agreed quite well with the measured effective bandgaps of AlGaN alloys.

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광열변위의 위상차를 이용한 불투명 고체의 열확산계수 측정 (Thermal diffusivity measurements of opaque solid using the phase lag of photothermal displacement.)

  • 이은호;이광재;전필수;유재석
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2000년도 춘계학술대회논문집B
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    • pp.138-143
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    • 2000
  • A new method of measuring the thermal diffusivity of solid material at room temperature with photothermal displacement method is proposed. The influence of the parameters on phase lag was studied. From the minimum position of phase of measured deflection with respect to the pump beam the thermal diffusivity of the materials can be obtained. The minimum position of phase is determined using multiparameter least-square regression fitting. The experimental values for different samples obtained by applying new method are in good agreement with the literature values.

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광열변위의 최소위상을 이용한 열확산계열수 측정 (Measurement of Thermal Diffusivity Using Minimum Phase Based on the Photothermal Displacement)

  • 이은호;이광재;전필수;유재석;김기현
    • 대한기계학회논문집B
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    • 제25권3호
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    • pp.296-304
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    • 2001
  • A new method of measuring the thermal diffusivity of solid material at room temperature using photothermal displacement is proposed. The influence of the parameters, such as radius and modulation frequency of the pump beam and the sample thickness, was studied. From the minimum position of phase of measured deflection with respect to the pump beam, the thermal diffusivity of the materials can be obtained. The position where phase has the minimum value is determined using multiparameter least-square regression fitting. The experimental values for different samples obtained by applying the new method are in good agreement with the literature values.

광열편향법을 이용한 열확산계수 결정에 대한 이론적 연구 (A Theoretical Study for the Thermal Diffusivity Measurement Using Photothermal Deflection Scheme)

  • 전필수;이은호;유재석;목재균;최강윤
    • 에너지공학
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    • 제10권1호
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    • pp.63-70
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    • 2001
  • 재료의 열확산계수를 비접촉적인 방법으로 구하기 위하여 광열편향법에 대한 3차원 모델을 해석하였다. 이 방법은 가열빔이 재료에 광학적으로 흡수될 때 검사빔의 초기궤적이 시편과 시편주의 매질의 온도상승으로 인하여 나타나는 굴절지수의 구배에 의하여 검사빔이 편향되는 원리를 이용하는 것이다. 기존의 연구에서는 주로 가열빔과 검사빔의 상대거리를 변화시키면서 편향의 위상각을 측정하여 열확산계수를 결정하였다. 하지만 본 연구에서는 고정된 상대거리에서 가열빔의 변조주파수를 변화시키면서 편향의 위상각을 계산하여 열확산계수를 구할 수 있는 관계식을 제시하였다. 본 연구에서 제시한 열확산계수 결정 방법은 다른 방법에 비하여 실험과 해석이 간단하고 비교적 측정하기가 어려운 상대거리에 영향을 받지 않는 방법이다.

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Observation of Methyl Radical Recombination Following Photodissociation of CH3I at 266 nm by Time-Resolved Photothermal Spectroscopy

  • Suh, Myung-Koo;Sung, Woo-Kyung;Li, Guo-Sheng;Heo, Seong-Ung;Hwang, Hyun-Jin
    • Bulletin of the Korean Chemical Society
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    • 제24권3호
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    • pp.318-324
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    • 2003
  • A time-resolved probe beam deflection (PBD) technique was employed to study the energy relaxation dynamics of photofragments produced by photodissociation of $CH_3I$ at 266 nm. Under 500 torr argon environment, experimental PBD transients revealed two energy relaxation processes; a fast relaxation process occurring within an acoustic transit time (less than 0.2 ㎲ in this study) and a slow relaxation process with the relaxation time in several tens of ㎲. The fast energy relaxation of which signal intensity depended linearly on the excitation laser power was assigned to translational-to-translational energy transfer from the photofragments to the medium. As for the slow process, the signal intensity depended on square of the excitation laser power, and the relaxation time decreased as the photofragment concentration increased. Based on experimental findings and reaction rate constants reported previously, the slow process was assigned to methyl radical recombination reaction. In order to determine the rate constant for methyl radical recombination reaction, a theoretical equation of the PBD transient for a radical recombination reaction was derived and used to fit the experimental results. By comparing the experimental PBD curves with the calculated ones, the rate constant for methyl recombination is determined to be $3.3({\pm}1.0)\;{\times}\;10^6\;s^{-1}torr^{-1}$ at 295 ± 2 K in 500 torr Ar.

태양전지의 특성분석에 관한 고찰 (A Consideration on Characterization Methods for Solar Cells)

  • 박종완
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1988년도 춘계학술대회 논문집
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    • pp.33-34
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    • 1988
  • 태양전지의 특성분석에 관한 최근의 동향을 고찰해 보기로 한단. 첫째, $CuInSe_2$와 비정질 실리콘 등의 광전압 용도의 태양전지의 재료선택에 관한 일반 규칙을 살펴 보고, 둘째, AM1 조건에서 보다 정확한 전지효율의 측정방법을 조사하며, 셋째, 태양전지의 중요 특성분석방법들을 소개 설명한다. 특히 생산 품질관리의 규모로 까지 확대적용이 가능한 다음과 같은 태양전지의 특성분석방법들의 장치개선 및 컴퓨터제어를 고찰하기로 한다. 전지효율 및 기타 전지특성을 위한 전류-전압 성질 측정장치, 양자효율을 위한 분광반응장치, 소수 이동자의 확산거리를 위한 표면광전압장치, 또한 에너지갭 내의 양자상태밀도를 위한 광열굴절장치 등이다.

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CdS 박막제작 및 그 특성(발광 및 수광 소자 응용을 위한에 II-VI족 화합물 반도체들의 접착에 관한 기초연구) (Growth and Properties of CdS Thin films(A Study on the adhesion of II-VI compound semiconductor for applications in light emitting and absorbing devices))

  • Kang, Hyun-Shik;Cho, Ji-Eun;Kim, Kyung-Wha
    • 태양에너지
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    • 제17권2호
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    • pp.55-66
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    • 1997
  • CdTe/CdS 태양전지 제작에 필요한 다결정 CdS 박막을 ITO 전도 유리기판위에 SSD법, SPD법 및 CBD법 으로 제작하고 열처리 한 후 그 결정구조와 광학적 특성을 조사하였다. 박막은 모두 Wurtzite 구조를 보였고 SSD법과 CBD법의 박막은 $0.5{\mu}m$ 크기의 CdS 입자가 불규칙적으로 형성되어 증착되어 있음을 보였고, $400^{\circ}C$로 진공중에서 열처리 할 때 입자의 크기가 약간 증가하였다. SPD법의 박막은 (002)방향으로 결정이 성장되고 입자의 크기가 $0.1-0.3{\mu}m$ 이었다. 에너지 밴드갭 및 결함 상태를 광학적 흡수, 광 루미니센스, 라만 및 광 열 편기 스펙트럼(PDS) 측정을 통해 조사하였다.

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