• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.11a
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• pp.487-490
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• 1999

The Maxwell displacement current was generated from 4-octyl-4'-(5-carboxyl-pentamethyleneoxy)- azobenzene (denoted as 8A5H) monolayer Langmuir-Blodgett films prepared on Cr/Au-coated glass substrates due to trans-cis photoisomerization of 8A5H by application of alternate irradiation with UV light and Visible light. The displacement current was generated due to the trans-to-CIS photoisomerization by irradiation with ultraviolet light($\lambda_1$=360nm). Whereas the displacement current was generated in the opposite direction due to the cis-to-trans photoisomerization by photoirradiation with visible light($\lambda_2$=450nm). Finally, We concluded that Displacement current change according to power capacity photoirradiation, the more higher generate the more higher power capacity magnitude.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2000.04b
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• pp.139-142
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• 2000

Displacement current was generated in the light stimulus. Solution of azobenzene molecules (8A5H) have to character trans-to-cis. The Maxwell displacement current measuring technique has been applied for the investigation of azobenzene organic thin films under alternating photoirradiation with ultraviolet($\lambda_1$) and visible($\lambda_2$) light. also, As laser beam(630~670nm) investigate light response. As result, ultraviolet($\lambda_1$) and visible($\lambda_2$) light see photoisomerization response, but laser beam not appear photoisomerization in current that differ wave range reagent.

• Rapid Communication in Photoscience
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• v.4 no.1
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• pp.25-28
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• 2015

The time-resolved photoexcitation dynamics of electrical conductivity of the magnetic organic superconductor ${\lambda}-(BETS)_2Fe_{0.45}Ga_{0.55}Cl_4$ has been studied with a nanosecond visible laser pulse at its three different phases, i. e., metallic phase, superconducting phase and insulating phase. A transient increase of the resistance is induced by photoirradiation at all the temperatures measured for all three phases, but the decay profile shows a significant temperature dependence. The relaxation rate in the metallic and insulating phase are different from each other, and the decay time is relatively faster and almost constant in the metallic phase. However, a prolongation of the relaxation time is observed at temperature just around the narrow superconducting phase. Nonbolometric (nonthermal) origin of the observed photoresponse of the electrical conductivity is confirmed in the superconducting phase.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1999.05a
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• pp.41-44
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• 1999

Displacement current was generated in the pressure stimulus and light stimulus. Solution of azobenzene molecules (8A5H) have to character trans-to-cis. Pressure stimulus generate in the pressure and current. light stimulus generate in the displasement current. The Maxwell displacement current measuring technique has been applied for the investigation of azobenzene organic thin films under alternating photoirradiation with ultraviolet(360nm) and visible (450nm) light. The displacement current was generated due to the trans-to-cis photoisomerization by irradiation with ultraviolet light(λ$_1$=360 nm) Whereas the displacement current was generated in the opposite direction due to the cis-to-trans photoisomerization by irradiation with visible light(λ$_2$=450nm). As result, To show twice reaction certainly phase transition in pressure. A first range generated from 24$\AA$$^2$ to 29$\AA$$^2$and second range generated from 20$\AA$$^2$to 24$\AA$$^2$. Also, cetainfy stimulus apper low pressure and high pressure in photoirradiation. To see different every moment phase transition.

• Journal of Photoscience
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• v.4 no.3
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• pp.127-132
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• 1997

Acanthamoeba strains were photoirradiated in the presence of light-sensitive organic peroxides (hydroperoxynaphthalimide derivatives) including a Photo-Fenton reagent at 366 nm. The survival rates of Acantharnoeba strains determined after 20 h culture showed a significant decrease only upon photoirradiated conditions. The most effective hydroperoxynaphthalimides among these compounds was the bromohydroperoxynaphthalimide (Br-HPO II). The minimum inhibitory concentration (MIC) of Br-HPO II is 100 times lower than that of hydrogen peroxide.

• Journal of the Korean Electrochemical Society
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• v.5 no.4
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• pp.189-191
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• 2002

Reversible trans-cis isomerization of meta-bipyridylazobenzene coordinated to cobalt was achieved by a combination of photoirradiation with a single UV light source and a Co(II)/Co(III) redox reaction. The trans/cis conversion performance was significantly improved in the meta-form compared with the meta-form ligated to cobalt.

• Journal of Photoscience
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• v.9 no.2
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• pp.138-141
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• 2002

A photo-labile compound which is bioinactive but, upon irradiation with light, yields bioactive species is called as "caged compound". Photolysis of caged compounds generating bioactive species, has become a general method to produce a desired amounts of bioactive species in the specific time interval at the desired place or area of the target biological systems. For this purpose, we designed and synthesized caged hydroxyl radical., "Photo-Fenton Reagent" NP-IIl. NP-IIl has a strong absorption maximum at 377 nm and yields hydroxyl radicals upon UV light irradiation. The antioxidant activity of the ${\alpha}$ -lipoic acid and other naturally occurring compounds has been examined by using NP-IIl as a molecular probe. For example, upon photoirradiation of NP-lII with BSA or apolipoprotein of human low density (LDL), the significant oxidative modifications were observed in both cases. The oxidation was completely suppressed in the presence of ${\alpha}$-lipoic acid, which clearly demonstrates the strong hydroxyl radical scavenging activity of ${\alpha}$-lipoic acid. Other applications of NP-lII will also be described

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1424-1427
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• 1996

The pressure-area isotherm(${\pi}$-A isotherm) of 8A5H(4-octyl-4'-(5-Carboxyl-pentamethyleneoxy)-azobenzene) at the air/water interface were obtained. Using the Xe/Hg Xe 500w(93' model 68811), an activities of molecule at the air/water interface were certified. In addition, using a current-measuring technique, we investigated the abrupt changes of a current observed at the liquid-to-solid phase transition in a current-area (I-A) isotherm of a fatty acid monolayer at the air/water interface

• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.424.2-424.2
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• 2014

Ag-modified BiOX (X=Cl, Br and I) nanoplates were synthesized by an ion-exchange reaction. We examined the fundamental properties by scanning electron microscopy (SEM), electron transmission microscopy (TEM), X-ray diffraction, UV-visible absorption, Fourier-transform infrared and photoluminescence spectroscopy. The adsorption and photocatalytic performances of the catalysts were tested with dyes under UV and visible light. A chemical scavenger method was employed to test the roles of active species (${\cdot}OH$, ${\cdot}O2-$ and h+) and understand photodegradation mechanism. Photoluminescence spectroscopy was used to examine ${\cdot}OH$ radical formation using terephthalic acid during photoirradiation.

• Bulletin of the Korean Chemical Society
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• v.29 no.5
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• pp.948-952
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• 2008

The molecular association of acceptors with electron donors is studied in the highly-polar solvent $CH_3CN$. Tetracyanoquinodimethane (TCNQ) forms a stable charge-transfer complex with donor molecules such as 4- aminobiphenyl (4-AB), benzidine (BD) and 2-aminobiphenyl (2-AB) with high association constants. The complexes of TCNQ with 4-AB or BD show new absorption bands at around 800 and 500 nm, which can be identified as reduced $TCNQ^{{\bullet}-}$ and $TCNQ^{2-}$ species, respectively. These bands grow quickly upon photoirradiation, implying that the charge-transfer complexes are easily formed in an excited state. Conversely, a small spectral manifestation of the charge transfer was observed in the case of 2-AB complex. It is demonstrated that the structural orientation between the geminate ion pairs could play an important role in building a stable complex.