Journal of the Korean Electrochemical Society (전기화학회지)

The Korean Electrochemical Society (한국전기화학회)
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A Large Trans/cis Conversion Ratio In Redox-Conjugated Single-Light Reversible Isomerization of a Cobalt Complex with meta-Bipyridylazobenzene Ligands

  • Kume, Shoko (Department of Chemistry, School of Science, the University) ;
  • Kurihara, Masato (Department of Chemistry, School of Science, the University) ;
  • Nishihara, Hiroshi (Department of Chemistry, School of Science, the University)
  • Published : 2002.11.01
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Abstract

Reversible trans-cis isomerization of meta-bipyridylazobenzene coordinated to cobalt was achieved by a combination of photoirradiation with a single UV light source and a Co(II)/Co(III) redox reaction. The trans/cis conversion performance was significantly improved in the meta-form compared with the meta-form ligated to cobalt.

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References

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