• Title/Summary/Keyword: Photoelectric conversion

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Photoelectric Effects of Cyanine Dye and Charge Transfer Complex (Cyanine 색소 및 그 전하이동착체의 광전효과)

  • 권태선
    • Journal of the Korean Graphic Arts Communication Society
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    • v.11 no.1
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    • pp.17-29
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    • 1993
  • As inverstigating the influence of monomers and photoinitiator in the polymerization rate of photopolymerization by using IR spectroscopy, photopolymerizations initiated by ultraviolet radiation are characterized by the presence of an autoacceleration in the polymerization rate as the reaction proceeds. The conversion for the end of the autoacceleration varies considerably depending on the monomer and reaction condition which determines coil size and viscosity. In UV curable systems, the autoacceleration begins at only a few percent conversion and continues to 40% in HEA solution and 60% conversion in EHA solution. The polymerization ate in HEA solution increased as follow; DMHA > HCPK > DMPA and could be explained by the interaction between the initiating radical and HEA monomer and the size of the photodissociated radical of initiator. But the tendency of autoacceleration in EHA solution is almost independent on initiator.

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High power efficient solar cell using the organic polymer materials (유기고분자 재료를 이용한 우수한 효율의 태양전지)

  • Lee, Junghoon;Park, Jukwang;Chang Seoul
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.356-357
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    • 2003
  • Organic materials are suitable for use in photoelectric conversion devices. Thus, Organic semiconductors are promising materials for photovoltaic devices and other optoelectronic applications such as light emitting diodes(LED). The organic solar cell seems to be the usefulness in comparison with the inorganic solar cell in terms of workability, ease of processing, low cost, flexibility and area expansion. (omitted)

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Photoelectrochemical Behavior of Chlorophyll a Langmuir-Blodgett Films

  • Choe, Hyeon-Gu;Jeong, U-Cheol;Kim, Yeong-Gi;Lee, Won-Hong;Choe, Jeong-U
    • 한국생물공학회:학술대회논문집
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    • 2000.04a
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    • pp.572-575
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    • 2000
  • The highly efficient photoelectric conversion of chlorophyll a (Chl a) monolayers and multilayers was investigated. Using the Langmuir-Blodgett (LB) technique, Chl a monolayers and multilayers were fabricated onto optically transparent electrode, such as ITO glass. The photocurrent could be observed according to the light illumination. The action spectrum of the Chl a LB films was well consistent with its absorption spectrum. The possible application of the proposed system as a constituent of the artificial color recognition device was suggested.

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Syntheses and Characterisitics of New Photochromic Spiroxazine Dyes (새로운 광변색성 Spiroxazine색소의 합성과 특성)

  • 김성훈
    • Journal of the Korean Graphic Arts Communication Society
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    • v.12 no.1
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    • pp.159-168
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    • 1994
  • The Aggregation State of thin vapor deposite Film made by Cyanine Dye were changed into Monomeric molecular state(M) and Dimeric Aggregation(D) at the acidic treatment, into reversible H-Aggregation (H) at alkalic gas or heat treatment. Photo-electric properties were higher H than D and M, this stats were effective in enhancing Photoelectric-conversion characteristic. Substitute group of Meso-Position being stronger electronic Donors, Electronic density is higher and Electric conductivity is enhanced, we confirmed Oscillator Strength calculated by PPP-Molecular Orbital Calculation and Absorption Spectra at solvent stats were agreed good.

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Photoelectric Conversion Efficiency of DSSC According to Plasma Surface Treatment of Conductive Substrate (전도성 기판의 플라즈마 처리에 따른 염료감응형 태양전지 광전변환 효율 특성 변화)

  • Ki, Hyun-Chul;Kim, Seon-Hoon;Kim, Doo-Gun;Kim, Tae-Un;Hong, Kyung-Jin;So, Soon-Yeol
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.11
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    • pp.902-905
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    • 2012
  • This study is explore the photoelectric conversion change of dye-sensitized solar cells with surface treatment of the conductive substrate. gases of FTO surface treatment were $N_2$, and $O_2$. Treatment conditions of surface were gas flux from 25 sccm to 50 sccm and RF power were from 25 W to 50 W. Treatment time and pressure were fixed 5 min and 100 mtoor. The best sheet resistance and surface roughness were obtained by $O_2$ 50 sccm and 50 W and that result were 7.643 ${\Omega}/cm^2$ and 17.113 nm, respectively. The best efficiency result was obtained by $O_2$ 50 sccm and 50 W and that result of Voc, Jsc, FF and efficiency were 7.03 V, 14.88 $mA/cm^2$, 63.75% and 6.67%, respectively.

Characteristics of Organic Solar Cell having an Electron Transport Layer co-Deposited with ZnO Metal Oxide and Graphene using the Cyclic Voltammetry Method (순환전류법을 이용해 ZnO 금속산화물과 Graphene을 동시에 제막한 전자수송층을 갖는 유기태양전지의 특성)

  • Ahn, Joonsub;Han, Eunmi
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.1
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    • pp.71-75
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    • 2022
  • Graphene oxide was stirred with a ZnCl2:NaCl electrolyte and electrochemically coated by cyclic voltammetry to simplify the electron transpfer layer film forming process for organic solar cells and to fabricate an organic solar cell having it. The device structure is FTO/ZnO:graphene/P3HT:PCBM/PEDOT:PSS/Ag. Morphology and chemical properties of ETL were confirmed by scanning electron microscopy(SEM), X-ray photoelectron spectroscopy (XPS), and Raman spectroscopy. As a result of XPS measurement, ZnO metal oxide and carbon bonding were simultaneously confirmed, and ZnO and graphene peaks were confirmed by Raman spectroscopy. The electrical characteristics of the manufactured solar cell were specified with a solar simulator, and the ETL device coated twice at a rate of 0.05 V/s showed the highest photoelectric conversion efficiency of 1.94%.

A Study of Fabrication Techniques of Thin film Photo-Electric Energy Conversion Elements (박막 광전에너지 변환소자의 개발에 관한 연구)

  • 성영권;민남기;성만영;김승배
    • 전기의세계
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    • v.25 no.5
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    • pp.63-69
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    • 1976
  • Among various types of photo-electric energy conversion element which can transfer solar energy into electric energy through the photo voltaic effect, Si solar cells were investigated on photoelectric characteristics, improvements of its efficiency and economical evaluation for its production cost. To study the above subjects, we decided best conditions on fabricating of thin film Si solar cell by epitaxial growth and knew that the thin solar cell by epitaxial growth was more efficient than that by diffusion process. And also higher photo voltaic output was obtained as a effect of SiO as antireflection coating by several methods, i.e. vacuum evaporating techniques of electrode to decrease the contact resistance and to form best ohmic contact, and concentration techniques of sun's ray by lenz or both-sided illumination through special structure for reflection using mirrors.

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Synthesis of Zr-incorporated TiO2 Using a Solvothermal Method and its Photovoltaic Efficiency on Dye-sensitized Solar Cells

  • Kim, Su-Jung;Kang, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.32 no.9
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    • pp.3317-3322
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    • 2011
  • This study examines the photoelectric conversion efficiency of dye-sensitized solar cells (DSSCs) when nanometer-sized Zr (0.1, 0.5, and 1.0 mol %)-$TiO_2$ prepared using a solvothermal method is utilized as the working electrode material. The particle sizes observe in the transmission electron microscopy (TEM) images are < 30 nm in all samples. The absorption band is slightly broadened at the tail for the 0.1 mol % Zr-$TiO_2$, and the intensity of the photoluminescence (PL) curves of the Zr-incorporated $TiO_2$ is significantly smaller than that of the pure $TiO_2$. Compared to that using pure $TiO_2$, the energy conversion efficiency is enhanced considerably by the application of Zr-$TiO_2$ in the DSSCs to approximately 6.17% for 0.5 mol % Zr-$TiO_2$ with the N719 dye (10.0 ${\mu}m$ film thickness and 5.0 mm ${\times}$ 5.0 mm cell area) under 100 mW/$cm^2$ of simulated sunlight.

Improving the Performances of Dye-Sensitized Solar Cell by the Optimal $TiO_2$ Photoelectrode Thickness and Light-Scattering Enhancement (최적 $TiO_2$ 전극 두께 및 광산란 증가에 의한 염료감응형 태양광전지의 효율 개선)

  • Niu, Zeng Yuan;Kweon, Hyun Kyu;Park, Chang Yong
    • Journal of the Semiconductor & Display Technology
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    • v.13 no.2
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    • pp.37-44
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    • 2014
  • In this study, the performance of dye-sensitized solar cells with different thickness of the photelectrode film was simulated by using the electron-diffusion differential model. Through this simulation, the relationships between the thickness of the photoelectrode film and the performances (open-circuit voltage, short-circuit current density, and overall photoelectric-conversion efficiency) of cells were understood and the performances with different thickness of the photoelectrede film were also examined. For considering the refractive index in the liquid electrolyte and exploring the scattering effect of titanium dioxide particles with different sizes using the Mie light-scattering theory, the highest scattering effect of each particles was found out and the optimal size of the titanium dioxide particle was determined for light scattering in the photoelectrode film of dye-sensitized solar cell. Through experiment, the mixed titanium dioxide cell was better than the single titanium dioxide cell and generated a higher overall conversion efficiency because the optimal titanium dioxide particles in the phoelectrode film as light scattering.

Effect of Performance in Dye-sensitized Solar Cells by PEG Contents (PEG 함량변화가 염료감응형 태양전지의 효율에 미치는 영향)

  • Baek, Hyoung-Youl;Han, Zhen-Ji;Li, Hu;Gu, Hal-Bon;Park, Kyung-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.2
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    • pp.178-181
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    • 2008
  • A solar cell based on dye-sensitized photoelectric conversion was studied by investigating the effects of the amount of polyethylene glycol(PEG), added to the $TiO_2$ paste, on surface morphology of the $TiO_2$ films and on the solar cell performance. Energy conversion efficiency was found to increase with PEG addition up to 20 % by weight of $TiO_2$ and then decrease with further addition due to the aggregation of $TiO_2$ nano particles in the $TiO_2$ film. In this study, the best result of dye-sensitized solar cell was the short circuit current(Isc) of $22.6mAcm^{-2}$, the open circuit voltage (Voc) of 0.73 V, the fill factor (ff) of 0.55 and the overall energy conversion efficiency (${\eta}$) of 9.1 % under illumination with AM 1.5 simulated sunlight.