• 한국세라믹학회지
• /
• 제31권4호
• /
• pp.375-380
• /
• 1994

Matrices retaining electrolyte in phosphoric acid fuel cell were prepared with SiC to SiC whisker mixing ratios of 1:0.5, 1:1, 1:1.5, 1:2, 1:3 by tape casting method. When viscosity of the slurry was 5.9 poise and the SiC to SiC whisker mixing ratios were 1:1, 1:1.5, 1:2, the ranges of porosity, acid absorbency and bubble pressure were 80~90%, 2.5~6 and 700~2200 mmH2O, respectively. Those ranges are acceptable for a practical electrolyte-retaining matrix. With increasing the mixing ratio of SiC whisker to SiC, the porosity and the vol.% of large pores in the main pore size distribution which is between 1 and 10 ${\mu}{\textrm}{m}$, increased rapidly. Impedance spectroscopy was measured to know characteristics of matrix inside and contact region of matrix to catalyst layer. When the SiC to SiC whisker mixing ratio was 1:2, hydrogen ions were transported in the matrix most effectively because of high ionic conductivity and low activation energy due to high acid absorbency in spite of high interfacial resistance. The cell current density of the cell made using the matrix was 220 mA/$\textrm{cm}^2$ at 0.7 V.

• 한국수소및신에너지학회논문집
• /
• 제31권5호
• /
• pp.405-410
• /
• 2020

In this literature, we are introduce a basic design of multi energy hub based on natural gas governor station. Multi energy hub consists of turbo expender generator, phosphoric acid fuel cell, pressure swing adsorption, H₂ charging station, utilities and etc. We design a hybrid energy hub system that provides energy using these complex energies, and calculates the amount of electricity that can be produced and the amount of hydrogen charged through the process analysis. TEG and phosphoric acid fuel cell produce 2,290 to 2,380 kW and can supply electricity to 500 houses. In addition, By-product H₂ gas is refined to H₂ vehicle fuel. This will help maximize the balance of energy demand and supply and improve national energy efficiency by integrating unused decompression energy power generation technology and various power generation/heat source technologies.

• 한국수소및신에너지학회논문집
• /
• 제28권5호
• /
• pp.471-480
• /
• 2017

A proton exchange membrane fuel cell (PEMFC) operated at $150^{\circ}C$ was evaluated by a controlling different amount of phosphoric acid (PA) to a membrane-electrode assembly (MEA) without humidification of the cells. The effects on MEA performance of the amount of PA in the cathode are investigated. The PA content in the cathodes was optimized for higher catalyst utilization. The highest value of the active electrochemical area is achieved with the optimum amount of PA in the cathode confirmed by in-situ cyclic voltammetry. The current density-voltage experiments (I-V curve) also shows a transient response of cell voltage affected by the amount of PA in the electrodes. Furthermore, this information was compared with the production variables such as hot pressing and vacuum drying to investigate those effect to the electrochemical performances.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1996년도 하계학술대회 논문집 C
• /
• pp.1707-1709
• /
• 1996

For the improvement of the performance and life time of phosphoric acid fuel cell, the management of electrolyte in the electrocatalyst layer and electrolyte matrix in the cell structure is very important. Porous bipolar pinto structure, that is known as an advanced type, is generally used for the storage of electrolyte in the cell. In this paper, the single cell was made of the electrode by coating directly electrocatalyst layer on porous bipolar plate. The single cell showed $186\;mA/cm^2$ at 0.6V. This performance is similar to the performance of the conventional nonporous plate single cell. The technology of porous plate single cell could be directly used to the fabrication of stack in order to improve the performance and life time of phosphoric acid fuel cell.

• Korean Membrane Journal
• /
• 제9권1호
• /
• pp.43-51
• /
• 2007

This paper describes the preparation and characterization of two kinds of fluorinated polybenzimidazole (PBI)s which can be potentially used for phosphoric acid-doped, high-temperature polymer electrolyte membrane fuel cells. Two kinds of perfluorocyclobutane (PFCB)-containing monomers were prepared via following synthetic steps; after fluoroalkylation of methyl 3-(hydroxy) benzoate and methyl 4-(hydroxy) benzoate with 1,2-dibromotetrafluoroethane and subsequent Zn-mediated dehalogenation, these compounds were cyclodimerized at $200^{\circ}C$ affording the ester-terminated monomers containing PFCB ether groups. The synthesized intermediates and monomers were characterized using FT-IR, $^1H-NMR,\;^{19}F-NMR$, and mass spectroscopy. The fluorinated PBIs were then successfully prepared through the solution polycondensation of the monomers and 3,3'-diaminobenzidine in polyphosphoric acid. Compared with traditional PBI, the glass transition temperatures of the fluorinated PBIs were obtained at $262^{\circ}C\;and\;269^{\circ}C$ which are lower than that of PBI and their initial degradation temperatures were still high over $400^{\circ}C$ under nitrogen. The fluorinated PBIs showed higher d-spacing values and improved solubility in several organic solvents as well as phosphoric acid, which confirmed they could be good candidates for the high temperature fuel cell membranes.

• 대한전기학회:학술대회논문집
• /
• 대한전기학회 1994년도 하계학술대회 논문집 C
• /
• pp.1409-1412
• /
• 1994

The electrodes for Phosphoric Acid Fuel Ceil were fabricated as a condition of PTFE contents in electrocatalyst layer and sintering temperature in the range of 25 -- 65 wt% and 310 -- $390^{\circ}C$, respectively. For the fabricated electrode, the accelation testing of cathode half cell at open circuit potential was investigated. While the performance of electrode showed maximum at the low level of PTFE contents in the initial stage of accelation testing, the maximum performance was shifted to higher PTFE contents of 45wt% after 24hrs accelation testing.

• 한국표면공학회지
• /
• 제22권2호
• /
• pp.55-61
• /
• 1989

A fuel cell which causes electrochemical ratio of conventional with oxygen consists of mainly there parts, such as electrolyte, fuel and oxidant electrode. IN this paper, most efforts were delivered to manufacturing PETE-bonded gas-diffusion electrode, and preparation methods of the porous electrodes has been discussd. A medio temperature, phosphoric acid fuel cell (PAFC) provided with fuel (hydrogen) and oxygen showed oxygen showed excellent performance characteristics with made electrodes. Performance data obtained from hydrgen-oxygen cell were presented to illustrate their properties. It was found that the optimum amounts of platinum in clectrode for hydrgen-oxygen PAFC were about 3mg/cm3 and the PTFE content of gas diffusion layer and catalyst layer were 25% and 15%, respectively.

• 한국전기화학회:학술대회논문집
• /
• 한국전기화학회 2001년도 춘계총회 및 학술발표회
• /
• pp.52-52
• /
• 2001

• 공업화학
• /
• 제3권4호
• /
• pp.567-573
• /
• 1992

• 한국에너지공학회:학술대회논문집
• /
• 한국에너지공학회 1998년도 추계 학술발표회 논문집
• /
• pp.293-296
• /
• 1998