• Title/Summary/Keyword: Phenolphthalein

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Utilization of Immersion-Drying Method for Measuring Damage Depth of Fire-Damaged High-Strength Concrete (화재로 손상된 고강도 콘크리트의 손상 깊이 측정을 위한 수중침지 건조방법의 활용)

  • Kim, Jong;Lim Gun-Su;Beak, Seung-Bok;Han, Min-Cheol
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.3
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    • pp.297-308
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    • 2024
  • This study presents a novel approach for evaluating fire-induced damage depth in concrete. The methodology leverages the principle that exposure to high temperatures causes internal expansion within concrete, leading to increased voids and microcracks in the damaged zones. This heightened porosity results in greater absorption rates compared to undamaged areas. By immersing fire-damaged concrete samples in water and subsequently monitoring the drying process, the depth of damage can be assessed. Differences in drying rates and color variations between damaged and undamaged areas serve as visual indicators for determining the extent of the damage. Experimental results from this water immersion method revealed damage depths of 38.7mm and 37.5mm for two different concrete mixtures. These measurements notably surpass the damage depths estimated using traditional phenolphthalein-based methods. This discrepancy suggests that utilizing the absorption rate principle, which is directly linked to the physical changes caused by thermal expansion, offers a more accurate and sensitive assessment of fire damage depth compared to methods relying solely on the presence of Portlandite for colorimetric indication.

Evaluation of Physical Properties for 53-Years Old Railway Tunnel Linning Concrete (53년 경과된 철도터널 라이닝 콘크리트의 물성 평가)

  • 이상민;이태규;김동석;이웅종;김종우
    • Proceedings of the Korea Concrete Institute Conference
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    • 1995.04a
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    • pp.360-365
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    • 1995
  • The purpose of this study is to identify the various characteristics of the 53-years old railway tunnel linning concrete. The nondestructive technique such as the surface hardness method and the ultrasonic method, the extent of carbonation by the phenolphthalein indicator, and the chemical analysis due to XRD/XRF are considered Also the concrete core was cut in two pieces per tunnel for the exact evaluation of strength. On the basis of the experimental result, it is concluded that the durability and the serviceability of old tunnel linning concrete are affected by the initial mixing condition and the environmental effect.

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Carbonation depth in 57 years old concrete structures

  • Medeiros-Junior, Ronaldo A.;Lima, Maryangela G.;Yazigi, Ricardo;Medeiros, Marcelo H.F.
    • Steel and Composite Structures
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    • v.19 no.4
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    • pp.953-966
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    • 2015
  • Carbonation depth was verified in 40 points of two 57 years old concrete viaducts. Field testing (phenolphthalein spraying) was performed on the structures. Data obtained were statistically analyzed by the Kolmogrov-Smirnov's test, one-way analysis of variance (ANOVA's test), and Fisher's method. The results revealed significant differences between maximum carbonation depths of different elements of the same concrete structure. Significant differences were also found in the carbonation of different concrete structures inserted in the same macroclimate. Microclimatic factors such as temperature and local humidity, sunshine, wind, wetting and drying cycles, among others, may have been responsible by the behavior of carbonation in concrete.

Studies on Acid-Base Indicators in the Mixtures of Some Solvents(I) : Determination of Ampicillin, Amoxicillin and Cephalexin in Aqueous Organic Solvents (혼합용매중에서의 산-고기 지시약에 관한 연구(I) : 수-유기용매 혼합용매중 Ampicillin, Amoxicillin 및 Cephalexin의 정량)

  • 이왕규;심창구
    • YAKHAK HOEJI
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    • v.20 no.1
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    • pp.32-36
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    • 1976
  • The pH titration curves of ampicillin, amoxicillin and cephalexin in aqueous acetone, ethanol and N, N'-dimethylformamide by use of 0.02N-KOH solution showed that 80% acetone was the most effective solvent for alkali titration of them. The pH jumps of samples in 80% acetone were sharp enough to determine the contents of them by use in 80% acetone (9, 4) was coincided with each equivalent point of ampicillin, amoxicillin and cephalexin, but those of phenolphthalein, thymolphthalein, thymol blue and bgrom cresol purple were not. The color change of brom thymol blue at equivalent points was very clear except the case of amoxicillin that the determination of smaples in 80% acetone with 0.02 N-KOH solution by the aid of brom thymol blue could be available.

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Microstructural Evaluation on the Quality of Tunnel Lining Concrete in Subway Structures (지하철 터널라이닝 콘크리트의 품질에 대한 미세구조적 평가)

  • Kim, Seong-Soo;Kim, Dong-Gyou;Lee, Gyu-Phil;Jung, Ho-Seop;Bong, Won-Yong
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.593-596
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    • 2006
  • Recently, as it has greatly increased the demand on the serviceability of subway, cable tunnel, the stability of the tunnel structures has been attracting the concern of engineers and researchers. The purpose of this study is to idently the various characteristics of lining concrete in subway structures. The nondestructive technique such as the surface hardness method and the extend of carbonation by phenolphthalein indicator and chemical analysis due to XRD are considered. Also, the concrete core was cut in three pieces per tunnel for the exact evaluation of strength.

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Analysis of Mining Performance and Flow Measurement Inside a Micro Mixer (마이크로 혼합기 내의 유동 계측 및 혼합 특성 해석)

  • Sung Jaey-ong;Lee In-won;Kim Byoung-Gyun;Yoon Eui-sik;Lee In-Seop
    • 한국가시화정보학회:학술대회논문집
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    • 2002.11a
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    • pp.45-48
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    • 2002
  • To investigate the flow related to the mixing, micro PIV measurements were performed in the middle plane of the channel. A passive micro mixer analyzed in this work has been designed in the shape of a three-dimensional microchannel and fabricated with PDMS molding process by KAIST. The mixing performance was evaluated for different flow rates using phenolphthalein and sodium hydroxide solutions. Results show that mixing is enhanced by the increase of flow rate, which yields stronger secondary flows with helical streamlines.

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Non-destructive assessment of carbonation in concrete using the ultrasonic test: Influenced parameters

  • Javad Royaei;Fatemeh Nouban;Kabir Sadeghi
    • Structural Engineering and Mechanics
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    • v.89 no.3
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    • pp.301-308
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    • 2024
  • Concrete carbonation is a continuous and slow process from the outside to the inside, in which its penetration slows down with the increased depth of carbonation. In this paper, the results of the evaluation of the measurement of concrete carbonation depth using a non-destructive ultrasonic testing method are presented. According to the results, the relative nonlinear parameter caused more sensitivity in carbonation changes compared to Rayleigh's fuzzy velocity. Thus, the acoustic nonlinear parameter is expected to be applied as a quantitative index to recognize carbonation effects. In this research, combo diagrams were developed based on the results of ultrasonic testing and the experiment to determine carbonation depth using a phenolphthalein solution, which could be considered as instructions in the projects involving non-destructive ultrasonic test methods. The minimum and maximum accuracy of this method were 89% and 97%, respectively, which is a reasonable range for operational projects. From the analysis performed, some useful expressions are found by applying the regression analysis for the nonlinearity index and the carbonation penetration depth values as a guideline.

Effect of water cut-off by M.S.G. method for weathered soil and alluvial soil (풍화토 및 충적토 지반에 적용된 M.S.G공법의 차수효과)

  • 지덕진;우상백;강진기;김태한;박종호
    • Proceedings of the Korean Geotechical Society Conference
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    • 2003.03a
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    • pp.85-92
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    • 2003
  • Generally, ordinary portland cement(OPC) is widely used for grouting to reduce permeability of ground under the foundations of structures. But, it is hard to be injected into the microscopic voids, fissures and crevices in soil or rock formation for the OPC material. Therefore new method what is called MSG(Micro Silica Grouting) has been developed recently to improve the weak point of the OPC material. In this case study, in order to verify performance of the MSG's water cut-off, trial injections were performed in rear of CIP(Cast in Place Pile) on the site A(weathered soil) and B(alluvial soil) that are constructed for the subway No. 9 nowadays. To take the proper grouting method of the MSG in the trial injecting, the injections are carried out for grouting types(constant pressure or fixed Quantity) and grouting methods(1.5shot or 2.0shot) and to confirm the effects of water cut-off and the injection range of the MSG, the tests of permeability and indicator(phenolphthalein) response were performed before and after the injection. Through the tests results, we could affirm the effects of water cut-off of the MSG and the injection range for the weathered and alluvial soil layers near the Han River. Finally we could make sure the application of the MSG method in actual construction under the layers.

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Development of a Barrier Embedded Chaotic Micromixer (배리어가 포함된 카오스 마이크로 믹서의 개발)

  • 김동성;이석우;권태헌;이승섭
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.28 no.1
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    • pp.63-69
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    • 2004
  • It is of great interest to enhance mixing performance in a microchannel in which the flow is usually characterized as a low Reynolds number (Re) so that good mixing is quite difficult to be achieved in this laminar flow regime. In this regard, we present a new chaotic passive micromixer, named Barrier Embedded Micromixer (BEM), of which the mixing mechanism is based on chaotic flows. In BEM, chaotic flow is induced by periodic perturbation of the velocity field due to periodically inserted barriers along the channel wall while a helical type of flow is obtained by slanted grooves on the bottom surface of the channel in the pressure driven flow. To experimentally compare the mixing performance, a T-microchannel and a microchannel with only slanted grooves were also fabricated. All microchannels were made of PDMS (Polydimethylsiloxane) from SU-8 masters that were fabricated by conventional photolithography. Mixing performance was experimentally characterized with respect to an average mixing intensity by means of color change of phenolphthalein as pH indicator. It was found that mixing efficiency decreases as Re increases for all three micromixers. Experimental results obviously indicate that BEM has better mixing performance than the other two. Chaotic mixing mechanism, suggested in this study, can be easily applied to integrated microfluidic systems , such as Micro-Total-Analysis-System, Lab-on-a-chip and so on.

The Experimental Study on the Progress of Concrete Carbonation According to the Service Life (콘크리트의 사용연한에 따른 중성화의 진행에 관한 실험적 연구)

  • Lee, Joon-Gu;Park, Kwang-Soo;Shin, Su-Gyun;Kim, Kwan-Ho;Park, Mi-Hyun
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2001.10a
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    • pp.123-128
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    • 2001
  • This study was performed to find out variation of carbonation progress of agricultural hydraulic concrete structures along the used years with using Thermo Gravimetric analysis/Differential Thermal Analysis(TG/DTA) and Indicator(phenolphthalein). In this study some conclusions such as follows were derived. Firstly, The result that the age of structures and the content of $Ca(OH)_{2}\;and\;CaCO_{3}$ in concrete have proportional relationships was found in the method of TG/DTA. This relational functions could be used to estimate remain lifetime of structures, obtaining the limits of the content of $CaCO_{3}$ in concrete which reinforcement corrosion could be occurred with breaking protection cover of alkalinity. Second, if the result of strength, voids, permeability characteristics could be combined with this relational function this may be able to be used as a new more accurate assessment technique for the quality of concrete than current usual methods. Third, environmental affect could be more superintendent for concrete carbonation than the age of agricultural hydration structures. Forth, It is difficult to estimate the used year of agricultural hydraulic concrete structures with the carbonation depth measured by indicator method. Finally, the accuracy of this relational function could be decided to be upgraded with continue analysis for more structures.

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