• Title/Summary/Keyword: Phase changing material

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Aqueous synthesis of quantum dots using functionalized ionic liquid (이온성 액체를 이용한 수계 양자 점 합성)

  • Choi, Suk-Young;Kim, Tae-Young;Suh, Kwang-S.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.254-254
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    • 2010
  • We report aqueous synthesis of cadmium telluride (CdTe) quantum dots(QDs) using imidazolium-based ionic liquids with various functional groups. The functinalized ionic liquids were designed to have thiol groups, and then phase transfer with aqueous or organic solvents can be adjusted by changing side chain lengths of the cation and the choice of anion. The quantum yield was obtained IL-functionalized CdTe QDs reached up to 40% by post-treatment method.

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Experiment Study on Mixing Efficiency of Material for Improving Reclamation Soil Quality in Dredging Soil Pipeline using CFD (준설토 배송관로 내에서의 개질재 혼합효율에 대한 CFD 해석)

  • Park, Byongjun;Kang, Byungyoon;Chung, Minchul;Shin, Jaeryul
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.35 no.5
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    • pp.1083-1096
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    • 2015
  • This study utilised Computational Fluid Dynamics(CFD) for preliminary assessment of mixing efficiencies of 2-phase fluids in a pipe at which a slurry flow and an injected solidifier join, for the purposes of reducing trial-and-error-based instances of physical experiments and conducting the overall research in an economical way. Using OpenFOAM$^{(R)}$, we simulated behavior of 3-phase fluids under 18 different settings generated by changing diameters of a dredged soil transportation pipe, a quality improving material injection pipe and the confluence angle. While difference in mixing efficiencies amongst the instances was insignificant, discernible boundary layers amongst the materials were observed in all of the instances. In order to break the boundary layers, we designed a substructure inside a pipe and found out that it could remarkably improve mixing efficiencies particularly for short distance applications.

The study on Topology Optimization for Crashworthiness enhancement in Protective shell frame of Rolling Stock leading-cab (철도 차량 전두부 충돌 피해 저감을 위한 Protective shell frame의 위상 최적화에 관한 연구)

  • Kim, Hyun-Jun;Kim, Se-Hoon;Jung, Hyun-Seung;Kwon, Tae-Su;Suh, Myung-Won
    • Proceedings of the KSR Conference
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    • 2007.05a
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    • pp.138-143
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    • 2007
  • The leading-cab (high energy absorption area) of rolling stock directly is impacted on the frontal crash unlike other cabs. Thus, leading-cab has a structurally complex shape to solve getting concentrated loads. However, in order to enhance structural performance and to achieve the weight reduction of cab, changing the sizes and adjusting the distance of members do not take an effective result. Therefore, in design phase, to find the material arrangement which helps structural capacity be better should be done. This research applies the topology optimization to concept design of protective shell frame on strategy of crush energy absorption with considering pressure and vertical loads acting on the principal part of leading-cab. In this research, topology optimization method focuses on structural design, and which yields optimal material arrangement under given loads and boundary conditions using density method which has the density of material as design variables. Finally, this research presents optimal material arrangement and structure of protective shell frame on given loads with applying topology optimization.

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Free vibration and static analyses of metal-ceramic FG beams via high-order variational MFEM

  • Madenci, Emrah
    • Steel and Composite Structures
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    • v.39 no.5
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    • pp.493-509
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    • 2021
  • There is not enough mixed finite element method (MFEM) model developed for static and dynamic analysis of functionally graded material (FGM) beams in the literature. The main purpose of this study is to develop a reliable and efficient computational modeling using an efficient functional in MFEM for free vibration and static analysis of FGM composite beams subject to high order shear deformation effects. The modeling of material properties was performed using mixture rule and Mori-Tanaka scheme which are more realistic determination techniques. This method based on the assumption that a two phase composite material consisting of matrix reinforced by spherical particles, randomly distributed in the beam. To explain the displacement components of the shear deformation effects, it was accepted that the shear deformation effects change sinusoidal. Partial differential field equations were obtained with the help of variational methods and then these equations were transformed into a novel functional for FGM beams with the help of Gateaux differential derivative operator. Thanks to the Gateaux differential method, the compatibility of the field equations was checked, and the field equations and boundary conditions were reflected to the function. A MFEM model was developed with a total of 10 degrees of freedom to apply the obtained functional. In the numerical applications section, free vibration and flexure problems solutions of FGM composite beams were compared with those predicted by other theories to show the effects of shear deformation, thickness changing and boundary conditions.

Fluid dynamical characteristics of microencapsulated phase change material slurries (미립잠열슬러리의 유체역학적 특성연구)

  • 이효진;이승우;이재구
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.4
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    • pp.549-559
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    • 1999
  • An experimental study was peformed to measure the viscosity of microencapsulated PCM slurries as the functions of its concentration and temperature, and also influence to its fluid dynamics. For the viscosity measurement, a rotary type viscometer, which was equipped with temperature control system, was adopted. The slurry was mixed with water and Sodium Lauryl Sulphate as a surfactant by which its suspended particles were dispersed well without the segregation of particles during the experiment. The viscosity was increased as the concentration of MicroPCM particle added. The surfactant increased 5% of the viscosity over the working fluid without particles. Experiments were proceeded by changing parameters such as PCM particles'concentration as well as the temperature of working fluid. As a result, a model to the functions of temperature for the working fluid and its particle concentration is proposed. The proposed model, for which its standard deviation shows 0.8068, is agreed well with the reference's data. The pressure drop was measured by U-tube manometer, and then the friction factor was obtained. It was noted that the pressure drop was not influenced by the state of PCM phase, that is solid or liquid in its core materials at their same concentration. On the other hand, it was described that the pressure drop of the slurry was much increased over the working fluid without particles. A friction factor was placed on a straight line in all working fluids of the laminar flow regardless of existing particles as we expected.

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Variation of Transient-response in Open-ended Microstrip Lines with Optically-controlled Microwave Pulses

  • Wang, Xue;Kim, Kwan-Woong;Kim, Yong-K.
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.2
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    • pp.53-57
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    • 2009
  • In this paper we develop a method to observe faults in semiconductor devices and transmission lines by calculating the variation of the reflection function in a dielectric microstrip line that has an open-ended termination containing an optically induced plasma region. It is analyzed with the assumption that the plasma is distributed homogeneously in laser illumination. With the non linear material of degradation, the concentration of the carrier in the part of the material has changed. Since the input wave has produced the phenomenon of reflection, the input signal to the open-ended microstrip lines can be observed on reflection to identify the location of the fault. The characteristic impedances resulting from the presence of plasma are evaluated by the transmission line model. The variation of the reflection wave in the microwave system has been calculated by using an equivalent circuit model. The transient response has been also evaluated theoretically for changing the phase of the variation in the reflection. The variation of characteristic response in differentially localized has been also evaluated analytically.

Ultrasonic Images Enhancement of the SS Reference Specimen and the Reference Calibration Block for NPPs by the Combining Bases of Support for Spatial Frequency (공간주파수대역에서 기저대역 확장을 통한 원전 대비시험편과 대비 보정 시험편의 초음파 영상 개선)

  • Park, Chi-Seung;Kim, Seon-Jin
    • Korean Journal of Materials Research
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    • v.13 no.10
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    • pp.651-657
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    • 2003
  • Ultrasonic microscope has been used to detect the defects on surface or inner solid. Conventionally, it has used at a single operating frequency. The resolution and quality of the measured images are determined by a characteristic of the transducer of the ultrasonic microscope. The conventional ultrasonic microscope has been used envelope detector to detect the amplitude of reflected signal, but the changes in amplitude is not sensitive enough for specimen with microstructure that in phase. In this paper, we have studied multi-frequency depth resolution enhancement with ultrasonic reflection microscope for the reflectors of a stainless steel reference specimen and a reference calibration block to be used as the material in nuclear power plants for ISI, PSI. Increased depth resolution can be obtained by taking two, three-dimensional images at more that one frequency and numerically combining the results. As results of the experiment, we could get enhanced images with the rate of contrast in proportion and high quality signal distribution for the image to the changing rate of depth for the reflectors of the two kinds of specimens.

Joint Properties of Inconel 718 Additive Manufactured on Ti-6Al-4V by FGM method (Ti-6Al-4V 합금 기지 위에 FGM 방식으로 적층제조 된 Inconel 718의 접합 특성 분석)

  • Park, Chan Woong;Park, Jin Woong;Jung, Ki Chae;Lee, Se-Hwan;Kim, Sung-Hoon;Kim, Jeoung Han
    • Journal of Powder Materials
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    • v.28 no.5
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    • pp.417-422
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    • 2021
  • In the present work, Inconel 718 alloy is additively manufactured on the Ti-6Al-4V alloy, and a functionally graded material is built between Inconel 718 and Ti-6Al-4V alloys. The vanadium interlayer is applied to prevent the formation of detrimental intermetallic compounds between Ti-6Al-4V and Inconel 718 by direct joining. The additive manufacturing of Inconel 718 alloy is performed by changing the laser power and scan speed. The microstructures of the joint interface are characterized by scanning electron microscopy, energy-dispersive X-ray spectroscopy, and micro X-ray diffraction. Additive manufacturing is successfully performed by changing the energy input. The micro Vickers hardness of the additive manufactured Inconel 718 dramatically increased owing to the presence of the Cr-oxide phase, which is formed by the difference in energy input.

Engineering Characteristic of High Density Expansion Materials for Structure Restoration Technology (기초침하복원을 위한 급속 팽창재료의 공학적 특성에 관한 연구)

  • Shin, Eun-Chul;Cha, Yong-In
    • Journal of the Korean Geosynthetics Society
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    • v.7 no.2
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    • pp.1-5
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    • 2008
  • The differential settlement on ordinary concrete buildings and paved roads are often occurred and which caused the failure of structure. The grouting method can be used for correcting the settlement of the structure. However, the grouting method has a disadvantage like that it takes a long time period to get a desired strength, and it is not a continuous in the phase of reinforced effect. In this paper, as an injecting material called GPCON to complement disadvantage, it is estimated about the characteristic that has a high-density expansion. With the changing of ground conditions and amount of injection, the change of physical strength on compression, the stability against chemical material are studied through the filming of SEM. The physical strength with compression is developed to high strength due to mixing with other material. It is not react with most of the material on chemical conditions except the component of alcohol. Through the SEM test. it is confirmed that the strength of material was increased as formation is being densified.

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Synthesis of Periodic Mesoporous Organosilica by Microwave Heating

  • Yoon, Sang-Soon;Son, Won-Jin;Biswas, Kalidas;Ahn, Wha-Seung
    • Bulletin of the Korean Chemical Society
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    • v.29 no.3
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    • pp.609-614
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    • 2008
  • A periodic mesoporous organosilica material was synthesized by microwave heating (PMO-M) using 1,2-bis(trimethoxysilyl)ethane as a precursor in a cationic surfactant solution, and textural properties were compared with those of the product produced by conventional convection heating (PMO-C). These synthesized materials were characterized using XRD, TEM/SEM, N2 adsorption isotherm, 29Si and 13C NMR, and TGA, which confirmed their good structural orders and clear arrangements of uniform 3D-channels. Synthesis time was reduced from 21 h in PMO-C to 2-4 h in PMO-M. PMO-M was made of spherical particles of 1.5-2.2 m m size, whereas PMO-C was made of decaoctahedron-shaped particles of ca. 8.0 m m size. Effect of synthesis temperature, time, and heating mode on the PMO particle morphology was examined. The particle size of PMO-M could be controlled by changing the heating rate by adjusting microwave power level. PMO-M demonstrated improved separation of selected organic compounds compared to PMO-C in a reversed phase HPLC experiment. Ti-grafted PMO-M also resulted in higher conversion in liquid phase cyclohexene epoxidation than by Ti-PMO-C.