• Title/Summary/Keyword: Phase change behavior

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Fabrication of AlN Thin Film by Reactive RF Magnetron Sputtering and Sensing Characteristics of Oil Pressure (반응성 RF 마그네트론 스퍼터링에 의한 AlN 박막 제조 및 유압 감지 특성)

  • Seok, Hye-Won;Kim, Sei-Ki;Kang, Yang-Koo;Hong, Yeon-Woo;Lee, Young-Jin;Ju, Byeong-Kwon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.12
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    • pp.815-819
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    • 2014
  • Aluminum nitride (AlN) thin film and TiN film as a buffer layer were deposited on INCONEL 600 substrate by reactive RF magnetron sputtering at room temperature(R.T.) under 25~75% $N_2/Ar$ atmosphere. The as-deposited AlN films at 25~50% $N_2/Ar$ showed a polycrystalline phase of hexagonal AlN, and an amorphous phase. The peak of AlN (002) plane, which was determinant on a performance of piezoelectric transducer, became strong with increasing the $N_2/Ar$ ratio. Any change in the preferential orientation of the as-deposited AlN films was not observed within our $N_2$ concentration range. The piezoelectric sensing properties of AlN module were performed using pressure-voltage measurement system. The output signal voltage of AlN module showed a linear behavior between 20~80 mV in 1~10 MPa range, and the pressure-sensing sensitivity was calculated as 3.6 mV/MPa.

A Study on Consciousness & Value of Sexuality of Elementary School Children (초등학교 학생들의 성 의식 및 가치관에 관한 연구)

  • Lee, Hae-Yun;Park, Young-Soo
    • The Journal of Korean Society for School & Community Health Education
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    • v.2 no.1
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    • pp.53-65
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    • 2001
  • The purposes of this study were to collect basic data on education of Sexuality(Health education) of consciousness & value of sexuality of elementary school children. 584,6th grade students in elementary school in Yong-In city were analysed and the results are as follow; 1. Knowledges of sexuality for children was at a average level, especially "physical change of puberty" and "sexual violence" were well recognized but "the physical characteristics of male & female" and "physiological phenomena of men" were less recognized. Attitudes of sexuality were positive for "relationship with partners" and "expression of mind". Practices of sexuality were at a low rate in the case of "shaking hands with partner" and "experience of sexual behavior". The Value of sexuality was at a high rates in the case of "the role of sex", "equality" & "self-identification", therefore students need good education of sexuality from childhood 2. Sexuality education of students increased knowledges of sexuality as a consciousness. There was no relationship between attitudes and pratices of sexuality. Educated children valued sexuality move highly than uneducated children. This result shows that education is needed with regard to both the knowledge and value of sexuality in a planned system. We need some program to provide more information on sexual attitudes and practices. 3. There was a high correlation between the consciousness of sexuality and value placed on it. As sexual awareness increases amongst students codes of morality develop Positive sexual attitudes served as good role models for sex. In particular positive sexual attitudes have a big effect on sexual values. In addition, as sexual awareness and attitude increase amongst students the role of sexual development. The elementary school phase sexual values are developed and determined. It is therefore an important phase.

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Growth of Spinel CoMn2O4 Thin Films and Post-growth Annealing Effects on Their Physical Properties (CoMn2O4 스피넬 박막의 합성과 후열처리가 박막의 물리적 특성에 미치는 영향)

  • Kim, D.R.;Kim, J.K.;Yoon, S.W.;Song, J.H.
    • Journal of the Korean Magnetics Society
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    • v.25 no.5
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    • pp.144-148
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    • 2015
  • We grew spinel structured $CoMn_2O_4$ thin films and have studied post-growth annealing effects on their physical properties. After post-growth annealing at $700^{\circ}C$ that is lower than the growth temperature ($720^{\circ}C$), crystal structure became cleared accompanying a change of surface structure. In the temperature dependences of magnetization, phase transitions were observed at ~100 K for both before and after post-growth treated samples which were not observed for the bulk. For both samples, ferromagnetic behaviors were observed above 100 K while it turned to ferrimagnetism at low temperature below 100 K. In particular, the ferrimagnetic behavior became strong after the post-growth treatment. These results indicate that the post-growth annealing process plays an important role in determining the physical properties of spinel $CoMn_2O_4$ thin film.

Fabrication of Porous Mo-Cu by Freeze Drying and Hydrogen Reduction of Metal Oxide Powders (금속산화물 분말의 동결건조 및 수소환원에 의한 Mo-Cu 다공체 제조)

  • Kang, Hyunji;Han, Ju-Yeon;Oh, Sung-Tag
    • Journal of Powder Materials
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    • v.26 no.1
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    • pp.1-5
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    • 2019
  • In this study, porous Mo-5 wt% Cu with unidirectionally aligned pores is prepared by freeze drying of camphene slurry with $MoO_3-CuO$ powders. Unidirectional freezing of camphene slurry with dispersion stability is conducted at $-25^{\circ}C$, and pores in the frozen specimens are generated by sublimation of the camphene crystals. The green bodies are hydrogen-reduced at $750^{\circ}C$ and sintered at $1000^{\circ}C$ for 1 h. X-ray diffraction analysis reveals that $MoO_3-CuO$ composite powders are completely converted to a Mo-and-Cu phase without any reaction phases by hydrogen reduction. The sintered bodies with the Mo-Cu phase show large and aligned parallel pores to the camphene growth direction as well as small pores in the internal walls of large pores. The pore size and porosity decrease with increasing composite powder content from 5 to 10 vol%. The change of pore characteristics is explained by the degree of powder rearrangement in slurry and the accumulation behavior of powders in the interdendritic spaces of solidified camphene.

Phase behavior of CO2 + H2O + 2,2,3,3,3-pentafluoro-1-propanol mixture (이산화탄소+물+2,2,3,3,3-pentafluoro-1-propanol 혼합물의 상거동)

  • Shin, Hun Yong
    • Clean Technology
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    • v.24 no.4
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    • pp.275-279
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    • 2018
  • In this study, microemulsion formation of water and carbon dioxide was investigated by using surfactant as one of the methods for increasing the mutual solubility between water and carbon dioxide. The surfactant 2,2,3,3,3-Pentafluoro-1-propanol was added to form a microemulsion of water and carbon dioxide. The cloud point change and trend of micro emulsion were investigated by adding water and a certain amount of surfactant, 2,2,3,3,3-Pentafluoro-1-propanol to supercritical carbon dioxide. In the case of surfactant + carbon dioxide system, it was 8.35 ~ 12.69 MPa in temperature range of 313.2 ~ 353.2 K. In the case of water + surfactant + carbon dioxide system, the temperature ranged from 318.2 ~ 338.2 K to pressure range 7.83 ~ 17.28 MPa.

Effect of Microstructure on Piezoelectric Properties and TCC Behavior in PZT-PZN Ceramics (PZT-PZN 세라믹의 미세구조가 압전 특성 및 TCC 거동에 미치는 영향)

  • Seo, Intae;Choi, Yongsu;Cho, Yuri;Kang, Hyung-Won;Kim, Kang San;Cheon, Chae Il;Han, Seung Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.5
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    • pp.445-451
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    • 2022
  • Ultrasonic sensor is suitable as a next-generation autonomous driving assist device because its lower price compared to that of other sensors and its sensing stability in the external environment. Although Pb(Zr, Ti)O3 (PZT)-relaxor ferroelectric system has excellent piezoelectric properties, the change in capacitance is large in the daily operating temperature range due to the low phase transition temperature. Recently, many studies have been conducted to improve the temperature stability of ferroelectric ceramics by controlling the grain size and crystal structure, so it is necessary to study the effect of the grain size on the piezoelectric properties and the temperature stability of PZT-relaxor ferroelectric system. In this study, the piezoelectric properties, phase transition temperature, and temperature coefficient of capacitance (TCC) of 0.9 Pb(Zr1-xTix)O3-0.1 Pb(Zn1/3Nb2/3)O3 (PZTx-PZN) ceramics with various grain sizes were investigated. PZTx-PZN ceramics with larger grain size showed higher piezoelectric properties and temperature stability, and are expected to be suitable for ultrasonic devices in the future.

Synthesis and Analysis of the Impact of Partial Mercury Replacement with Lead on the Structural and Electrical Properties of the Hg1-xPbxBa2Ca2Cu3O8+δ Superconductor

  • Kareem Ali Jasim;Chaiar Abdeen Zaynel Saleh;Alyaa Hamid Ali Jassim
    • Korean Journal of Materials Research
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    • v.34 no.1
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    • pp.21-26
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    • 2024
  • In this investigation, samples of the chemical (Hg1-xPbxBa2Ca1.8Mg0.2Cu3O8+δ) were prepared utilizing a solid-state reaction technique with a range of lead concentrations (x = 0.0, 0.05, 0.10, and 0.20). Specimens were pressed at 8 tons per square centimeter and then prepared at 1,138 K in the furnace. The crystalline structure and surface topography of all samples were examined using X-ray diffraction (XRD) and atomic force microscopy (AFM). X-ray diffraction results showed that all of the prepared samples had a tetragonal crystal structure. Also, the results showed that when lead was partially replaced with mercury, an increase in the lead value impacted the phase ratio, and lattice parameter values. The AFM results likewise showed excellent crystalline consistency and remarkable homogeneity during processing. The electrical resistivity was calculated as a function of temperature, and the results showed that all samples had a contagious behavior, as the resistivity decreased with decreasing temperature. The critical temperature was calculated and found to change, from 102, 96, 107, and 119 K, when increasing the lead values in the samples from 0.0 to 0.05, 0.10, and 0.20, respectively.

Effects of Red LED Spectra and Different Photoperiods on the Circadian Rhythm of Abalones (Haliotis discus hannai)

  • Jin A Kim;Min Ju Kim;Jun-Hwan Kim;Cheol Young Choi
    • Ocean and Polar Research
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    • v.46 no.1
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    • pp.55-64
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    • 2024
  • Light is an external environmental factor that affects the biorhythms of aquatic organisms and is involved in their behavior, reproduction, and various biological responses. The biorhythm (24-h cycle) of organisms is controlled internally by clock genes, such as period (Per), cryptochrome (Cry), and melatonin receptor (MT-R), and is externally controlled by light, food, and temperature. In this study, the experimental organisms were divided into photoperiod and LED groups. The photoperiod group was exposed to two photoperiods (LD, 12 h light: 12 h darkness; DD, constant darkness), and the LED group was exposed to a red LED light (wavelength, 630 nm; 12 h LED light: 12 h darkness). Per and Cry mRNA expression levels increased during the bright phase and decreased during the dark phase. MT-R mRNA expression decreased during the bright period and increased during the dark period. The trend in clock gene expression in the RD group was similar to that in the DD group but not in the LD group. Red LED irradiation induced gene expression similar to the 24 h memorization condition, suggesting that long-wavelength light conditions can change the biorhythm of abalones. This study provides academic information on the biorhythm cycle of abalone (a marine gastropod), which is less well known than that of fish and can aid in predicting the physiological response of abalones to changes in light wavelength.

Leidenfrost Points Tuned via Surface Coating and Structures

  • Jeon, Deok-Jin;Lee, Jun-Young;Yeo, Jong-Souk
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.126.1-126.1
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    • 2015
  • A quantitative relationship between Leidenfrost point and surface characteristics such as surface material and roughness is investigated. Based on the relationship, we have fabricated the surfaces with their Leidenfrost points (LFP) tuned by controlling surface coating and structures. As discovered by Leidenfrost, liquids placed on a hot plate levitate on the gas phase-air gap formed by the vaporization of liquids. This phenomenon is called 'Leidenfrost effect'. A change of LFP has attracted many researchers for several years but the ability to tune LFP is still a remaining issue. Many of previous work has progressed for various conditions so the systematic approach and analysis are needed to clearly correlate the LFP and the surface conditions. In this report, we investigate a relation of surface energy and LFP using various coating materials such as Octadecyltrichlorosilane (OTS) and 1H, 1H, 2H, 2H-Perfluorooctyltrichlorosilane (FOTS). Also, we analyze how surface roughness affects LFP via surface micro structuring with ICP-RIE fabrication process. The improved understanding can have potential applications such as the control of liquid droplet behavior at elevated temperatures for efficient cooling system.

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A Study on Ablation Behavior of Graphite Nozzle using Liquid Rocket Engine (액체로켓엔진을 이용한 Graphite 노즐의 삭마 거동 연구)

  • Cho Nam Choon;Park Hee Ho;Keum Young Tag
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • v.y2005m4
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    • pp.119-122
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    • 2005
  • Ablation phenomena is very complicated because it includes momentum, energy and mass transfer, chemical reactions as well as phase change. In this paper, ablation at the rocket nozzle throat is modeled as unsteady one dimensional axi-symmetric with proper boundary conditions and field equation is solved numerically. Analytical results are compared with measured ablation data from firing experimental liquid rocket engine. Test variables are combustion pressure and mixture ratio. for low combustion pressure and low mixture ratio, the discrepancy between analysis and experiments are large but for the normal rocket operation range, two results show a simliar trend with maximum discrepancy of $100\%$.

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