• Bulletin of the Korean Chemical Society
• /
• v.29 no.6
• /
• pp.1229-1232
• /
• 2008

The surface structure, electrochemical behavior, and wetting property of self-assembled monolayers (SAMs) formed by dioctyl diselenide (DODSe) on Au(111) were investigated by scanning tunneling microscopy (STM), cyclic voltammetry (CV), and contact angle measurements. In contrast to the formation of well-ordered SAMs by octanethiol on Au(111), the SAMs formed by DODSe have a disordered phase and many unusual vacancy islands (VIs). In addition, the formation of DODSe SAMs is largely influenced by the solution concentration used. DODSe SAMs formed in 5 $\mu$ M and 50 $\mu$ M solutions have two mixed domains consisting of missing-row ordered phases and disordered phases, while DODSe SAMs formed in 1 mM and 5 mM solutions have only disordered phases with an abnormally high VI fraction of 22-24%. We also found that the wetting property and electrochemical behavior of DODSe SAMs on Au(111) are markedly influenced by the formation of ordered SAMs and the density of VIs.

• New & Renewable Energy
• /
• v.2 no.2 s.6
• /
• pp.28-36
• /
• 2006

Numerical analysis of wind turbine scale effect was performed by using commercial CFD code, Fluent. For the numerical analysis of wind turbine, the three dimensional Navier-Stokes solver with various turbulence models was tested. As a turbulence mode, the realizable k-e turbulence model was selected for the simulation of wind turbines. To validate the present method, performance of NREL (National Renewable Energy Laboratory) Phase VI wind turbine model was analyzed and compared with its wind tunnel test and blind test data. Using the present method, numerical simulations for various size of wind tunnel models were carried out and characteristics were analyzed in detail. For wind tunnel test model, the size of nacelle may not be scaled down precisely because of available motor. The effect of nacelle size was also computed and analyzed though CFD simulation. The present results showed the good correlations in pre-stall region but much to be improved in post-stall region. In 2006 and 2007, the performance and the scale effect of standard wind turbine model will be tested in KARI(Korea Aerospace Research Institute) LSWT(Low Speed Wind Tunnel) and the present results will be validated with the wind tunnel data.

• 한국신재생에너지학회:학술대회논문집
• /
• 2011.05a
• /
• pp.61.1-61.1
• /
• 2011

풍력 터빈은 복잡한 바람 조건에 노출되어 운용 되는 시스템으로서 경제성과 신뢰성을 확보하기 위해서는 이러한 조건하에서 시스템에 작용하는 정확한 공력 하중 예측이 필요하다. 여러 조건 중에서도 요에러는 풍향이 수시로 바뀌기 때문에 피할 수 없는 비정상 유동 중에 하나이다. 본 연구에서는 이러한 요에러 발생시 공력 하중예측을 적절히 예측하기 위해서 와류 격자 기법을 기반으로 하는 비선형 와류 보정기법을 적용하였다. 비선형 와류 보정기법은 실속 이후의 공력 예측을 위해 기지의 공력 테이블을 이용하는 방법으로서 실속 이후의 공력 테이블 값의 양력과 와류 격자 기법에서의 양력 값이 일치하도록 순환(circulation)을 분포시키는 기법이다. 또한 요에러시에 발생할 수 있는 동적 실속을 계산하기 위해 Beddoes-Leishmen 동적 실속 모델을 비선형 와류 보정 기법에 적용하는 연구를 수행하였다. 요에러시 공력 하중 예측에 관한 수치해석 기법 연구의 적절성을 알아보기 위해 NREL-Phase VI Rotor 실험 결과와 비교 하였다. 그 결과 기존의 여타의 기법들과 비교하여 본 연구에서 제안한 기법의 적절성을 확인 할 수 있었다. 앞으로 본 연구를 바탕으로 다양한 비정상 공력 조건에 대한 풍력 블레이드의 공력 하중 해석에 대해 수행할 계획이다.

• Natural Product Sciences
• /
• v.16 no.3
• /
• pp.164-168
• /
• 2010

High-performance liquid chromatographic method with diode-array detector and electrospray ionization with multi-stage tandem mass spectroscopy (HPLC/DAD/ESI-$MS^n$) was used to identify the major constituents in a methanolic extract of Eclipta prostrata. The chromatographic separation was performed on a C18 column. Acetonitrile-water was used as a mobile phase. HPLC/DAD/ESI-$MS^n$ allowed the characterization of constituents of E. prostrata, mainly triterpenoids (eclalbasaponin I, II, III, IV, VI), flavonoids (luteolin 7-O-glucoside, demethylwedelolactone, wedelolactone, luteolin, demetylwedelolactone sulfate, luteolin sulfate, apigenin sulfate) and phenolic acids (5-O-caffeoylquinic acid, 3, 4-O-dicaffeoylquinic acid, 3, 5-O-dicaffeoylquinic acid, 4, 5-Odicaffeoylquinic acid).

• Journal of the Korean Ceramic Society
• /
• v.45 no.11
• /
• pp.667-674
• /
• 2008

In this study, we prepared Fe-activated carbon fiber(ACF)/$TiO_2$ composites with titanium (VI) n-butoxide (TNB) as the titanium source for ACF pre-treated with iron compounds through the impregnation method. In terms of textural surface properties, the composites demonstrate a slight decrease in the BET surface area of the samples and an increase in the amount of iron compounds treated. The surface morphology of the Fe-ACF/$TiO_2$ composites was characterized by means of SEM. The composites have a porous texture with homogenous compositions of Fe and titanium dioxide distributed on the sample surfaces. The phase formation and structural transition of the iron compounds and titanium dioxide were observed in X-ray diffraction patterns of the Fe-ACF/$TiO_2$ composites. The chemical composition of the Fe-ACF/$TiO_2$ composites, which was investigated with EDX shows strong peaks for the C, O, Fe and Ti elements. The photo degradation results confirm that the Fe-ACF/$TiO_2$ composites show excellent removal activity for the COD in piggery waste due to photocatalysis of the supported $TiO_2$, radical reaction by Fe species, and the adsorptivity and absorptivity of ACF.

• Journal of information and communication convergence engineering
• /
• v.9 no.1
• /
• pp.21-26
• /
• 2011

In this paper, we suggest the object-oriented methodology for the design and implementation scheme for the program development in the application of control and instrumentation such as the detection system of RFID defective tags which needs the embedded programming. We apply the design methodology of UML in the system design phase, and suggest the implementation scheme of LabVIEW programs using LVOOP(LabVIEW Object Oriented Programming)in which make it possible to write the object-oriented programming. We design the class diagram and the sequence diagram using UML, and write the classes of LVOOP from the designed class diagram and the main VI from the sequence diagram, respectively. We show that it is possible to develop the embedded programs such as the RFID application through the implementation example of the detection system of RFID defective tags in this paper. And, we obtain the advantages based on the object-oriented design and implementation using the LVOOP approach such as the development of LabVIEW programs by adding the classes and the concept of object of the object-oriented language to LabVIEW.

• Bulletin of the Korean Chemical Society
• /
• v.25 no.1
• /
• pp.79-84
• /
• 2004

The existing technological schemes for processing rhenium-containing raw materials involve the recovery of Re from solutions, which can be effectively achieved by anion exchange method. The application of anion exchange also allows to study rhenium state in aqueous solutions and to develop analytical control methods. The present work is focused on investigation of ion exchange equilibrium in the analytical system Re(VII)-HCl-$SnCl_2$-KSCN-anion exchanger by means of sorption-desorption method as well as by electron, IR- and diffuse reflection spectroscopy. It was shown that rhenium can be quantitatively recovered from this system. It is proposed to use the sorption-spectroscopic method for Re(VII) determination in aqueous solutions. The calibration curve is linear in the concentration range of 0.5-20.0 mg/L (sample volume is 25.0 mL) and the detection limit is 0.05 mg/L. The presence of Mo(VI), Cu(II), Fe(II, III), Ni(II), Zn(II) as well as $K^+,\;Na^+$ do not hinder the solid-phase determination of rhenium. Rhenium (VII) determination by diffuse reflection spectroscopy was carried out in model solutions as well as in samples of river-derived water and in solutions obtained after the dissolution of spent catalysts.

• Proceedings of the KIEE Conference
• /
• 2006.07e
• /
• pp.47-48
• /
• 2006

본 논문에서는 LabVIEW를 이용한 휴대용 3상 유도전동기 회전자 바 고장 진단 시스템을 개발하였다. LabVIEW는 NI사에서 개발한 그래픽컬 프로그래밍 언어로서 VI(Virtual Instrument)기술을 이용하여 계측, 분석, 표현 프로그램에 최적화된 언어이다. 유도전동기의 입력단에 Current Probe를 연결하여 전류를 측정하였고, NI사의 USB-DAQ보드를 이용하여 데이터를 수집한 후 노트북 컴퓨터에서 실행되는 LabVIEW 프로그램에 의해 고장을 진단할 수 있는 실시간 휴대용 진단 시스템을 개발하였다. 회전자 바에 고장이 일어나면 선 전류의 불균형, 손실 증가, 토크맥동과 평균 토크의 감소를 가져올 수 있다. 고장 진단 방법으로는 회전자 바 고장의 특징 주파수를 찾아 진단하는 방법이 있다. 회전자 바 고장에 대하여 1개와 2개 바를 절단한 회전자를 사용하여 각각 실험하였으며, FFT 분석에 의하여 실시간으로 유도전동기 회전자 바 고장을 진단 할 수 있음을 보였다.

• The korean journal of orthodontics
• /
• v.52 no.6
• /
• pp.451-460
• /
• 2022

Moebius syndrome (MBS) is a congenital neurologic disorder that causes cranio-facial abnormalities. It involves paralysis of the VI and VII cranial nerves and causes bilateral or unilateral facial paralysis, eye movement disorder, and deformation of the upper and lower limbs. The orofacial dysfunctions include microstomia, micrognathia, hypotonic mimetic and lip muscles, dental enamel hypoplasia, tongue deformity, open bite or deep overbite, maxillary hypoplasia, high arched palate, mandibular hyperplasia or features indicating mandibular hypoplasia. This case report presents a 7-year-old male patient who was diagnosed with MBS at the age 2 years. The patient displayed typical clinical symptoms and was diagnosed with Class II malocclusion with a large overjet/overbite, tongue deformity and motion limitation, and lip closure incompetency. Treatment was initiated using a removable appliance for left scissor bite correction. After permanent tooth eruption, fixed appliance treatment was performed for correction of the arch width discrepancy and deep overbite. A self-ligation system and wide-width arch form wire were used during the treatment to expand the arch width. After 30 months of phase II treatment, the alignment of the dental arch and stable molar occlusion was achieved. Function and occlusion remained stable with a Class I canine and molar relationship, and a normal overjet/overbite was maintained after 9.4 years of retainer use. In MBS patients, it is important to achieve an accurate early diagnosis, and implement a multidisciplinary treatment approach and long-term retention and follow-up.

• Economic and Environmental Geology
• /
• v.38 no.2 s.171
• /
• pp.187-196
• /
• 2005

Structural sites which cations can occupy in garnet structure are centers of the tetrahedron, octahedron, and distorted cube sharing edges with the tetrahedron and octahedron. Among them, the size of cation occuping at tetrahedral site (the center of tetrahedron) is closely related with the size of a unit cell of garnet. Accordingly, garnet containing iron with relative large ionic radii in tetrahedral site can be considered as a promising matrix for the immobilization of the elements with large ionic radii, such as actinides in radioactive wastes. We synthesized several garnets with the batch composition of $Ca_{1.5}GdCe_{0.5}ZrFeFe_3O_{12}$, and studied their properties and phase relations under various conditions. Mixed samples were fabricated in a pellet form under a pressure of $200{\~}400{\cal}kg/{\cal}cm^2$ and were sintered in the temperature range of $1100\~1400^{\circ}C$ in air and under oxygen atmospheres. Phase identification and chemical analysis of synthesized samples were conducted by XRD and SEM/EDS. In results, garnet was obtained as the main phase at $1300^{\circ}C$, an optimum condition in this system, even though some minor phases like perovskite and unknown phase were included. The compositions of garnet and perovskite synthesized from the batch composition of $Ca_{1.5}GdCe_{0.5}ZrFeFe_3O_{12}$ were ranged $[Ca_{l.2-1.8}Gd_{0.9-1.4}Ce_{0.3-0.5}]^{VIII}[Zr_{0.8-1.3}Fe_{0.7-1.2}]^{VI}[Fe_{2.9-3.1}]^{IV}O_{12}$ and $Ca_{0.1-0.5}Gd_{0.0-0.8}Ce_{0.1-0.5}\;Zr_{0.0-0.2}Fe_{0.9-1.1}O_3$, respectively. Ca content was exceeded and Ce content was depleted in the 8-coordinated site, comparing to the initial batch composition. This phenomena was closely related to the content of Zr and Fe in the 6-coordinated site.