• Title/Summary/Keyword: Phase Changing Material

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Optimized for Low-temperature Sintering of TiO2 Paste with TTIP (TTIP를 이용한 저온소성용 TiO2 페이스트 최적화)

  • Jung, You-Ra;Jin, En Mei;Gu, Hal-Bon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.8
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    • pp.608-613
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    • 2013
  • In this paper, the low-temperature sintering of $TiO_2$ is approached to solve the problem of high temperature sintering which decreases the interconnection between particles or between substrate and particle. $TiO_2$ paste is prepared with Titanium (IV) isopropoxide as the precursor material and calcinate at different conditions (low temperature). In the results, since the changing of temperature and time of sintering, crystalline phase do not change and the intensities of anatase, rutile phase are higher. At $110^{\circ}C$, 7 h sintering condition, crystalline size of anatase and rutile phase are the smallest which are 13.07 and 17.47 nm, respectively. In addition, the highest zeta potential is about 32.77 mV and the repulsive force increases thus leading to the best of the dispersion characteristics between $TiO_2$ particles. Futhermore, DSSCs at that condition exhibits the highest efficiency with the values of $V_{oc}$, $J_{sc}$, FF and ${\eta}$ are 0.69 V, $8.60mA\;cm^{-2}$, 67.93% and 4.06%, respectively.

Crystal Structure and Quantitative Phase Analysis of Multiphase Sample using RIETAN and MEED (RIETAN 및 MEED법에 의한 다상시료의 결정구조 및 정량상 분석)

  • 김광복;천희곤;조동율;신종근;구경완
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.303-307
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    • 2000
  • The crystal structure of ZnS fabricated by gas-liquid phase reaction was obtained by XRD and refined by RIETAN near R$_{wp}$ factor 10%. The increasement of HCP phase depended on extra H$_2$S gas and the lattice parameter and crystalline size changed by the relative ratio of multiphase. Using ZnS of the different multiphase ratio and crystalline size, sintered ZnS:Cu, Al green phosphor and the CL property resulted optimum luminescence in the range of 91~94% and 150~190$\AA$, respectably, FCC/HCP ratio and crystalline size. As changing of structure ratio, the reason of different luminescence property is now studying. As well as, after XRD pattern of TiO$_2$powder fitted by RIETAN and the structure factor using MEED method simulated about each atom of (002) plane. Additionally, we proposed RIETAN and MEED were the methods of the study of luminescence mechanism for many phosphor materials.s.

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Mix Design and Mechanical Properties of Aerated Concrete for Incorporation of Low Temperature PCM (저온 PCM 혼입을 위한 경량기포콘크리트의 배합설계 및 기계적 특성)

  • Baasankhuu, Batzaya;Lim, Myung-Kwan;Lim, Hee-Seob;Choi, Dong-Uk
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.4
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    • pp.110-115
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    • 2017
  • This research was performed to investigate the mechanical performance of lightweight concrete including phase changing material(Low temperature PCM). Micro capsulised PCM consisted of wax type core and melamine based wall. Also, for PCM of one single kind, paraffin wax was inserted into Vermiculite and the surface was coated with melamine resin. Interfacial polymerization is based on the principle that macromolecule reaction takes place on the surfaces between 1-dodecanol(core material) and water (solvent) to form the wall material. Lightweight concrete has compressive strength of 10 MPa, tensile strength of 1.5 MPa, and oven dried density of 1.0kg/liter which included 10%, 20%, or 30% PCM by weight. To do so, this study fabricated light-weight foamed concrete ($1.0kg/m^3$) in pre-foaming method and mixed it with PCM micro capsule of 1-dodecanol and melamine to examine its physical properties.

Application of PCM Technology to Concrete II : Effects of SSMA(Sulfonated Styrene-Maleic Anhydride) on the Properties of the 1-Dodecanol Micro-Capsule (PCM 기술의 콘크리트 적용 II : 계면중합법에 의한 1-도데카놀 마이크로 캡슐에 있어서 계면활성제로 사용된 SSMA의 표면활성도가 마이크로 캡슐의 특성에 미치는 영향)

  • Shin, Se-Soon;Jung, Jae-Yun;Lim, Myung-Kwan;Choi, Dong-Uk;Kim, Young-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.17-25
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    • 2013
  • Thermal storage technology used for indoor heating and cooling to maintain a constant temperature for a long period of time has an advantage of raising energy use efficiency. This, the phase changing material, which utilizes heat storage properties of the substances, capsulizes substances that melt at a constant temperature. This is applied to construction materials to block or save energy due to heat storage and heat protection during the process in which substances melt or freeze according to the indoor or outdoor temperature. The micro-encapsulation method is used to create thermal storage from phase changing material. This method can be broadly classified in 3 ways: chemical method, physical and chemical method and physical and mechanical method. In the physical and chemical method, a wet process using the micro-encapsulation process utilized. This process emulsifies the core material in a solvent then coats the monomer polymer on the wall of the emulsion to harden it. In this process, a surfactant is utilized to enhance the performance of the emulsion of the core material and the coating of the wall monomer. The performance of the micro-encapsulation, especially the coating thickness of the wall material and the uniformity of the coating, is largely dependent on the characteristics of the surfactant. This research compares the performance of the micro-capsules and heat storage for product according to molecular mass and concentration of the surfactant, SSMA (sulfonated styrene-maleic anhydride), when it comes to micro-encapsulation through interfacial polymerization, in which Dodecan-1 is transformed to melamin resin, a heat storage material using phase changing properties. In addition, the thickness of the micro-encapsulation wall material and residual melamine were reduced by adjusting the concentration of melamin resin microcapsules.

A Study on the Formation of Dynamism in the Modern Fashion (현대패션에 표현된 dynamism의 조형성 연구)

  • 이은숙
    • Journal of the Korea Fashion and Costume Design Association
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    • v.4 no.1
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    • pp.143-153
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    • 2002
  • Fashion has been analyzed and explained in diverse ways. Fashion, like every phase of culture, is a reflection of the Zeitgeist. In order to understand the changing fashion we must understand the changing society. For fashion of a period are expressions of the interrelation of the various elements of the culture, including the social and political values, the economic and industrial progress, art, the development of technology, etc... Particularly fashion is closely connected with a style of art. In a style of art, futurism focused on the "dynamism" resulting from super-speed and high-technology. This study aimed to review literatures, fashion magazines, web-site in order to know how the dynamism of futurism is expressed in modern fashion. The results of this study were as follows; 1. Dynamism was expressed by means of lines, colors, patterns through the eyesights visually. Asymmetrical oblique lines, zig-zag lines or bold cutting expressed the mechanical and offensive dynamism. In contrast, such lines as curves and spirals expressed the soft and natural dynamism. Primary colors or complementary contrast expressed energetic and rhythmical dynamism. The geometrical patterns and automobile wheels patterns expressed dynamism resulting from mechanical aesthetics. 2. Dynamism was expressed through repeat of lines, colors, patterns, and textiles. Particularly Vinyl material, fluorescent material, metallic material, beads, and spangle expressed a strong dynamism. On the other hand, natural materials, paper and other similar ones are used to signify the orientation towards a futuristic high-technology society.y society.

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Effect of Phase Stability on the Microstructure Development of α-SiAlON Ceramics

  • Kim, Joosun;Lee, Hae-Weon;Chen, I-Wei
    • Journal of Powder Materials
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    • v.10 no.2
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    • pp.118-122
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    • 2003
  • Alpha-SiAlON ceramics having various compositions and modifying cations were investigated with respect to their phase stability, transformation kinetics. and resulting microstructures. Each composition was heat treated at 150$0^{\circ}C$ for 1h and measured the $\alpha$-SiAlON transformation. The phase-boundary composition in the single-phase $\alpha$-SiAlON region showed sluggish transformation from $\alpha$-$Si_3N_4$ to $\alpha$-SiAlON compared to the phase-center composition in the diagram. Using the different rare earth modifying cations, dependence of transformation kinetics on the phase stability in a fixed composition was also explained. By changing size of the stable u-phase region with exchanging cations, systematic change in transformation was observed. Transformation rate of $\alpha$-SiAlON at low temperature has an important role on controlling the final microstructure. Less transformation gives more chances to develop elongated grain in the microstructure.

Experimental study for optimizing the thermal regulating system with phase change material on the photovoltaic panel (태양광패널 온도제어를 위한 PCM시스템 최적화에 관한 실험적 연구)

  • Lee, Hyo-Jin;Chun, Jong-Han
    • 한국태양에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.273-278
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    • 2009
  • The experimental study is performed to investigate the optimum design of the system dissipating properly heat from the in-situ solar panel installed on site. For this purpose, six 12-Watts panels, which are set at the different conditions of the solar panels contained phase change material, changing the array of the aluminum fin and honeycomb at the back of the panel, are tested. PCM, which has $44^{\circ}C$ melting point, is chosen in this study. In order to enhance the thermal heat from the absorbed heat in PCM, finned aluminum plate is placed. Furthermore, Aluminum honeycomb is imbedded in the back container to find if it would improve the thermal conductivity of PCM. As a result, the solar panel, which is combined with honeycomb and outward fins with PCM instead of placing the fine inward, is showing the best performance in terms of controling panel temperature and efficiency.

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Temperature Control for PV Panel Absorbing Heat by Phase Change Material and its Estimation (상변환물질을 활용한 태양광 패널 표면온도 제어효과 및 최적화 시스템)

  • Lee, Hyo-Jin;Chun, Jong-Han
    • Journal of the Korean Solar Energy Society
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    • v.30 no.2
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    • pp.10-15
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    • 2010
  • The experimental study was conducted to optimize the system dissipating properly heat from the in-situ solar panel installed on the roof. For this purpose, six 12-Watt panels, which were consisted of the different design conditions such as containing phase change material(PCM), changing the array of the aluminum fin and honeycomb at the back of the panel, were tested. PCM, which had $44^{\circ}C$ melting point, was chosen in this study. In order to enhance absorbing and expelling heatin PCM, profiled aluminum fin was placed either inward oroutward from the panel. Furthermore, Aluminum honeycomb is imbedded in the back container to find if it would improve the thermal conductivity of PCM. During the experiment, there were ranged to $26^{\circ}C\sim32^{\circ}C$ for outdoor temperature and $700W/m^2\sim1000W/m^2$ for irradiance. As a result, the solar panel, combined with honeycomb and outward fins with PCM instead of placing the fins inward, is showing the best performance in terms of controling panel temperature and its efficiency.

Photoreflectance of A $I_x$Ga${1-x}$As(x.<=.0.15) grown by liquid-phase epitaxy (Liquid-phase epitaxy로 성장시킨 A $I_x$Ga${1-x}$As(x.<=.0.15)의 photoreflectance)

  • 배인호;김인수;이철욱;최현태;김말문;김상기
    • Electrical & Electronic Materials
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    • v.7 no.4
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    • pp.300-305
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    • 1994
  • We determined the alloy composition of the liquid-phase epitaxy(LPE) grown $Al_{x}$G $a_{1-x}$ As by the photoreflectance(PR), and observed the variation of PR signal by changing the condition of annealing and thickness of epilayer. As the measuring temperature was decreased, the broadening parameter was decreased, and the amplitude of PR signal was increased. When the temperature of annealing was increased, the surface carrier concentration was decreased and then the shape and amplitude of PR signal were affected by the surface electric field. The structure change was observed when the specimen was annealed for long time at a high temperature. We found that the surface electric field increased when the thickness of epilayer was decreased by etching, because the band bending was increased by the decreased of the width of depletion layer....

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Electromagnetic Interference shielding effectiveness of carbon black / Glass fiber woven roving and Carbon fiber unidirectional fabric reinforced composite (카본블랙/섬유강화 복합재료의 전자파 차폐효과)

  • Kim J.S.;Han G.Y.;Ahn D.G.;Lee S.H.;Kim M.S.
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2005.06a
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    • pp.1322-1325
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    • 2005
  • The main objectives of this research work are to develop conductive glass fiber woven roving and carbon fiber unidirectional fabric composite materials and to determine their electromagnetic shielding effectiveness(EMSE). Epoxy is the matrix phase and glass, carbon fiber are the reinforcement phase of the composite material. Carbon black are incorporated as conductive fillers to provide the electromagnetic shielding properties of the composite material. The amount of carbon black in the composite material is varied by changing the carbon black composition, woven roving and unidirectional (fabric) structure. The EMSE of various fabric composites is measured in the frequency range from 300MHz to 800MHz. The variations of EMSE of woven roving and unidirectional composites with fabric structure, metal powder composite are described. Suitability of conductive fabric composites for electromagnetic shielding applications is also discussed.

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