• 제목/요약/키워드: Petroleum Oil

검색결과 667건 처리시간 0.023초

항공분야 온실가스 감축을 위한 바이오항공유 제조기술 (Bio-Jet Fuel Production Technologies for GHG Reduction in Aviation Sector)

  • 김재곤;박조용;임의순;민경일;박천규;하종한
    • 한국수소및신에너지학회논문집
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    • 제26권6호
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    • pp.609-628
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    • 2015
  • Thie study presents the biomass-derived jet (bio-jet) fuel production technologies for greenhouse gas (GHG) reduction in aviation sector. The aviation sector is responsible for the 2% of the world anthropogenic $CO_2$ emissions and the 10% of the fuel consumption: airlines' costs for fuel reach 30% of operating costs. In addition, the aviation traffic is expected to double within 15 years from 2012, while fuel consumption and $CO_2$ emissions should double in 25 years. Biojet fuels have been claimed to be one of the most promising and strategic solutions to mitigate aviation emissions. This jet fuel, additionally, must meet ASTM International specifications and potentially be a100% drop-in replacement for current petroleum jet fuel. In this study, the current technologies for producing renewable jet fuels, categorized by alcohols-to-jet, oil-to-jet, syngas-to-jet, and sugar-to-jet pathways are reviewed for process, economic analysis and life cycle assessment (LCA) on conversion pathways to bio-jet fuel.

토양경작법의 사례 분석을 통한 적용방안 개선 (Improvement of Landfarming Applicability from Analysis of Case Studies)

  • 김종원;최상일;양재규;김보경
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제15권1호
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    • pp.19-28
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    • 2010
  • Considering six screen matrix to select an optimum remediation method for the Kunsan military base contaminated with petroleum oil, the following order was obtained: landfarming > biopile > soil washing > thermal desorption = incineration. When the landfarming method was applied for the remediation of 2,250 $m^3$ soil contaminated with petroleum oil ranging from 500 to 2,404 mg/kg as TPH, contamination level decreased below target concentration 450 mg/kg after 20~42 days depending on the initial contamination. From the evaluation of case studies of landfarming, it is suggested that ratty-truss or single-arch structure is suitable in the landfarming plant for the treatment of large-scale contaminated soil requiring long period of remediation. But, vinyl-house structure is suitable in the landfarming plant for the treatment of small-scale contaminated soil requiring short period of remediation. Therefore vinyl-house structure is recommended in the remediation of contaminated soil less than 5,000 $m^3$ requiring within 1 year of remediation period but ratty-truss or single-arch structure is recommended for the remediation of contaminated soil more than 5,000 $m^3$.

HDPE, PP 및 PS의 등온열분해에 의한 액화 특성 (Liquefaction Characteristics of HDPE, PP and PS by Isothermal Pyrolysis)

  • 유홍정;박수열;이봉희
    • 한국응용과학기술학회지
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    • 제19권3호
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    • pp.198-205
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    • 2002
  • Isothermal pyrolysis of high density polyethylene(HDPE), polypropylene(PP) and polystyrene(PS) was performed at $450^{\circ}C$, respectively. The effect of pyrolysis time on yield and product composition was investigated. Conversion and liquid yield obtained during HDPE pyrolysis continuously increased with time up to 80minutes, but those of PP and PS did not largely change after 35minutes. Each liquid product formed during the pyrolysis was classified into gasoline, kerosene, light oil and wax according to the distillation temperature based on the petroleum product quality standard of Korea Petroleum Quality Inspection Institute. The major liquid product of HDPE pyrolysis was light oiH34 wt.% based on the amount of HDPE treated) and the amounts of the other liquid ingredients(gasoline, kerosene and wax) were almost the same. On the other hand, the pyrolysis of PP produced 27 wt.% gasoline, 22 wt.% kerosene, 24 wt.% light oil and 13wt.% wax, and the pyrolysis of PS produced 56 wt.% gasoline, 12 wt.% kerosene, 9 wt.% light oil and 13 wt.% wax.

저온 열분해시 HDPE 및 LDPE의 액화 특성 (Liquefaction Characteristics of HDPE and LDPE in Low Temperature Pyrolysis)

  • 이봉희;박수열;김지현
    • 한국응용과학기술학회지
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    • 제23권4호
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    • pp.307-318
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    • 2006
  • The pyrolysis of high density polyethylene(HDPE) and low density polyethylene(LDPE) was carried out at temperature between 425 and $500^{\circ}C$ from 35 to 80 minutes. The liquid products formed during pyrolysis were classified into gasoline, kerosene, gas oil and wax according to the petroleum product quality standard of Korea Petroleum Quality Inspection Institute. The conversion and yield of liquid products for HDPE pyrolysis increased continuously according to pyrolysis temperature and pyrolysis time. The influence of pyrolysis temperature was more severe than pyrolysis time for the conversion of HDPE. For example, the liquid products of HDPE pyrolysis at $450^{\circ}C$ for 65 minutes were ca. 30wt.% gas oil, 15wt.% wax, 14wt.% kerosene and 11wt.% gasoline. The increase of pyrolysis temperature up to $500^{\circ}C$ showed the increase of wax product and the decrease of kerosene. The conversion and yield of liquid products for LDPE pyrolysis continuously increased according to pyrolysis temperature and pyrolysis time, similar to HDPE pyrolysis. The liquid products of LDPE pyrolysis at $450^{\circ}C$ for 65 minutes were ca. 27wt.% gas oil, 18wt.% wax, 16wt.% kerosene and 13wt.% gasoline.

Preparations of Carbon Fibers from Precursor Pitches Synthesized with Coal Tar or Petroleum Residue Oil

  • Yang, Kap-Seung;Park, Young-Ok;Kim, Yong-Min;Park, Sang-Hee;Yang, Cheol-Min;Kim, Yong-Joong;Soh, Soon-Young
    • Fibers and Polymers
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    • 제1권2호
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    • pp.97-102
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    • 2000
  • Pitch precursors were synthesized from coal tar(CT) and pyrolysis fuel oil(PFO, petroleum residue oil) at relatively low temperature of $250^{\circ}$, in the presence of horontrifluorideidiethyletherate complex(BFDE) as a catalyst and nitrobenzene(NB) as a co-catalyst. The softening point, nitrogen content and carbon yield increased with an increase of concentration of NB. The pitch precursors with good spinnability were prepared by removing the volatile components through $N_2$ blowing. The precursor pitches were spun through a circular nozzle, stabilized at $310^{\circ}$ and finally carbonized at $1000^{\circ}$. The optically anisotropic structure formed at the absence of NB was changed into isotropic structure, showing a decrease in size of the flow domain. The hollow carbon fiber could be prepared in the process of stabilization. The results proposed that the morphology of carbon materials could be controlled by changing the concentration of catalyst and/or co-catalyst and/or stabilization condition that affect on the mobility of molecules during carbonization.

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HDPE의 열분해에 의한 액화 특성 (Liquefaction Characteristics of HDPE by Pyrolysis)

  • 유홍정;이봉희;김대수
    • 폴리머
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    • 제27권1호
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    • pp.84-89
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    • 2003
  • 열분해 온도 및 열분해 시간이 HDPE의 열분해에 미치는 영향을 해석하였다. HDPE 열분해의 시작온도와 활성화에너지는 가열속도가 증가함에 따라 증가하였다. 전환율과 액체수율은 열분해 온도와 시간이 증가함에 따라 계속 증가하였고, 특히 45$0^{\circ}C$에서 열분해 시간에 매우 민감하게 변하였다. 전환율에 있어 열분해 온도가 열분해 시간보다 더 큰 영향을 주었다. 열분해 과정에서 생성된 각각의 액체성분을 한국석유품질검사소 석유제품 품질기준에 기초하여 증류온도에 따라 가솔린, 등유, 경유, 왁스로 분류하여 본 결과, 450 $^{\circ}C$에서는 경유 > 왁스 > 등유 > 가솔린 순이었고, 475$^{\circ}C$와 50$0^{\circ}C$에서는 왁스 > 경유 > 등유 > 가솔린 순이었다.

Application of nanoparticles in extending the life of oil and gas transmission pipeline

  • Yunye, Liu;Hai, Zhu;Jianfeng, Niu
    • Structural Engineering and Mechanics
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    • 제84권6호
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    • pp.733-741
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    • 2022
  • The amount of natural gas that is used on a worldwide scale is continuously going up. Natural gas and acidic components, such as hydrogen sulfide and carbon dioxide, cause significant corrosion damage to transmission lines and equipment in various quantities. One of the fundamental processes in natural gas processing is the separation of acid gases, among which the safety and environmental needs due to the high toxicity of hydrogen sulfide and also to prevent wear and corrosion of pipelines and gas transmission and distribution equipment, the necessity of sulfide separation Hydrogen is more essential than carbon dioxide and other compounds. Given this problem's significance, this endeavor aims to extend the lifespan of the transmission lines' pipes for gas and oil. Zinc oxide nanoparticles made from the environmentally friendly source of Allium scabriscapum have been employed to accomplish this crucial purpose. This is a simple, safe and cheap synthesis method compared to other methods, especially chemical methods. The formation of zinc oxide nanoparticles was shown by forming an absorption peak at a wavelength of about 355 nm using a spectrophotometric device and an X-ray diffraction pattern. The size and morphology of synthesized nanoparticles were determined by scanning and transmission electron microscope, and the range of size changes of nanoparticles was determined by dynamic light scattering device.

해저 석유 생산시스템 내 유동안정성 확보를 위한 불투명 오일의 왁스생성온도 측정법 (Wax Appearance Temperature Measurement of Opaque Oil for Flow Assurance in Subsea Petroleum Production System)

  • 임종세;백승영;강판상;유승렬;김효상;박지홍
    • Journal of Advanced Marine Engineering and Technology
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    • 제36권1호
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    • pp.185-194
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    • 2012
  • 비교적 접근이 용이한 육상 및 천해에서 석유의 생산은 이미 완료되었거나 대부분이 진행 중이기에 석유 생산 지역이 점차 심해로 확장되고 있다. 심해와 같은 저온환경에서 석유생산이 이루어지면 석유의 부존환경과 다른 온도와 압력에 노출되어 생산시스템에 다양한 고형물이 집적되어 석유가 안정적으로 생산되지 못하게 하는 유동안정성 확보 문제가 발생할 수 있다. 고형물 중 왁스는 온도에 민감하기 때문에 왁스의 집적을 예측하고 제어하기 위해서는 오일 내 왁스가 석출되기 시작하는 온도인 왁스생성 온도의 정확한 측정이 요구되나 표준화된 측정법이 존재하지 않아 다양한 방법이 제안되고 있는 실정이다. 이 연구에서는 점도측정법, 시차주사열량법, 필터막힘점측정법, 압력필터측정법을 적용하여 불투명 오일의 왁스생성온도를 측정하고, 이를 검증하기 위해 고형물생성유도장치와 가스크로마토크래피를 이용하였다. 이 연구결과를 통해 오일특성에 따른 왁스생성온도 실험법을 체계화한다면 불투명 오일의 왁스생성온도 측정법 표준화하는데 주요자료로 이용할 수 있어 왁스에 의한 유동안정성 확보 문제를 예측하고 해결하는데 활용될 수 있을 것이다.

북한 해양분지의 석유지질학적인 특징과 남북한 해양과학기술 협력 방안 (Characteristics of Petroleum Geology of the Marine Basins in North Korea and Mutual Cooperative Plans for MT (Marine Technology))

  • 허식;유해수;권석재;오위영;배성환
    • 한국석유지질학회지
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    • 제12권1호
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    • pp.27-33
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    • 2006
  • 북한의 서한만 분지는 일일 생산량 450 배럴의 원유가 생산되고 있어 석유부존 가능성이 확인되었고, 중국에서 큰 유전중 하나인 발해만 유전지대와 지리적으로 근접해 있어 대규모 매장 가능성도 있다. 지금까지 북한의 석유탐사 및 투자 현황을 살펴보면, 탐사가 진행중인 곳은 3개 지역으로 서한만 B&C 광구 (스웨덴 Taurus사), 북부 서한만 및 육상 안주분지 (캐나다 SOCO사), 동한만 광구 (호주 Beach Petroleum사) 등이다. 상기 이외의 해저에는 원유가 부존할 만한 분지가 존재하지 않으며, 길주-명천 지구대 등 일부 육상 지역에서는 원유가 발견된 곳도 있으나 경제성이 없는 것으로 추정된다. 지금까지 밝혀진 북한 서한만의 지질은 중국의 발해만과 유사하다. 후기 원생대와 초기 고생대에 생성된 기반암 위에는 최대 $6,000{\sim}10,000\;m$ 두께의 중생대 탄산염암 및 퇴적암과 $4,000{\sim}5,000\;m$ 두께의 신생대 퇴적암이 집적되어 있다. 근원암은 3,000 m 이상되는 쥬라기 및 $1,000{\sim}2,000\;m$ 두께의 백악기 흑색 셰일 그리고 수천 m 두께의 중생대 이전의 탄산염암으로 구성되어 있다. 저류층은 높은 공극률을 가진 중생대부터 신생대에 퇴적된 사암과 중생대전에 균열된 탄산염암이다. 원유 트랩은 배사구조, 단층구조, 파묻혀 있는 언덕 (buried hill) 그리고 층서형 트랩 형태다. 따라서 서한만에서의 퇴적층들은 다양한 형태의 근원암을 가지며 또한 공극률과 투수율이 높고, 많은 단층에 의한 이동경로를 가지게 되므로, 사암으로 이루어진 석유 저장지만 발견하면 석유를 생산할 수 있을 것으로 추정된다. 연안국의 200해리 배타적 경제수역 설정 등 해양관할권 확대가 주류를 이루는 새로운 국제해양질서가 구축되고 있는 상황과 동일한 해역을 대상으로 하는 남북한 해양개발의 인접성 등을 감안할 때, 실리주의적 세계의 변화에 공동으로 대처하고 남북한 상호 경제발전을 도모하기 위해서는 남북한 해양과학기술 협력교류의 활성화와 새로운 첨단 해양기술의 공동 연구 개발 둥 남북 상호간의 능동적이고 적극적인 협력자세가 무엇보다 필요하다고 생각된다. 또한 한반도 주변해양에서 남북한 각기 독자적인 해양관리 및 해양산업의 전개보다는 양국 공동협력에 의해 주변국의 한민족 공동체가 참여하는 방안이 시급한 과제라고 판단된다.

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