• Title/Summary/Keyword: Peroxide

Search Result 3,765, Processing Time 0.035 seconds

Elctrokinetic-Fenton 기법 적용시 토질조건과 오염원의 종류에 따른 과산화수소의 주입특성

  • 김정환;김병일;한상재;김수삼
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2002.04a
    • /
    • pp.30-33
    • /
    • 2002
  • In this study, feasibility of using hydrogen peroxide as a chemical oxidant for in-situ treatment by EK-Fenton technology were investigated. Kaolinite, kaolinite/sand mixture and illitic soil spiked by phenol and phenanathrene were used and variation of electrochemical characteristics were examined by EK-Fenton test. For kaolinite that having low buffer capacity, hydrogen peroxide was injected effectively from anode reservoir. However illitic soil that having relatively higher buffer capacity had low hydrogen peroxide introducing efficiency. The test results showed that Hydrogen ions generated by current increased during the treatment decreased under pH 3 in the most of kaolinite specimen. Therefore, stabilized hydrogen oxide was injected more effectively in the kaolinite specimen. This study suggests that efficiency of hydrogen peroxide injection by EK-Fenton thechnoloty is dependent of variation of pH in the soil

  • PDF

A Study on the Characteristics of Pyrolysis of Methyl Ethyl Ketone Peroxide with Addition of Sulfuric Acid (황산의 첨가에 따른 Methyl Ethyl Ketone Peroxide의 열분해 특성에 관한 연구)

  • Jung Doo-Kyun;Choi Jae-Wook;Lee In-Sik
    • Fire Science and Engineering
    • /
    • v.18 no.4
    • /
    • pp.52-56
    • /
    • 2004
  • An experiment to examine the characteristics of pyrolysis of Methyl Ethyl Ketone Peroxide was conducted in an air-present environment, using TG-DTA. Decomposition starting temperature was decreased as the increase of 98% concentrated H₂SO₄ to the MEKPO and the maximum decomposition temperature of MEKPO was 116.8℃. The activated energy calculated from differential method of pure MEKPO, MEKPO with 1 wt%, 3wt%, and 5wt% of H₂SO₄ were 0.576㎉/mo1, 0.355㎉/㏖, 0.284㎉/㏖ and 0.258㎉/㏖ respectively.

Development of Hydrogen Peroxide Thruster adopted Silver Catalyst (은을 촉매로 사용하는 과산화수소 추력기 개발)

  • Lee, Su-Lim;Lee, Choong-Won
    • Journal of the Korean Society of Propulsion Engineers
    • /
    • v.11 no.4
    • /
    • pp.67-73
    • /
    • 2007
  • In recent years hydrogen peroxide has become considerably more attractive as a green rocket propellant so a laboratory model of hydrogen peroxide thruster adopted silver catalyst and a test facility has been developed to research a hydrogen peroxide propulsion. The design scheme of thruster and the test data are presented including ignition delay, efficiency of characteristic exhaust velocity. As a result, 95% of efficiency of characteristic exhaust velocity was obtained at steady state operation condition.

Development of a Hydrogen-Peroxide Rocket Engine of l00N Thrust (l00N $H_2O_2$ Monopropellant 로켓 엔진의 개발)

  • Sang-Hee Ahn;S. Krishnan;Choog-Won Lee
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2003.10a
    • /
    • pp.131-134
    • /
    • 2003
  • There has been a renewed interest in the use of hydrogen peroxide as an oxidizer in bipropellant liquid rocket engines as well as in hybrid rocket engines. This is because hydrogen peroxide is a propellant of low toxicity and enhanced versatility. The present paper details the features of the designed engine of l00N thrust and its facility. Also explained is the arrangement of the distillation unit to be used to prepare rocket-grade hydrogen-peroxide propellant. Results of the simulated "cold" tests are presented.

  • PDF

Ignition Studies Of Igniter using Hydrogen Peroxide And Kerosene (Catalyst Ignition) (과산화수소/케로신(촉매점화) 점화기의 점화특성에 관한 연구)

  • Kim, Ki-Woo;Kim, Tae-Wan;Lee, Yang-Suk;Kim, Yoo;Ko, Young-Sung;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
    • /
    • 2009.05a
    • /
    • pp.57-60
    • /
    • 2009
  • Exothermic and ignition characteristic of igniter is very important factor in engine performance. Since the igniter performance is effected by Hydrogen Peroxide decomposition rate, we have to test the preliminary catalyst performance test. In this report, after making igniter using hydrogen peroxide/kerosene, a thermal characteristic were examined by comparing hydrogen peroxide mass and catalyst mass. And then we study ignition characteristic of the affects of O/F ratio using the previous data.

  • PDF

Effects of the Fractions from the Leaves, Fruits, Stems and Roots of Cudrania tricuspidata and Flavonoids on Lipid Peroxidation (꾸지뽕나무 잎, 열매, 줄기 및 뿌리의 분획물 과 플라보노이드 화합물이 흰쥐의 과산화지질 함량에 미치는 영향)

  • Park, Jong-Cheol;Choi, Jae-Sue;Choi, Jong-Won
    • Korean Journal of Pharmacognosy
    • /
    • v.26 no.4
    • /
    • pp.377-384
    • /
    • 1995
  • We studied the effects of the methanolic extracts and fractions from leaves, fruits, stems and roots of Curadrania tricuspidata on the formation of lipid peroxide. The methanol extracts of leaves, fructus and stem of this plants decreased the formation of lipid peroxide in the isolated rat liver. The ethyl acetate fraction of leaves and n-butanol fraction of stems reduced the lipid peroxide formation. It showed that arthocarpesin, one of the constituents isolated from this plant, lowered the formation of lipic peroxide by 13%, 21%, 22% and 25% at the concentration of $10^{-8},\;10^{-6},\;10^{-4}\;and\;10^{-2}mg/ml$, respectively.

  • PDF

Treatment of High Strength para-Nitrophenol using Fenton-like Oxidation Catalyzed by Steeler's Dust (제강분진을 촉매로 활용한 펜톤유사산화에 의한 고농도 para-Nitrophenol의 처리)

  • 배범한;정재훈;이성재;장윤영;박규홍;장윤석
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
    • /
    • 2000.11a
    • /
    • pp.136-139
    • /
    • 2000
  • Fenton-like oxidation of para-nitrophenol(PNP) was studied using hydrogen peroxide iii combination with steeler's dust substituted for ferrous iron in Fenton's reaction. Various factors critical in the degradation of PNP were studied, including hydrogen peroxide dosage, concentration of steeler's dust. and initial pH. Experimental results showed that 1,000mg/L PNP and its oxidation intermediate could be mostly decomposed within 30m1n by 10g/L steeler's dust, 0.25% hydrogen peroxide, and initila pH of 3.0. The reaction rate constant (k) of CODcr concentration were calculated with the addition of steeler's dust(0.0059 min$^{-1}$ (g/L)$^{-1}$ ) and hydrogen peroxide(0.2965 min$^{-1}$ (%)$^{-1}$ ), respectively.

  • PDF

Biodegradation of Hydrogen Peroxide in Semiconductor Industrial Wastewater with Catalase from Micrococcus sp.

  • Oh, Sung-Hoon;Yu, Hee-Jong;Kim, Moo-Sung;So, Sung;Suh, Hyung-Joo
    • Preventive Nutrition and Food Science
    • /
    • v.7 no.1
    • /
    • pp.33-36
    • /
    • 2002
  • A catalase from Micrococcus sp. isolated from soil was applied to degrade hydrogen Peroxide in wastewater from a semiconductor industry. The degradation rates of hydrogen peroxide increased with increasing reaction time and catalase concentrations in the reaction mixture. However, in the presence of aluminum chloride or chloride oxide used in detergent compounds, the degradation rate of hydrogen peroxide was not affected. Enzyme stabilizers and antifoam did not affect the degradation rates of hydrogen peroxide.

Anticomplementary Activity of Ergosterol Peroxide from Naematoloma fasciculare and Reassignment of NMR Data

  • Kim, Dong-Seon;Baek, Nam-In;Oh, Sei-Ryang;Jung, Keun-Young;Lee, Im-Seon;Kim, Jung-Hee;Lee, Hyeong-Kyu
    • Archives of Pharmacal Research
    • /
    • v.20 no.3
    • /
    • pp.201-205
    • /
    • 1997
  • A very high content (at least 0.23%) of ergosterol peroxide was isolated from Naematoloma fasciculare Karst. Not only ergosterol peroxide but also ergosterol showed very strong anticomplementary activity on the classical pathway, the $IC_{50}$ values being $5.0 {\mu}M$ and $1.0 {\mu}M$, respectively. The $ ^{1}H $and $^{13}C$ NMR data of ergosterol peroxide were revised and completely assigned by DEPT, $^{1}H-^{1}H$ COSY, HMQC and HMBC correlations.

  • PDF

Low-temperature Dyeing of Silk Fabrics using a Glyoxal/Hydrogen peroxide Redox System (Glyoxal/Hydrogen peroxide-Redox System을 사용한 견직물의 저온염색)

  • 이내연;백두현;임종열;임영훈
    • Textile Coloration and Finishing
    • /
    • v.6 no.1
    • /
    • pp.1-7
    • /
    • 1994
  • A low-temperature dyeing system for silk fabrics based on a redox system has been investigated. Some factors affecting dyeing of silk fabrics with levelling acid dyes in the absence and presence of certain redox system were investigated under different conditions. The variables studied were; type and concentration of redox system, dyeing conditions, i. e. temperature and time, dye concentration, material-to-liquor ration(LR) and colour fastness. The colour strength(K/S value) is outstandingly higher in the presence than in the absence of redox system. A comparison between the colour strength values of such dyeings abtained the three redox system would call for the following order ; Glyoxal/hydrogen peroxide>thiourea/hydrogen peroxide>glucose/hydrgen peroxide> nothing. In the presence of redox system, free radicals are supposed to be formed in both the fiber and the dye and the interaction between these free radicals bring about covalent fixation beside the usual electrostatic bonds, hydrogen bonds and Van der Waals forces.

  • PDF