• Bulletin of the Korean Chemical Society
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• v.33 no.10
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• pp.3391-3396
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• 2012

Two-dimensional infrared (2D-IR) spectroscopy can probe the fast structural evolution of molecules under thermal equilibrium. Vibrational frequency fluctuation caused by structural evolution produced the time-dependent line shape change in 2D-IR spectrum. A variety of methods has been used to connect the evolution of 2D-IR spectrum with Frequency-Frequency Correlation Function (FFCF), which connects the experimental observables to a molecular level description. Here, a new method to extract FFCF from 2D-IR spectra is described. The experimental observable is the time-dependent frequency shift of maximum peak position in the slice spectrum of 2D-IR, which is taken along the excitation frequency axis. The direct relation between the 2D-IR peak shift and FFCF is proved analytically. Observing the 2D-IR peak shift does not need the full 2D-IR spectrum which covers 0-1 and 1-2 bands. Thus data collection time to determine FFCF can be reduced significantly, which helps the detection of transient species.

• Progress in Superconductivity and Cryogenics
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• v.5 no.1
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• pp.111-117
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• 2003

In the design of the split type free displacer Stilting cryocooler the motion of the displacer is very important to decide the cooling capacity, which depends upon the working gas pressure, the swept volume in the compression space and the expansion space, operating frequency, the phase shift between piston and displacer, etc. In this study, Stirling cryocooler actuated by the electric farce of the dual linear motor is designed and manufactured. Cool down characteristics of the cold end with laser displacement sensor in the expander of the Stilting cryocooler is evaluated. The charging pressure was 15kg$_{f}$/$\textrm{cm}^2$ and operating frequency was 50Hz. Input power and the lowest temperature were about 32W and 67K, respectively. And, displacement of the piston is measured by LVDTs (Linear Variable Differential Transformers), displacement of thedisplacer is measured by laser optic method, and phase shift between piston and displacer is discussed. As the peak-to-peak pressure of the compressor was increased, peak-to-peak displacement of the displacer was increased. The peak-to-peak displacement of the displacer increases in the range of 0 - 64.5Hz(resonant frequency of the displacer), but decreases steeply when the operating frequency is bigger than the resonant frequency. Finally when the phase shift between displacements of the Piston and displacer is 45。, operating frequency is optimum and is decided by resonant frequency of the expander, mass and cross section area of the displacer and constant by friction and flow resistance.e.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.38 no.5
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• pp.456-466
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• 2010

Typical combustion instability such as DC-Shift found in the hybrid rocket motor is characterized by non-linearity. DC-Shift can occur in two different realizations. One is so-called a positive shift of measured DC voltage where the pressure increase suddenly. The other is a negative shift where the pressure drops abruptly. In the present work, specifically the negative DC-Shift was investigated to analyze the effect of oxidizer flow condition and the resonance between fundamental frequency and other ones, such as Helmholtz frequency, and acoustic frequency. Results show a peak frequency of several hundreds HZ shifts as combustion proceeds. A negative DC-shift was found as the result of phase cancellation between two dominant frequency, combustion frequency and flow related frequency. Still is it required to study further to identify the change of dominance of frequency during the combustion.

• Geophysics and Geophysical Exploration
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• v.21 no.1
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• pp.54-60
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• 2018

The data acquired from seismic exploration can be used to detect the existence of oil and gas resources through appropriate processing and interpretation. The seismic attributes indicating the existence of resources are extracted from amplitude information, where the Q-factor representing intrinsic attenuation plays an useful role of hydrocarbon indicator. So, the accuracy of Q-factor estimation is very important to investigate the existence of resources. In this study, we calculated the Q-factor and analyzed the error rate through a numerical example. To mimic real data, random noise was added to the synthetic data. With the noise-added data, the Q-factor was estimated and the error rate was analyzed by using the spectral ratio method (SRM) and peak frequency shift method (PFSM). Both methods provided a relatively accurate Q-factor when the signal-to-noise ratio was 90 dB. However, the peak frequency shift method (PFSM) produced better results than the spectral ratio method (SRM) as the level of random noise increased.

• Phonetics and Speech Sciences
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• v.4 no.3
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• pp.43-49
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• 2012

This paper describes the categorical effects of pitch accent contrasts in a mimicry task. It focuses, specifically, on examining how fundamental frequency (f0) variation reflects phonological contrasts from speakers of two distinct varieties of Korean (i.e., North Kyungsang and South Cholla). The results showed that, in a mimicry task using synthetic speech continua, there was a categorical effect in f0 peak timing for North Kyungsang speakers, but the timing of f0 peaks and valleys in the responses of South Cholla speakers was more variable, presenting a gradient or non-categorical effect. Evidence of categorical effects was represented as the shift of f0 peak times along an acoustic continuum for North Kyungsang speakers. The range for the shift of f0 valley times was much narrower, compared to that of f0 peak times. The degree of a shift near the middle of the continuum showed variability across individual mimicry responses. However, the categorical structure in mimicry responses regarding the clustering of f0 peak points was more significant for North Kyungsang speakers than for South Cholla speakers. Additionally, the finding of the current study implies that the location of f0 peak times depends on individuals' imitative (or cognitive) abilities.

• Proceedings of the Korean Magnestics Society Conference
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• 2003.06a
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• pp.60-61
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• 2003

Theoretical considerations on a giant magneto-impedance (GMI) effect in amorphous ribbons (i.e., thin films) have been made in terms of the expressions of effective permeability and impedance derived in the frame of classical electrodynamics and ferromagnetism. The dependence of GMI effect on the external do magnetic field (H$\_$ext/) and the frequency of alternating current are simulated and discussed in the knowledge of energy conversion consisting of the current energy loss, the ferromagnetic energy consumption, and the magnetic energy storage in the film. The obtained results are summarized as follow: (a) As frequency f< 20 ㎒, the real part of effective permeability (${\mu}$′) changes slightly. The peak of the ${\mu}$′curve always locates at H$\_$ext/=H$\_$ani/ - the anisotropy field. However, the peak value of ${\mu}$′ tends to increase with increasing frequency in the frequency range of 11-20 ㎒. (b) In the frequency range, f= 21-23 ㎒, a negative peak additionally appears. Meanwhile, both the positive and negative peak values rapidly increase with increasing frequency and their peak positions shift towards a high H$\_$ext/. (c) The positive peak value of ${\mu}$′ starts to decrease at f= 29 ㎒ and its negative peak does so at about 35 ㎒. Then, both peaks keep such a tendency and their peak positions move to high H$\_$ext/, as increasing frequency. (d) The dependence of the imaginary part of effective permeability (${\mu}$") on the external dc magnetic field and the frequency of the alternating field indicates that there is only one peak involved in ${\mu}$" for the whole frequency range. (e) The impedance vs. magnetic field curves at various frequencies show that there is a critical value of frequency around f= 18-19 ㎒ where the transition between two frequency regimes occurs; the one (low frequency) in which ${\mu}$′ predominantly contributes to the GMI effect and the other (high frequency) in which ${\mu}$" determines the GMI effect.

• Bulletin of the Korean Chemical Society
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• v.32 no.11
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• pp.4011-4015
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• 2011

We explored the interpretation of the well-accepted correlation between the apparent peak maximum position shift and extent of molecular interactions, like hydrogen bonding and dipole-dipole interactions, based on the overlapped multiple band model. The simulation of two overlapped Lorentzian bands was carried out to interpret how the maximum position of a composite peak relates to the relative contributions of two species representing the different levels of molecular interactions, i.e., free (or very weekly bound) vs. strongly bound. To demonstrate the validity of our interpretation of the origin of the peak position shift, the temperaturedependent IR spectra of ethylene glycol were also analyzed. It was found through the analysis of simulated and experimental spectra that the apparent peak shift in certain case can be safely interpreted as the measure of the strength of hydrogen bonding. The result of this study gives a new insight to interpret molecular interactions probed by vibrational spectroscopy.

• Journal of Broadcast Engineering
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• v.19 no.6
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• pp.967-970
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• 2014

An efficient peak detection algorithm in magnitude spectrum is proposed to distinguish the M-frequency shift keying(FSK) signals from other digitally modulated signal. In addition, recognition of the modulation order estimation of FSK signals is also studied based on the fact that the magnitude spectrum of FSK signals reveals the number of peaks equal to the modulation order. When no a priori information about the signals, we utilize the histogram of the magnitude spectrum to determine the threshold which is important factor in peak detection algorithm. The simulation results show high probability of classification under 500 symbols and signal-to-noise ratio(SNR) higher than 4dB.

• ETRI Journal
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• v.28 no.2
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• pp.235-238
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• 2006

In this letter, a block code that minimizes the peak-to-average power ratio (PAPR) of orthogonal frequency division multiplexing (OFDM) signals is proposed. It is shown that peak envelope power is invariant to cyclic shift and codeword inversion. The systematic encoding rule for the proposed code is composed of searching for a seed codeword, shifting the register elements, and determining codeword inversion. This eliminates the look-up table for one-to-one correspondence between the source and the coded data. Computer simulation confirms that OFDM systems with the proposed code always have the minimum PAPR.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.21 no.4
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• pp.61-72
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• 2007

This study proposed a high efficiency DC-DC converter with a new current doubler rectifier for fuel-cell systems for use with the Nexa(310-0027) PEMFC from the Ballard Co. The proposed high efficiency DC-DC converter for the fuel-cell system generated ZVS by applying partial resonance and using a phase shift PWM control method. Constantly switching frequency, loss of switching, peak current, and peak voltage were reduced by this system. In addition to this system, two inductors were attached to a rectifier circuit allowing it to be able to provide the direct current(DC) and DC voltage safely to a load with reduced ripple components. Also, by using the newly proposed current doubler rectifier, the high frequency DC-DC converter for the fuel cell system was capable of reaching a highest efficiency of 92[%] as compared to 88.3[%] efficiency in previous results, which means that efficiency increased 3.7[%]. The overall results were confirmed by a simulation and laboratory experiment.