• 제목/요약/키워드: Passive sampling

검색결과 109건 처리시간 0.03초

수술실 내의 아산화질소($N_2O$) 노출평가 (Finite Element Analysis on the Strength Safety of a Fuel Tank for Highly Compressed Gas Vehicle)

  • 백종배;엄민용
    • 한국가스학회지
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    • 제13권6호
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    • pp.34-38
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    • 2009
  • 마취가스로 사용되는 아산화질소($N_2O$)는 만성건강 잠재위험을 일으킬 수 있기 때문에 근무자를 보호하기 위해 아산화질소 노출을 감시하고 제어하는 것이 필요하다. 이 연구에서는 아산화질소 노출평가를 위해서 흡착제로는 molecular sieve 5A를 사용하였고 $7m{\ell}$ vial에 보관한 후 heating block에서 $100^{\circ}C$로 12시간 이상 가열하여 GC-ECD를 이용하여 분석, 평가하였다. GC-ECD에 의한 검량선 설명력계수($R^2$)는 0.9992이며 검출한계는 $0.96{\mu}g$/injection, 정량한계는 $3.21{\mu}g$/injection, 탈착효율은 평균 $94.78\;{\pm}\;4.50%$이다. 파과는 각 농도대비 10% 범주 내에 있었다. GC-ECD에 의한 $N_2O$의 수술 전과 수술 중의 노출평가에서는 수술 전의 평균농도는 5.12ppm이고 수술 중의 평균 농도는 42.33ppm으로 수술 중의 아산화질소의 농도가 높게 나타났고 중대한 차이가 있다(P<0.05). GC-ECD에 의한 $N_2O$의 근무자의 근무위치에 따른 노출 평가에서는 중대한 차이가 없고(P>0.005), 시료채취 법에서는 능동식 시료채취 법에서의 $N_2O$ 농도가 높게 나타났다(P<0.05).

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인터넷 쇼핑몰에서의 관계혜택이 고객만족도와 고객충성도에 미치는 효과에 대한 인터넷 라이프스타일의 조절효과 (제2보) (The Moderating Effect of Internet lifestyle among Relational Benefits, Customer Satisfaction and Customer Loyalty on the Internet Shopping Mall (Part II))

  • 고은주;이수경;김선숙
    • 한국의류학회지
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    • 제33권4호
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    • pp.586-597
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    • 2009
  • The purpose of this study is to identify the moderating effect of Internet lifestyle among relational benefits effect, customer satisfaction and customer loyalty on the Internet shopping mall. For the study, utilizing the convenient sampling method, the sample of study was composed of female and male adults aged between 20 and 30 living in Seoul metropolitan area who had experienced purchase of fashion products on the web. Of 350 distributed, 311 useful questionnaires were returned. The survey research design was employed with structured questionnaire. For data analysis, descriptive statistics, factor analysis, reliability analysis, cluster analysis and multiple-regression analysis were used. The results of this study are as follows: The results of Internet lifestyle were regarding 4 cluster of Internet lifestyle. 1) information seeking type, 2) shopping maniac type, 3) social gathering type and 4) passive follower type were obtained. The interaction of psychological benefits and the type of Internet lifestyle affected customer satisfaction positively. The interaction of customer satisfaction and Internet lifestyle reinforced customer loyalty. Especially interaction of shopping maniac type among Internet lifestyle types and customer satisfaction affected customer loyalty strongly.

REVIEW OF GROUNDWATER CONTAMINANT MASS FLUX MEASUREMENT

  • Goltz, Mark N.;Kim, Seh-Jong;Yoon, Hyouk;Park, Jun-Boum
    • Environmental Engineering Research
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    • 제12권4호
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    • pp.176-193
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    • 2007
  • The ability to measure groundwater contaminant flux is increasingly being recognized as crucial in order to prioritize contaminated site cleanups, estimate the efficiency of remediation technologies, measure rates of natural attenuation, and apply proper source terms to model groundwater contaminant transport. Recently, a number of methods have been developed and subsequently applied to measure contaminant mass flux in groundwater in the field. Flux measurement methods can be categorized as either point methods or integral methods. As the name suggests, point methods measure flux at a specific point or points in the subsurface. To increase confidence in the accuracy of the measurement, it is necessary to increase the number of points (and therefore, the cost) of the sampling network. Integral methods avoid this disadvantage by using pumping wells to interrogate large volumes of the subsurface. Unfortunately, integral methods are expensive because they require that large volumes of contaminated water be extracted and managed. Recent work has investigated the development of an integral method that does not require extraction of contaminated water from the subsurface. We begin with a review of the significance and importance of measuring groundwater contaminant mass flux. We then review groundwater contaminant flux measurement methods that are either currently in use or under development. Finally, we conclude with a qualitative comparison of the various flux measurement methods.

지리정보시스템을 활용한 서울시 유해대기오염물질 우선순위 측정지역 선정 (Selection of Priority Monitoring Areas for Hazardous Air Pollutants (HAPs) in Seoul using Geographic Information System)

  • 김성준;박현진;이상진;김창혁;이승복;최성득
    • 한국대기환경학회지
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    • 제34권2호
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    • pp.223-232
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    • 2018
  • As the Seoul metropolitan city has the largest numbers of population and vehicles, the citizens can be exposed to hazardous air pollutants(HAPs) mainly from the vehicular exhaust and human activities. In this study, we proposed a systematic method for the selection of priority monitoring areas for HAPs using Geographic Information System (GIS). First, emission parameters(emission data, vehicle registration, monitoring data, and so on) and population parameters (population and population density) were plotted using the inverse distance weighted (IDW) interpolation. Then, the interpolation data for individual parameters, which were normalized between 1 and 5 points, were compiled for 270 grids with a resolution of $2km{\times}2km$. The total score of each grid was calculated using weights(1~5) for the individual parameters. The final ranking of each grid was assigned by four scenarios with varying fractions of the emission and population parameters from 50 : 50 to 80 : 20. Consequently, nine grids were suggested as priority monitoring areas, and all of them are located in the southwestern part of Seoul.

새로운 기준 전압 인가 방법을 사용하는 8b 200MHz 시간 공유 서브레인징 ADC (An 8b 200MHz Time-Interleaved Subranging ADC With a New Reference Voltage Switching Scheme)

  • 문정웅;양희석;이승훈
    • 전자공학회논문지SC
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    • 제39권4호
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    • pp.25-35
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    • 2002
  • 본 논문에서는 단일 폴리 공정을 기반으로 하여 8b 해상도로 200MHz의 고속 동작을 하기 위해 최적화된 시간 공유 서브레인징 ADC(Analog-to-Digital Converter)를 제안한다. 제안하는 ADC는 높은 정확도를 요구하는 하위 ADC에 이중 채널 구조를 적용하여 높은 샘플링 주파수를 보장하였고, 새로운 기준 전압 인가 방식을 적용하여 기준 전압의 빠른 정착 시간을 얻으면서 동시에 칩 면적을 크게 감소시켰다. 기준 전압을 생성하는 저항열에서는 선형성 및 속도 향상을 위해 기존의 인터메쉬드 구조를 보완한 새로운 저항열을 사용하였다. 8 비트 수준의 정밀도에서 면적 및 전력 소모를 최소화하기 위해 공통 드레인(common- drain) 증폭기 구조를 사용하여 샘플-앤-홀드 증폭기(Sample-and-Hold Amplifier:SHA)를 설계하였으며, 입력단에 스위치와 캐패시터로 구성된 동적 공통 모드 궤환 회로(Dynamic Common Mode Feedback Circuit)를 사용하여 SHA의 동적 동작 범위(dynamic range)를 증가시켰다. 동시에 상위 ADC와 하위 ADC간의 신호 처리를 단순화시키기 위해 상위 ADC에 새로운 인코딩 회로를 제안하였다.

SMAP 토양수분을 위한 Landsat 기반 상세화 기법 개발 (Development of Landsat-based Downscaling Algorithm for SMAP Soil Moisture Footprints)

  • 이태화;김상우;신용철
    • 한국농공학회논문집
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    • 제60권4호
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    • pp.49-54
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    • 2018
  • With increasing satellite-based RS(Remotely Sensed) techniques, RS soil moisture footprints have been providing for various purposes at the spatio-temporal scales in hydrology, agriculture, etc. However, their coarse resolutions still limit the applicability of RS soil moisture to field regions. To overcome these drawbacks, the LDA(Landsat-based Downscaling Algorithm) was developed to downscale RS soil moisture footprints from the coarse- to finer-scales. LDA estimates Landsat-based soil moisture($30m{\times}30m$) values in a spatial domain, and then the weighting values based on the Landsat-based soil moisture estimates were derived at the finer-scale. Then, the coarse-scale RS soil moisture footprints can be downscaled based on the derived weighting values. The LW21(Little Washita) site in Oklahoma(USA) was selected to validate the LDA scheme. In-situ soil moisture data measured at the multiple sampling locations that can reprent the airborne sensing ESTAR(Electronically Scanned Thinned Array Radiometer, $800m{\times}800m$) scale were available at the LW21 site. LDA downscaled the ESTAR soil moisture products, and the downscaled values were validated with the in-situ measurements. The soil moisture values downscaled from ESTAR were identified well with the in-situ measurements, although uncertainties exist. Furthermore, the SMAP(Soil Moisture Active & Passive, $9km{\times}9km$) soil moisture products were downscaled by the LDA. Although the validation works have limitations at the SMAP scale, the downscaled soil moisture values can represent the land surface condition. Thus, the LDA scheme can downscale RS soil moisture products with easy application and be helpful for efficient water management plans in hydrology, agriculture, environment, etc. at field regions.

대기 중 폴리브롬화디페닐에테르의 소나무 잎, 소나무 껍질 및 토양으로의 침착 특성 (Depositional Characteristics of Atmospheric PBDEs on Pine Needles, Bark and Soil)

  • 천만영
    • 한국환경보건학회지
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    • 제40권3호
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    • pp.215-224
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    • 2014
  • Objective: This study was carried out in order to determine the depositional characteristics of pine needles, pine bark, and soil used as a passive air sampler (PAS) for atmospheric polybrominated diphenyl ethers (PBDEs). Methods: All three media were sampled from the same site. The PBDE concentrations were analyzed by HRGC/HRMS, and the lipid contents were measured using the gravimetric method by n-hexane extraction. Results: The total PBDE concentration was the highest in soil (22,274.57 pg/g dry), followed by pine bark (20,266.39 pg/g dry), and then pine needles (7,380.22 pg/g dry). Pine needles contained the highest lipid contents (21.31 mg/g dry), whereas soil (10.01 mg/g dry), and pine bark (4.85 mg/g dry) contained less. There were poor correlations between lipid content and total PBDE concentrations in the media ($R^2$=0.8216, p=0.2814). Congeners BDE 47, 99, 183, 196, 197, 206, 207 and 209 showed peak concentrations. Among these, BDE 206, 207, and 209 are highly brominated PBDEs that exist as particulates in ambient air. They accounted for 81.2% [69.2 (pine needles) - 89.0% (tree bark)] of the concentration and therefore are noted as the main congener of the total PBDEs. Conclusions: It can therefore be concluded that for reducing error by improper sampling, the same species of media should be recommended for use as a PAS for atmospheric PBDEs due to the differences in depositional characteristics.

상시미동 측정을 통한 천부 횡파속도 연구 (Shallow Shear-wave Velocities Using the Microtremor Survey Method)

  • 황윤구;김기영
    • 지질공학
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    • 제16권4호
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    • pp.381-392
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    • 2006
  • 상시미동을 이용하는 수동적 표면파 탐사를 결정질암 기반암 지역에서 실시하여, 내진설계 지반분류 기준인 30 m 깊이까지의 평균 횡파속도(Vs30)를 구하고자 연구를 수행하였다. 시험자료는 조사지 A와 B에서 삼각형 배열과 'L' 자형 직각 배열로 2 ms 간격으로 4초 동안 기록하였다. 조사지 A에서 기록한 자료를 공간 자기상관 방법으로 분석하여 위상속도 스펙트럼을 작성하고, 수신기 배열의 길이 및 형태, 기록 횟수, 수신기 수 등의 주요인자들의 영향을 고찰하였다. 조사지 B에서 상시미동 기록자료의 역산을 통해서 구한 횡파속도와 근처 시추공에서 수직탄성파 방법으로 구한 결과가 대체로 일치함을 보여 상시미동을 이용한 표면파 탐사법이 Vs30을 구하는데 효율적인 방법으로 판단된다.

여대생의 스트레스와 대처방식이 건강관련 행동에 미치는 영향 (The Effect of Stress and Stress Coping Method on Health Related Behavior in Female University Students)

  • 최은영;김혜숙;박영미
    • 한국학교보건학회지
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    • 제20권1호
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    • pp.103-111
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    • 2007
  • Purpose : The purpose of this study was to investigate the effects of stresses to female university students and their habits of dealing with stresses through drinking alcohol and smoking. Methods : Subjects, 313 students, were selected through convenience sampling method from the 2 four-year universities in Chonbuk and Chonnam province from May to June, 2005. Data were collected through the structured questionnaires that include general characteristics, Quantity Frequency methods, the number of cigarette per day, campus stress scale, and stress coping style scale, and they were analyzed by Cronbach' alpha, descriptive statistics, ANOVA and t-test by using SPSS/PC+ program. Results: In this study, 80% of subjects have drunk alcohol. The mean frequency of drinking alcohol per month was 4.68 times and the mean number of alcohol consumption amount per drinking 6.16 glasses. The rate of smoking was 13.7%, and the mean number smoking cigarette per day in the previous month was 12.4. The mean score of stress was 2.20. Among 8 sub-factors of stress, study related stress scored highest among the sub-factors. The mean score of coping styles was 2.50. Among 4 coping styles, hopeful thought was mostly used. Among stresses, the concern of one's future affected her drinking habits. Faculty relationship, academic problem, and value affected smoking habits. Hopeful thought comes out to affect smoking, while drinking, perceived health status, and practice time showed no relationship with coping style. Conclusion: Based on the results, developing a life stress counseling program and effective coping program for women's university students is imperative, especially for those of who show passive attitude toward stress and solve it emotionally instead of using problem-oriented methods. Also, it will be necessary to study further nursing intervention to curb university females' drinking alcohol and smoking.

지하수 내 중금속 모니터링을 위한 diffusive gradients in thin films의 적용 가능성 평가 (Feasibility of Diffusive Gradients in Thin Films for Monitoring Heavy Metals in Groundwater)

  • 심규영;박광진;이승우;최종민;최수빈;안진성;남경필
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제29권4호
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    • pp.12-20
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    • 2024
  • Diffusive gradients in thin films (DGT) are passive sampling devices used to determine the time-weighted average concentrations (TWAC) of contaminants. To ensure accurate performance in groundwater, it is crucial to identify environmental characteristics and maintain optimal operational conditions. This study examined the deployment time required to reach effective capacity, the thickness of the diffusive boundary layer (DBL) under stagnant water conditions, and biofilm formation on the DGT surface using groundwater samples. When using DGT with Chelex gel (A=3.14 cm2), the effective capacity was 0.7 ㎍ for Cd and 250 ㎍ for Zn, with a deployment time of 24 h. Lower Cd accumulation was due to the competition effect of coexisting ions. The DBL thickness under stagnant conditions was 0.074 cm, 93% of the diffusion gel's thickness (0.08 cm). Neglecting DBL thickness in TWAC calculations led to a 79% decrease in the determined concentration. No biofouling was observed during the 28-d DGT deployment in groundwater. In conclusion, it is essential to consider the appropriate deployment time, DBL thickness, and biofilm formation to ensure accurate DGT performance in determining contaminant levels in groundwater.