• Title/Summary/Keyword: Particle dispersion

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Monitoring of the Fugitive and Suspended Dust Dispersion at the Saemangeum Reclaimed Land and Neighboring Farm areas (새만금 지역 간척지 및 인근 농경지에서의 비산 및 부유먼지의 지역별, 시기별 모니터링)

  • Hwang, H.S.;Lee, I.B.;Shin, M.H.;Lee, G.Y.;Hong, S.W.;Seo, I.H.;Yoo, J.I.;Bitog, J.P.;Kwon, K.W.;Kim, Y.H.
    • Journal of The Korean Society of Agricultural Engineers
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    • v.51 no.5
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    • pp.9-17
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    • 2009
  • A study on fugitive dusts was conducted at Saemangeum reclaimed land and the neighboring farm located at the west coast of Korea. After the area was completely reclaimed in 2006, halophyte plants and several windbreak systems were installed. The distributions of suspended dust particle was regularly measured through field experiment. The size of dust source area was also analyzed periodically and then it was determined to be in the following order: Buan > Gimje > Gunsan. The suspended dust which were dispersed to the neighboring areas were significantly affected by the size of the soil particles, wind velocity and wind direction. The results of Big Spring Number Eight (BSNE) experiments also showed that the concentration of the fugitive dust generated from the reclaimed land was reduced remarkably by the presence of halophyte plants. Recently, in 2008, the measured dust concentration rate was decreased by an average of 30.6%. The average dust concentration is expected to decrease further as more areas are being covered by halophyte plants.

Spray characteristics on mixing region scale of twin fluid atomizer (이류체 분사노즐의 혼합영역 형상에 따른 분무특성)

  • 김병문;김혁주;이충원
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.6
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    • pp.2147-2159
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    • 1991
  • The effects of principal dimensions of internal mixing twin-fluid atomized and operating conditions on the atomizing characteristics are experimentally investigated. The tests are conducted over the wide range of air/liquid ratio to predict influences of the diameter and length of nozzle, contacting angle between air and liquid in the mixing chamber, and air orifice diameter on the mean drop size(SMD), spray angle, distribution of drop size, and spray dispersion, And also, initial distribution of liquid column by air stream within the mixing chamber are observed through the transparent nozzles. A He-Ne laser particle sizer(MALVERN Model 2604) was used to measure the Sauter.s mean diameter( $D_{321}$) and droplet sizes distribution. In this experiment the air/liquid ratio, mixing length and nozzle diameter have a great influence on SMD, spray angle, droplet sizes distribution and spray dispersion.

Analysis of Hybrid Emulsion Surfaces by the Phase Lag Mapping Atomic Force Microscopy (위상지연 원자간력 현미경법에 의한 혼성 에멀젼 표면의 분석)

  • Han, Sang-Hoon;Kim, Jong-Min;Park, Dong-Won
    • Applied Chemistry for Engineering
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    • v.17 no.4
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    • pp.381-385
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    • 2006
  • We applied a new analyzing technique for the polyurethane acrylate hybrid emulsion sample composed of polyurethane resin and acrylate resin using the phase-lag mapping techniques of atomic force microscopy. For the analysis, we synthesized similarly sized pure polyurethane dispersion and acrylate emulsion particles, which were used for measuring the standard phase-lag intensities for each material. Based on these signal intensity, we could discriminate acryl particle in the polyurethane dispersion matrix with the resolution of a few tens of nanometers. Thus, the techniques show a new possibility in the analysis of the organic two-phase particles, and we believe the techniques are helpful to design organic particles.

Simulation and Modeling of Polyethylene/Clay Nanocomposite for Dielectric Application

  • Zazoum, Bouchaib;David, Eric;Ngo, Anh Dung
    • Transactions on Electrical and Electronic Materials
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    • v.15 no.4
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    • pp.175-181
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    • 2014
  • In this paper, the simulation and modeling of a polyethylene/clay nanocomposite were undertaken to predict the nanocomposite's dielectric behavior and to help design a nanocomposite material with optimum electrical properties for electrotechnical or electronic applications. A 3-D simulation model using the finite elements method was employed in order to study the effective permittivity and electric field distribution of two-phase nanocomposite materials for ordered and random distributions of inclusions in a low-loss host matrix such as polyethylene. The influence of the dispersion of reinforcing particles, and of the permittivity and radius of the inclusions, was analysed. The simulation results were compared with alternative, known theoretical solutions obtained from classical models, and were found to be in good agreement. The numerical results also indicate that for fixed volume fractions of nanoparticles the effective permittivity of the mixture, for ordered and random distributions, does not vary with the degree of dispersion. The variation of the effective permittivity with the particle radius is shown, using numerical data, to agree with the analytical modules.

Effect of Ball milling Time on Graphite Dispersion and Mechanical Properties in Rapidly Solidified 6061 Al Composite (급속응고 6061Al/Graphite 복합재료의 볼밀링 시간에 따른 흑연 분산거동 및 기계적 특성)

  • Son, Hyeon-Taek;Lee, Jae-Seol;Hong, Soon-Jik;Chun, Byong-Sun
    • Journal of Powder Materials
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    • v.16 no.3
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    • pp.209-216
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    • 2009
  • A composite of rapidly solidified Al-6061 alloy powder with graphite particle reinforcements was prepared by ball milling and subsequent hot extrusion. The microstructure and mechanical properties of these composites were investigated as a function of milling time. With increasing milling time, the gas atomized initially and spherical powders became elongated with a maximum aspect ratio after milling for 30 h. Then, refinement and spheroidization were achieved by further milling to 70 h with a homogeneous and fine dispersion of graphite particles forming between the matrix alloy layers. The best compression and wear properties were obtained in the powder milled for 70 h, associated with the increased fine and homogeneous distribution of graphite particles in the aluminum alloy matrix.

Effect of Preparation Conditions on the Hydrogenation Activity and Metal Dispersion of Pt/C and Pd/C Catalysts

  • Jhung, Sung-Hwa;Lee, Jin-Ho;Lee, Jong-Min;Lee, Ji-Hye;Hong, Do-Young;Kim, Myong-Woon;Chang, Jong-San
    • Bulletin of the Korean Chemical Society
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    • v.26 no.4
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    • pp.563-568
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    • 2005
  • The Pt/C and Pd/C catalysts were prepared from conventional chloride precursors by adsorption or precipitation-deposition methods. Their activities for hydrogenation reactions of cyclohexene and acetophenone were compared with those of commercial catalysts. The Pt/C and Pd/C catalysts obtained from the adsorption procedure reveal higher hydrogenation activity than commercial catalysts and the catalysts prepared by the precipitation-deposition method. Their improved performances are attributed to the decreased metal crystallite sizes of Pt or Pd formed on the active carbon support upon the adsorption of the precursors probably due to the same negative charges of the chloride precursor and the carbon support. Under the preparation conditions studied, the reduction of the supported catalysts using borohydrides in liquid phase is superior to a gas phase reduction by using hydrogen in the viewpoint of particle size, hydrogenation activity and convenience.

Surface Morphology Control of Monodisperse Crosslinked-Polymer Particle (단분산 가교고분자 미립자의 표면 모폴로지 제어 연구)

  • Kim, Dong-Ok;Jin, Jeong-Hee;Oh, Seok-Heon
    • Polymer(Korea)
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    • v.30 no.1
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    • pp.50-55
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    • 2006
  • When the monodisperse polystyrene(PS)/HDDA polymer particles were synthesized via one-step polymerization using polystyrene seed particles by dispersion polymerization, the effects of 1) the molecular weight of seed polymer particles, 2) the ratio of the absorbed HDDA to the seed polymer particles (swelling ratio) and 3) seeded polymerization rate on the surface morphology of PS/HDDA polymer particles were investigated. It was observed that the creation of the crater shaped defect on the surface of PS/HDDA polymer particles was irrespective of the molecular weight of seed polymer ant swelling ratio. But its surface morphology could be controlled by the change of the seeded polymerization rate.

Optimum Coagulation of Water Treatment Plant using On-line Floc Monitoring System (정수장 응집제주입 최적화를 위한 플럭 모니터링)

  • Hwang, Hwando;Lim, Sangho;Sung, Kyujong;Han, Youngjin;Kim, Youngbeom;Kwak, Jongwoon
    • Journal of Korean Society of Water and Wastewater
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    • v.23 no.4
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    • pp.397-406
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    • 2009
  • This study was conducted to monitor the floc sizes forming in the mixing zone in the water treatment plant. The dosing amount of poly aluminium chloride(PAC) was determined by particle dispersion analyzer(iPDA) in the lab and field scale test. During a field test period, PAC coagulant was used and the raw water was taken from Nakdong river. PAC wad diluted to activate the coagulant, leading to bring the more homogeneous dispersion in the shorter time. To monitor the floc sizes, the unit of floc size index(FSI) was used. With increasing of raw water turbidity, FSI value was increased. Also, the increased dosing amount of PAC brought the increased FSI and with overdosing of coagulant was in turn decreased. When the PAC was fed into the raw water after dilution in a field scale test, the width of FSI was narrower compared with the feeding of the mother liquor of PAC, implying that the formed flocs are denser and more uniform sizes. The width of FSI in average was varied on depending on the basicity of coagulant. Also, dF value, fractal dimension was evalued with the different coagulants, showing from 2.01 to 2.03. On-line floc monitor was effective for the optimal dosing in the drinking water plant.

Effect of Soft Segment Length on the Dispersion and Physical Properties of Polyurethane Ionomer (Soft Segment 길이가 Polyurethane Ionomer의 분산특성 및 물리적 특성에 미치는 영향)

  • Kim, Byung Kyu
    • Textile Coloration and Finishing
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    • v.5 no.4
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    • pp.60-66
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    • 1993
  • Aqueous polyurethane(PU) anionomer dispersions were prepared from isophorone diisocyanate (IPDI), polytetramethylene adipate glycol(PTAd) and dimethylol propionic acid(DMPA) as potential anionic centers. The effects of polyol molecular weight(Mn) on the state of dispersion, thermal, mechanical, and viscoelastic properties and swelling of emulsion cast film were determined. With increasing Mn of PTAd, particle size of emulsion and soft segment T$_{g}$ decreased, and solvent swell, emulsion viscosity, and hard segment $T_{g}$ increased. Tensile strength showed minimum with PTAd 1000, and elongation at break generally increased with the Mn of PTAd. These results were possibly nterpreted in terms of soft segment-hard segment phase separation and crystallization of high molecular weight PTAd.

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Geochemical Dispersion of Cu, Pb, Zn, and Cd and Their Mode of Occurrences in Soils and Dusts in Changhang Smelter Area (장항제련소 지역 토양과 분진중의 Cu, Pb, Zn 및 Cd의 지구화학적 분산과 산출상태)

  • Kim, Ju-Yong;Chon, Hyo-Taek
    • Economic and Environmental Geology
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    • v.26 no.2
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    • pp.175-185
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    • 1993
  • Soils and dusts collected from Changhang smelter area were analyzed for Cu, Pb, Zn, and Cd in order to determine their dispersion pattern and mode of occurrences, and to investigate the pollution level of heavy metals such as Cu, Pb, Zn, and Cd by smelting activity. The soil pH of Changhang area is in the range of 3.7~8.8, and increased with increasing distance from the smelter site. The particles containing heavy metals are several tens of ${\mu}m$ in diameter, and have well crystal form. Samples collected near the smelter show similar particle properties in size, shape, and composition, which means that they could be originated from the same contamination source. Element couples of Cu, Pb, Zn, and Cd indicate high correlation with each other, which means that Cu, Pb, Zn, and Cd could be originated from the same point source of smelter. Heavy metal contents were decayed to background levels from 2.5 kilometer away from the smelter.

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