• Title/Summary/Keyword: Particle Growth

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Making Hygiene Paper by Surface Modification Method of the Functional Particle (기능성 미립자의 표면개질방법에 의한 위생지 제조)

  • Cho, Jun-Hyung;Kim, Yeon-Oh;Kim, Won-Duck
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.40 no.2
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    • pp.29-36
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    • 2008
  • In order to give pulp surfaces anti-bacterial functionality and photo-catalytic deodorant ability, functional pulps was made using a surface modification method with Ag nano-colloidal solution and $TiO_2$ filler. Hygiene paper was made with the specially modified pulp, and anti-bacterial and deodorant tests were carried out. The Ag nano-colloidal solution was coated on the surface of the pulp using the high pressurized gas phase squirt through the spray nozzle mounted on the hybridization system. The surface modified functional pulp was hybridized with the optimum ratio of $TiO_2$(fine particle) to pulp(core particle) under the condition of $6,000{\sim}10,000$ rpm for $3{\sim}7$ minutes in the system. The anti-bacterial functionality of the hygiene paper was confirmed by the halo test in which the formation of the clear zone around the hygiene paper sample was observed. The inhibition growth test using MIC bioscreen C showed the inhibition growth effect of the bacteria as the reaction time was increased. The photo-catalytic effect measurement of the $TiO_2$ for 4 hours of the reaction showed $50{\sim}60%$ of decomposition rate, reaching over 60% for 5 hours of the reaction.

Kinetics of Seed Growth of α-Ferric Oxyhydroxide (α-Ferric oxyhydroxide 입자의 핵성장 반응에 관한 연구)

  • Seul, Soo-Duk;Shin, Dong-Ock
    • Applied Chemistry for Engineering
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    • v.8 no.4
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    • pp.602-609
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    • 1997
  • The seed formation and growth of $\alpha$-ferric oxyhydroxide with aerial oxidative precipitation from aqueous solution of ferrous sulfate with KOH, NaOH, $Na_2CO_3$ and $K_2CO_3$ as precipitants have been studied by free pH drift experiment. It has been shown that all precipitants give same particle formation and growth path, and average particle length from KOH and NaOH as precipitants was about 1.5 times shorter than that of $K_2CO_3$ and $Na_2CO_3$. When initial mole ratio, $R_o=[Fe^{2+}]_o/[OH^-]_o$ of KOH was decreased the particle was grown oxyhydroxide seed growth from aqueous solution of ferrous sulfate with KOH has been studied. The influence of the air flow rate, reaction temperature and initial mole ratio, $R_o=[Fe^{2+}]_o/[OH^-]_o$, on the kinetics of seed growth are investigated by static pH experiment. The oxidation rate of seed growth increased with increase in the air low rate, reaction temperature and initial mole patio. The activation energy of seed growth is 16.16 KJ/mol and the rate equation of seed growth can be written as follows: $-\frac{d[Fe^{2+}]}{dt}=1.46{\times}10^4[P_{o2}]^{0.66}[OH^-]^{2.19}exp(-\frac{16.16}{dt})$.

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Particle Contamination in PCVD Reactor for Semiconductor Processing (반도체 제조용 PCVD 반응기에서의 미립자 오염)

  • Kim, Dong-Joo;Kim, Kyo-Seon
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1492-1494
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    • 1996
  • We have studied the generation, growth and behavior of chemical species and particles in silane PCVD. We included the plasma chemistry of silane, particle nucleation by homogeneous formation, acrosol dynamics and transport phenomena of chemical species and particles. The concentration profile of chemical species and particles were shown as a function of reactor length. The effects of process variables such as reactor pressure, total gas flow rate and electrical field strength on the behavior of chemical species and particles were analyzed.

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Microstructural Change of Doped-Alumina Membrane (도핑된 알루미나 여과막의 미세구조 변화)

  • 이진하;최성철;한경섭
    • Journal of the Korean Ceramic Society
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    • v.36 no.10
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    • pp.1040-1047
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    • 1999
  • After alumina sol was prepared by Yoldas process supported membranes were fabricated by adding ce and Re solution and SiO2 sol into alumina sol. The particle size of alumina sol was 11 nm and it was monodispersed transparent and stable for long time. The pore size of un-doped membrane started to increase to about 7,5nm at 1000$^{\circ}C$ and it was grown to twice (about 15nm) at 1100$^{\circ}C$ However the pore size of doped alumina was uniform to 1100$^{\circ}C$. The effect of retardation of grain growth was superior in SiO2 addition to that of Ce and Ru Because SiO2 doped samples transformed to needed-like phase and densified at 1200$^{\circ}C$ their application in membranes was limited. Ce and Ru doped sample showed vermicular structure identical to the un-doped ones at 1200$^{\circ}C$ But the particle size was smaller than that of un-doped ones.

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A Test of Two Models for the Bacteria Flux across the Sediment/Water Interface in an Effluent-dominated Stream (하수처리 방류 소하천내 퇴적물로부터의 박테리아 유출 플럭스모델 비교)

  • Ahn, Jong-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.2
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    • pp.165-172
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    • 2010
  • Treated sewage could enable growth by providing key nutrients or seeding the sediments with enterococci strains that can grow in the environment. This study is to test the hypothesis that the flux of bacteria into the water column is rate-limited by the transfer of bacteria across the sediment/water interface. Two conceptual models are derived for the transfer of bacteria to the water column from the sediment/water interface: convective diffusion of isolated bacteria and resuspension of particle-associated bacteria. The model predictions are directly tested together with field measurements of bacteria and sediment in an effluent-dominated stream where high concentrations of enterococci in this stream originate primarily from growth of the bacteria in stream sediments. The results reveal that high concentrations of enterococci in this stream are transported primarily by resuspension of particle-associated bacteria accumulated at the sediment/water interface, either in the form of bacterial aggregates or in the form of inorganic particles.

Development of functional microsphere (I) - Formation and characteristics of poly(ethylene-co-vinyl acetate) microspheres via thermally induced phase separation - (기능성 마이크로스피어의 개발 (I) - 열유도 상분리에 의한 Poly(ethylene-co-vinyl acetate) 마이크로스피어의 제조와 특성 -)

  • 이신희;김효정;박수민
    • Textile Coloration and Finishing
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    • v.15 no.4
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    • pp.57-64
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    • 2003
  • Poly(ethylene-co-vinyl acetate)(EVA) microspheres were prepared by a thermally induced phase separation. The microsphere formation occurred by the nucleation and growth mechanism in the metastable region. The diluent used was toluene. The microsphere formation and growth was followed by the cloud point of the optical microscope measurement. The microsphere size distribution, which was obtained by SEM observation and particle size analyzer, became broader when the polymer concentration was higher, the content of vinyl acetate in EVA copolymer was higher, and the cooling rate of EVA copolymer solution was lower.

Diameter Control of Carbon Nanotubes Using Surface Modified Fe Nano-Particle Catalysts with APS (APS로 표면 처리한 Fe 나노 입자 촉매를 이용한 CNT의 직경제어)

  • Lee, Sunwoo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.6
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    • pp.478-481
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    • 2013
  • Diameter controlled carbon nanotubes (CNTs) were grown using surface modified iron nano-particle catalysts with aminpropyltriethoxysilane (APS). Iron nano-particles were synthesized by thermal decomposition of iron pentacarbonyl-oleic acid complex. Subsequently, APS modification was done using the iron nano-particles synthesized. Agglomeration of the iron nano-particles during the CNT growth process was effectively prevented by the surface modification of nano-particles with the APS. APS plays as a linker material between Fe nano-particles and $SiO_2$ substrate resulting in blocking the migration of nano-particles. APS also formed siliceous material covering the iron nano-particles that prevented the agglomeration of iron nano-particles at the early stages of the CNT growth. Therefore we could obtain the diameter controlled CNTs by blocking agglomeration of the iron nano-particles.

Development of functional microsphere(II) - Formation and Characteristics of Poly(ethylene-co-vinylacetate) Microsphere with Pigment - (기능성 마이크로스피어의 개발(II) - 안료를 함유한 에틸렌-비닐아세테이트 공중합체의 마이크로스피어 제조와 특성 -)

  • Lee, Shin-Hee;Park, Soo-Min
    • Textile Coloration and Finishing
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    • v.17 no.4 s.83
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    • pp.15-20
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    • 2005
  • Poly(ethylene-co-vinylacetate)(EVA) microspheres were prepared by thermally induced phase separation in toluene. The microsphere formation occurred by the nucleation and growth mechanism in metastable region. The effects of the polymer or pigment weight percentage and cooling rate on microsphere formation were investigated. The microsphere formation and growth were followed by the cloud point of the optical microscope measurement. The microsphere size distribution, which was obtained by particle size analyzer, became broader when the polymer concentration was higher, the pigment concentration and the cooling rate of EVA copolymer solution were lower.

Glycothermal Synthesis of Ultrafine ZnFe2O4 power

  • Bae, Dong-Sik;Han, Kyong-Sop;Park, Sang-Hael
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1996.06a
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    • pp.497-501
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    • 1996
  • The ZnFe2O4 powder were prepared under glycothermal conditions by precipitation from metal nitrates with aqueous potassium hydroxide. Ultrafine particles of the ZnFe2O4 were obtained at temperatures as low as 225-300$^{\circ}C$. The microstructure and phase of the ZnFe2O4 powder was studied by SEM and XRD. The properties of the powder were studied as a function of various parameters (reaction temperature, reaction time, solid loading). The average particle diameter of the ZnFe2O4 increased with increasing reaction temperature. After glycothermal treatment at 270$^{\circ}C$ for 8hrs., the average particle diameter of the ZnFe2O4 was about 50 nm.

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Reduction of Soot Emitted from a $C_2$$H_4$ Normal Diffusion Flame with Application of DC Corona Discharge (DC 코로나 방전이 적용된 에틸렌 정상 확산 화염의 Soot 배출 저감)

  • Lee, Jae-Bok;Hwang, Jeong-Ho
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.4
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    • pp.496-506
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    • 2001
  • The effect of corona discharge on soot emission was experimentally investigated. Size and number concentrations of soot aggregates were measured and compared for various voltages. Regardless of the polarity of the applied voltage, the flame length decreased and the tip of flame spreaded with increasing voltage. For the experimental conditions selected, the flame was blown off toward the ground electrode by corona ionic wind. When the negative applied voltage was greater than 3kV(for electrode spacing = 3.5cm), soot particles in inception or growth region were affected by the corona discharge, resulting in the reduction of number concentration. The results show that the ionic wind favored soot oxidation and increased flame temperature. Number concentration and primary particle size greatly increased, when the corona electrodes were located the region of soot nucleation or growth(close to burner mouth).