• 한국산학기술학회논문지
• /
• 제13권8호
• /
• pp.3800-3805
• /
• 2012

본 논문에서는 도심 열섬현상 방지 및 에너지 효율을 높이기 위하여 적외선 반사율이 30%이상인 건물 내 외장재용 흑색 차열안료 및 도료에 대한 연구를 하였다. 안료는 $Fe_2O_3$과 $Cr_2O_3$의 혼합원료를 $900{\sim}1,200^{\circ}C$에서 소성하여 합성하였으며, 도료는 합성한 안료에 아크릴수지와 기타첨가제를 사용하여 제조하였다. 연구결과, Cr과 Fe을 1:0.9 몰비로 혼합하여 $1,000^{\circ}C$에서 소성한 안료의 발색도가 가장 우수하였고, 차열안료 20%에 분산제 1.5%를 첨가하여 제조한 차열도료로 $125{\mu}m$ 두께의 도막을 형성시켰을 때 적외선 반사가 가장 우수하였다. 차열도료와 일반도료의 표면온도 차이는 $36.5^{\circ}C$로 나타났으며 700~2,500nm 파장대의 적외선 반사율(TSR)은 39.3%로 측정되었다. 또한, 500시간의 내후성 평가에서 색상변화는 거의 나타나지 않았다.

• 보존과학연구
• /
• 통권21호
• /
• pp.119-143
• /
• 2000

The pigments composition and structure of the mural painting at Pongjongsa Kuknakjon is discussed. The structure of inner wall is consisited of Paint layer, Ground divided two layers of yellow and white pigments, Support. In case of outer wall, it is consisted of Paint layer, Ground divided three layers of yellow and green pigments, a layer mixed green pigments and paint layer, Support. As a result of compositon analysis of mural painting pigments at Pongjongsa Kuknakjon using Micro-area X-ray diffraction system, the red pigment on inner wall is consisted of Heamatite($Fe_2O_3$), Magnetite($Fe_3O_4$)of deep black pigment, and Chalcocite($Cu_2S$) of light black pigment. The white pigment on outer wall is consisted of Anglesite($PbSO_4$) and Atacamite($Cu_2CI(OH)_3$) of green pigment. We found out that natural pigments painted in the mural painting at Pongjongsa Kuknakjon has kept up its own color for a long time due to using the natural pigment not to artificial synthetic pigment.

• 한국산업보건학회지
• /
• 제31권4호
• /
• pp.295-303
• /
• 2021

Objective: Paint manufacturing industry workers are exposed to various lung cancer carcinogenic substances including hexavalent chromium and crystalline silica. Studies have been conducted on lung cancer in Paint manufacturing industry workers and the concentration of hexavalent chromium in paint industry; however, the concentration of crystalline silica and hexavalent chromium and cases of lung cancer in a single Paint factory has never been reported in Korea. Methods: To determine whether the cancer was related to his work environment, we assessed the level of exposure to carcinogens during pouring and mixing talc and pigment. In addition, a mask fit test was performed for the worker. Results: Analysis of talc and silica bulk powder materials showed that crystalline silica (quartz) was 5% in talc and 100% in silica. The green and yellow pigments contained 87% and 92% of lead chromate, respectively. Our quantitative analysis of pigment powder samples showed that the hexavalent chromium contents quantified in the green and yellow pigment samples were 87% and 92%, respectively. In order to estimate his exposure level of hexavalent chromium, we measured a personal exposure level of hexavalent chromium for a worker in accordance with the National Institute for Occupational Safety and Health #7605 method. The results showed that the worker was exposed to the high level of hexavalent chromium (0.033 mg m-3). In addition, the talc powder also contained 5% quartz, and the worker's exposure level to respirable quartz exceeded OEL. As a result of the respiratory protection fit test for workers, the overall Fit Factor was '15' when wearing a second-grade mask and '25' when wearing a first-grade mask, significantly lower than the US Occupational Safety and Health Agency (OSHA) pass value of "100". Conclusion: Workers who pouring and mixing powder materials such as talc or colored pigments in paint manufacturing company may be exposed to high concentrations of carcinogenic substances. These findings indicate that it is necessary to local ventilation system inspection, safety and health education for employers and workers, and periodically monitoring and manage the working environment.

• 한국멀티미디어학회논문지
• /
• 제17권7호
• /
• pp.906-914
• /
• 2014

There are many studies to create realistic paint effects and the research area still has attracted attention in these days. However, the consideration for the characteristics of the real paint effects from the point of viewers is not enough. In this paper, we extract the important paint features and survey the importance values. Based on the survey results, we suggest a new paint system. The paint system utilizes the paint simulation that reflects viscoelasticity and mixing suggested by You et al. (2013) and proposes the paint rendering method that represents the details of a paint, a solvent, and pigments. We survey the quality of our results and prove that our paint system is superior to the previous studies.

• 한국산업보건학회지
• /
• 제18권4호
• /
• pp.293-302
• /
• 2008

Lead chromate is made by sodium dichromate and lead acetate, and has being used widely in the part of pigment, paints, inks, plastics and so on. Even though lead chromate has health hazards which like both lead and chromium, there are a few study about pigment workplaces using lead chromate in Korea. The purpose of this study is to evaluate workers' exposure levels and airborne lead and chromium concentration in the pigment workplaces using lead chromate. There are 20 workers in the total 5 workplaces. 10 workers(50%) have been exposed to lead and 3 workers(15%) have been exposed to chromium, which exceeded the American Conference of Governmental Industrial Hygienists(ACGIH) Threshold Limit Value (Pb: $0.05\;mg/m^3$, Cr: $0.012\;mg/m^3$) and Korean Ministry of Labor's Standard. Geometric mean (GM) of airborne lead was highest in pigment ($0.0421\;mg/m^3$), paint ($0.0020\;mg/m^3$) and PVC coloring ($0.0007\;mg/m^3$), respectively(p<0.05). The result of airborne chromium concentration was paint ($0.0033\;mg/m^3$), paint ($0.0004\;mg/m^3$) and PVC coloring ($0.0003\;mg/m^3$). Also the lead and chromium concentration in the manual process is each 30 times and 10 times higher than the value in automatic process(p<0.01). In the classified process by detail, the concentration of airborne lead was $0.0638\;mg/m^3$ in grinding & packaging, mixture & after-measuring ($0.0436\;mg/m^3$), filtration & drying ($0.0402\;mg/m^3$), lead nitrate & dissolution($0.0129\;mg/m^3$), pigment commitment & mixture ($0.0013\;mg/m^3$) and dispersion & grinding ($0.0010\;mg/m^3$) (p<0.05). Moreover the concentration of a sample in weighting & packaging was $0.0023\;mg/m^3$. The concentration of lead in workers' blood was pigment (15.12 ug/dl), paint (4.74 ug/dl) and PVC coloring (2.50 ug/dl), and some samples have exceeded biological exposure limit. In conclusion, the depending on their work industry and process, workers have been exposed to the high lead chromate.

• 한국자동차공학회논문집
• /
• 제18권5호
• /
• pp.130-135
• /
• 2010

Paint is used as top coat in Automobile Refinishing that is divided into 1K paint of base type and 2K paint of urethane type. after using 1K paint, it can be reusable. However 2K paint is not available that is mixed a certain amount of base with hardner, so 2K paint has to be used all at a time or discarded the rest. This study covered that colored Urethane paint and colorless urethane paint in top coating process of AR. Top coat urethane paint is divided into colored urethane paint and transparent urethane paint like clear coat. Colored urethane paint is used for paint that contains resin, pigment, solvent and additives. It is color such as black and white. While transparent urethane paint is used for paint that contains resin, solvent and additives. Urethane paint has a paint system that cur after several hours of mixing base and hardner. By a paint technician of a field and empirical data, we can also recognize that according to worker's paint style and experience, although he or she paint same car model and area, paint use of one's is different. There aren't guidelines workers refer to about paint use by car models and work scope because ARP works various car models that are in different color, size and area. After using urethane paint, the rest of paint has come, and there are highs and lows in paint use each time he or she works. Therefore, this study suggest a basic guideline to use paint efficiently and regularly by understanding area, the type of work, and paint use that are appropriate for each car model and regardless of workers and work scopes in AR.

• 한국도로학회논문집
• /
• 제17권5호
• /
• pp.67-73
• /
• 2015

PURPOSES : This study was conducted to derive the optimum mixing ratio of phosphorescent pigment for the development of phosphorescent line marking. METHODS: In this study, we utilized a literature review and case study methodology, to describe the domestic and foreign state of practice for the production and mixing of phosphorescent pigment for use in line marking. The optimal mixing ratio was derived by comparing the reduction in luminance over time for the various phosphorescent pigment mixing ratios identified in the literature. In addition, performance and construction characteristics were analyzed using field testing techniques. RESULTS : The results were as follows: 1) the results of the luminance performance standards tests showed that all of the phosphorescence test specimens satisfied the phosphorescent fire protection standard. As the phosphorescent pigment mixing ratio increased, the luminance value increased, 2) the luminance reduction rate was minimum at the mixing ratio of 50%. However, when compared to a mixing ratio 40%, a small difference was recorded, the luminance reduction rate from the mixing ratio of 40% is judged as being converged. Therefore, in view of the economic efficiency, it was determined that the optimal mixing ratio was 40%, 3) as a result of construction on the field, a mixing ratio of 40% was found to have a higher luminance value than the general line marking for up to three hours after sunset, 4) it was found that the phosphorescent line markings without glass beads spraying had a higher luminance value than the phosphorescent line markings with glass beads spraying. CONCLUSIONS : Through the results of the basic experiments of the line markings obtained by blending a phosphorescent pigment, the results could be applied to play an important role in the development of phosphorescent line marking paint technology and in establishing application planning for on-site construction characteristics.

• 대한환경공학회지
• /
• 제39권4호
• /
• pp.180-185
• /
• 2017

안료 페인트 생산 업체 7개를 방문하여 제품 21개(안료 17개, 페인트 4개)를 시료채취 하였으며, 대형 온라인 판매상을 통하여 50개 제품을 구매하였다. 총 71개 제품에 대하여 EPA 7473 방법으로 수은 함량분석을 하였고, 물질흐름 분석을 위한 폐기물 내 수은함량은 타 연구(2010)의 안료 페인트 제조 업체에서 발생되는 분진 슬러지 폐페인트 38건의 수은 함량 자료를 사용하였다. 물질흐름분석은 제품 또는 특정 화학물질을 대상으로 하는 Micro 수준의 물질흐름 추적방식을 이용하여 흐름도를 작성하였다. 수은분석 결과, 71개 제품에서 0~0.25 mg-Hg/kg, 38개 폐기물에서 0.23~0.69 mg-Hg/kg으로 나타났다. 물질흐름을 살펴보면 유통단계의 수은흐름량이 연간 10.06 kg인데 반해 폐기되는 수은의 양은 25.27 kg으로 유통량 보다 폐기량이 더 높게 나타났다. 이는 제품과 폐기물의 시료채취 시기가 달라 발생된 현상으로 제품은 2014년도 제품, 폐기물은 2010년 분석된 자료를 사용하여 RoHS 등과 같은 규제의 영향으로 수은 함유 페인트 제품이 감소됨에 따른 것으로 판단된다. 현재 생산되는 제품 중 수은의 농도는 매우 낮고 페인트에 의한 수은의 유출은 미미한 것으로 판단된다.

• 한국식품영양학회지
• /
• 제32권1호
• /
• pp.41-49
• /
• 2019

Carotene, xanthophyll, carotenoid anthocyan, phycopyrine, chlorophyll, and monascus pigments are used as natural coloring agents since they are more stable to human body than synthetic coloring agents. Among them, monascus pigments are a natural red pigment produced by the Monascus purpureus. For the development of edible paint using natural pigment, Monascus purpureus strain was cultured at a temperature of $35^{\circ}C$ for 15 days on a PDYA plate and liquid medium to produce a red pigment. In addition, a large amount of the red pigment was extracted from Hongkuk Koji in parallel with water extraction and ultrasonic wave extraction. At this time, the yield of ultrasonic extract was 2~4 times higher. Thus, Monascus purpureus strains, etc. were prepared by freeze-drying powder. In conclusion, natural paints made with red pigments have enabled the development of been edible paints that can be used as eco-friendly materials with good viscosity, enhanced spread ability and coloration.

• 박물관보존과학
• /
• 제15권
• /
• pp.66-77
• /
• 2014

국립중앙박물관에 소장되어 있는 은조사 구장복은 조선 말기에 고종이 착용하였던 것으로 기록된 구장문이 그려진 대례복의 하나이다. 이 장문은 왕이 나라를 통치함에 있어 필요한 덕목을 상징적으로 표현한 것으로, 적색·황색·청색·녹색, 회색의 안료로 채색되어 있다. XRF 분석 결과, 적색 안료는 진사/주, 황색 안료는 금·황동, 청색 안료는 청색 유기안료와 연백, 녹색 안료는 구리-비소로 구성된 합성안료인 양록, 회식 안료는 은으로 판단되었다. 또한 유사한 시기에 제작된 국립중앙박물관 소장 적의본과 폐슬본의 안료 성분을 비교 검토한 결과, 차이점과 유사점을 확인할 수 있었다. 이러한 분석 결과는 19세기 말 궁중에서 사용된 안료에 대한 기초적인 자료로 활용할 수 있을 것으로 기대된다.