• Title/Summary/Keyword: PROCESS ADDITIVES

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Preparation of Silicon Carbide Ceramic Thick Films by Liquid Process (액상공정을 이용한 탄화규소 세라믹 후막의 제조)

  • Kim, Haeng-Man;Kim, Jun-Su;Lee, Hong-Rim;Ahn, Young-Cheol;Yun, Jon-Do
    • Journal of the Korean Ceramic Society
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    • v.49 no.1
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    • pp.95-99
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    • 2012
  • Silicon carbide ceramics are used for oxidation resistive coating films due to their excellent properties like high strength, good oxidation resistance, and good abrasion resistance, but they have poor formability and are prepared by vapor process which is complicated, costly, and sometimes hazardous. In this study, preparation of silicon carbide coating film by liquid process using polymer precursor was attempted. Coating film was prepared by dip coating on substrate followed by heat treatment in argon at $1200^{\circ}C$. By changing the dipping speed, the thickness was controlled. The effects of plasticizer, binder, or fiber addition on suppression of crack generation in the polymer and ceramic films were examined. It was found that fiber additives was effective for suppressing crack generation.

The Electric Properties of SrTiO$_3$Varistor Prepared by Co-precipitation Process (공침법으로 제초한 SrTiO$_3$바리스터의 전기적 특성)

  • 이종필;신현창;최정철;최승철
    • Journal of the Microelectronics and Packaging Society
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    • v.7 no.3
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    • pp.7-11
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    • 2000
  • The low-voltage driven $SrTiO_3$ceramic varistor device was fabricated from $SrTiO_3$ powders prepared by co-precipitation method with $CuO-SiO_2$additives. Compare with conventional process, this process has advantages such as the reduction of the sintering temperature of $SrTiO_3$ ceramics by 100-$150^{\circ}C$ and the simplification of processing procedure. The non-linear coefficient value ($\alpha$) of the varistor showed 8.47 when it was sintered at $1350^{\circ}C$ for 2 h with 5 wt% additives in reducing atmosphere of 5% $H_2/N_2$ mixed gas. The low-voltage driven $SrTiO_3$ceramic varistor was obtained which has a breakdown voltage as low as 7 V.

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Physical Properties of Pulp Extrudates Mixed with Expanding Additives (팽연보조재 혼합에 따른 펄프압출물의 물리적 특성)

  • Song D. B.;Kim C. H.;Jung H. S.;Lee Y. M.
    • Journal of Biosystems Engineering
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    • v.30 no.5 s.112
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    • pp.285-292
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    • 2005
  • Extrusion process and physical properties of extrudates of pulp powder (TMP, thermomechanical pulp fibers) mixed with expanding additives was evaluated to develop biodegradable packaging materials. To find out the optimum condition, the status of extrusion process, coefficient of elastic and expansion ratio of extrudates were tested on the composites (wheat flour, soluble starch, polyvinyl alcohol), blending conditions of composites and moisture contents of extrudates. In case of material composition, wheat flour played a key role to keep extrusion process irrespective of the added amounts of soluble starch and polyvinyl alcohol. The coefficient of elastic of extrudates was increased and the expansion ratio was reduced as the added amounts of wheat flour increased. Also, the coefficient of elastic of extrudates was decreased as the moisture content of extrudates increased. The lowest coefficient of elastic was 439.55 kPa under the condition, of pulp powder mixed with $20\%$ of wheat flour based on pulp weight and $10\%$ of soluble starch based on wheat flour weight and controlled $20\%$(wb) of moisture content.

Removal of NOx using electron beam process with NaOH spraying

  • Shin, Jae Kyeong;Jo, Sang-Hee;Kim, Tae-Hun;Oh, Yong-Hwan;Yu, Seungho;Son, Youn-Suk;Kim, Tak-Hyun
    • Nuclear Engineering and Technology
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    • v.54 no.2
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    • pp.486-492
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    • 2022
  • Nitrogen oxides (NOx; NO and NO2) are major air pollutants and can cause harmful effects on the human body. Electron Beam Flue Gas Treatment (EBFGT) is a technology that generates electrons with an energy of 0.5-1 MeV using electron accelerators and effectively processes exhaust gases. In this study, NOx was removed using an electron beam accelerator with spraying additives (NaOH and NH4OH). NO and NO2 were 100% and more than 94% removed, respectively, at an electron beam absorbed dose of 20 kGy and an additive concentration of 0.02 M (mol/L). In most cases, NOx was removed better with lower initial NOx concentrations and higher electron beam absorbed doses. As the irradiation strength (mA) of the electron beam increases, the probability of electron impact on the material accordingly rises, which may lead to increase removal efficiency. The results of the present study show that the continuous electron beam process using additives achieved more effective removal efficiency than either individual process (wet-scrubbing or EB irradiation only).

Improvement of Hot Dip Galvanizing Process by Additive to Flux Solution (플럭스액의 첨가제에 의한 용융아연도금 공정개선)

  • Moon, Kyung-Man;Jeong, Jae-Hyun;Park, Jun-Mu;Lee, Myeong-Hoon;Baek, Tae-Sil
    • Journal of Surface Science and Engineering
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    • v.49 no.6
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    • pp.513-520
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    • 2016
  • Many surface protection methods have been developed to apply to constructional steels which have been used under severe corrosive environments. One of these methods, hot dip galvanizing is being widely used to the numerous constructional steels such as a guard rail of high way, various types of structural steel for manufacturing ship and for some other industrial fields etc.. Recently, the cost of zinc is getting higher and higher, thus, it is considered that improvement of hot dip galvanizing process to reduce the cost of production should be developed possibly. In this study, additives such as acid cleaning solution, $NH_4OH$, $Al(OH)_3$ and $H_2O_2$ were added to flux solution, and omission of water washing treatment after acid cleaning was investigated with some types of flux solutions added with some additives mentioned above. The decrement of pH by adding the acid cleaning solution could be controlled due to neutralization reaction with addition of $NH_4OH$. The flux solution added with both $NH_4OH$ and $Al(OH)_3$ exhibited nearly the same color and pH value as those of orignal flux solution with no added, and the sample dipped to the flux solution which was added with additives mentioned above indicated a relatively good corrosion resistance compared to other samples. However, the flux solution added with $NH_4OH$, $Al(OH)_3$ and $H_2O_2$ exhibited a different color, sediment and a bad corrosion resistance. Consequently, it is considered that omission of water washing treatment may be able to perform by adding optimum additives to the original flux solution.

Study on the Whiteness Improvement of Glyoxal Treated Cotton Fabric - Effects of Additives - (글리옥살 처리 면직물의 백도 개선에 대한 연구 - 첨가제의 영향 -)

  • Cho, Hang Sung;Lee, Bum Hoon
    • Textile Coloration and Finishing
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    • v.29 no.4
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    • pp.284-290
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    • 2017
  • The glyoxal has been used as formaldehyde free DP(durable press) agents in wrinkle free treatment for cotton fabrics. However, the yellowing problem is a disadvantage of DP finishing process for cotton fabrics with glyoxal. In order to improve the whiteness, it was investigated that the effect of coreactant and treatment method with various whitening additives such as STB(sodium tetraborate, $Na_2B_4O_7$), SPB(sodium perborate, $NaBO_3$), SC(sodium chlorite, $NaClO_2$) and SPC(sodium percarbonate, $Na_2CO_3{\cdot}1.5$ $H_2O_2$). The increasing the concentration of whitening additives(STB, SPB, SC and SPC), the whiteness and the strength retention ratio of cotton fabrics were increased but the wrinkle recovery angles were decreased in one bath method. It was not suitable to improve whiteness because the whiteness value is about 60. In the case of SC used two bath method, the whiteness is near 70, which is similar to untreated fabrics, without decreasing of WRA and strength.

Effect of Thiourea on the Copper Electrodeposition (구리 전기 도금에 Thiourea가 미치는 효과)

  • Lee, Joo-Yul;Yim, Seong-Bong;Hwang, Yang-Jin;Lee, Kyu-Hwan
    • Journal of Surface Science and Engineering
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    • v.43 no.6
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    • pp.289-296
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    • 2010
  • The effect of organic additives, thiourea (TU), on the copper electroplated layer of large rectangular size was investigated through physical and various electrochemical techniques. It was found that TU had strong adsorption characteristics on the Ni substrate and affected the initial electroplating process by inducing surface reaction instead of mass transfer in the bulk solution. TU additives had its critical micelle concentration at 200 ppm in copper sulphate solution and showed abrupt change in morphological and electrochemical impedance spectroscopic results around this concentration, which could be related with the destruction of adsorption structure of TU-Cu(I) complex formed at the Ni substrate surface. By conducting a commercial electroplating simulation, when TU additives was included at cmc in the plating solution, it acted as a depolarizer for copper electrodeposition and was effective to reduce the unevenness of copper deposits between centre and edge region at high current densities of 10 ASD.

Morphology control in PVDF membranes using PEG/PVP additives and mixed solvents

  • Rajabi, Shima;Khodadadi, Foroogh;Mohammadi, Toraj;Tavakolmoghadam, Maryam;Rekabdar, Fatemeh
    • Membrane and Water Treatment
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    • v.11 no.4
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    • pp.237-245
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    • 2020
  • The effects of the mixed two solvents, Dimethylacetamide (DMAc) and Dimethylformamide (DMF), and Polyethylene glycol (PEG) and Polyvinylpyrrolidone (PVP) as additives on performance of Polyvinylidene fluoride (PVDF) membranes were studied. Initially, PEG200 was used as a primary additive at fixed percentage of 5% wt. PVP was then blended with PEG200 in different concentrations. PVDF and DMAc were used as polymer and solvent in the casting solutions, respectively. To control the diffusion rate of PVP in the presence of PEG200 and PVP blend, mixtures of DMAc and DMF were used as the mixed solvent in the casting solutions. Asymmetric PVDF membranes were prepared via phase inversion process in a water bath and the effects of two additives and two solvents on the membrane morphology, pure water flux (PWF), hydrophilicity and rejection (R) were investigated. Attenuated Total Reflection Fourier Transform Infrared Spectra (ATR-FTIR) analysis was used to show the residual PVP on the surface of the membranes. Atomic Force Microscopy (AFM) was utilized to determine roughness of membrane surface. The use of mixed solvents in the casting solution resulted in reduction of PVP diffusion rate and increment of PEG diffusion rate. Eventually, PWF and R values reduced, while porosity and hydrophilicity increased.

Study on Cu CMP by using Semi-Abrasive Free Slurry (준 무연마제 슬러리를 아용한 Cu CMP 연구)

  • Kim, Nam-Hoon;Lim, Jong-Heun;Eom, Jun-Chul;Kim, Sang-Yong;Kim, Chang-Il;Chang, Eui-Goo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05c
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    • pp.158-161
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    • 2003
  • The primary aim of this study is to investigate new semi-abrasive free slurry including acid colloidal silica and hydrogen peroxide for copper chemical-mechanical planarization (CMP). In general, slurry for copper CMP consists of colloidal silica as an abrasive, organic acid as a complex-forming agent, hydrogen peroxide as an oxidizing agent, a film forming agent, a pH control agent and several additives. We developed new semi-abrasive free slurry (SAFS) including below 0.5% acid colloidal silica. We evaluated additives as stabilizers for hydrogen peroxide as well as accelerators in tantalum nitride CMP process. We also estimated dispersion stability and Zeta potential of the acid colloidal silica with additives. The extent of enhancement in tantalum nitride CMP was verified through anelectrochemical test. This approach may be useful for the application of single and first step copper CMP slurry with one package system.

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Studies on the development of functional paper with herbal medicine and herbal medicine waste(Part 1) -Development of functional paper with Astragalus membranaceus, Angelica acutiloba and Artemisia capillaris waste- (한약재 및 한약 폐잔재를 이용한 기능지 개발에 관한 연구(제 1보) - 황기, 당귀, 인진쑥의 폐잔재를 이용한 기능지 개발 -)

  • Kim, Kyoung-Shin;Yoon, Seung-Lak;Ro, Jeong-Kwan;Jo, Hyun-Jin;Kim, Byoung-Soo;Kim, Yun-Geun
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.45 no.3
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    • pp.9-19
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    • 2013
  • This research was performed to make functional papers by using the waste of herbal medicine such as Astragalus membranaceus, Angelica acutiloba, and Artemisia capillaris as additives, and to evaluate their physical and optical properties of the manufactured paper. The physical and optical properties were decreased with the increase of the amount of herbal medicine. Of those manufactured papers, the functional paper with Artemisia capillaris showed the dramatic decrease in its physical properties. Adding the herbal medicine waste as additives developed the aesthetic pattern on the surface of the manufactured paper. The paper showing the black pattern on white surface was most favored. Different patterns could be made by changing the size of fibers and the amount of wastes. There was odor emitted from the paper due to the herbal medicine waste, which make the paper to have a potential for the diverse purpose. The herbal medicine waste can be applied to replace weighting agents in the manufacturing process of paper or used for the fuctional additives, resulting in the reduce of the quantity of a pulp consumed. The paper with 10-20% Angelica acutiloba waste were thought to have the most excellent quality on the process point of view.