• Title/Summary/Keyword: PP2A

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Fabrication and Properties of Natural Fiber-Reinforced Waste Wool/Polypropylene Composites (NFRP) (천연섬유강화 폐양모/폴리프로필렌 복합재료(NFRP)의 제조 및 특성)

  • Kim, Ki Hyun;Cho, Donghwan;Kim, Jong Hyun
    • Journal of Adhesion and Interface
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    • v.9 no.2
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    • pp.16-23
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    • 2008
  • In this study, novel waste wool/polypropylene NFRPs (natural fiber reinforced polymer composites), which are constituted with waste wool discarded as industrial scrap during manufacturing processes of woven fabrics and general purpose thermoplastic polypropylene (PP), were fabricated by means of compressionmolding and their mechanical and thermal properties were characterized. The mechanical properties of PP resin were significantly improved by an introduction of waste wool to PP. In particular, as the loading of waste wool was 50 vol% in the NFRP, the flexural strength of the NFRP was increased about 20%, the flexural modulus about 143%, the tensile strength about 76%, and the tensile modulus about 90% in comparison with each of PP control. In addition, the maximum value of the heat deflection temperature (HDT) obtained with the NFRP was $138^{\circ}C$ at a 50 vol% loading of waste wool. This is $21^{\circ}C$ higher than the HDT of PP control. The result here suggests that waste wool be a potential candidate for a reinforcing material of thermoplastic matrix resins.

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Production of 3D Printer Filament Using Exfoliated Graphene and Recycled PP Composite and Their Application to 3D Printing (재활용 PP와 박리 그래핀을 이용한 3D 프린터용 원사의 제조 및 3D 프린터를 이용한 성형)

  • Lee, Jaeyu;Lee, Jea Uk;Lee, Kyung Jin
    • Applied Chemistry for Engineering
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    • v.32 no.2
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    • pp.157-162
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    • 2021
  • In this study, 3D printing filaments using recycled polypropylene (rPP) were produced by a single screw extruder. Graphene composite filament was also prepared using electrochemically exfoliated graphene (EEG) as a composite filler by adding 10, and 20 wt% of EEG to rPP. The graphene and rPP were successfully dispersed with great homogeneity, so that 3D filaments were uniformly produced, and their thermal properties increased as the graphene content increased. The mechanical property was also improved when EEG was 10 wt% but decreased when EEG was 20 wt% compared to that of rPP. 3D structures were successfully manufactured using prepared 3D filaments by a conventional 3D printer, and great advantages can be expected in terms of environmental and economical perspective by adopting plastic waste.

Effects of Storage Temperature and Materials on Maintenance of Quality of Solidago virgaurea spp. gigantea in Modified Atmosphere Packaging (MAP 포장재의 종류와 온도가 울릉미역취의 품질에 미치는 영향)

  • Choi, Mal-Gum;Chung, Hun-Sik;Moon, Kwang-Deog
    • Food Science and Preservation
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    • v.15 no.6
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    • pp.804-809
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    • 2008
  • Modified atmosphere packaging (MAP) was assessed in terms of extending the shelf life of Solidago virgaurea spp. gigantea. In June 2005 Solidago virgaurea spp. gigantea were harvested from Ulleung Island, packaged in $30\;{\mu}m$ PP, $30\;{\mu}m$ Antifogging-OPP, $30\;{\mu}m$ LDPE, $18\;{\mu}m$ Macroperforated-HDPE, $60\;{\mu}m$ nylon/PE, or $85\;{\mu}m$ PVC/PE film, then stored at 4, 10 or $20^{\circ}C$ for up to 14 days. The $O_2$ concentration decreased to $9{\sim}10%$ in the PP and A-OPP packaging, to $12{\sim}16%$ in LDPE packaging, and to 2% in nylon/PE and PVC/PE packaging at $10^{\circ}C$. The $CO_2$ concentration increased to 5% at $10^{\circ}C$ in PP, A-OPP and LDPE packaging, but increased consistently in the nylon/PE and PVC/PE packaging. Weight loss was markedly reduced by all MAP films except M-HDPE, and which was enhanced with decreasing storage temperature. The soluble solids and pH were not affected by the packaging material at $4^{\circ}C$ and $10^{\circ}C$, but were affected at $20^{\circ}C$. The highest score for sensory qualities (appearance, color and overall acceptability) was obtained for vegetables stored at $4^{\circ}C$ in PP films. Our results show that MAP using PP films and $4^{\circ}C$ storage can effectively maintain the quality of Solidago virgaurea spp. gigantea.

Effects of Dietary Persimmon Peel and its Ethanol Extract on the Production Performance and Liver Lipids in the Late Stage of Egg Production in Laying Hens

  • Oh, S.T.;Zheng, L.;Shin, Y.K.;An, B.K.;Kang, C.W.
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.2
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    • pp.260-265
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    • 2013
  • The purpose of this study was to investigate the dietary effects of persimmon peel (PP) and PP ethanol extract (PPE) on egg production, egg quality, and liver lipids in the late stage of egg production in laying hens. One hundred and twenty 50-wk-old Hy-Line Brown layers (n = 120) were fed different diets. Four replicate groups of 6 hens each were randomly assigned to 5 dietary treatments. The 5 dietary treatments were as follows: i) CON, basal diet; ii) PP 0.15, CON+0.15% PP (0.035% tannin); iii) PP 0.5, CON +0.5% PP (0.117% tannin); iv) PPE 0.075, CON+0.075% PPE (0.03% tannin); and v) PPE 0.25, CON+0.25% PPE (0.11% tannin). The total tannin concentration of PPE was higher (p<0.05) than that of PP. Egg production in the PP 0.5 group was higher than in the other groups. Egg production and mass of hens in the PPE 0.25 group showed a greater decrease than that in the other groups (p<0.05). Eggshell color in the PP 0.15, PP 0.5, and PPE 0.075 groups was lighter than that of the control group (p<0.05). The Haugh unit for the groups that were fed PP and PPE were significantly higher than that in the other groups after 7 d of storage (p<0.05). Therefore, PP seems an effective feed additive for improving the production performance and egg quality in late stage laying hens.

Gradient Structures and Surface Composition of Polypropylene/Ethylene-Propylene Rubber Blends (폴리프로필렌/에틸렌-프로필렌 고무 블렌드 경사구조 및 표면조성)

  • Kim, Seog Je;Lee, Sung-Goo;Lee, Jae Heung;Choi, Kil-Yeong
    • Journal of Adhesion and Interface
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    • v.2 no.4
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    • pp.24-31
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    • 2001
  • Polypropylenes(PP) with different melt index values were mixed with ethylene-propylene rubber(EPR) or ethylene-propylene diene monomer rubber(EPDM) and an ethylene copolymer containing carboxylic acid group in a twin screw extruder. Then test specimens were prepared from the pellets of the blends with an injection molding machine. The mechanical properties and morphology of fractured surfaces were measured. Relative peak intensities of carboxylic acid group on the specimen surface were measured with an attennuated total reflection infrared spectrometer (ATR-IR) and compared with each other. The blend specimens were found to have the gradient morphology of rubber domains in PP matrix in the core region and PP skin layer. The blends containing PP of higher melt index showed greater content of ethylene copolymer containing carboxylic acid on the surface when the relative peak intensities of ATR-IR for carboxylic acid were compared. As the melt index values were increased, the decrease tendency in mechanical propeties such as tensile strength and impact strength was more significant for PP/EPR blends than PP/EPDM blends.

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The Prevalence and Characteristics of Positional Obstructive Sleep Apnea

  • Kim, Cheon-Sik;Lee, Yong-Seok;Cho, Cheon-Ung;Pae, Sang-Ho;Lee, Sang-Ahm
    • Korean Journal of Clinical Laboratory Science
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    • v.44 no.2
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    • pp.52-58
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    • 2012
  • Patients with obstructive sleep apnea (OSA) often have more aggravated symptoms in the supine position. We tried to investigate the clinical characteristics and the predictive factors for positional OSA. Polysomnographic data were reviewed for OSA patients (apnea hypopnea index, $AHI{\geq}5$) from April, 2008 to April, 2011 at the Asan Medical Center. Clinical data, comorbid medical condition data and questionnaires (SF-36, MFI-20, ESS, BDI, STAI) were assessed. All patients were classified into two groups: positional patients (PP) group and non-positional patients (NPP) group. PP was defined as a patient who had the AHI in the supine position was at least twice as high as that in the lateral position. The body position of patients was confirmed by sleep position sensor and video monitor. All patients had at least 30 minutes of positional and 30 minutes of non-positional sleep. We compared clinical, medical, polysomnographic data, and questionnaire results between two (PP and NPP) groups and investigated predictive factors for the PP group using binary logistic regression analysis. In total, 371 patients were investigated. 265 (71.4%) was categorized as PP group and 106 (28.5%) as NPP group. The mean age ($mean{\pm}SD$) was higher in the PP group ($52.4{\pm}9.8$) than in the NPP group ($49.5{\pm}11.9$) (p<0.05). Comparison of sleep parameters between the PP and the NPP group showed that the PP group had significantly lower BMI (PP: $26.1{\pm}3.2kg/m^2$; NPP: $27.8{\pm}4.3kg/m^2$, p<0.001), neck circumference (PP: $39.7{\pm}2.8cm$; NPP: $41.5{\pm}3.7cm$, p<0.001) and hypertension rate (PP: n=89/265 (33.5%); NPP: n=48/106 (45.2%), p=0.0240). In the PP group, the percentage of deep sleep (PP: $8.7{\pm}8.1%$; NPP: $5.6{\pm}7.0%$, P=0.001) and rapid eye movement (REM) (PP: $17.5{\pm}6.1%$; NPP: $14.0{\pm}6.9%$, p<0.001) were significantly higher whereas the percentage of light sleep (stage N1) was significantly lower than the NPP group (PP: $30.4{\pm}12.3$; NPP: $44.5{\pm}20.8%$, p<0.001). During the sleep, the AHI in the supine position (PP: $48.6{\pm}19.5$; NPP: $60.5{\pm}22.6$, p<0.001) and in the non-supine position (PP: $9.4{\pm}8.9$; NPP: $48.4{\pm}24.8$, p=<0.001) were significantly lower and the minimal arterial oxygen saturation in non-REM sleep was significantly higher in the PP group (PP: $80.3{\pm}7.6$; NPP: $75.1{\pm}9.9$, p=<0.001). There were no significant differences in all questionnaires including quality of life. The results of the binary logistic regression analysis showed that age, the amount of REM sleep(%) and AHI were significant predictive factors for positional OSA. The significant predictive factors for positional OSA were older age, higher percentage of REM and lower AHI. The questionnaire results were not significantly different between the two groups.

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The Influence of Dietary Calcium and Phosphorus Imbalance on Intestinal NaPi-IIb and Calbindin mRNA Expression and Tibia Parameters of Broilers

  • Li, Jianhui;Yuan, Jianmin;Guo, Yuming;Sun, Qiujuan;Hu, Xiaofei
    • Asian-Australasian Journal of Animal Sciences
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    • v.25 no.4
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    • pp.552-558
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    • 2012
  • A $2{\times}2$ factorial experiment was conducted to study the effect of dietary calcium and non-phytate phosphorus (nPP) imbalance on calbindin and NaPi-IIb mRNA levels in the small intestine and tibia parameters of broiler chicks. One hundred and forty four 1-d-old Arbor Acres male broiler chicks were divided into four treatments consisted of six replicates with six chicks each. The two dietary calcium levels were 1.10% and 0.60%, and two dietary nPP levels were 0.50% and 0.27%. Results showed that a high Ca/nPP ratio diet (4.07:1) significantly depressed feed intake and weight gain of broilers (p<0.05), but a lower Ca:nPP ratio (1.2:1) had no influence (p>0.05). Low-Ca with low-P diet resulted in low tibia minerals and tibia breaking strength of broilers, and all the tibia parameters were further decreased when the dietary ratio of Ca to P was relative higher. Low dietary Ca or P up-regulated the calbindin and NaPi-IIb mRNA expression levels. Low Ca with normal P diet up-regulated duodenal calbindin mRNA expression level to the greatest extent. Low P with a normal Ca diet significantly enhanced NaPi-IIb mRNA expression level to the highest extent. These results suggest that the calbindin and NaPi-IIb mRNA expression were enhanced by the imbalance between dietary Ca and nPP, and their expression were not only influenced by Ca or nPP level, but also the ratio of Ca:nPP.

Changes in Color Response of MTT formazan by Zinc Protoporphyrin (MTT formazan의 발색에 미치는 zinc protoporphyrin의 영향)

  • Park, Kyung-A;Choi, Hyun-A;Kim, Mi-Ri;Choi, Yoo-Mi;Kim, Hyun-Jung;Hong, Jung-Il
    • Korean Journal of Food Science and Technology
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    • v.43 no.6
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    • pp.754-759
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    • 2011
  • Zinc protoporphyrin (ZnPP) is produced endogenously during heme metabolism and treated in cells as a heme oxygenase inhibitor. In the present study, the effects of ZnPP on the color response of 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide (MTT) assay, a commonly-used method for analyzing cell viability, were investigated. ZnPP induced rapid decolorizaion of MTT formazan under light; the degradation rates were 10- and 20- folds faster in the presence of 5 and $10{\mu}M$ ZnPP, respectively. Methylene blue (MB), another type of photosensitizer, also accelerated degradation of formazan under light. Butylated hyroxytoluene did not inhibit ZnPP- or MB-induced formazan degradation. The color degradation of formazan dye was signficantly delayed in the presence of N-acetylcysteine or ${\beta}$-carotene. The present results suggest that certain photosensitizing compounds may affect the color and stability of MTT formazan, which should be carefully considered when conducting the MTT assay.

Characteristics Analysis of Nano-composites Films Using Extruder (압출성형기를 이용한 나노복합재 필름의 특성 분석)

  • Kwon, Il-Jun;Park, Sung-Min;Yoo, Sung-Hun;Yeum, Jeong-Hyun
    • Textile Coloration and Finishing
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    • v.28 no.2
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    • pp.101-108
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    • 2016
  • Polypropylene(PP)/multiwalled carbon nanotubes(MWCNT) nanocomposites films and PP/poly(vinyl alcohol)/CNT nanocomposites films were prepared through melt mixing method by the extruder. The PP/CNT nanocomposites films, which contain CNT of a variable content, were prepared for the first time and research on a appropriate content of the CNT on the PP/CNT nanocomposites films was conducted. The effects of take-up speed of the extruder on the mechanical and chemical properties of the PP/CNT and PP/PVA/CNT nanocomposites film were studied. Field emission scanning electron microscope(FE-SEM) was used to examine the surface morphology and the DSC measurement and tensile test were conducted. It was found that the properties decreased when take-up speed was increased.

Influence of Dilauroyl Peroxide on Mechanical and Thermal Properties of Different Polypropylene Matrices (Dilauroyl Peroxide의 PP에 대한 기계적, 열적 성질 변화)

  • Sirin, Kamil;Yavuz, Mesut;Canli, Murat
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.200-209
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    • 2015
  • In this study, the influence of dilauroyl peroxide on mechanical and thermal properties of different polypropylene (PP) matrices was investigated. Polypropylene matrices, different molecular weight isotactic PP containing 0.01, 0.02, 0.04, 0.06, 0.08, and 0.1 wt% of dilauroyl peroxide (DLP) were prepared by using a single-screw extruder. The effect of the visbreaking agent (DLP) on mechanical, physical, thermal and morphological properties of different molecular weight PP had been studied. Mechanical properties (tensile strength at break point, at yield and elongation at break point), melt flow index (MFI), scanning electron microscope (SEM) and differential scanning calorimetric (DSC) analyses of these matrices were examined. Melting ($T_m$) and crystallization ($T_c$) temperatures, crystallinity ratio (%) and enthalpies were determined. The microstructure of isotactic polypropylene matrix was investigated by scanning electron microscopy (SEM). From SEM analysis, it was observed that the surface disorder increased by the increasing amount of DLP. As a result of DSC analyses, the crystallinity ratio of the PP matrices has varied between 1.64-7.27%. Mechanical properties of the matrices have been improved. Particularly, the mechanical tests of PP have given interesting results when compounded with 0.06-0.08 wt% dilauroyl peroxide (DLP). Mechanical properties and thermal decomposition processes were all changed by increasing the amount of DLP in the matrix structure.