• Title/Summary/Keyword: PO2

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Defect Structure and Electrical Conduction Mechanism of Yttrium Sesquioxide (산화이트륨의 결함구조 및 전기전도 메카니즘)

  • Kim, Keu-Hong;Park, Sung-Ho;Choi, Jae-Shi
    • Journal of the Korean Chemical Society
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    • v.28 no.3
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    • pp.149-154
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    • 1984
  • The electrical conductivity of p-type yttrium sesquioxide has been measured as a function of temperature and of oxygen partial pressure at temperatures from 650 to 1050$^{\circ}C$C and oxygen partial pressures from $1 {\times}10^{-5}\;to\;2{\times}10^{-1}$atm. Plots of log conductivity vs. 1/T at constant oxygen partial pressures are found to be linear with low-and high-temperature dependences of conductivity. The high-temperature dependence of conductivity shows two different defect structures. The plots of log conductivity vs. log $Po_2$ are found to be linear at $Po_2$'s of $10^{-5}\;to\;10^{-1}$ atm. The electrical conductivity dependences on $Po_2$ are found to be ${{\sigma}{\propto}Po_2}^{1/6}$at $850{\sim}950^{\circ}C,\;{{\sigma}{\propto}Po_2}^{3/16}$ at $950{\sim}1050^{\circ}C\;and\;{{\sigma}{\propto}Po_2}^{1/7.5}{\sim}{{\sigma}{\propto}Po_2}^{1/8.3}\;at\;650{\sim}800^{\circ}C$, respectively. The defect structures are$O_i{''}$ at $850{\sim}950^{\circ}C$ and $V_M{'''}$ at $950{\sim}1050^{\circ}C$. The electron hole is main carrier type, however, ionic contribution is found at lower temperature portion.

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Germination of Carrot, Lettuce, Onion, and Welsh Onion Seeds as Affected by Priming Chemicals at Various Concentrations (당근, 상추, 양파 및 파 종자 발아촉진을 위한 Priming 약제 종류와 농도에 따른 효과)

  • Jeong, Yeon-Ok;Kang, Seong-Mo;Cho, Jeoung-Lai
    • Horticultural Science & Technology
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    • v.18 no.2
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    • pp.93-97
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    • 2000
  • This study was conducted to determine the appropriate osmotic priming chemicals and their concentrations to improve germination of carrot, lettuce, onion, and Welsh onion seeds. Each chemical, including $KNO_3$, $KH_2PO_4$, $K_3PO_4$, NaOH, $Ca(NO_3)_2$, and PEG 8000, was tested at three to four concentrations. Percent germination, number of days to attain 50% of the final germination percentage (T50), and mean number of days to germination (MDG) of primed seeds were compared with those of water-imbibed or nonprimed seeds. With the exception of 100 or 200 mM NaOH, other priming chemicals did not affect percent germination of carrot and lettuce seeds. However, the chemical priming did reduce T50 and MDG, especially with -0.5 MPa PEG 8000 for carrot and with 50 mM $K_3PO_4$ or 200 mM $KH_2PO_4$ for lettuce. Among the chemicals with no influence on percent germination did 200 mM $KH_2PO_4$ significantly reduced both T50 and MDG of onion seeds. No chemicals improved percent germination of Welsh onion seeds. Reduction in T50 and MDG was significant only with $KH_2PO_4$ and $Ca(NO_3)_2$.

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A Study on the Durable Press Finishing of Cotton Fiber Treated with Polycarboxylic Acid (폴리카르복시 산 처리 면섬유의 DP가공에 관한 연구)

  • 이찬민;최철민
    • Textile Coloration and Finishing
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    • v.9 no.6
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    • pp.58-67
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    • 1997
  • PTCA(1,2,3-propanetricarboxylic acid) and BTCA(1,2,3-butanetetracarboxylic acid) are selected as new nonformaldehyde agents for ester crosslinking of cotton cellulose to replace the traditional DMDHEU reagent. A goal of this research is to propose unknown ester mechanism of cotton cellulose by PTCA or BTCA using crystal structure model suggested by Meyer and Takahashi. In pursuit of these goals, we have treated 100% cotton broad cloth with PTCA or BTCA and different catalysts. They were used with $NaH_2PO_2,\;NaH_2PO_4,\;Na_2HPO_4,\;NaH_2PO_2,\;Na_3PO_4,$ catalysts to produce nonformaldehyde fabric finishes. Treatments were applied to all cotton fabrics using a pad-dry -cure process. The esterfication of cotton treated with BTCA or PTCA was investigated using Fourier transform infrared(FT-IR) spectra and the breaking strength, abrasion retention and discoloration properties were determined to prove the durable finished fabrics. Patterns with respect to abrasion resistance were more complex. Because PTCA and BTCA add-ons were comparable, the data suggest that the more effective catalysts, $NaH_2PO_2$ and mixed phosphate $NaH_2PO_2/NaH_2PO_4$) are effecting either a great number of crosslinks in the cotton or producing crosslinks that differ in actual structure.

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Enhancement of Porosity and Strength of Porous Al2O3 Ceramics by Al(H2PO4)3 Addition

  • Bai, Jiahai;Piao, Jiasi;Gao, Jie;He, Jing;Du, Qingyang;Li, Chengfeng
    • Journal of the Korean Ceramic Society
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    • v.56 no.4
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    • pp.350-353
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    • 2019
  • Porous alumina ceramics with addition of 0, 5, 10, 15, and 20 wt% Al(H2PO4)3 were sintered at 1300, 1350, and 1400℃. The effects of the Al(H2PO4)3 addition on crystal phases, water absorption, open porosity, pore size distribution, microstructures, and flexural strength were studied extensively. The experimental results revealed that only characteristic peaks of corundum were indexed in the XRD patterns of the as-prepared porous ceramics. The water absorption and open porosity of the porous Al2O3 ceramics increased remarkably with an increase in Al(H2PO4)3 addition. The flexural strength first increased to a maximum value when 5 wt% Al(H2PO4)3 was added and then decreased as additional Al(H2PO4)3 was further added. SEM images showed that the average Al2O3 grain size in the porous ceramics changed in an opposite way as the flexural strength. The porous Al2O3 ceramics with 10 wt% Al(H2PO4)3 addition exhibited comparable flexural strength to the ceramics without Al(H2PO4)3 addition, although the latter had much higher porosity.

Changes in Blood pH, $Pco_2$ and $Po_2$ During Passive Tilt (체위 변화시의 혈액 pH, $Pco_2$$Po_2$의 변화)

  • Jun, Sang-Yun;Chae, E-Up
    • The Korean Journal of Physiology
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    • v.12 no.1_2
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    • pp.35-40
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    • 1978
  • To evaluate orthostatic brain hypoxia from the passive tilt, anesthetized dogs were tilted from supine to $90^{\circ}C$ upright and $90^{\circ}C$ head down position. Blood pH, $Pco_2$ and $Po_2$ changes during tilt were measured on 8 dogs. Respiratory rate was decreased in upright position and increased in head down position comparing to that in rte horizontal position. pH in arterial blood was increased in upright position and decreased in venous blood comparing to that in the horizontal position. No significant changes were found in the head down position. $Pco_2$ of arterial and venous blood was decreased both in upright and head down. position A significant decrease was found in the head down position. $Po_2$ in arterial blood was increased both in the upright and head down position. However, it was decreased in the venous blood. The cause of increased $Po_2$ in arterial blood seemed to do due to hyperventilation and the cause of decreased $Po_2$ in venous blood was thought to be due to increased $O_2$ consumption of animals during the tilt.

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Synthesis and characterization of Li3V2(PO4)3/C composite cathode materials using direct co-precipitation method (직접 공침법을 이용한 Li3V2(PO4)3/C 복합체 양극 활물질 합성 및 특성)

  • Jeong-Hwan Song
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.5
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    • pp.167-173
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    • 2023
  • Li3V2(PO4)3 and Li3V2(PO4)3/C composite with single phase monoclinic structure for the cathode materials are successfully synthesized by direct co-precipitation method using N2H4·H2O as the reducing agent and alginic acid as the carbon source, and their electrochemical properties were compared. The particles with approximately 1~2 ㎛ size and the uniform spherical-like morphology of the narrow particle size distribution were obtained. In addition, the residual carbon can also improve the electrical conductivity. The Li3V2(PO4)3/C composite has improved initial specific discharge capacity and excellent cycle characteristics to maintain capacity stably than Li3V2(PO4)3. The results indicate that the reducing agent and carbon composite can affect the good crystallinity and electrochemical performance of the cathode materials.

Temperature Dependent Optical Performance of the NaSr(PO3)3:Eu2+ Blue Phosphors (NaSr(PO3)3:Eu2+ 청색 형광체의 온도 의존적 형광 특성)

  • Yoon, Chang yong;Lee, Sang ho
    • Journal of the Korean Society of Radiology
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    • v.15 no.3
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    • pp.391-399
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    • 2021
  • Eu2+ doped polyphosphate NaSr(PO3)3 blue-emitting phosphors were synthesized by the conventional solid state method in a reductive atmosphere. The phase formation of NaSr(PO3)3 phosphors were characterized by using the X-ray powder diffraction (XRD) measurement. The photoluminescence emission and excitation spectra of the NaSr(PO3)3:Eu2+ phosphor, and decay curves were measured. Under the near-UV excitation, the phosphor exhibits a band emission around 420 nm assigned to the 4f65d→f7(8S7/2) transition of Eu2+. The temperature dependent emission spectra and decay curves were measured to elevate the thermal properties of the Eu2+ doped phosphors. The as-prepared NaSr(PO3)3:Eu2+ phosphors show a strong temperature dependent performance, which can serve as a promising temperature sensor.

A Study on the Transition of Salmi in Dapo Type Kong-Po(拱包) - Focused on Inner and Outer Same Chulmok(出目) - (다포계 공포의 살미 변천에 관한 연구 - 내외 2출목·내외 3출목 공포를 중심으로 -)

  • Lee, Byung-Chun;Lee, Ho-Yeol
    • Journal of architectural history
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    • v.22 no.4
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    • pp.7-18
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    • 2013
  • Integrated-Salmi can be suggested as a character of Da-po type Kong-po in Korea's traditional architecture. However, only few studies are made on this subject yet. This study is to investigate the integration process of Salmi through cases of certain Kong-po which have the same number of inner and outer Chul-mok and are also known to precede in time. The results of the study are like below. First, Integrated-Salmi is more dominant in inner and outer 3 Chul-mok Kong-po than in inner and outer 2 Chul-mok Kong-po. Second, While inner and outer 2 Chul-mok prevail in Yeong-nam region, inner and outer 3 Chul-mok prevail in Ho-nam region. Third, integrated Salmi of Inner and outer 3 Chul-mok, first appeared in internal Jusangpo to be carried over to internal Juganpo then eventually to outer Salmi. Fourth, the reason why integrated form precede in internal salmi of inner and outer 3 Chul-mok Kong-po is due to 2 main factors. First of which is the impact of integrated Boaji that developed in Da-po type since the early 16th century. The second factor is downward expansion of Cho-gak's Boaji which was adopted to cope with disorders made in structure of Chum-Cha, due to inner and outer 3 Chul-mok type buddhist temples' wide reconstruction throughout Jeolla region following the Japanese invasion of Korea in 1592. This study is to disclose the regularity of development process of Salmi's Cho-gak(草刻) which is a characteristic of Korea's Da-po type Kong-po.

Electrochemical Characteristics of $LiFePO_4$ with Conductivity Materials for Lithium Polymer Batteries

  • Jin, En Mei;Wang, Jiao;Zhao, Xing Guan;Park, Kyung-Hee;Gu, Hal-Bon;Park, Bok-Kee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2009.11a
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    • pp.132-132
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    • 2009
  • Phospho-olivine $LiFePO_4$ cathode materials were prepared by hydrothermal reaction. In this study, Multi-walled carbon nanotube (MWCNT) and Carbon black was added to enhance the electrical conductivity of $LiFePO_4$. $LiFePO_4$, $LiFePO_4$-MWCNT and $LiFePO_4$-C particles were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM) transmission electron microscope (TEM). $LiFePO_4/SPE/Li$, $LiFePO_4$-MWCMT/SPE/Li and $LiFePO_4$-C/SPE/Li cells were characterized electrochemically by charge/discharge experiments at a constant current density of $0.1mA\;cm^{-2}$ in a range between 2.5 and 4.3 V vs. $Li/Li^+$ and cyclic voltammetry (CV).

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Involvement of Pro-Phenoloxidase 3 in Lamellocyte-Meidated Spontaneous Melanization in Drosophila

  • Nam, Hyuck-Jin;Jang, In-Hwan;Asano, Tsunaki;Lee, Won-Jae
    • Molecules and Cells
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    • v.26 no.6
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    • pp.606-610
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    • 2008
  • Phenoloxidase (PO), a melanin-forming enzyme around the foreign bodies, is an important component of the host defense system in invertebrates. Pro-PO is the enzymatically inactive zymogen form of PO. In the Drosophila genome, three Pro-PO isoforms have been identified to date. These include Pro-PO1 and 2, which are primarily expressed in crystal cells, and Pro-PO3, which is predominantly found in the lamellocytes. In this study, we demonstrated that Drosophila Pro-PO3, but not Pro-PO1 or 2, is enzymatically active in its zymogen form. These findings were evidenced by spectacular melanin forming capacities of various cells and tissues that overexpressed these pro-enzymes. Furthermore, the melanization phenotype observed in the lamellocyte-enriched $hop^{Tum-l}$ mutant was drastically reduced in the absence of PPO3, indicating that PPO3 plays a major role in the lamellocyte-mediated spontaneous melanization process. Taken together, these findings indicate that the biochemical properties, activation mode and in vivo role of Pro-PO3 are likely distinct from those of the other two Pro-PO enzymes involved in Drosophila physiology.