• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.1511-1511
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• 2001

Energy content, expressed as calories per gram, is an important part of the evaluation and marketing of foods in developed countries. Currently accepted methods of measurement of energy by U.S. food labeling legislation include measurement of gross calories by bomb calorimetry with an adjustment for undigested protein and by calculation using specific factors for the energy values of protein, carbohydrate less the amount of insoluble dietary fiber, and total fat. The ability of NIRS to predict the energy value of diverse, processed and unprocessed cereal food products was investigated. NIR spectra of cereal products were obtained with an NIR Systems monochromator and the wavelength range used for analysis was 1104-2494 nm. Gross energy of the foods was measured by oxygen bomb calorimetry (Parr Manual No. 120) and expressed as calories per gram (CPGI, range 4.05-5.49 cal/g). Energy value was adjusted for undigested protein (CPG2, range 3.99-5.38 cal/g) and undigested protein and insoluble dietary fiber (CPG3, range 2.42-5.35 cal/g). Using a multivariate analysis software package (ISI International, Inc.) partial least squares models were developed for the prediction of energy content. The standard error of cross validation and multiple coefficient of determination for CPGI using modified partial least squares regression (n=127) was 0.060 cal/g and 0.95, respectively, and the standard error of performance, coefficient of determination, bias and slope using an independent validation set (n=59) were 0.057 cal/g, 0.98, -0.027 cal/g and 1.05 respectively. The PLS loading for factor 1 (Pearson correlation coefficient 0.92) had significant absorption peaks correlated to C-H stretch groups in lipid at 1722/1764 nm and 2304/2346 nm and O-H groups in carbohydrate at 1434 and 2076 nm. Thus the model appeared to be predominantly influenced by lipid and carbohydrate. Models for CPG2 and CPG3 showed similar trends with standard errors of performance, using the independent validation set, of 0.058 and 0.088 cal/g, respectively, and coefficients of determination of 0.96. Thus NIRS provides a rapid and efficient method of predicting energy content of diverse cereal foods.

• Asian-Australasian Journal of Animal Sciences
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• 제17권12호
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• pp.1736-1740
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• 2004

Since the application of relatively high levels of heavy metals in the compost poses a potential hazard to plants and animals, the content of heavy metals in the compost with animal manure is important to know if it is as a fertilizer. Measurement of heavy metals content in the compost by chemical methods usually requires numerous reagents, skilled labor and expensive analytical equipment. The objective of this study, therefore, was to explore the application of near-infrared reflectance spectroscopy (NIRS), a nondestructive, cost-effective and rapid method, for the prediction of heavy metals contents in compost. One hundred and seventy two diverse compost samples were collected from forty-seven compost facilities located along the Han river in Korea, and were analyzed for Cr, As, Cd, Cu, Zn and Pb levels using inductively coupled plasma spectrometry. The samples were scanned using a Foss NIRSystem Model 6500 scanning monochromator from 400 to 2,500 nm at 2 nm intervals. The modified partial least squares (MPLS), the partial least squares (PLS) and the principal component regression (PCR) analysis were applied to develop the most reliable calibration model, between the NIR spectral data and the sample sets for calibration. The best fit calibration model for measurement of heavy metals content in compost, MPLS, was used to validate calibration equations with a similar sample set (n=30). Coefficient of simple correlation (r) and standard error of prediction (SEP) were Cr (0.82, 3.13 ppm), As (0.71, 3.74 ppm), Cd (0.76, 0.26 ppm), Cu (0.88, 26.47 ppm), Zn (0.84, 52.84 ppm) and Pb (0.60, 2.85 ppm), respectively. This study showed that NIRS is a feasible analytical method for prediction of heavy metals contents in compost.

• 응용통계연구
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• 제30권5호
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• pp.633-645
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• 2017

본 연구는 컨테이너선의 연료 소비 패턴의 발견을 위해 운항데이터 분석의 통계적 절차를 제안한다. 우리는 현 시점의 연료 소비를 발견하기 위해 연료 소비에 영향을 미치는 변수들을 파악하는 동시에 예측 모델을 개발 및 적용하는 것을 목적으로 한다. 선박의 데이터는 크게 운항데이터와 기기데이터로 분류할 수 있으며, 운항데이터는 항로, 항해 정보, 대수속도, 대지속도, 바람과 같은 외력에 대한 정보 등이 있고, 기기데이터는 엔진출력, RPM, 연료 소모량, 기기들의 온도 및 압력 등이 있다. 본 연구에서, 우리는 선박에 미치는 외력의 영향을 Beaufort Scale (BFS)을 기준으로 구분한 후에 PLS 회귀분석을 통한 예측 모델을 개발하였다.

• Journal of the Korean Wood Science and Technology
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• 제43권3호
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• pp.311-319
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• 2015

근적외선 반사율 분광분석법을 이용하여 리기다 소나무, 소나무, 잣나무, 백합나무의 섬유포화점 이하 함수율 예측모델을 개발하였다. 시편들을 다양한 평형함수율 상태로 유도한 후 1000 nm~2400 nm 파장영역의 반사율 스펙트럼을 획득하였다. 최적 함수율 예측 모델을 선정하기 위해 5가지의 수학적 전처리(moving average (smoothing point: 3), baseline, standard normal variate (SNV), mean normalization, Savitzky-Golay $2^{nd}$ derivatives (polynomial order: 3, smoothing point: 11))를 8가지 조합으로 각 시편의 반사율 스펙트럼에 적용하였다. 수학적 전처리 후, 변형된 스펙트럼을 이용하여 PLS 회귀분석을 실시하였다. 그 결과, 최적 함수율 예측 모델을 도출한 전처리 방법은 리기다 소나무와 소나무의 경우 moving average/SNV, 잣나무와 백합나무의 경우 moving average/SNV/Savitzky-Golay $2^{nd}$ derivatives이며, 모든 모델은 3개의 주성분을 포함하고 있었다.

• 농업과학연구
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• 제39권4호
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• pp.603-612
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• 2012

In this research, the feasibility of non-destructive measurement technique of pungency measurement was investigated for the red-pepper powders produced in different domestic areas in South Korea. The near-infrared absorption spectra in the range of 1100 nm~2300 nm was used to measure capsaicinoids content in red-pepper powders by using a NIR spectroscopy equipped with Acousto-optic tunable filters (AOTF). Fourth three different red-pepper powders from 14 different locations were collected and separated in three different particle size (below 0.425 mm, 0.425~0.71 mm, 0.71~1.4 mm) for the spectral measurements. The partial least square regression (PLSR) models to predict the capsaicinoids content depends on particle size were developed with the measured spectra. The determinant coefficients and standard errors of the developed models for the red-pepper powders of below 0.425 mm, 0.425~0.71 mm, and 0.71~1.4 mm were in the range of 0.859~0.887 and 12.90~12.99 mg/100 g, respectively. The PLS model with the pretreatment of Standard Normal Variate (SNV) for the red-pepper powders below 1.4 mm particle size showed the best performance with the determinant coefficient of 0.844 and the standard error of 14.63 mg/100 g.

• Journal of Biosystems Engineering
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• 제36권1호
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• pp.33-39
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• 2011

An optical sensing approach based on diffuse reflectance has shown potential for rapid and reliable on-site estimation of soil properties. Important sensing ranges and the resulting regression models useful for soil property estimation have been reported. In this study, a similar approach was applied to investigate the potential of reflectance sensing in estimating soil properties for Korean paddy fields. Soil cores up to a 65-cm depth were collected from 42 paddy fields representing 14 distinct soil series that account for 74% of the total Korean paddy field area. These were analyzed in the laboratory for several important physical and chemical properties. Using air-dried, sieved soil samples, reflectance data were obtained from 350 to 2500 nm on a 3 nm sampling interval with a laboratory spectrometer. Calibrations were developed using partial least squares (PLS) regression, and wavelength bands important for estimating the measured soil properties were identified. PLS regression provided good estimations of Mg ($R^2$ = 0.80), Ca ($R^2$ = 0.77), and total C ($R^2$ = 0.92); fair estimations of pH, EC, $P_2O_5$, K, Na, sand, silt, and clay ($R^2$ = 0.59 to 0.72); and poor estimation of total N. Many wavelengths selected for estimation of the soil properties were identical or similar for multiple soil properties. More important wavelengths were selected in the visible-short NIR range (350-1000 nm) and the long NIR range (1800-2500 nm) than in the intermediate NIR range (1000-1800 nm). These results will be useful for design and application of in-situ close range sensors for paddy field soil properties.

• 한국환경과학회지
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• 제33권3호
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• pp.193-203
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• 2024

This study aims to determine the factors affecting the level of satisfaction with the Cell Broadcast Service (CBS) among citizens in Incheon. Partial least squares (PLS) regression, instead of multiple regression, was used for the analysis because it can solve multicollinearity and sample size issues. The analysis results are as follows: The factor with the greatest effect on satisfaction with CBS among Incheon citizens, was the elimination of redundancies (VIP=1.185). Therefore, local governments, government agencies, and public organizations must coordinate their ideas and collectively create guidelines to eliminate redundancies. The second most influential factor was the expansion in the broadcast medium from legal, institutional, and policy aspects (VIP=1.087). This is because differences in generation, age, gender, and personal characteristics were not considered. Therefore, it is necessary to devise a customized messaging tool through the expansion of broadcast media. The broadcast criteria of the legal, institutional, and policy perspectives comprised the third most influential factor, with a high VIP value of 1.053. Consequently, it is essential to devise a plan to avoid distributing unnecessary cell broadcast services, by establishing criteria for areas and sections, time, and the direct and indirect impact zones of a disaster. In the future, this study could be used as base data to develop policies, guidelines, and response measures for Incheon CBS. Given the lack of research on the diverse characteristics of each social class and the city traits of each region, and a lack of concrete empirical research on each factor, continuous and in-depth studies are required in the future.

• 원예과학기술지
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• 제32권1호
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• pp.105-114
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• 2014

본 연구에서는 UV-VIS spectrophotometer를 이용한 total carotenoids, flavonoids, phenolics 함량 데이터와 FT-IR 스펙트럼 데이터를 다변량통계분석법을 통하여 기능성 성분 함량이 높은 아프리칸 얌 고속 선발 시스템을 구축하였다. 62개 아프리칸 얌의 total carotenoids 함량은 $0.01-0.91{\mu}g{\cdot}g^{-1}$ dry wt 나타냈다. Total flavonoids와 phenolics 함량은 $12.9-229.0{\mu}g{\cdot}g^{-1}$ dry wt와 $0.29-5.2mg{\cdot}g^{-1}$ dry wt로 각각 나타났다. 아프리칸 얌은 FT-IR 스펙트럼상의 1700-1500, 1500-1300, $1,100-950cm^{-1}$, 부위에서 중요한 스펙트럼 변화가 나타났다. 이 부위는 각각 amide I과 II을 포함하는 아미노산 및 단백질계열의 화합물, phosphodiester group을 포함한 핵산 및 인지질 그리고 단당류나 복합 다당류를 포함하는 carbohydrates 계열의 화합물들의 질적, 양적 정보를 반영하는 부위이다. PCA 분석과 PLS-DA 분석에서 62개 아프리칸 얌은 유연성이 높은 종으로 3개의 그룹을 형성하였다. 아프리칸 얌의 FT-IR 스펙트럼 데이터와 UV-VIS spectrophotometer을 이용한 total carotenoids, flavonoids, phenolics 함량 데이터 간에 PLS regression 분석하였다. Total carotenoids, flavonoids, phenolics 함량 성분의 실측 값과 예측 값간에 상관계수($R^2$)가 각각 0.83, 0.86, 0.72로 나타났다. 이 결과, 아프리칸 얌으로부터 FT-IR 스펙트럼을 이용한 total carotenoids, flavonoids, phenolics 함량 예측이 가능하였다. 본 연구에서 확립된 대사체 수준에서 아프리칸 얌의 유용 기능성 성분 함량 예측 모델링을 통해 품종, 계통의 신속한 선발 수단으로 활용이 가능할 것으로 예상된다.

• 한국근적외분광분석학회:학술대회논문집
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• 한국근적외분광분석학회 2001년도 NIR-2001
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• pp.4111-4111
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• 2001

When a drug is prepared in a tablet, the active component represents only a small portion of the dosage form. The other components of the formulation include materials to assist in the dissolution, antioxidants, coloring agents and bulk fillers. The tablets are tested using approved testing methods usually involving separation and subsequent quantification of the active component. Tablets may also be tested by near-Infrared Reflectance spectrometry (NIRS). In the present study, based on NIRS and multivariate calibration methods, a novel and precise method is developed for direct determination of ascorbic acid in vitamin C tablet. Two different tablet formulations were powdered in three different sizes, 63-125 ${\mu}{\textrm}{m}$, and examined. Spectral region of 4750-4950 $cm^{-1}$ / was used and optimized for quantitative operations. Partial least squares (PLS) and multiple linear regression (MLR) methods were performed for this spectral region. The results of optimized PLS and MLR methods showed that reproducibility increase with decreasing grain size and standard error of calibration (SEP) of less than 1% w/w of ascorbic acid and a correlation coefficient of 0.998 can be achieved. The PLS method showed better results than MLR. Seven overdose and underdose samples (prepared in the laboratory to match marketed products) were tested by proposed and iodometric standard methods. A correlation between NIRS predicted ascorbic acid values and iodomet.ic values was calculated ($R^2$=0.9950). Finally, the direct analysis of individual intact tablets in their unit-dose packages (Blistering in aluminum and PVC foils) obtained from market were also carried out and a correlation coefficient of 0.9989 and SEP of 0.931% w/w of ascorbic acid were achieved.

• Korean Chemical Engineering Research
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• 제45권1호
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• pp.67-72
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• 2007

부분 최소자승회귀, 균형 잡힌 realization, 균형 잡힌 truncation을 결합함으로써, MIMO 상태공간 모델의 모델인식을 위한 효과적인 방법이 개발되었다. 개발된 방법에서 MIMO 시스템은 고차 ARX 모델로 표현되는 다중 MISO 시스템으로 분해된다. 이 때, ARX 모델의 파라미터는 부분 최소자승회귀에 의해 추정된다. 그 후, realization을 통해 각각의 MISO ARX 전달함수에 대한 MISO 상태공간 모델이 만들어지며, MIMO 상태공간 모델로 결합된다. 최종적으로, 균형 잡힌 realization과 균형 잡힌 truncation을 통해 최소의 균형 잡힌 MIMO 상태공간 모델이 얻어진다. 제안된 방법은 고압 $CO_2$ 용해도 측정 실험 장치의 온도제어를 위한 모델 예측 제어의 설계에 적용되었다.