• IMMUNE NETWORK
• /
• 제22권4호
• /
• pp.30.1-30.3
• /
• 2022

• Bulletin of the Korean Chemical Society
• /
• 제32권6호
• /
• pp.1851-1858
• /
• 2011

Details of the double-bond isomerization of 1-hexene over H-ZSM-5 were clarified using density functional theory. It is found that the reaction proceeds by a mechanism which involves the Br${\o}$nsted acid part of the zeolite solely. According to this mechanism, 1-hexene is first physically adsorbed on the acidic site, and then, the acidic proton transfers to one carbon atom of the double bond, while the other carbon atom of the double bond bonds with the Br${\o}$nsted host oxygen, yielding a stable alkoxy intermediate. Thereafter, the Br${\o}$nsted host oxygen abstracts a hydrogen atom from the $C_6H_{13}$ fragment and the C-O bond is broken, restoring the acidic site and yielding trans-2-hexene. The calculated activation barrier is 12.65 kcal/mol, which is in good agreement with the experimental value. These results well explain the energetic aspects during the course of double-bond isomerization and extend the understanding of the nature of the zeolite active sites.

• 한국산학기술학회논문지
• /
• 제11권8호
• /
• pp.3106-3111
• /
• 2010

본 연구에서는 천연가스의 온도를 $-40^{\circ}C$까지 냉각시키기 위해서 프로판을 냉매로 사용한 1단 냉동과 2단 냉동 사이의 비교연구를 수행하였다. 열역학 모델식으로는 Peng-Robinson 상태방정식을 적용하였으며, 냉동 사이클의 전산모사를 위해서 Invensys사의 PRO/II with PROVISION 8.3을 활용하였다. 본 연구에서로부터 2단 압축 냉동 사이클을 최적화한 결과 1단 압축 냉동 사이클에 비해서 압축기의 소요동력을 33.5% 가량 줄일 수 있었다.

• 한국초전도ㆍ저온공학회논문지
• /
• 제22권2호
• /
• pp.12-16
• /
• 2020

Circulating cooling systems consume a lot of water, and most of the water from river, which contains a large amount of Ca2+, Mg2+, et al, and has the characteristics of high hardness and large turbidity. The water can form scale on the surface of the heat exchanger and the pipes, which would reduce the heat transfer efficiency and affect the heat exchanger's length of service. In this study, the Superconducting High Gradient Magnetic Separation (S-HGMS) technology was used in river water treatment and the effects of agent A, agent B, and S-HGMS on the removal of hardness and turbidity were discussed. The results showed that the hardness removal rate reached 71.3% and the turbidity was decreased to 0.5 NTU.

• KSII Transactions on Internet and Information Systems (TIIS)
• /
• 제11권12호
• /
• pp.6169-6187
• /
• 2017

With the fast growth of mobile services, Mobile Cloud Computing(MCC) has gained a great deal of attention from researchers in the academic and industrial field. User authentication and privacy are significant issues in MCC environment. Recently, Tsai and Lo proposed a privacy-aware authentication scheme for distributed MCC services, which claimed to support mutual authentication and user anonymity. However, Irshad et.al. pointed out this scheme cannot achieve desired security goals and improved it. Unfortunately, this paper shall show that security features of Irshad et.al.'s scheme are achieved at the price of multiple time-consuming operations, such as three bilinear pairing operations, one map-to-point hash function operation, etc. Besides, it still suffers from two minor design flaws, including incapability of achieving three-factor security and no user revocation and re-registration. To address these issues, an enhanced and provably secure authentication scheme for distributed MCC services will be designed in this work. The proposed scheme can meet all desirable security requirements and is able to resist against various kinds of attacks. Moreover, compared with previously proposed schemes, the proposed scheme provides more security features while achieving lower computation and communication costs.

• 대한전자공학회:학술대회논문집
• /
• 대한전자공학회 2001년도 The 6th International Symposium of East Asian Resources Recycling Technology
• /
• pp.404-408
• /
• 2001

This paper focuses on the pilot-scale investigation of direct recycling of electric arc furnace (EAF) stainless steelmaking dust. The direct recycling of EAF dust is to make pellets with the mixture of the dust and the reducing agent carbon, then introduce the pellets to the EAF. The valuable metals in the dust are reduced and get into the steel as the alloying elements. Experiments simulating direct recycling in an EAF were performed using an induction furnace. But it seems difficult to reduce all metal oxides in the dust so that some metal reducing agents added in the late stage of reduction process. The valuable metals in the dust were reduced partly by carbon and partly by metal reducing agent for the economical concern. The recovery of iron, chromium and nickel from the flue dust and the amount of metal oxides in the slag were measured. The results showed that the direct recycling of EAF stainless steelmaking dust is practicable. It wes also found that direct recycling of flue EAF stainless steelmaking dusts does not affect the chemistry and quality of stainless steel produced in the EAF. It is benefit not only for the environmental protection but also for the recovery of valuable metal resources in this way.

• 한국항공우주학회지
• /
• 제38권8호
• /
• pp.823-833
• /
• 2010

액체 로켓 및 항공용 엔진 연료로서 사용되는 케로신의 열역학적 상태량을 연구하기 위해 surrogate 모델이 조사되었다. 초임계 조건에서 실제 기체 상태 방정식(SRK 상태 방정식, PR 상태 방정식)과 NIST SUPERTRAPP(ECS 원리)을 이용하였을 경우의 밀도 분포가 기존의 실험 결과와 비교되었다. 또한 surrogate 모델의 종류에 따른 열역학적 상태량의 오차 범위에 대한 고찰이 수행되었다. 탄화 수소 계열 연료에 대해서는 PR 상태 방정식과 ECS 원리가 높은 정확도를 나타내지만 압력, 온도와 같은 작동 환경에 따라 적절한 surrogate 모델을 선별하여 선택해야 함을 확인하였다.

• Structural Engineering and Mechanics
• /
• 제66권2호
• /
• pp.151-160
• /
• 2018

With the aim to evaluate the fatigue damage accumulation and predict the residual life of engineering components under variable amplitude loadings, this paper proposed a new strain energy-based damage accumulation model by considering both effects of mean stress and load interaction on fatigue life in a low cycle fatigue (LCF) regime. Moreover, an integrated procedure is elaborated for facilitating its application based on S-N curve and loading conditions. Eight experimental datasets of aluminum alloys and steels are utilized for model validation and comparison. Through comparing experimental results with model predictions by the proposed, Miner's rule, damaged stress model (DSM) and damaged energy model (DEM), results show that the proposed one provides more accurate predictions than others, which can be extended for further application under multi-level stress loadings.

• Journal of Microbiology and Biotechnology
• /
• 제23권2호
• /
• pp.260-266
• /
• 2013

Rhodococcus sp. strain p52, a previously isolated dibenzofuran degrader, could effectively inhibit the growth of cyanobacteria, including species of Microcystis, Anabaena, and Nodularia. When strain p52 was inoculated at the concentration of $7.7{\times}10^7$ CFU/ml, 93.5% of exponentially growing Microcystis aeruginosa ($7.3{\times}10^6$ cells/ml initially) was inhibited after 4 day. The threshold concentration for its algicidal activity against M. aeruginosa was $7.7{\times}10^6$ CFU/ml. Strain p52 exerted algicidal effect by synthesizing extracellular substances, which were identified as trans-3-indoleacrylic acid, DL-pipecolic acid, and L-pyroglutamic acid. The effective concentrations of trans-3-indoleacrylic acid and DL-pipecolic acid against M. aeruginosa were tested to be 0.5 mg/l and 5 mg/l, respectively.

• 한국염색가공학회지
• /
• 제33권3호
• /
• pp.141-146
• /
• 2021

Supercritical fluid has excellent dissolving power for various materials based on low viscosity and high diffusion coefficient and is used as solvents in various chemical processes. However, its industrial application can be very tricky because the design, especially the size of the supercritical apparatus, should be carefully chosen to optimize the cost and the production of supercritical fluidic state. And the first step of the supercritical fluid apparatus design is to choose the appropriate size of the reactor vessel to produce supercritical fluid above its critical pressure and temperature. Therefore, this study aims to analyze thermodynamic behaviors of dichloromethane based on ideal gas, van der Waals, Redlich-Kwong, Soave-Redlich-Kwong, and Peng-Robinson equations of state. The correlation between the volume and pressure of dichloromethane at 200℃ was revealed and it can be used to design the optimized size of the supercritical apparatus for industrial production.