• Title/Summary/Keyword: PEMFC (polymer electrolyte membrane fuel cell)

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Analysis of Thermal Effect by Coolant Plate Number in High-Temperature Polymer Electrolyte Membrane Fuel Cell Stack (고온형 고분자 전해질 연료전지 스택 내부의 냉각판 수가 스택에 미치는 열 영향성의 수치적 연구)

  • Choi, Byung Wook;Ju, Hyun Chul
    • Transactions of the Korean hydrogen and new energy society
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    • v.26 no.2
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    • pp.127-135
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    • 2015
  • High-Temperautre Polymer Electrolyte Membrane Fuel Cell (HT-PEMFC) with phosphoric acid-doped polybenzimidazole (PBI) membrane has high power density because of high operating temperature from 100 to $200^{\circ}C$. In fuel cell stack, heat is generated by electrochemical reaction and high operating temperature makes a lot of heat. This heat is caouse of durability and performance decrease about stack. For these reasons, heat management is important in HT-PEMFC. So, we developed HT-PEMFC model and study heat flow in HT-PEMFC stack. In this study, we placed coolant plate number per cell number ratio as variable and analysed heat flow distribution in stack.

A Study on Performance Characteristics of PEMFC with Thermal Variation (온도에 따른 고분자 전해질형 연료전지시스템의 출력 특성 연구)

  • Park, Se-Joon;Shin, Young-Sik;Jeong, Seong-Chan;Choi, Jeong-Sik;Cha, In-Su
    • Proceedings of the KIEE Conference
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    • 2009.04b
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    • pp.212-214
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    • 2009
  • The polymer electrolyte membrane fuel cell(PEMFC) with the advantages of low-operating temperature, high current density, low cost and volume, fast start-up ability, and suitability for discontinuous operation becomes the most reasonable and attractive power system for transportation vehicle and micro-grid power plant in a household. 200W PEMFC(Polymer electrolyte membrane fuel cell) system applied to middle and small-scaled micro-grid power system was constructed by this study, then the electrical characteristics and diagnosis of the fuel cell were analyzed with thermal variation.

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Pore-network Study of Liquid Water Transport through Multiple Gas Diffusion Medium in PEMFCs (고분자 연료전지의 다공성층 내에서의 액상수분 이동에 관한 공극-네트워크 해석 연구)

  • Kang, Jung-Ho;Lee, Sang-Gun;Nam, Jin-Hyun;Kim, Charn-Jung
    • 한국전산유체공학회:학술대회논문집
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    • 2011.05a
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    • pp.46-53
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    • 2011
  • Water is continuously produced in polymer electrolyte membrane fuel cell (PEMFC), and is transported and exhausted through polymer electrolyte membrane (PEM), catalyst layer (CL), microporous layer (MPL), and gas diffusion layer (GDL). The low operation temperatures of PEMFC lead to the condensation of water, and the condensed water hinders the transport of reactants in porous layers (MPL and GDL). Thus, water flooding is currently one of hot issues that should be solved to achieve higher performance of PEMFC. This research aims to study liquid water transport in porous layers of PEMFC by using pore-network model, while the microscale pore structure and hydrophilic/hydrophobic surface properties of GDL and MPL were fully considered.

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Impedance analysis of electrochemical systems using an ion-conducting polymer electrolyte membrane (전도성 고분자 전해질막을 이용하는 전기화학적 시스템의 임피던스 해석)

  • Park, Jin-Soo;Moon, Seung-Hyeon;Kim, Chang-Soo
    • Proceedings of the Membrane Society of Korea Conference
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    • 2004.05b
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    • pp.1-8
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    • 2004
  • Ion-conducting polymer electrolyte membranes (PEMs) have recently used in developing fuel cell or solar cell for portable, mobile and residential applications [1]. Polymer electrolyte membrane fuel cell (PEMFC), direct methanol fuel cell (DMFC), alkaline electrolyte fuel cell (AFC) and dye-sensitized solar cell have been employing the ion-conducting PEMs to complete their electrical circuits to produce electricity.(omitted)

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Implementation of a DSP Based Fuel Cell Hardware Simulator (DSP기반 연료전지 하드웨어 시뮬레이터 구현)

  • Oum, Jun-Hyun;Lim, Young-Cheol;Jung, Young-Gook
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.23 no.1
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    • pp.59-68
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    • 2009
  • Fuel cell generators as the distributed generation system with a few hundred watt$\sim$a few hundred kilowatt capacity, can supply the high quality electric power to user as compared with conventional large scale power plants. In this paper, PEMFC(polymer electrolyte membrane fuel cell) generator as micro-source is modelled by using PSIM simulation software and DSP based fuel cell hardware simulator based on the PSIM simulation model is implemented. The relation of fuel cell voltage and current(V-I curve) is linearized by first order function on the ohmic area in voltage-current curve of fuel cell. The implemented system is composed of a PEMFC hardware simulator, an isolated full bridge dc boost converter, and a 60[Hz] voltage source PWM inverter. The voltage-current-power(V-I-P) characteristics of the implemented fuel cell hardware simulator are verified in load variation and transient state and the 60[Hz] output voltage sinusoidal waveform of the PWM inverter is investigated under the resistance load and nonlinear diode load.

Effect of Tip Size and Aspect Ratio on Reforming Performance in a Methane Reformer for Polymer Electrolyte Membrane Fuel Cell (PEMFC) (고분자 전해질 막 연료전지를 위한 메탄 개질기에서 형상 변화가 개질 성능에 미치는 영향에 대한 연구)

  • Seo, Dong-Kyun;Noh, In-Kyu;Hwang, Jung-Ho;Choi, Jong-Kyun;Shin, Dong-Hoon;Kim, Hyung-Sik
    • Transactions of the Korean hydrogen and new energy society
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    • v.21 no.5
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    • pp.364-374
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    • 2010
  • Design of a reformer consisting of combustion chamber and reforming chamber was investigated for a 1 kW and a 5 kW polymer electrolyte membrane fuel cell (PEMFC), respectively, using the computational fluid dynamics (CFD). First, the 1kW reformer was considered to obtain the reliability of the numerical study. It was modeled, calculated and compared with experimental data. Second, the 5kW reformer was considered for a geometric study. Three tip sizes (35, 40, and 45 mm) and five aspect ratios was selected. It was found that the optimum was at tip sizes of 40 and 45 mm, at aspect ratios of -10% and -20% of the standard length.

An Experimental Analysis of the Ripple Current Applied Variable Frequency Characteristic in a Polymer Electrolyte Membrane Fuel Cell

  • Kim, Jong-Hoon;Jang, Min-Ho;Choe, Jun-Seok;Kim, Do-Young;Tak, Yong-Sug;Cho, Bo-Hyung
    • Journal of Power Electronics
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    • v.11 no.1
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    • pp.82-89
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    • 2011
  • Differences in the frequency characteristic applied to a ripple current may shorten fuel cell life span and worsen the fuel efficiency. Therefore, this paper presents an experimental analysis of the ripple current applied variable frequency characteristic in a polymer electrolyte membrane fuel cell (PEMFC). This paper provides the first attempt to examine the impact of ripple current through immediate measurements on a single cell test. After cycling for hours at three frequencies, each polarization and impedance curve is obtained and compared with those of a fuel cell. Through experimental results, it can be absolutely concluded that low frequency ripple current leads to long-term degradation of a fuel cell. Three different PEMFC failures such as membrane dehydration, flooding and carbon monoxide (CO) poisoning that lead to an increase in the impedance magnitude at low frequencies are simply introduced.

TA Study on the Performance and the Efficiency in Polymer Electrolyte embrane Fuel Cell (고분자전해질형 연료전지의 성능해석 및 효율에 관한 연구)

  • Kim Hong-Gun;Kim Yoo-Shin;Yang Sung-Mo;Nah Seok-Chan
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.4
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    • pp.75-80
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    • 2005
  • An experimental study is carried out to investigate the performance and the efficiency humidifying Membrane Electrolyte Assembly and having the double-tied catalyst layers in a fuel cell system which is taken into account the physical and thermal concept. Subsequently, an electric output produced by PEMFC(Polymer Electrolyte Membrane Fuel Cell) is measured to assess the performance of a stack, and the efficiency is also evaluated according to the different situation in which unit cell is placed with and without the humidification of the MEA. It is found that the measured values of stack voltage and current are influenced by the stack temperature, humidification, and the double-tied catalyst layers which give more enhanced values to be applied to electric units.

Research Trends of Polybenzimidazole-based Polymer Electrolyte Membranes for High-temperature Polymer Electrolyte Membrane Fuel Cells (고온 구동형 고분자 전해질 막 연료전지용 폴리벤즈이미다졸계 고분자 전해질 막의 개발 동향)

  • HyeonGyeong, Lee;Gabin, Lee;Kihyun, Kim
    • Membrane Journal
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    • v.32 no.6
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    • pp.442-455
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    • 2022
  • High-temperature polymer electrolyte membrane fuel cell (HT-PEMFC) has been studied as an alternative to low-temperature PEMFC due to its fast activation of electrodes and high resistance to electrode poisoning by carbon monoxide. It is highly required to develop stable PEMs operating at high temperatures even doped by ion-conducting materials for the development of high-performance and durable HT-PEMFC systems. A number of studies have been conducted to develop polybenzimidazole (PBI)-based PEMs for applications in HT-PEMFC due to their high interaction with doped ion-conducting materials and outstanding thermomechanical stability under high-temperature operation. This review focused on the development of PBI-based PEMs showing high performance and durability. Firstly, the characteristic behavior of PBI-based PEMs doped with various ion-conducting materials including phosphoric acid was systematically investigated. And then, a comparison of the physicochemical properties of the PEMs according to the different membrane manufacturing processes was conducted. Secondly, the incorporation of porous polytetrafluoroethylene substrate and/or inorganic composites to PBI matrix to improve the membrane performances was studied. Finally, the construction of cross-linked structures into PBI-based PEM systems by polymer blending method was introduced to improve the PEM properties.

Preparation of pore-filling membranes for polymer electrolyte fuel cells and their cell performances (고분자 연료전지용 세공충진막의 제조 및 연료전지 특성)

  • Choi, Young-Woo;Park, Jin-Soo;Lee, Mi-Soon;Park, Seok-Hee;Yang, Tae-Hyun;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.278-281
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    • 2009
  • Proton exchange membrane is the key material for proton exchange membrane fuel cells (PEMFC). Currently widely-used perfluorosulfonic acid membranes have some disadvantages, such as low thermal stability, easy swelling, excessive crossover of methanol and high price etc. Other membranes, including sulfonated polymer, radiation grafted membranes, organic-inorganic hybrids and acid-base blends, do not satisfy the criteria for PEMFC, which set a barrier to the development and commercialization of PEMFC. Pore-filling type proton exchange membrane is a new proton exchange membrane, which is formed by filling porous substrate with electrolytes. Compared with traditional perfluorosulfonic acid membranes, pore-filling type proton exchange membranes have many advantages, such as non- swelling, low methanol permeation, high proton conductivity, low cost and a wide range of materials to choose. In this research, preparation methodology of pore-filling membranes by particularly using all hydrocarbon polymers and fuel cell performances with the membranes are evaluated.

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