• Journal of the Korean Chemical Society
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• v.46 no.2
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• pp.117-124
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• 2002

Counterflow oxidation was developed and evaluated for treatment of organics that adsorbed in/on granular activated carbon(GAC). This reaction is a method that destructs and removes organics adsorbed, at the same time, regenerates waste carbon, uti lizing a self-sustained flame which propagates itself ina direction counter to the oxygen flow. The results showed that the mass loss of carbon and flam temperature were strongly dependent on the flow rate of oxyen, adsorptive capability of regenerated carbon completely was recovered, as well as destrution and removal efficiency of thermally stable PCBs was achieved with the value of better than 99.99%.

• Journal of Soil and Groundwater Environment
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• v.7 no.3
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• pp.61-70
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• 2002

Direct electron beam irradiation experiments on artificially contaminated soil by polynuclear aromatic hydrocarbons (PAHs) and polychlorinated biphenyls (PCBs) were performed to evaluate applicability of direct electron beam irradiation process for contaminated soil remediation. The removal efficiency of PAHs was about 97 % at 600 kGy and PCBs about 70 % at 800 kGy. PAHs were removed 27 % more, compared to PCBs although the absorbed dose was as low as 200 kGy. The contaminants decomposition was due predominantly to direct interaction of high-energy electrons and the target compounds rather than due to oxidation/reduction reaction by reactive intermediates. Radiolysis of electron beam may be able to decontaminate contaminated soil by toxic and recalcitrant organic compounds like as PAHs and PCBs effectively, but it may be economically uncompetitive. Thus, developments of post-treatment process of conventional site remediation technologies may be more practical and economical than direct radiolysis.

• Ocean and Polar Research
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• v.33 no.1
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• pp.45-53
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• 2011

Distribution of Polychlorinated biphenyls (PCBs) and organochlorine pesticides in sediments, seawater and fish tissues were examined. Concentrations of ${\Sigma}PCBs$ and ${\Sigma}DDTs$ in the intertidal sediments of Asan Bay ranged from $1.90{\sim}3.27\;ng\;g^{-1}$ dw (dry weight) and $0.51{\sim}1.26\;ng\;g^{-1}$ dw, respectively. ${\Sigma}PCBs$ concentrations in the tissue of greenling (Hexagrammos otakii), olive flounder (Paralichthys olivaceus) and finespotted flounder (Pleuronichthys cornutus) were $1.27{\pm}0.55$, $1.30{\pm}0.71$ and $1.19{\pm}0.43\;ng\;g^{-1}$ ww (wet weight), respectively. The profile of PCBs in the sediments and the 3 species of fish differed as witnessed by the dominance of tetra- to penta-chlorinated congeners in sediments while penta- to hexa-chlorinated congeners dominated in fish. ${\Sigma}DDTs$ concentrations were $0.67{\pm}0.52$, $0.79{\pm}0.61$, $1.58{\pm}1.05\;ng\;g^{-1}$ ww respectively in the tissue of greenling, olive flounder and finespotted flounder. The p,p'-DDE appeared to be the most important metabolite of DDT in studied fishes. The concentrations of PCBs and organochlorine pesticides measured in this study for fish were generally lower than those of previous studies. Compared to the pollutant concentration quality guidelines in marine fish, the environment of Asan Bay appears to be in a healthy state.

• Korean Journal of Environmental Agriculture
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• v.17 no.2
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• pp.117-121
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• 1998

In the study to reduce the error on the method of sampling pine needles to monitor the atmospheric concentration of polychlorinated biphenyls(PBCs),it was found that: 1. Concentration of PCBs almost linearly increased from new to three-years-old pine needles, so that the biomonitoring method using pine needles canbe applied to measuring long-term contamination from air in a local area. Needles of differernt age should not be mixed in sampling but be seperately analysed .It no good idea comparing PCB concentrations of differently aged needles. 2. Concentratio n of PCBs on pine needles had nothing to do whit the indivisual and age of the pine tree. 3. Concentration of PCBs on pine needles growing avobe was lower than that on needke below. 4. Concentration of PCBs on pine needles locatied in poorly ventilative places such as needle of a forest was lower than that on needles in well-ventilated areas.

• Journal of Aquaculture
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• v.16 no.4
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• pp.240-244
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• 2003

The primitive gonad development in Paralichthys olivaceus was classified into (ⅰ) primordial germ cell (PGC), (ⅱ) genital ridge type (GRT), (ⅲ) primitive gonad type I (PGT I) and (ⅳ) primitive gonad type II stages. In the control group, PGC was recognizable on the 3rd days after hatching, and the primodial gonad after 24th days, while it was around the 22nd day after hatching in the group exposed to PCBs 3.0 $\mu\textrm{g}$/L for 30 days. Likewise, the progress of kidney development was recognized in four stages; unitubular type of mesonephric duct (UTMD), the branched mesonephric duct (BMD), convoluted tubule formation (CTF) and glomerulus appearing (GA) stage. It was structurally completed between the 25th and 30th day after hatching in two groups. There was no significant difference (p>0.05) in the time scale of development of gonad, and kidney between control and the PCBs - exposed group.

• Analytical Science and Technology
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• v.18 no.1
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• pp.13-22
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• 2005

The elution patterns of seventeen 2,3,7,8-substituted PCDDs/Fs and 12 dioxin-like PCBs were studied by both manual open columns and automatic parallel LC columns in cleanup procedure. PCDDs/Fs and non-ortho-PCBs from other mono-ortho-PCBs were separated on automatic LC column, whereas they were not separated on an open manual column. The elution study on two cleanup methods was carried out using the PAR solution of unlabeled congeners and checked the recovery of each congener. Total recoveries of cleanup fractionation were ranged between 61.9 ~ 96.0% for PCDDs/Fs and 70.4 ~ 79.0% for PCBs by manual open columns and 71.8 ~ 104.5% for PCDDs/Fs and 61.3-120.3% for PCBs by automatic parallel LC columns, respectively. Unfortunately, #169-HxCB and 1,2,3,7,8-PeCDD were not separated on DB-5MS capillary column. The ions of 1,2,3,7,8-PeCDD were selected at M/M+2 instead of M+2/M+4 suggested by EPA method 1613. It is possible to discriminate 1,2,3,7,8-PeCDD and PCB #169 in HRGC/HRMS analysis.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.1
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• pp.88-95
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• 2009

This study is for understanding the domestic possibilities of the high temperature incineration of waste containing Polychlorinated Biphenyls (PCBs) with the analysis of normal operation case and waste gas, fly ash, dioxin about bottom ash, Total-PCBs, Co-PCBs, and the for analysis the heavy metal leaching feature included by bottom ash and fly ash, heavy metal leaching experiment was implemented. The result shows the dioxin density of the waste gas from waste containing PCBs was $0.00699{\sim}0.00763ng-TEQ/Nm^3$, which is lower than $0.0192ng-TEQ/Nm^3$ from the normal operation case. And each Co-PCBs and total PCBs shows $0.00043{\sim}0.00112ng-TEQ/Nm^3$ and $3.06{\sim}3.87ng/m^3$ respectively. The bottom ash test result shows Dioxin 0.00225~0.00630ng-TEQ/g, Co-PCBs 0.00027~0.00082ng-TEQ/g, Total PCBs 0.9~2.6ng/g, and the fly ash shows Dioxin 0.00164~0.00344ng-TEQ/g, Co-PCBs 0.00053~0.00054ng-EQ/g, Total PCBs 0.64~0.84ng/g. The bottom ash and fly ash experiments for heavy metal leaching did not show any leaching but when it comes to the ingredients of the fly ash, Pb elements shows 31.01~237.7ppm, higher than leaching criterion. The analysis of the density of all air pollution material from the waste gas shows the lower value than permissible criterion.

• Microbiology and Biotechnology Letters
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• v.34 no.2
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• pp.174-179
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• 2006

Bacterium capable of using biphenyl as a sole source of carbon and energy were isolated from soil, and based on the results of 16S rDNA sequence, strain BK10 identified as a Sphingobium yanoiktiyae. The optimum cultural conditions were as follows; $NH_4NO_3$ 1g, $K_2HPO_4$ 1g, $MgSO_4{\cdot}7H_2O$ 0.5g, $CaCO_3$ 0.2 g per 1 liter of distilled water. The Sphingobium yanoikuyae BK10 strain was completely utilized biphenyl in mineral salt media containing biphenyl at concentration 500 $\mu$g/ml of biphenyl as a sole carbon and energy source within 48 hours. Optimumal pH and temperature for biphenyl degradation and cell growth of strains were 6.0$\sim$8.0 and 20$\sim$50$^{\circ}C$, respectively. Especially, at 30$^{\circ}C$, cell-growth were higher than other temperature. Cell grown on biphenyl has been shown to have a higher removal rate for biphenyl than grown on sucrose. This study shows that Sphingobium yanoikuyae BK10 strain had a high biodegradation capability of biphenyl and can be simulate a candidate compounds the bioremediation of PCBs (Polychlorinated biphenyl) contaminant soil and water.

• Journal of Microbiology
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• v.41 no.3
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• pp.189-195
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• 2003

To enhance the reductive dechlorination of polychlorinated biphenyls (PCBs) under anaerobic conditions, we examined the adjunctive effects of cobalt (Co) and nickel (Ni), which are the central metals of transition-metal cofactors of coenzyme F$\_$430/ and vitamin B$\_$12/, respectively, on the dechlorination of Aroclor 1248. After 32 weeks of incubation, the average numbers of chlorines per biphenyl in culture vials supplemented with 0.2, 0.5, and 1.0 mM of Co reduced from 3.88 to 3.39, 2.92, and 3.28, respectively. However, the numbers of chlorine after supplementing with Ni decreased from 3.88 to 3.43, regardless of the Ni concentrations. The observed congener distribution patterns of all vials with different conditions were similar to the pattern produced by the dechlorination process of H' after 21 weeks of incubation, and these patterns were unchanged up to week 32, except for vials supplemented with 0.5 and 1.0 mM of Co. In vials containing 0.5 mM of Co, meta-rich congeners, such as 25/ 25-,24/25-, and 25/23-chlorobiphenyls (CBPs), which were found as accumulated products of dechlorination in other conditions, were further dechlorinated, and 25/2-, 24/2-, and 2/2-CBPs were concomitantly increased after 32 weeks of incubation. In this case, the congener distribution was similar to the dechlorination pattern of process M. From these results, we suggested that the enrichment of cultures with Co might stimulate the growth of specific populations of meta-dechlorinators, and that populations might promote a change in the dechlorination process from H' to M, which is known to be less effective on the dechlorination of the more highly chlorinated congeners of PCBs.

• Journal of Korean Society of Environmental Engineers
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• v.27 no.4
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• pp.385-389
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• 2005

To understand the pollution level by polychlorinated biphenyls (PCBs) in ambient air of industrial area, PCBs concentrations were measured at Sihwa and Banwol industrial region, Korea. The concentrations of total PCB and WHO-TEQ ranged from 2,080 to $5820\;pg/m^3$ (median value is 2,760) and from 0.19 to $1.01\;pgTEQ/m^3$ (median value is 0.42), respectively. In terms of homologues composition the fraction of highly chlorinated biphenyls(from hexa-CB to deca-CB) were higher than the air samples of other regions such as jeonju and yokohama area. The cluster analysis was conducted to study the relation between the air samples and sources such as incinerator flue gases and Aroclor samples. The isomer fractions in the homologue were used as input variables. Based on the results, the industrial ambient air samples were divided from source samples with long Euclidian distance. This suggest that the ambient air samples of Sihwa and Banwol were not on the influence of Aroclor and incinerators. Therefore, further investigation on systematical air monitoring will be required to estimate the sources of PCBs in the above industrial areas.