• Title/Summary/Keyword: P.E 필름

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P3HT의 두께와 결정화도가 ZnO/P3HT 태양전지에 미치는 영향 비교 분석

  • Park, Seong-Hwak;No, Im-Jun;Jo, Jin-U;Kim, Seong-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.278-278
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    • 2010
  • 3.37 eV의 와이드 밴드갭과 60 mV의 높은 엑시톤 결합에너지를 갖는 반도체인 ZnO는 화학 및 열적 안정성, 압전특성 등 다양한 특성을 갖는 물질로써, 수열합성법을 이용하여 길이 $1.5{\mu}m$, 직경 100nm의 n-type ZnO 나노와이어를 성장시켰으며, P3HT는 유기 태양전지에서 가장 많이 사용되는 고분자 도너로써 열처리를 통하여 결정화 됨에 따라, 엑시톤의 확산속도나 전하의 이동도가 증가하여 더 많은 광전류를 생성하는 장점을 가지고 있다. 본 연구에서는 ZnO 필름이 아닌 n-type ZnO 나노와이어와 Poly(3-hexylthiophene) (P3HT)를 사용 하여 ZnO/P3HT 이종접합 태양전지를 제작하였다. 기판으로 글래스, 전극으로 ITO (Indium Tin Oxide), 나노와이어의 씨앗층으로 ZnO:Al를 스퍼터로 100nm 증착 하였다. Znc nitrate hydrate와 hexamethylenetetramine이 혼합된 수용액에서 기판을 담그고 n-type ZnO 나노와이어 성장 시키고, P3HT의 스핀 코팅조건과 열처리 온도를 변화시켜 P3HT의 두께와 결정화도가 ZnO/P3HT 이종접합 태양전지에 미치는 영향을 비교 분석 하였다.

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Study of Efficiency Test and Subjective Responses about Pendent Task Lighting System Using Phosphor Luminescent Film LED (광기여 필름 LED 팬던트 작업조명시스템 주관평가와 성능검증)

  • Cha, Kwang-Seok;Kim, Hway-Suh
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.23 no.3
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    • pp.188-193
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    • 2011
  • For a long time work or study, pendent task lighting system prepared with phosphor luminescent film LED was developed for eye protection and working efficiency improvement. Developed lighting system was used together with pendent and ambient lighting. Such as, we made comfortable lighting environment system. Evaluation for developed lighting system, that had proceeded to Mock-up test and subjective evaluation. Also It had proceeded that lighting environment analyzed and compatibility valuation of installation. In subjective evaluation, the students have expressed themselves satisfied to phosphor luminescent film LED lighting system. In Mock-up test, It is not problem to intensity of illumination, luminance and color temperature. Therefore, developed LED lighting system was installed at the Daegu apartment. It is having a P.O.E study progress to phosphor luminescent film LED lighting system.

Changes in Quality of Shiitake Mushroom (Lentinus edodes) during Modified Atmosphere(MA) Storage (MA 저장중 표고버섯 (Lentinus edodes)의 품질변화에 관한 연구)

  • 김길환;이세은;김동만
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.20 no.2
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    • pp.133-138
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    • 1991
  • Several quality indices of Shiitake mushroom (Lentinus edodes) were measured during storage at modified atmosphere (MA) conditions made by plyethylene film bag with different thicknes. IN the mushrooms kept in the thicker film bag, larger amounts of ethyl alcohol and acetaldehyde were produced during storage. The lowest weight loss was marked by the mushrooms kept in 0.06mm thick film bag. Protein content of the mushrooms was increased with the storage period without any storage period without any significant trend depended on the storage treatments and electrophoresis pattern of protein was changed little in the mushrooms kept in 0.04mm thick P.E. film bag during storage.

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Evaluation of Elastic Properties of DLC Films Using Substrate Etching Techniques (기판 Etching 기법을 이용한 DLC 필름의 탄성특성 평가)

  • 조성진;이광렬;은광용;한준희;고대홍
    • Journal of the Korean Ceramic Society
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    • v.35 no.8
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    • pp.813-818
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    • 1998
  • A simple method to measure the elastic modulus E and Poisson's ratio v of diamod-like carbon (DLC) films deposited on Si wafer was suggested. Using the anisotropic etching technique of Si we could make the edge of DLC overhang free from constraint of Si substrate. DLC film is chemically so inert that we could not on-serve any surface damage after the etching process. The edge of DLC overhang free from constraint of Si substrate exhibited periodic sinusoidal shape. By measuring the amplitude and the wavelength of the sinu-soidal edge we could determine the stain of the film required to adhere to the substrate. Since the residual stress of film can be determine independently by measurement of the curvature of film-substrate com-posite we could calculated the biaxial elastic modulus E/(1-v) using stress-strain relation of thin films. By comparing the biaxial elastic modulus with the plane-strain modulus E/(1-{{{{ { v}^{2 } }}) measured by nano-in-dentation we could further determine the elastic modulus and Poisson's ratio independently. This method was employed to measure the mechanical properties of DLC films deposited by {{{{ { {C }_{6 }H }_{6 } }} rf glow discharge. The was elastic modulus E increased from 94 to 169 GPa as the {{{{ { V}_{ b} / SQRT { P} }} increased from 127 to 221 V/{{{{ {mTorr }^{1/2 } }} Poisson's ratio was estimated to be abou 0.16∼0.22 in this {{{{ { V}_{ b} / SQRT { P} }} range. For the {{{{ { V}_{ b} / SQRT { P} }} less than 127V/{{{{ {mTorr }^{1/2 } }} where the plastic deformation can occur by the substrate etching process however the present method could not be applied.

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Feasibility as radiation detectors of Flexible ITO film fabricated by roll-to-roll sputtering (롤-투-롤 스퍼터링으로 제작된 Flexible ITO Film의 방사선검출기 적용가능성 연구)

  • Kim, Sung-Hun;Lee, S.H.;Jeon, S.P.;Park, G.U.;Heo, E.S.;Sung, Han-Kyu;Park, J.G.;Nam, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.374-374
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    • 2010
  • 본 연구는 Roll-to-Roll Sputtering 장비를 사용하여 제작된 Flexible ITO electrode 필름의 방사선 검출기로의 적용가능성을 알아보기 위해 기존의 Glass ITO electrode의 전기적 특성을 비교 평가하였다. 본 연구는 Flexible ITO electrode와 Glass ITO electrode을 하부전극으로 형성하고, 최근에 X-ray 변환체로 활발히 연구되고 있는 Powder 형태의 반도체물질인 HgI2 와 PbI2를 Binder와 일정한 비율로 혼합하여 3-Rolls-Miller를 사용하여 Powder를 일정한 미세크기로 만들고, 대면적 제작이 용이한 Screen-Printing method을 이용하여 시편을 제작하였다. 제작된 필름은 하부전극의 종류에 따른 X-ray 입사 후의 전기적신호의 차이를 측정하고, HgI2와 PbI2 중 Flexible ITO electrode와 더욱 효율적으로 반응하여 기존의 Glass ITO electrode를 대체할 수 있는 전극을 발견하여 진단용 의료영상의 왜곡 현상을 제거할 수 있는 Flexible 방사선 검출기의 제작의 초석을 제공하는 연구를 목적으로 한다. SEM(Scanning Electron Microscope) 통하여 반도체 물질의 결정구조와 크기를 알아보았고, 하부 전극의 종류에 따른 전기적 신호검출을 위해 제작된 필름의 암전류(Dark current) 와 민감도(Sensitivity)를 측정한 후, SNR (Signal -to- Noise)을 계산하여 평가하였다.

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Synthesis and Characterization of Phenylene-Thiophene-Thieno[3,4-b]pyrazine Oligomer (Phenylene-Thiophene-Thieno[3,4-b]pyrazine 올리고머의 합성과 특성)

  • Hwang, Mi-Lim;Li, Ji-Cheng;Seo, Eun-Ok;Lee, Soo-Hyoung;Lee, Youn-Sik
    • Korean Chemical Engineering Research
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    • v.49 no.1
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    • pp.95-100
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    • 2011
  • During the development of low band-gap organic materials(p-type semiconducting organic compounds) for organic solar cells, an oligomer consisting of 2,5-dioctyloxyphenylene(OP), 3-hexylthiophene(HT), and 2,3-dimethylthieno[ 3,4-b]pyrazine(TP) as repeat units, oligo(OP-HT-TP), was synthesized. The oligomer was amorphous in nature in the temperature range studied, and well soluble in common organic solvents such as chloroform. The maximum absorption wavelength was 716 nm in solid state. The band-gap and HOMO/LUMO energy levels of oligo(OP-HT-TP) were measured to be 1.20 eV and -5.27/4.04 eV, respectively. However, the absorbance of the oligomer at maximum absorption wavelength was less than one fifth of that of poly(3-hexylthiophene) which has been most frequently used in fabrication of organic solar cells.

Studies on Persistence of Pesticides in Soils and Crops under Polyethylene Film Mulching Culture;III. Persistence of Soil Insecticides Endosulfan, Fonofos and Ethoprophos (폴리에틸렌 멀칭재배시(栽培時) 농약(農藥)의 토양(土壤) 및 작물체중(作物體中) 잔류(殘留)에 관한 연구(硏究);제(第)3보(報) 토양살충제 Endosulfan, Fonofos, Ethoprophos의 잔류성(殘留性))

  • Ryang, Hwan-Seung;Moon, Young-Hee;Kim, Nak-Eung
    • Korean Journal of Environmental Agriculture
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    • v.7 no.1
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    • pp.8-13
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    • 1988
  • This experiment was conducted to evaluate the effect of polyethylene film(P.E.) mulching on degradation of the soil insecticides, endosulfan(6,7,8,9,10,10-hexachloro-1,5,5a,6,9,9a-hexahydro-6,9-methano-2,4,3-benzodioxathiepin-3-oxide), fonofos(O-ethyl S-phenyl ethylphosphonodithioate), and ethorprophos(O-ethyl S, S-dipropyl phosphorodithioate) in red pepper, peanut, and sesame fields. Degradation of endosulfan, fonofos and ethoprophos in the soils under P.E. mulching and non-mulching followed first-order kinetics. The half-lives of fonofos, ethoprophos, ${\alpha}-$ and ${\beta}-endosulfan$ were $19{\sim}21$, $25{\sim}37$, $33{\sim}39$ and $56{\sim}81$ days, respectively. There were few differences in the half-lives of fonofos in either mulching or non-mulching concitions. However, half-lives of α-endosulfan, ethoprophos, and ${\beta}-endosulfan$ were 6, 12 and 25 days longer under P.E. mulching than under non-mulching conditions, respectively. The effect of P.E. mulching on degradation was remarkable for the slower degrading insecticides. Residues of ethoprophos in the harvested sesame under P.E. mulching and non-mulching conditions were 0.024 and 0.074ppm, respectively. Residues of fonofos in the harvested peanuts under P.E. mulching and non-mulching conditions were 0.078 and 0.017ppm, respectively. However, no endosulfan was detected in the harvested red peppers under either condition.

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Production of Transgenic Birdsfoot Trefoil (Lotus corniculatus L.) Plants by Introduction of E35S Promoter + AtNDPK2 Gene (E35S 프로모터 + AtNDPK2 유전자 도입에 의한 버즈풋 트레포일 (Lotus corniculatus L.) 형질전환체 생산)

  • Kim Ki-Yong;Jang Yo-Soon;Choi Gi-Jun;Sung Byung-Ryeol;Kim Won-Ho;Seo Sung;Lee Byung-Hyun;Kwak Sang-Soo
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.26 no.2
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    • pp.83-90
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    • 2006
  • To develop transgenic birdsfoot trefoil (Lotus corniculatus L.) plants tolerant to environmental stress, Arabidopsis NDPK gene (AtNDPK) was introduced into birdsfoot trefoil plants using Agrobacterium-mediated transformation and expressed powerfully under the control of the E35S promoter. The expression vector, pEN-K was used for introduction of AtNDPK gene into birdsfoot trefoil plaits. The transformed calli were selected on kanamycin containing medium and then regenerated. The transformed birdsfoot trefoil plants were cultivated for 4 months on BOi2Y medium. Genomic DNA PCR and Southern blot analysis confirmed the incorporation of AtNDPK into the birdsfoot trefoil genome.

The Bildegradability of Carrageenan-based Film by Microorganisms (Carrageenan 필름의 미생물에 의한 생분해도 측정)

  • Kang, Seong Gook;Jung, Soon-Teck;Park, Hyun Jin;Rhim, Jong Whan
    • Microbiology and Biotechnology Letters
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    • v.23 no.6
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    • pp.702-709
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    • 1995
  • Degradation Of $\kappa $-carrageenan-based film by microorganisms screened from carrageenan source and activated sludge of a carrageenan producing factory was investigated by measuring changes of pH, viscosity, total sugar and total organic carbon (TOC) of the medium containing $\kappa $-carrageenan as a carbon source. Initially fifteen strains of microorganism were isolated from carrageenan source and activated sludge and then three organisms among them were selected based on the ability of growing in the medium including 0.3% $\kappa $-carrageenan as a sole carbon source. They were identified as Escherichia coli, Saccharomyces cerevisiae and Aspergillus niger. As indices of biodegradability Of $\kappa $-carrageenan based film, the changes of pH, viscosity, total sugar, and TOC of the carrageenan film-based medium were tested by the cultivation of single or mixed strains of the identified organisms. Mixed culture showed the highest biodegradability, which resulted in the changes of pH from 6.5 to 3.0, viscosity from 164 cps to 15.6 cps, total sugar content from 2.35 g/l to 0.53 g/l and TOC from 5721 ppm to 232 ppm after 30 days of cultivation. The biodegradability determined as the reduction rate of TOC by pure cultures of Asp. niger, E. coli, Sacch. cerevisiae and mixed culture of the three organisms were 94%, 86%, 80% and 96%, respectively.

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Propagation of Crack in Concrete Subjected to Dynamic Loading (동적하중(動的荷重)을 받는 콘크리트의 구열(龜裂)성장)

  • Kang, Sung Hoo;Kim, Woo
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.8 no.2
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    • pp.135-145
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    • 1988
  • This study deals with the prediction of crack propagation in concrete mortar subjected to static and dynamic load. Total 54 CLWL-DCB(Crack-line-loaded-double-cantilever beam) concrete mortar specimens were tested to measure crack growth using ASTM 561-80. Main variables were sand to cement ratio and water to cement ratio. The resulting load(P)-COD(Crack Opening Displacement; $2V_1$) curves and COD-CTOD (Crack Tip Opening Displacement; $2V_2$) curves were analyzed to calculate effective crack length and physical crack length by way of ASTM 561-80 proposed. Replica crack length were also obtained directly during the test. The differences in crack propagation between under static load and under dynamic load were investigated.

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