• Title/Summary/Keyword: P recovery

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A study on the recovery of chromium from metal-plating wastewater with spent catalyst (폐산화철촉매에 의한 도금폐수중 크롬이온 회수에 관한 기초연구)

  • Lee Hyo Sook;Oh Yeung Soon;Lee Woo Chul
    • Resources Recycling
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    • v.13 no.2
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    • pp.9-15
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    • 2004
  • A large tons of spent iron oxide catalyst come from the Styrene Monomer(SM) production company. It is caused to pollute the land and underground water due to the high alkali contents in the catalyst by burying them in the landfill. In order to recycle the spent catalyst, a basic study on the recovery of chromium ion from metal plating wastewater with the spent catalyst was carried out. The iron oxide catalyst adsorbed physically $Cr^{+6}$ in the lower pH 3.0, that is the isoelectric point of the spent catalyst. It was found that the iron oxide catalyst reduced the $Cr^{+6}$ into Cr+3 by the oxidation of ferrous ion into ferric ion on the surface of catalyst, and precipitated as $Cr(OH)_3$ in the higher than pH 3.0. The $Cr^{+6}$ was recovered 2.0∼2.3g/L catalyst in the range of pH 0.5∼2.0, but it was recovered 1.5 g/L catalyst at pH 3.0 of wastewater. The recovery of Cr was increased as the higher concentration in the continuous process, but the flowrates were nearly affected on the Cr recovery.

STABLE AND ROBUST ℓp-CONSTRAINED COMPRESSIVE SENSING RECOVERY VIA ROBUST WIDTH PROPERTY

  • Yu, Jun;Zhou, Zhiyong
    • Journal of the Korean Mathematical Society
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    • v.56 no.3
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    • pp.689-701
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    • 2019
  • We study the recovery results of ${\ell}_p$-constrained compressive sensing (CS) with $p{\geq}1$ via robust width property and determine conditions on the number of measurements for standard Gaussian matrices under which the property holds with high probability. Our paper extends the existing results in Cahill and Mixon from ${\ell}_2$-constrained CS to ${\ell}_p$-constrained case with $p{\geq}1$ and complements the recovery analysis for robust CS with ${\ell}_p$ loss function.

Intensity of Intraoperative Spinal Cord Hyperechogenicity as a Novel Potential Predictive Indicator of Neurological Recovery for Degenerative Cervical Myelopathy

  • Guoliang Chen;Fuxin Wei;Jiachun Li;Liangyu Shi;Wei Zhang;Xianxiang Wang;Zuofeng Xu;Xizhe Liu;Xuenong Zou;Shaoyu Liu
    • Korean Journal of Radiology
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    • v.22 no.7
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    • pp.1163-1171
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    • 2021
  • Objective: To analyze the correlations between intraoperative ultrasound and MRI metrics of the spinal cord in degenerative cervical myelopathy and identify novel potential predictive ultrasonic indicators of neurological recovery for degenerative cervical myelopathy. Materials and Methods: Twenty-two patients who underwent French-door laminoplasty for multilevel degenerative cervical myelopathy were followed up for 12 months. The Japanese Orthopedic Association (JOA) scores were assessed preoperatively and 12 months postoperatively. Maximum spinal cord compression and compression rates were measured and calculated using both intraoperative ultrasound imaging and preoperative T2-weight (T2W) MRI. Signal change rates of the spinal cord on preoperative T2W MRI and gray value ratios of dorsal and ventral spinal cord hyperechogenicity on intraoperative ultrasound imaging were measured and calculated. Correlations between intraoperative ultrasound metrics, MRI metrics, and the recovery rate JOA scores were analyzed using Spearman correlation analysis. Results: The postoperative JOA scores improved significantly, with a mean recovery rate of 65.0 ± 20.3% (p < 0.001). No significant correlations were found between the operative ultrasound metrics and MRI metrics. The gray value ratios of the spinal cord hyperechogenicity was negatively correlated with the recovery rate of JOA scores (ρ = -0.638, p = 0.001), while the ventral and dorsal gray value ratios of spinal cord hyperechogenicity were negatively correlated with the recovery rate of JOA-motor scores (ρ = -0.582, p = 0.004) and JOA-sensory scores (ρ = -0.452, p = 0.035), respectively. The dorsal gray value ratio was significantly higher than the ventral gray value ratio (p < 0.001), while the recovery rate of JOA-motor scores was better than that of JOA-sensory scores at 12 months post-surgery (p = 0.028). Conclusion: For degenerative cervical myelopathy, the correlations between intraoperative ultrasound and preoperative T2W MRI metrics were not significant. Gray value ratios of the spinal cord hyperechogenicity and dorsal and ventral spinal cord hyperechogenicity were significantly correlated with neurological recovery at 12 months postoperatively.

A Study on the Physical Properties of Addition Silicone Impression Materials (부가중합형실리콘인상재의 물리적 특성에 대한 연구)

  • Kim, Soo-Hwa
    • Journal of dental hygiene science
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    • v.6 no.4
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    • pp.231-235
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    • 2006
  • This study evaluated the properties of polyvinylsiloxane impression materials: Strain-in-compression, Elastic recovery, Consistency, and Wettability. Four polyvinylsiloxane impression materials(Examixfine, GC, Japan; Aquasilultra, Dentsply, USA; Extrude, Kerr, USA; Perfect-F, Handae, Korea) were used in this study. The measured data were analyzed with SPSSWIN 12.0 program. The results were as follows : 1. The strain-in-compression values showed that Extrude had the lowest value, 4.86% and Examixfine had the highest value, 6.78%. Significant difference between Examixfine and Perfect-F was not found but the other groups had significant differences(p = 0.000). 2. In the elastic recovery test, Extrude had the highest, 99.83% and Perfect-F had the lowest, 96.54%. There is no significant difference between Examixfine and Aquasilultra. The other impression material groups showed significant differences(p = 0.000). 3. The measurement of consistency results that the diameter of Examixfine was the largest, 45.12mm and one of Perfect-F was the smallest, 40.28 mm. No differences were shown between Examixfine and Aquasilultra and between Extrude and Perfect-F(p = 0.001). 4. Aquasilultra had a better hydrophilicity($47.85^{\circ}$) than other materials. Perfect-F had a larger contact angle($94.89^{\circ}$) and was hydrophobic. There were significant differences between groups(p = 0.000). 5. As for correlation among the test types, contact angle correlated with strain-in-compression, elstic recovery and consistency. The strain-in-compression had correlation to contact angle and elastic recovery. The elastic recovery correlated with contact angle and strain-in-compression. And the consistency had correlation to contact angle.

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Comparison of Sampling Filters for Airborne Hexavalent Chromium in Plating Operation (도금공정 공기중 6가 크롬 시료채취여과지 비교에 관한 연구)

  • 이병규;신용철
    • Journal of Environmental Health Sciences
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    • v.29 no.2
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    • pp.69-76
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    • 2003
  • Hexavalent chromium may reduce on polyvinyl chloride (PVC) filter during sampling and storage of sample. Recently, new or modified filters for preventing Cr(VI) from the reduction has been introduced. Thus, this study was performed to compare the reduction behaviors of Cr(VI) on several sampling filters and to find the most appropriate filter for airborne Cr(VI) sampling in plating operation. The results were as follows. 1. There were statistically significant differences among PVC, polytetrafluoroethylene (PTFE). glass fiber (GF) and polyvinylidene fluoride (PVDF) filters in recovery rates of spiked Cr(VI) samples by storage time(p<0.05). There was no significant difference between PVC and PTFE filters(p>0.05). The PVC and PTFE filters showed higher recoveries than GF and PVDF filters(p<0.05). 2. The quartz fiber(QF) filter treated with an alkali solution(2% NaOH/3% Na$_2$CO$_3$, 1% NaOH) showed a significantly higher recovery of Cr(VI) by storage time than other filters(GF and QF filter)(p<0.05). There was no difference in recovery of Cr(VI) between alkali-treated and untreated GF it filters(p>0.05). But the QF filters treated with two alkali solution showed a significantly higher recovery than the untreated QF filter(p<0.05). There was no significant difference in recovery of Cr(VI) between QF filters treated with 1% NaOH and 2% NaOH/3% Na$_2$CO$_3$(p>0.05). In conclusion, treatment of QF fillers with alkali solution was most effective in protecting from the reduction of Cr(VI).

Manufacturing of Mg-Zeolite Using for Simultaneous Recovery of the N and the P from sewage water (하수로부터 질소(N)와 인(P)을 동시에 회수할 수 있는 Mg-Zeolite의 제조)

  • Cho, Heon-Young;Suh, Jung-Mok
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2003.10a
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    • pp.122-128
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    • 2003
  • To develop a Mg-Zeolite for simultaneous recovery of the N and the P from sewage water, the natural zeolite was treated with 20% $MgCl_2$ solution by changing the pH the temperature and the treating time of the solution. And the contents of Ca Fe Na K Mg of Mg-Zeolite were analyzed by ICP. The optimum treatment condition for Mg-Zeolite was induced to pH 7.0 $50^{\circ}C$ in 20% $MgCl_2$ solution and for 80min treatment. And the Na and the K ions in natural zeolite are significant factors for Mg exchange in the zeolite.

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A Study on Oxygen Consumption during Occupational Activities Performance of Adult Hemiplegia (성인 편마비 환자의 작업수행 중 산소소모량에 대한 연구)

  • Oh, Kyung-Ah;Yoon, Seoung-Ic;Min, Kyung-Ok;Kim, Yoon-Shin;Oh, Duck-Won;Chon, Seung-Chul
    • Journal of Korean Physical Therapy Science
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    • v.15 no.1
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    • pp.21-28
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    • 2008
  • The purposes of this study are to quantify energy expenditure by measuring oxygen consumption while performing occupational therapy activities most commonly used for adult hemiplegia patients, to recommend a optimal dosage of exercise by comparing energy expenditure according to the recovery stage, and to suggest a precaution in the treatment of patients with cardiac disorders. According to Brunnstrom recovery stages in hand function, subjects were allocated to group I(3rd and 4th Brunnstrom recovery stages) and group II(5th and 6th Brunnstrom recovery stages). Outcome measures included oxygen consumption, energy expenditure rate, and heart rate during each activity and in recovery period after the activity. Occupational activities including sanding activity, putty activity, and skateboard activity were carried out for all patients. In sanding and putty activities, there were significant differences of oxygen consumption and energy expenditure during the activity between groupⅠandⅡ(p<0.05), but there were not significant differences of oxygen consumption, energy expenditure and heart rate in the recovery period(p>0.05). In skateboard activity, there were no significant differences in oxygen consumption, energy expenditure and heart rates between the two groups during the activity and in the recovery period(p>0.05). The findings indicates that cardiovascular demands for basic activities usually peformed for a treatment may be depended on the physical recovery of patients with hemiplegia. Therefore, therapeutic activities for patients should be selected with the great care.

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Mg/Al Impregnated Biochar for the Removal and Recovery of Phosphates and Nitrate

  • Kim, Dong-Jin
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2019.10a
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    • pp.134-134
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    • 2019
  • Utilization of organic waste as a renewable energy source is promising for sustainability and mitigation of climate change. Pyrolysis converts organic waste to gas, oil, and biochar by incomplete biomass combustion. Biochar is widely used as a soil conditioner and adsorbent. Biochar adsorbs/desorbs metals and ions depending on the soil environment and condition to act as a nutrient buffer in soils. Biochar is also regarded as a carbon storage by fixation of organic carbon. Phosphorus (P) and nitrogen (N) are strictly controlled in many wastewater treatment plants because it causes eutrophication in water bodies. P and N is removed by biological and chemical methods in wastewater treatment plants and transferred to sludge for disposal. On the other hand, P is an irreplaceable essential element for all living organisms and its resource (phosphate rock) is estimated about 100 years of economical mining. Therefore, P and N recovery from waste and wastewater is a critical issue for sustainable human society. For the purpose, intensive researches have been carried out to remove and recover P and N from waste and wastewater. Previous studies have shown that biochars can adsorb and desorbed phosphates implying that biochars could be a complementary fertilizer. However, most of the conventional biochar have limited capacity to adsorb phosphates and nitrate. Recent studies have focused on biochar impregnated with metal salts to improve phosphates and nitrate adsorption by synthesizing biochars with novel structures and surface properties. Metal salts and metal oxides have been used for the surface modification of biochars. If P removal is the only concern, P adsorption kinetics and capacity are the only important factors. If both of P and N removal and the application of recovery are concerned, however, P and N desorption characteristics and bioavailability are also critical factors to be considered. Most of the researches on impregnated biochars have focused on P removal efficiency and kinetics. In this study, coffee waste is thermally treated to produce biochar and it was impregnated with Mg/Al to enhance phosphates and nitrate adsorption/desorption and P bioavailability to increase its value as a fertilizer. Kinetics of phosphates and nitrate adsorption/desorption and bioavailability analysis were carried out to estimate its potential as a P and N removal adsorbent in wasewater and a fertilizer in soil.

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Development of Peer-Leadership Program focused on Recovery of People with Mental Illness (정신장애인 회복에 초점을 둔 당사자 리더십 프로그램 개발 연구)

  • Kim, Min;Lee, Keunhee
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.6
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    • pp.256-265
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    • 2020
  • The purpose of this study was to develop and explore the effectiveness of a peer-leadership program on the recovery of people with mental illness. To develop the program, a literature review and an analysis of developed programs were performed.Brown's recovery framework was applied, including an understanding of mental illness, self-leadership, empowerment, and self-directed action plans. A program was developed (6 sessions over 3 days) including peer-led activities, disability awareness and perception, and recovery action plans. The program consisted of education, understanding, planning, and implementation. Its focus was on recovery-oriented activities for empowering people with mental illness. Twenty people with mental illness and using mental rehabilitation centers participated in the program. Four scales (i.e., stigma, empowerment, leadership, and disability awareness) were used for the pre-post analysis. The study results showed statistically significant differences in the participants' levels of stigma (p< .05), empowerment (p < .05), leadership (p< .01), and disability awareness (p< .05) after completing the program. These findings suggest that the peer-leadership program is a recovery program that includes increased understanding of mental illness, empowerment, and leadership capability. Discussions and suggestions were provided for a future study based on the results.

The Study on the Recovery Process of Zinc Metal from EAF Dust by Chemical Treatment (EAF 분전의 화학적처리에 와한 금속아연의 제조에 관한 연구)

  • Jeong, Rae-Youn;Lee, Jin-Hui
    • Journal of the Korean Applied Science and Technology
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    • v.27 no.2
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    • pp.208-215
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    • 2010
  • EAF dust which is contained around 30% of zinc, 15% of iron and 3% of lead individually, is chemically treated by ammonium chloride, ammonia water, ammonia gas and carbon dioxide, and also tested and identified the ratios of the recovery of In by applied the variations of particle size, pH and heating temperature as well, in order to getting optimized recovery of the In metal after performing all of those processes. Experimental results showed that the rate of Zn recovery is 97% when the mixture of 1.3 of $NH_4Cl$/EAF is heated to the temperature of $400^{\circ}C$ and leached by water, and 95% recovery of In when ammonia gas and carbon dioxide is added simultaneously and adjust the 9.5 of pH to the same mixture above. For the purpose of remove the impurities in the mixed sample, which is prepared by the two samples, indicated above showing as the ratio of 95% and 97% recovery, in case of applied the cementation process to it, and also by electrolytic process, produced the In plate of 95~97%, and acquired 99-99.5% of In metal ingot finally by applied the heating process at $470{\sim}500^{\circ}C$.