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Adsorption Characteristics of Ammonia, Hydrogen Sulfide and Methylmercaptan on Activated Carbons with Different pH (활성탄의 pH에 따른 Ammonia, Hydrogen Sulfide 및 Methylmercaptan 흡착 특성)

  • 김정열;신창호;서문원;김종열;김영호;이근회
    • Journal of the Korean Society of Tobacco Science
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    • v.19 no.1
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    • pp.46-50
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    • 1997
  • The pH of coconut based activated carbon was changed by treating with NaOH and HNO3 and we have calculated the adsorption amounts of ammonia, hydrogen sulfide and methylmercaptan on the activated carbons using the break-through time which was obtained from break-through curve experiments. As a result of this study, the adsorption amounts of ammonia Has on the activated carbons were 2,6 mg/g, 17.2 mg/g and 31.6 mg/g with the pH 11, pH 7 and pH 3, respectively. These results indicated that the adsorption ability of ammonia on activated carbon was increased with decreasing the pH of activated carbon. Otherwise, in the cases of the adsorption experiment of hydrogen sulfide and methylmercaptan on the activated carbons with different pH. the activated carbon with pH 11 showed higher adsorption capacity than the activated carbons with pH 7 and pH 3. The adsorption amounts of hydrogen sulfide and methylmercaptan were 39.9 mg/g and 178 mg/g with pH 11, respectively. Finally, we analyzed the amount of ammonia delivered from 88 Lights cigarette made of triple filter which contained the activated carbon. The amount of ammonia delivered to smoke from the filter cigarette containing the activated carbon with pH 3 was 45.1${\mu}g$/cig. This value was lower 23.8 % than that from the activated carbon with the pH 11.

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Expression of Glypican-3 in Mouse Embryo Stem Cells and its Derived Hepatic Lineage Cells Treated with Diethylnitrosamine in vitro

  • Kim, Young Hee;Kang, Jin Seok
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.11
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    • pp.6341-6345
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    • 2013
  • To clarify the role of stem cells in hepatocarcinogenesis, glypican-3 (GPC-3) and E-cadherin expression was investigated in embryonic cell lineages. Mouse embryonic stem cells (ESCs), hepatic progenitor cells (HPCs) and hepatocyte like cells (HCs), representing 0, 22 and 40 days of differentiation, respectively, were treated in vitro with diethylnitrosamine (DEN) at four doses (0, 1, 5 and 15 mM; G1, G2, G3 and G4, respectively) for 24 h and GPC-3 and E-cadherin expression was examined by relative quantitative real-time PCR and immunocytochemistry. GPC-3 mRNA expression was significantly different for G4 at day 0 (p<0.001) and for G4 at day 22 (p<0.01) compared with the control (G1). E-cadherin mRNA expression was significantly different for G3 and G4 at day 0 (p<0.05 and p<0.001, respectively), for G2 and G4 (p<0.05 and p<0.001, respectively) at day 22 and for G2 and G4 (p<0.01 and p<0.001, respectively) at day 40 compared with G1. Immunofluorescence staining for GPC-3 showed a membranous and/or granular expression in cytoplasm of ESCs and HPCs and granular and/or diffuse expression in cytoplasm of HCs, which were also stained by E-cadherin. DEN treatment increased GPC-3 expression in ESCs, HPCs and HCs, with increase of E-cadherin expression. Taken together, the expression of GPC-3 was altered by DEN treatment. However, its expression pattern was different at the stage of embryo stem cells and its derived hepatic lineage cells. This suggests that GPC-3 expression may be modulated in the progeny of stem cells during their differentiation toward hepatocytes, associated with E-cadherin expression.

PEBBLING EXPONENTS OF PATHS

  • Kim, Ju-Young;Kim, Sun-Ah
    • Honam Mathematical Journal
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    • v.32 no.4
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    • pp.769-776
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    • 2010
  • A pebbling move on a connected graph G is taking two pebbles off of one vertex and placing one of them on an adjacent vertex. For a connected graph G, $G^p$ (p > 1) is the graph obtained from G by adding the edges (u, v) to G whenever 2 $\leq$ dist(u, v) $\leq$ p in G. And the pebbling exponent of a graph G to be the least power of p such that the pebbling number of $G^p$ is equal to the number of vertices of G. We compute the pebbling number of fourth power of paths so that the pebbling exponents of some paths are calculated.

The effect of progesterone and 17-β estradiol on membrane-bound HLA-G in adipose derived stem cells

  • Moslehi, Akram;Hashemi-beni, Batool;Moslehi, Azam;Akbari, Maryam Ali;Adib, Minoo
    • The Korean Journal of Physiology and Pharmacology
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    • v.20 no.4
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    • pp.341-346
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    • 2016
  • Membrane-bound HLA-G (mHLA-G) discovery on adipose derived stem cells (ADSCs) as a tolerogenic and immunosuppressive molecule was very important. Many documents have shown that HLA-G expression can be controlled via some hormones such as progesterone (P4) and estradiol (E2). Therefore, this study was designed to evaluate progesterone and estradiol effects on mHLA-G in ADSCs at restricted and combination concentrations. Three independent cell lines were cultured in complete free phenol red DMEM and subcultured to achieve sufficient cells. These cells were treated with P4, E2 and P4 plus E2 at physiologic and pregnancy concentrations for 3 days in cell culture conditions. The HLA-G positive ADSCs was measured via monoclonal anti HLA-G-FITC/ MEMG-09 by means of flow cytometry in nine groups. Data were analyzed by one way ANOVA and Tukey's post hoc tests. There were no significant values of the mean percentage of HLA-G positive cells in E2-treated and the combination of P4 plus $E_2-treated$ ADSCs compared to control cells (p value>0.05) but P4 had a significant increase on mHLA-G in ADSCs (p value<0.05). High P4 concentration increased mHLA-G but E2 and the combination of P4 plus E2 could not change mHLA-G on ADSCs.

Food Quality of Muffin with Germinated Brown Rice Soaked in Mycelial Culture Broth of Phellinus linteus (상황버섯균사체 배양액 침지 발아현미를 첨가한 머핀의 식품학적 특성)

  • Jung, Kyong-Im;Cho, Eun-Kyung;Choi, Young-Ju
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.40 no.6
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    • pp.875-884
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    • 2011
  • The purpose of this study was to examine the qualities of optimized muffins with germinated brown rice soaked in mycelial culture broth of Phellinuslinteus (GBRP) using response surface methodology. Firstly, general compositions of optimized muffins with GBRP were higher than that of control and total sugar contents were similar. However, the total free amino acid and constitutional amino acid contents except for GABA were lower than those of control. Starch hydrolysis in control was higher than in optimized muffins with GBRP, whereas protein digestibility and protein efficiency ratio were not. The weights of optimized muffins with GBRP were higher than that of control (p<0.01), whereas height (p<0.01) and pH (p<0.001) were similar. The hardness (p<0.05) and chewiness (p<0.05) of optimized muffins with GBRP were higher compared to control; adhesiveness, springiness, and gumminess were similar, but cohesiveness (p<0.01) was not. The flavor (p<0.05) and taste (p<0.01) of optimized muffins with GBRP were higher than those of control; appearance, texture and overall acceptability were similar, but color (p<0.05) was not. The total polyphenol contents (p<0.01), DPPH radical scavenging activity (p<0.01), and superoxide dismutase-like activity (p<0.05) of optimized muffins with GBRP were higher than those of control, but nitrite scavenging activity was similar.

Comparison of soil nutrients, pH and electrical conductivity among fish ponds of different ages in Noakhali, Bangladesh

  • Tapader, Md. Morshed Alam;Hasan, Mehedi Mahmudul;Sarker, Bhakta Supratim;Rana, Md. Enayet Ullah;Bhowmik, Shuva
    • Korean Journal of Agricultural Science
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    • v.44 no.1
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    • pp.16-22
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    • 2017
  • An experiment was conducted to detect aquaculture pond bottom soil nutrients, pH and electrical conductivity with a view to optimize production and to incorporate the scientific method of fish nursing, rearing and culturing at Noakhali district in Bangladesh. The soil samples were collected from the recently dug ponds (1 - 5 years) and older ponds (> 5 years). Samples were taken from five different spots in a Z shape from each pond and were mixed to get a composite sample. The composite samples from the ponds were collected in polyethylene bags and shipped to the laboratory for analysis. The soil samples were analyzed with respect to pH, electrical conductivity (EC), organic carbon (OC), organic matter (OM), nitrogen (N), phosphorous (P), potassium (K) and sulfur (S). The average value of pH, OC, OM, N, P, K and S were $7.43{\pm}0.40$, $2.21{\pm}1.43%$, $1.47{\pm}0.53%$, $2.52{\pm}0.94{\mu}g\;g^{-1}$, $0.126{\pm}0.047{\mu}g\;g^{-1}$, $3.84{\pm}1.77{\mu}g\;g^{-1}$, $0.191{\pm}0.106{\mu}g\;g^{-1}$ and $306.72{\pm}222.05{\mu}g\;g^{-1}$ respectively, in Noakhali. The average EC, OC, OM, N and P contents were found to be higher in Subornachar than those in Sonapur. On the other hand pH, K and S were found to be higher in Sonapur than the values of Subornachar. The pH, EC, OC, OM, N and S contents were found to be higher in new ponds than old ponds whereas P and K contents were found to be higher in old pond than in new pond.

Detoxification and Paralytic Shellfish Poison Profile with Heating, Storage and Treatment of Alkaline in Blue Mussel, Mytilus edulis (알칼리 처리 및 가열, 저장에 따른 진주담치의 마비성 패류독 성분 특성 및 제독)

  • Jang, Jun-Ho;Yun, So-Mi;Lee, Jong-Soo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.35 no.2
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    • pp.212-218
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    • 2006
  • Changes of paralytic shellfish poison (PSP) contents, toxicity and toxin composition with pH and storing periods at different temperature in toxic blue mussel, Mytilus edulis, were tested by using fluorometric HPLC method. Toxicity at pH 3 was the highest as 14.1 MU/g $(100\%)$ and showed 12.9 MU/g $(92.1\%)$ at pH 5, 9.0 MU/g $(63.8\%)$ at pH 7, 3.6 MU/g $(25.5\%)$ at pH 9 and 0.8 MU/g $(5.7\%)$ at pH 10 which suggested PSP was unstable at alkaline conditions. The decrease in toxicity during storage days was depend on pH and temperature. The toxicity markedly decreased until during the first S day storage $(19.9\~65.3\%)$ at all pH (3, 5, 7, 9) and temperature (30, 5, $-20^{\circ}C$), but, slightly decreased after then till to 30 days. C group toxin (C1 and C2) was the major components and other toxins such as GTX 1,2,3,4, STX and dcSTX were detected. Among the 8 toxins, GTX1,4, dcSTX and STX were firstly decreased according to the decreasing the toxicity at all processing conditions. The toxicity in blue mussel (14.1 MU/g) were able to remove by heating over 10 minutes at pH higher than 7.

Composition of Crude Polysaccharides in Some Phezllinus Species (수 종 상황버섯의 조다당 분획물 조성)

  • Park, Mi-Jung;Ahn, Mi-Jeong;Kim, Jin-Woong;Ze, Keum-Ryon;Lee, Heum-Sook
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.36 no.1
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    • pp.131-135
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    • 2007
  • Various Phellinus species (Hymenochaetaceae) including P. linteus, P. baumii, P. pini, and P. igniarius of domestic and foreign products, were examined by gas chromatography to validate their composition of crude polysaccharides. The crude polysaccharide fraction, which is known to be one of the physiologically active fractions, were prepared by a cold ethanol precipitation method and the yield of the crude polysaccharide fractions of P. linteus, P. baumii, P. pini, and P. igniarius were 15.0%, 5.1%, 6.3% and 5.7%, respectively. The total monosaccharide amount of the crude polysaccharide fraction of P. linteus was 148.713 mg/g (dry weight of mushroom) while those of P. baumii, P. pini and P. igniarius were 29.022 mg/g, 29.222 mg/g and 1.546 mg/g, respectively. Although the major monosaccharide of all Phellinus mushrooms was glucose, there were remarkable differences in the absolute quantity of each monosaccharide. P. linteus included plenty of monosaccharides except mannose and ribose in comparison with P. baumii and P. pini. The absolute quantities of monosaccharides of P. baumii and P. pini were nearly similar except arabinose. The total monosaccharides of P. igniarius were minimal, but the portions of galactose and mannose in P. igniarius were greater than in the other species.

Preparation and Termination of Carbosilane Dendrimer Based on Siloxane Tetramer (실옥산테트라머를 이용한 나뭇가지꼴 실란거대분자의 제조와 정지반응)

  • Kim, Chung Kyun;Park, Eun Mi
    • Journal of the Korean Chemical Society
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    • v.42 no.3
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    • pp.277-284
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    • 1998
  • Dendritic macromolecules of the first to fourth generation were synthesized, using alkenylation and hydrosilation cycles with allylmagnesium bromide and dichloromethylsilane as building blocks and siloxane tetramer $(Me(CH_2=CH)SiO)_4$, as core molecule. By the reaction of the dichloromethylsilyl-capped generation (G4P) with p-bromophenol, p-phenylphenol and lithium phenyethynylide, dendrimers with specific functions (G4P-BP (Mw: 16,300), G4P-PP (16,121), and CAP-PA (11,764)) have been produced. Analysis of new dendrimers by NMR, UV and MALD1 mass spectrometry suggests that they are pure and unified.

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Water Requirement of Twist Peppers in Greenhouse (온실 재배 꽈리고추의 필요수량)

  • 윤용철
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.42 no.4
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    • pp.59-66
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    • 2000
  • This study was carried out to investigated the water requirement of twisted sweet peppers which are cultivated in a green house. The meteorological conditions during the experiment period was close to that of normal year except the temperature and relative humidity. The growth status was improved with the increased saturation ratio. The range of the variation of daily water requirement were very large. The peak consumption occurred in the early August. And the higher saturation ratio resulted in higher water requirement. The total water requirement were about 57.180g/d/plant for pot with 100% (P100) of saturation , about 38.700g/d/plant for pot with 80%(P80) of saturation , about 23,720g/d/plant for pot with 60%(P60) of saturation, and about 53, 390g/d/plant for field cultivation in the green house, respectively. The water requirement was correlated with average ambient temperature and growing status, while no significant correlation were found between water requirement and minimum relative humidity or intensity of solar radiation. And the higher correlation was shown as the saturation ratio was increased. The transpiration coefficients of twisted sweet pepper were 378.0g/g for field cultivation in the green house, 363.3g/g for P100, 338.7g for P80 which was the smallest among pot cultivation , and 472.1g/g for P60 , respectively.

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