• Title/Summary/Keyword: Ozone gas

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Ozone Generation Effect and application using Boron-doped Diamond Electrode (붕소가 도핑된 다이아몬드 전극을 이용한 오존 발생의 효과 및 응용)

  • Pi, Young-Min;Fujisima, Akira;Park, Soo-Gil
    • Proceedings of the KIEE Conference
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    • 2002.11a
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    • pp.170-172
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    • 2002
  • Thin, Boron-doped conducting diamond films are expected to be excellent electrodes for industrial electrolysis. Boron-doped diamond(BDD) were used as anode for generating ozone gas by electrolysis of acid solution. In this work, we have studied ozone generating system using BDD electrode. In order to determine the ozone generation properties of diamond electrode, experimental conditions, electrolyte concentration, temperature, flow rate and reaction time were varied diversely. As a result, we could confirm that ozone gas was generated successfully and the performance of diamond electrode was stable for electrolyte while $PbO_2$ electrode was disintegrated. Actually we are found that ozone amount increased by lowering the temperature of electrolyte.

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Effects of Ozone on $CO_2$ Assimilation and PSII Function in Two Tobacco Cultivars with Different Sensitivities

  • Yun, Myoung-Hui
    • Journal of Korean Society for Atmospheric Environment
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    • v.22 no.E2
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    • pp.89-98
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    • 2006
  • Two tobacco cultivars (Nicotiana tabacum L.), Bel-B and Bel-W3, tolerant and sensitive to ozone, respectively, were grown in a greenhouse supplied with charcoal filtered air and exposed to 200 ppb ozone for 4 hr. Effects on chlorophyll fluorescence, net photosynthesis, and stomatal conductance are described. Quantum yield was calculated from chlorophyll fluorescence and the initial slope of the assimilation-light curve measured by the gas exchange method. Only the sensitive cultivar, Bel-W3, developed visual injury symptoms on up to 50% of the $5^{th}$ leaf. The maximum net photosynthetic rate of ozone-treated plants was reduced 40% compared to control plants immediately after ozone fumigation in the tolerant cultivar; however, photosynthesis recovered by 24 hr post fumigation and remained at the same level as control plants. On the other hand, ozone exposure reduced maximum net photosynthesis up to 50%, with no recovery, in the sensitive cultivar apparently causing permanent damage to the photosystem. Reductions in apparent quantum efficiency, calculated from the assimilation-light curve, differed between cultivars. Bel-B showed an immediate depression of 14% compared to controls, whereas, Bel-W3 showed a 27% decline. Electron transport rate (ETR), at saturating light intensity, decreased 58% and 80% immediately after ozone treatment in Bel-B and Bel-W3, respectively. Quantum yield decreased 28% and 36% in Bel-B and Bel-W3, respectively. It can be concluded that ozone caused a greater relative decrease in linear electron transport than maximum net photosynthesis, suggesting greater damage to PSII than the carbon reduction cycle.

Development of a Candidate Equipment for Ozone SRP and its Uncertainty Evaluation (오존 SRP의 제작과 측정 불확도 평가)

  • 정규백;우진춘;이진홍
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.4
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    • pp.313-319
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    • 2001
  • The development of ozone SRP (Standard Reference Photometer) designated as a G-7 project by the Korean Ministry of Environment began 1997 and is now nearly completed. With the completion of the ozone SRP we will not only acquire a qualification to participate in the international ozone calibration system but also enhance calibration credibility of ozone similarly to that of other ambient air pollution monitors. As the ozone SRP uses highly cleaned blank air that can be distinguished from general ozone analyzer, it is possible to reduce errors associated with the determination of ozone via elongation of the absorption length as long as 1 meter In addition, gas chopping method hat been adopted to cut down interference of other substances and time drift. Furthermore, the system has also been modified to minimize the strayed ultra-violet noise along the light path. In this paper, a new method for uncertainty evaluation has been introduced, which is guided by the ISO (International Standard Organization) GUM (Guide to the Expression of Uncertainty in Measurement) through assessments of the uncertainty type B (that was impossible to estimate before) as well as the uncertainty type A (based on statistics).

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The Characteristics of Plate Type Ozonizer with Variation of Electrode Form (전극 형태에 따른 평판형 오존발생기의 특성)

  • Yoon, Byung-Han;Lee, Chang-Ho;Woo, Sung-Hun;Lee, Kwang-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.1
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    • pp.149-156
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    • 2008
  • Recently, ozone is utilized in various fields and its needs are expanding. In this paper, plate type ozonizer have been fabricated to investigate discharge parameter(input power, flow rate of supplied gas, electrode form, etc.) effect to discharge. And the conditions of discharge parameter have been investigated for optimum ozone generation. Ozone concentration is continuously increased with increasing input power for same discharge space, and ozone yield is also increased until maximum point after that it is saturated. Ozone concentration is inversely proportional to flow rate of supplied gas but ozone generation and ozone yield characteristics are improved.

A Characteristic Analysis of Ozone Generator Using the Al2O3 Ceramic Dielectric According to Gas Type(O2/Air) (Al2O3 유전체를 이용한 산소/공기 원료에 따른 오존발생기의 특성)

  • Park, Hyun-Mi;Song, Hyun-Jig;Park, Won-Joo;Lee, Kwang-Sik
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.28 no.5
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    • pp.76-81
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    • 2014
  • The ozone generation is commonly made with silent discharge method using quartz glass dielectric. In this paper, using $Al_2O_3$ dielectric to instead of the traditional quartz glass dielectric to improve the system efficiency is presented. The dielectric was manufactured as tube shape (Internal diameter${\times}$ Outside diameter: $11{\times}15mm$) using 99% $Al_2O_3$ ceramic. The characteristics of dielectric discharge and ozone generation were studied of experiments with variation of discharge power, discharge electrode space and rate of flow for supplied gas ($O_2$/Air). As the experimental results, in the same discharge space, the ozone concentration continuously increased with input power increasing, and ozone yield increased until saturation happened. Also, the expended power increased with discharge space extended due to discharge power increased. In additional, the ozone concentration of oxygen ozone was higher than air that was observed when using oxygen ozone in proposed experiments.

Gate dielectric SiO2 film deposition on poly Silicon using UV-excited ozone gas without heating substrate.

  • Kameda, Naoto;Nishiguchi, Tetsuya;Morikawa, Yoshiki;Kekura, Mitsuru;Nonaka, Hidehiko;Ichimura, Shingo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.915-918
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    • 2007
  • We have grown $SiO_2$ film on a polycrystalline Si layer using excited ozone gas, which is produced by ultra-violet light irradiation to ozone gas, without heating substrate. The obtained $SiO_2$ film shows dielectric properties comparable to the device quality films measured at the MIS capacitor configuration.

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Exhaust Emissions Characteristics on the SI Engine according to the Air-Fuel Mixture with Ozone (혼합기 오존 첨가에 따른 SI기관의 배기배출물 특성)

  • Lee, B.H.;Yi, C.S.;Lee, Y.H.;Lee, C.K.;Jeong, H.M.;Chung, H.S.
    • Journal of Power System Engineering
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    • v.10 no.3
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    • pp.5-10
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    • 2006
  • In a conventional and lean operating engine, the state of mixture is very important in the combustion and emission characteristics. Lean operation is known to decrease the formation while maintaining a good fuel economy, but the unstable operation due to misfire and erratic combustion prevents engines from being operated at very lean mixtures, so both combustion rates and exhaust emission formation need to be satisfied comparably. In this study, it is designed and experimented the modified engine, and analyzed the combustion and exhaust emission according to the change of engine speed and with adding ozone. The conclusions were drawn out and enumerated as follows. 1. At the experimental result of automobile diesel engine, it has been verified that the formation of particulate matter(PM) gas is able to be lower with the addition of optimum quantities of ozone. 2. Carbon monoxide(CO) was formed by the lack of oxygen and the thermal dissociation in the combustion process. Therefore, with the change of swirl valve's position and addition of oxygen and ozone, CO formation was decreased by the increasing of excessive O2, but it was increased by the temperature of combustion gas growing higher. As a result of the two effects, CO formation was decreased in this study. 3. Hydrocarbon(HC) was formed by the lack of O2, and the flow of mixture in cylinder. According to opening of the swirl valve and adding the oxygen and ozone, hydrocarbon gas was decreased by 20%, 9%, and 27.5%, respectively. 4. Nitric oxides($NO_x$) was strongly affected by the combustion gas temperature. As a result of respectively experimental conditions, $NO_x$ formation was increased about 20% due to (be the) high(er) combustion gas temperature.

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Semiconductor Wafer Cleaning and PR Strip Processes using Ozone (오존을 이용한 반도체 웨이퍼 세정 및 PR 제거 공정)

  • 채상훈;정현채;문세호;손영수
    • Proceedings of the IEEK Conference
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    • 2003.07b
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    • pp.1089-1092
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    • 2003
  • This paper has been studied on wafer cleaning and photoresist striping in semiconductor fabrication processes using ozone solved deionized water. In this work, we have developed high concentration ozone generating system and high contact ratio ozone solving system to get high efficiency DIO$_3$. Through this study, we obtained 11% ozone gas concentration, 99.5% of ozone efficiency and 51% of solubility in deionized water.

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Phenanthrene으로 오염된 불포화토양내에서 오존이동 모델링

  • 정해룡;배기진;최희철
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.86-88
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    • 2002
  • The mathematical model was proposed to simulate ozone transport and remediation in unsaturated soils contaminated with phenanthrene. Soil column experiments were also carried out to calibrate the mathematical model. The experimental results successfully matched with the modeling results in various soil conditions. The model proposed nondimensional fraction factor to reveal reactivity between phenanthrene and gas phase ozone and liquid phase ozone. From sensitivity analysis, the fraction factor and stoichiometric coefficient decreased as water content increased. Simulation results showed increased SOM content retarded the ozone transport and the phenanthrene removal due to increased ozone consumption.

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