• 제목/요약/키워드: Oxygen Precipitation

검색결과 166건 처리시간 0.024초

CZ 방법에 의해 성장된 실리콘에서 산소 석출물의 성장/감소에 관한 모델 및 해석 (Modeling and Analysis for the Growth/Dissolution of Oxygen Precipitation in CZ-grown Silicon)

  • 고봉균;곽계달
    • 전자공학회논문지D
    • /
    • 제35D권10호
    • /
    • pp.29-38
    • /
    • 1998
  • 본 논문에서는 CZ 방법으로 성장된 실리콘에서 임의의 열처리 과정 또는 VLSI 공정중에 발생하는 산소석출물(oxygen precipitates)의 성장 및 감소에 대한 모델을 유도하고 수치해석법으로 시뮬레이션을 수행하여 모델에 대한 타당성을 검증하였다. 확산제한 성장법칙(diffusion-limited growth law)과 DBET(detailed balance equilibrium theory)를 이용하여 산소 석출물의 성장률과 감소율을 유도하고 이를 CREs(chemical rate equations)와 PFE (Fokker-Planck equation)이 결합된 식에 적용하여 수치해석법으로 풀었다. 또한 어닐링 분위기에 따라 표면에서 일어나는 현상을 달리 고려해야 하는데, 특히 O₂가스 분위기에서는 산화막이 성장되는 조건을 고려해야 하므로 산화막 성장 모델과 산소 용해도 증가등의 영향을 고려하였다. 이 방법으로 기존의 결과보다 더 정확하게 깊이에 따른 산소 농도의 분포와 산소 석출물의 밀도분포 함수를 계산할 수 있었다.

  • PDF

Source identification and Pathway analysis of Nitrate contamintation in "Cultural village", Jeungpyeong

  • 전성천;이강근;배광옥;정형재
    • 한국지하수토양환경학회:학술대회논문집
    • /
    • 한국지하수토양환경학회 2002년도 총회 및 춘계학술발표회
    • /
    • pp.254-257
    • /
    • 2002
  • The purposes of this research are to identify the source and to analyze the pathway of nitrate contamination in "cultural village", Jeungpyeong. In order to examine recharge processes and flow pattern that closely related to the influent of nitrate contaminant, the flow field was simulated and the oxygen and hydrogen stable isotopes were analyzed. The nitrogen isotope was used to delineate contaminant sources. The shallow groundwater was mainly composed of precipitation, but leakage of domestic water and sewage contributed to the recharge. Nitrate contaminants were possibly from the leakage of sewage and animal waste. The nitrate concentration decreased due to dilution by low concentration water.ion water.

  • PDF

汚濁河川水의 地球化學的인 硏究 (第 II 報) 서울市內 河川水 및 工場排水의 化學的 酸素要求量 (Geochemical Investigations of Contaminated River Waters Part II-Chemical Oxygen Demand of River Water and Industrial Waste Water in Seoul)

  • 이용근
    • 대한화학회지
    • /
    • 제14권1호
    • /
    • pp.5-12
    • /
    • 1970
  • River water and industrial waste water in Seoul were studied by means of chemical oxygen demand(COD) as an indicator for water pollution, from August 1967 to July 1968. Rivers flowing through residential and industrial areas are badly contaminated and COD of water in Han River increases as it progresses to downstream. Seasonal variation of COD showed that higher value of COD was observed in spring and lower in autumn. It is clear that the seasonal variation of COD is influenced by the precipitation. Close relationship was found between COD and population density. The lowest COD curve obtained by plotting COD values against population density and show that the curve slopes upward. The discontinuation of the curve was shown at the population density of 14,000/km$^2$; an increase in COD was acute over the population density of 14,000/km$^2$.

  • PDF

습지의 생지화학적 반응과 전지구적 기후 변화의 영향 (Influence of Global Climatic Changes on Wetland Biogeochemical Processes)

  • 강호정
    • 한국생물공학회:학술대회논문집
    • /
    • 한국생물공학회 2004년도 학술대회지
    • /
    • pp.35-45
    • /
    • 2004
  • This paper reviewed effects of global climatic changes on wetland biogeochemistry, Wetlands play key roles in global as well as local material cycle, which includes carbon sequestration, $CH_4$ emission and DOC leaching, Increased air temperature, elevated $CO_2$ levels and changed precipitation patterns are believed to affect those processes substantially by modifying oxygen supply, carbon sources, and decomposition rates. For example, elevated $CO_2$ may increase $CH_4$ emission as well as DOC leaching from wetlands. In addition, interactions of multiple effects warrant further investigation.

  • PDF

Oxidative Dimerization of Methane over Lead Aluminate Spinel Catalysts

  • 장종산;박상언
    • Bulletin of the Korean Chemical Society
    • /
    • 제16권12호
    • /
    • pp.1148-1152
    • /
    • 1995
  • Oxidative dimerization of methane to C2-hydrocarbons was performed over lead aluminate spinel catalysts. These spinel catalysts were prepared by co-precipitation, aerogel, and sol-gel methods. The active phase of lead aluminate oxides was found to be PbAl2O4 spinel. The activities of the catalysts were strongly dependent on the preparation method as well as the composition of PbAl2O4 phase. The proper oxygen mobility of PbAl2O4 spinel oxides appeared to be important to get high catalytic activity and selectivity for C2-hydrocarbon formation.

송어양식장의 위해요소 관리를 위한 수질 모니터링 (Water Quality Monitoring for Hazard Analysis in Aquaculture Farm of Rainbow Trout)

  • 김영목;이명숙;정용현
    • 수산해양교육연구
    • /
    • 제25권4호
    • /
    • pp.819-827
    • /
    • 2013
  • Water quality has been considered to be one of sanitation standard operating procedures (SSOP) for hazard analysis critical control points (HACCP) application in aquaculture farms. This study was conducted to evaluate a hazard caused by water used in aquaculture farm of rainbow trout. The water quality was analyzed to investigate both physiochemical and bacteriological level in water samples collected from aquaculture farm of rainbow trout, Oncorhynchus mykiss. No significant difference were observed on water temperature and pH from season to season. However, the levels of dissolved oxygen were decreased as the outside temperature was increased, even if the levels were adequate for aquaculture. Also, other physiochemical analysis including biochemical oxygen demand (BOD), chemical oxygen demand (COD) and suspended solid (SS) revealed that the waters for aquaculture analyzed in this study was suitable for rainbow trout aquaculture. The bacterial analyses were also revealed that the waters for aquaculture were met to both coliform group (<18 MPN/100mL) and viable cell count (<100 CFU/mL). However, some of waste waters from aquaculture farms showed higher levels of BOD and COD than those of waste water standard (<2 ppm), suggesting that regular cleaning of fish tank and precipitation tank is needed.

젖음성 차이와 무전해도금을 이용한 연성 구리 회로패턴 형성 (Etchless Fabrication of Cu Circuits Using Wettability Modification and Electroless Plating)

  • 박상진;고태준;윤주일;문명운;한준현
    • 한국재료학회지
    • /
    • 제25권11호
    • /
    • pp.622-629
    • /
    • 2015
  • Cu circuits were successfully fabricated on flexible PET(polyethylene terephthalate) substrates using wettability difference and electroless plating without an etching process. The wettability of Cu plating solution on PET was controlled by oxygen plasma treatment and $SiO_x$-DLC(silicon oxide containing diamond like carbon) coating by HMDSO(hexamethyldisiloxane) plasma. With an increase of the height of the nanostructures on the PET surface with the oxygen plasma treatment time, the wettability difference between the hydrophilicity and hydrophobicity increased, which allowed the etchless formation of a Cu pattern with high peel strength by selective Cu plating. When the height of the nanostructure was more than 1400 nm (60 min oxygen plasma treatment), the reduction of the critical impalement pressure with the decreasing density of the nanostructure caused the precipitation of copper in the hydrophobic region.

THE EFFECT OF HYDROGEN AND OXYGEN CONTENTS ON HYDRIDE REORIENTATIONS OF ZIRCONIUM ALLOY CLADDING TUBES

  • CHA, HYUN-JIN;JANG, KI-NAM;AN, JI-HYEONG;KIM, KYU-TAE
    • Nuclear Engineering and Technology
    • /
    • 제47권6호
    • /
    • pp.746-755
    • /
    • 2015
  • To investigate the effect of hydrogen and oxygen contents on hydride reorientations during cool-down processes, zirconium-niobium cladding tube specimens were hydrogen-charged before some specimens were oxidized, resulting in 250 ppm and 500 ppm hydrogen-charged specimens containing no oxide and an oxide thickness of $0.38{\mu}m$ at each surface. The nonoxidized and oxidized hydrogen-charged specimens were heated up to $400^{\circ}C$ and then cooled down to room temperature at cooling rates of $0.3^{\circ}C/min$ and $8.0^{\circ}C/min$ under a tensile hoop stress of 150 MPa. The lower hydrogen contents and the slower cooling rate generated a larger fraction of radial hydrides, a longer radial hydride length, and a lower ultimate tensile strength and plastic elongation. In addition, the oxidized specimens generated a smaller fraction of radial hydrides and a lower ultimate tensile strength and plastic elongation than the nonoxidized specimens. This may be due to: a solubility difference between room temperature and $400^{\circ}C$; an oxygen-induced increase in hydrogen solubility and radial hydride nucleation energy; high temperature residence time during the cool-down; or undissolved circumferential hydrides at $400^{\circ}C$.

질소 정제 시스템의 산소 제거용 구리계 촉매 연구 (A Study on Cu-based Catalysts for Oxygen Removal in Nitrogen Purification System)

  • 오승교;성민준;전종기
    • 청정기술
    • /
    • 제27권1호
    • /
    • pp.9-16
    • /
    • 2021
  • Active Matrix Organic Light-Emitting Diode (AMOLED) 봉지 공정은 수분과 산소에 매우 취약하기 때문에, 수분과 산소의 함량이 최소화된 고순도의 질소를 사용하여야 한다. 본 연구의 목적은 AMOLED 봉지 공정에 사용하는 질소에서 산소를 제거하기 위한 용도로 사용되는 구리계 촉매를 최적화하는 것이다. CuO, Al2O3, 또는 ZnO의 조성으로 이루어진 2성분계 및 3성분계 촉매를 공침법을 통해서 제조하였다. 제조된 촉매들을 BET, XRD, TPR, XRF의 분석장비를 활용하여 촉매의 특성을 분석하였다. 촉매의 산소 제거 성능을 확인하기 위해 고정층 반응기에서 촉매 산소 제거 반응 실험을 수행하고 산소 분석기를 통해 산소 함량을 측정하였다. 또한 사용된 촉매의 반복 재생을 통해 촉매의 재사용 성능을 검증하였다. CuO와 Al2O3 비율이 6 : 4, 7 : 3 및 8:2로 제조된 2 성분계 촉매의 특성과 산소 제거 능력을 비교하였다. CuO와 Al2O3의 비율이 8:2인 촉매의 환원성이 가장 높았는데, 이는 CuO의 분산도가 가장 높기 때문이다. 결과적으로, 2성분계 촉매 중에서 CuO와 Al2O3의 비율이 8 : 2 인 촉매의 산소 제거 능력이 가장 우수한 것으로 나타났다. CuO : Al2O3 의 비율이 8:2인 촉매에 ZnO를 2 wt% 넣어준 촉매가 3성분계 촉매 중에는 가장 우수한 산소제거 능력을 보였으며, 이는 뛰어난 환원성에 기인한다고 할 수 있다. 또한 이 촉매는 재생 실험을 통해서도 산소 제거능력이 유지된다는 것을 확인하였다.

유성 소유역의 강수 및 지열수의 산소.수소 안정동위원소 조성 변화 (The Variation of Oxygen and Hydrogen Isotopic Composition in Precipitation and Geothermal Waters from the Yuseong Catchment)

  • 문상호;조성현;이광식;윤욱
    • 자원환경지질
    • /
    • 제40권4호
    • /
    • pp.389-401
    • /
    • 2007
  • 2001년부터 2004년까지 유성 소유역내 강수, 지하수, 지열수의 산소 및 수소 동위원소 조성 변화를 검토하였다. 1975년부터 2006년까지의 강수 패턴을 분석한 결과, 연구지역은 $6{\sim}7$년의 가뭄 주기성을 보였다. 2001년도 가뭄 시기부터 2004년까지 4년간 강수의 산소 수소 동위원소 조성은 점차 무거운 성분으로 변화해가는 양상을 보였다. 연구 지역에서 4년간의 강수량을 고려한 동위원소의 가중 평균간을 구해 보면 ${\delta}^{18}O=-7.7%o,\;{\delta}D=-51%o$로서, 동일 기간 내의 지하수와 지열수의 동위원소보다 무거운 조성 범위를 보였다. 이는 연구 지역의 지수 및 지열수가 동위원소적 관점에서 2-3년 이내의 강수에 의해 큰 영향을 받지 않는 것을 의미한다. 기존 자료들을 검토해 볼 때, 연구지역에서의 지하수와 지열수는 1990년과 1992년이 가장 무거운 동위원소 조성을 보였으며 이후로는 산소 및 수소 동위원소 조성이 점차 가벼워지는 쪽으로 변화해가는 양상을 보였다.