• Title/Summary/Keyword: Oxide loss

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Fabrication and Characteristics of Supported Type Planar Solid Oxide Fuel Cell By Co-firing Process (공소결법에 의해 제조된 지지체식 평판형 고체산화물 연료전지 성능 특성)

  • Song, Rak-Hyun
    • Korean Journal of Materials Research
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    • v.13 no.3
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    • pp.160-168
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    • 2003
  • The co-firing processes for the supported type planar solid oxide fuel cell were investigated. A flat cell of $7.7${\times}$10.8\textrm{cm}^2$ was fabricated successfully by the co-firing process, in which green films were co-sintered in the forms of two layers of anode/electrolyte or of three layers of anode/electrolyte/cathode with gas distributor. A co-fired cell of two layers yielded a power of 200 ㎽/$\textrm{cm}^2$ at 608 ㎷. Its performance loss was mainly due to iR drop in the anodic gas distributor, which was attributed to poor contact between anodic gas distributor and current collector. The performance in the co-fired cell of three layers was much lower than that of two layers, which resulted from the large iR drop and activation overvoltage at the cathodic side. In the co-fired cell of two layers, the impedance analysis indicated that the performance decay during cell operation is due to both anode overvoltage and iR drop at anode side. Also the electrode reaction of the co-fired two layers' cell is considered to be controlled by activation overvoltage within the low current of 50 ㎃.

Temperature Maintenance of an ITO Nanoparticle Film Heater (ITO 나노입자 면상발열체의 온도유지에 대한 연구)

  • Yang, Kyungwhan;Cho, Kyoungah;Im, Kiju;Kim, Sangsig
    • Journal of IKEEE
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    • v.20 no.2
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    • pp.171-173
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    • 2016
  • In this study, we fabricate a high efficiency heater consisting of the indium tin oxide (ITO) nanoparticle (NP)-paste and polydimethylsiloxane (PDMS) and investigate the effect of PDMS on temperature maintenance of the heater through the comparison with the PDMS-free ITO film heater. Compared to the ITO film heater, the temperature of the PDMS/ITO film heater lasts 1.5 times longer. And the power consumption of the PDMS/ITO film heater is reduced by 35%, owing to the low thermal conductivity of the PDMS layer.

Oxidative Decomposition of TCE over TiO2-Supported Metal Oxide Catalysts (TiO2에 담지된 금속 산화물 촉매상에서 TCE 산화분해반응)

  • Yang Won-Ho;Kim Moon-Hyeon
    • Journal of Environmental Science International
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    • v.15 no.3
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    • pp.221-227
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    • 2006
  • Oxidative TCE decomposition over $TiO_2$-supported single and complex metal oxide catalysts has been conducted using a continuous flow type fixed-bed reactor system. Different types of commercial $TiO_2$ were used for obtaining the supported catalysts via an incipient wetness technique. Among a variety of titanias and metal oxides used, a DT51D $TiO_2\;and\;CrO_x$ would be the respective promising support and active ingredient for the oxidative TCE decomposition. The $TiO_2-based\;CrO_x$ catalyst gave a significant dependence of the catalytic activity in TCE oxidation reaction on the metal loadings. The use of high $CrO_x$ contents for preparing $CrO_x/TiO_2$ catalysts might produce $Cr_2O_3$ crystallites on the surface of $TiO_2$, thereby decreasing catalytic performance in the oxidative decomposition at low reaction temperatures. Supported $CrO_x$-based bimetallic oxide systems offered a very useful approach to lower the $CrO_x$ amounts without any loss in their catalytic activity for the catalytic TCE oxidation and to minimize the formation of Cl-containing organic products in the course of the catalytic reaction.

Effect of the Frit of the 2nd Firing Oxide in $SrTiO_3$-Based GBLC on the Dielectric Properties ($SrTiO_3$계 Grain Boundary Layer Capacitor에서 2차 열처리 산화물의 Frit화가 유전적 성질에 미치는 영향)

  • 유재근;최성철;이응상
    • Journal of the Korean Ceramic Society
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    • v.28 no.4
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    • pp.261-268
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    • 1991
  • The dielectric properties and microstructure of SrTiO3-based grain boundary layer (GBL) capacitor were investigated, and SrTiO3 GBL capacitor was made by penetrating the Frit (PbO-Bi2O3-B2O3 system). The Nb2O5-doped SrTiO3 ceramics were fired for 4-hours, at 145$0^{\circ}C$ in H2-N2 atomsphere to get semiconductive ceramics. The grain size of SrTiO3 sintered at reduction atmosphere had increased as the amount of Nb2O5 increases and then decreased as the amount of Nb2O5 exceeded 0.2 mole%. Insulating reagents which contained PbO-Bi2O3-B2O3 system frit and oxide mixture were printed on the each semiconductive ceramics and fired at varying temperature and for different holding time. The optimum dielectric properties could be obtained by second heat treatment at 110$0^{\circ}C$ for 1 hour, when frit paste was printed. A SrTiO3-based GBLC had the apparent permitivity of about 3.2$\times$104, the dielectric loss of 0.01~0.02 and the stable temperature coefficient of capacitance. The influence of frit paste on dielectric properties was similiar to that of oxide paste but the stability of temperature property of capacitance was improved.

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Electrical Properties in GDC (Gd2O3-Doped CeO2)/LSCF (La0.6Sr0.4Co0.2Fe0.8O3) Cathode Composites for Intermediate Temperature Solid Oxide Fuel Cells

  • Lee, Hong-Kyeong;Hwang, Jin-Ha
    • Journal of the Korean Ceramic Society
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    • v.48 no.1
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    • pp.110-115
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    • 2011
  • $Gd_2O_3$-doped $CeO_2$ (GDC) and $La_{0.6}Sr_{0.4}Co_{0.2}Fe_{0.8}O_3$ (LSCF) composite cathode materials were prepared in order to be applied to intermediate-temperature solid oxide fuel cells. The electrochemical polarization was evaluated using ac impedance spectroscopy involving geometric restriction at the interface between an ionic electrolyte and a mixed-conducting cathode. In order to optimize the cathode composites applicable to a GDC electrolyte, the cathode composites were evaluated in terms of polarization losses with regard to a given electrolyte, i.e., GDC electrolyte. The polarization increased significantly with decreasing temperature and was critically dependent on the compositions of the composite cathodes. The optimized cathode composite was found to consist of GDC 50 wt% and LSCF 50 wt%; the corresponding normalized polarization loss was calculated to be 0.64 at $650^{\circ}C$.

Superoxide Formation and Cytotoxicity of RAW264.7 Macrophages Induced by Nitric Oxide

  • Lee, Hong;Pae, Hyun-Ock;Jun, Chang-Duk;Yoo, Ji-Chang;Park, Rae-Kil;Chung, Hun-Taeg
    • Toxicological Research
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    • v.13 no.3
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    • pp.247-250
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    • 1997
  • We have studied cytotoxicity of S-nitroso-N-acetyl- N-DL-penicillamine(SNAP), a Nitric oxide (NO)-releasing compound, in RAW264.7 macrophages. SNAP is cytotoxic to RAW264.7 cells in a concentration-dependent manner. PMA(200 nM) stimulated cells to produce superoxide anton radical($O_2^{-\cdot}$) and caused a little loss of RAW264.7 cell viability for 12 hr and diminished the cytotoxicity of SNAP. The mechanism by which PMA can protect cells against NO-mediated cytotoxicity was studied by peroxynitrite-enhanced chemiluminescence method. Observed results suggested that $O_2^{-\cdot}$ produced by PMAstimulated RAW264.7 cells may quench NO released by SNAP and reduce NO, thus attenuating NO-related damages.

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Hydrogen Reduction Behavior of Oxide Scale in Water-atomized Iron Powder (수분사 Fe 분말의 산화물 및 이의 수소가스 환원거동)

  • Shin, Hea-Min;Baik, Kyeong-Ho
    • Journal of Powder Materials
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    • v.21 no.6
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    • pp.422-428
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    • 2014
  • In this study, the reduction kinetics and behaviors of oxides in the water-atomized iron powder have been evaluated as a function of temperature ranging $850-1000^{\circ}C$ in hydrogen environment, and compared to the reduction behaviors of individual iron oxides including $Fe_2O_3$, $Fe_3O_4$ and FeO. The water-atomized iron powder contained a significant amount of iron oxides, mainly $Fe_3O_4$ and FeO, which were formed as a partially-continuous surface layer and an inner inclusion. During hydrogen reduction, a significant weight loss in the iron powder occurred in the initial stage of 10 min by the reduction of surface oxides, and then further reduction underwent slowly with increasing time. A higher temperature in the hydrogen reduction promoted a high purity of iron powder, but no significant change in the reduction occurred above $950^{\circ}C$. Sequence reduction process by an alternating environment of hydrogen and inert gases effectively removed the oxide scale in the iron powder, which lowered reduction temperature and/or shortened reduction time.

Sodium nitroprusside mediates seedling development and attenuation of oxidative stresses in Chinese cabbage

  • Sung, Chang-Hyun;Hong, Jeum-Kyu
    • Plant Biotechnology Reports
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    • v.4 no.4
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    • pp.243-251
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    • 2010
  • Nitric oxide (NO) has been shown to be involved in diverse physiological processes in microbes, animals and plants. In this study, the involvement of NO in the development and possible roles in oxidative stress protection of Chinese cabbage (Brassica rapa subsp. pekinensis cv. Samrack-ulgari) seedlings were investigated. Exogenous application of sodium nitroprusside (SNP) retarded root elongation, while increasing lateral root formation of Chinese cabbage. Plants showed no signs of external stress due to SNP application in true leaves. Cotyledons of 3-week-old Chinese cabbage plants were found to be highly sensitive to SNP application. Treated cotyledons displayed rapid tissue collapse and associated cell death. Although SNP application reduced root growth under normal growth conditions, it also enhanced methyl viologen (MV)-mediated oxidative stress tolerance. Analysis of SNP application to Chinese cabbage leaf disks, revealed SNP-induced tolerance against oxidative stresses by MV and $H_2O_2$, and evidence includes prevention of chlorophyll loss, superoxide anion (${O_2}^-$) accumulation and lipid peroxidation. This report supports a role for nitric oxide in modulating early seedling development, programmed cell death and stress tolerance in Chinese cabbage.

Implementation of LED Module Using MCPCB with Hard Barrier Anodizing Oxide Layer (경장벽 산화막 절연층 MCPCB를 이용한 LED 모듈 구현)

  • Hong, Dae-Woon;Lee, Sung-Jae;Cho, Jae-hyun
    • Korean Journal of Optics and Photonics
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    • v.20 no.4
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    • pp.236-240
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    • 2009
  • LED modules, based on MCPCB with a hard barrier oxide layer and an improved thermal dissipation property, are presented. Reflecting cups were also formed on the surface of the MCPCB such that optical coupling between neighboring chips was minimized for improving the photon absorption loss. LED chips were directly attached on the MCPCB by using the COB (Chip On Board) scheme. The LED modules showed significantly enhanced light outputs, compared to the LED modules based on conventional MCPCBs.

Effect of Fillers on the Mechanical and Thermal Properties of Glass/Novolac Composites (충전재의 종류에 따른 유리/노볼락 복합재료의 기계적 및 열적 성질 연구)

  • Lee, Soo;Lee, In-Kyu;Park, Sang-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.1
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    • pp.15-22
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    • 2008
  • The effects of fillers on the mechanical and thermal properties of glass/novolac composites have been studied. The matrix polymer and reinforcement were novolac type phenolic resin and milled glass fiber, respectively. Three different fillers, such as calcium carbonate, aluminum oxide, and wood powder were used for glass fiber reinforced plastic(GFRP) manufacture. Gravity, moisture content, tensile and flexural strength were measured to analyze the mechanical properties of GFRP and the final composites was burned in the electronic furnace at $1000^{\circ}C$ to confirm thermal properties GFRP containing aluminium oxide shows the highest thermal stability with 32% of weight loss at $1000^{\circ}C$ for one hour. GFRP containing calcium carbonate shows the maximum flexural strength (146 MPa), but that containing wood powder dose the highest tensile strength (65 MPa). Conclusively, we found that the characteristics of final composites strongly depend on several factors, such as types of materials, contents and chemical affinity of fillers. Therefore, it is very important to set up the combination of fillers for GFRP manufacturing to improve both mechanical and thermal properties at the same time.