• Title/Summary/Keyword: Organic space

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Characterization of Li+-ion Exchanged Zeolite Y using Organic Solvents

  • Kim, Hu Sik;Lee, Seok Hee;Park, Kyun Hye;Park, Yong Hyun;Park, Jun Woo;Hwang, Ji Hyun;Park, Jong Sam;Choi, Sik Young;Lim, Woo Taik
    • Korean Journal of Soil Science and Fertilizer
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    • v.48 no.3
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    • pp.180-188
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    • 2015
  • To investigate the tendency of $Li^+$ exchange from polar organic solvents, $Li^+$-ion exchange into zeolite Y (Si/Al = 1.56) was attempted by undried methanol (crystal 1) and formamide (crystal 2) solvent. Two single crystals of Na-Y were treated with 0.1 M LiNO3 in each of the two solvents at 323 K, followed by vacuum dehydration at 723 K. Their structures were determined by single-crystal synchrotron X-ray diffraction techniques in the cubic space group $Fd{\bar{3}}m$, at 100(1) K. In both structures, $Li^+$ for $Na^+$ ions filled preferentially sites I' and II. The remaining $Na^+$ ions occupied sites I', II, and III' in both structures, in additional to above sites, and $Na^+$ ions occupied site I in crystal 2. While the 68 % exchange of $Li^+$ for $Na^+$ was achieved from undried methanol, only 40 % exchange was observed from undried formamide, indicating that the undried methanol was more effective than undried formamide as solvent for $Li^+$ exchange under the conditions employed.

Role of Environment-friendly Design & Green Amenity in Space Design - a focus on ecology designs using green materials - (공간디자인에 있어서의 환경친화와 Green Amenity의 역할에 관한 연구 - 그린(Green Materials)을 이용한 에콜로지디자인을 중심으로 -)

  • 이정민
    • Archives of design research
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    • v.16 no.1
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    • pp.137-148
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    • 2003
  • Environment-friendly design becomes one of the main issues of the contemporary design. It has been developed with the advent of the organic view of the wend. It started as the environment-protective orientation and then enlarged its boundary including the designs which aims to revive the organic relationship between human and nature. Recent design approach in environment design emphasizes to be 'synchronized with the nature' and its basic attitude is the revival of the right relationship between man and nature. It also can be described as the design for Green Amenity. This paper researches on the concepts, types and the roles of the environmentally-friendly design. There are two basic concepts : one is environment-protective attitude and the other is the attitude which emphasizes the function of Green Amenity. This paper focuses on the latter approach. Through the analysis of the necessity and the function of the environmentally-friendly design, it aims to prove the fact that valuable human life need the design which connects human life aye with natural environment.

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Volatile organic compounds of pyroligneous liquor of bamboo sprout produced in damyang-gun (담양군 죽초액의 휘발성성분 분석)

  • Lee, Eunsil;Jang, Hyejin;Lee, Songjin;Ha, Jaeho
    • Analytical Science and Technology
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    • v.26 no.5
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    • pp.299-306
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    • 2013
  • Pyroligneous liquor as a byproduct from charcoal production of bamboo sprout produced damyang-gun has the broad benefits such as improvement of soil quality, plant growth control and is mainly used for the treatment of atopic dermatitis, fungi and many other skin diseases. In this study, flavor compounds of pyroligneous liquor from bamboo sprout produced in Damyang-gun were analyzed and compared using three different methods including direct analysis (DA), headspace solid phase microextraction (HS-SPME) and stir bar sorptive extraction (SBSE). Simultaneously, the analytical conditions of GC-MS for the determination of volatile compounds were optimized. Based on volatile organic compounds detected by GC-MS, SBSE and SPME methods showed higher sensitivity than direct analysis. Major compounds of pyroligneous liquor were cresol, guaiacol, p-ethyl guaiacol and syringol. These phenolic compounds are reported as the useful chemicals with medicinal activity.

Advanced Water Treatment by Hybrid Process of Multi-channel Ceramic MF and Photocatalyst: Effect of Organic Materials (광촉매 및 다채널 세라믹 정밀여과 혼성공정에 의한 고탁도 원수의 고도정수처리: 유기물의 영향)

  • Amarsanaa, Bolor;Park, Jin-Yong
    • Membrane Journal
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    • v.21 no.4
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    • pp.351-359
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    • 2011
  • For advanced drinking water treatment of high turbidity water, we used the hybrid process that was composed of photocatalyst packing in space of between outside of multi-channel ceramic microfiltration membrane and membrane module inside. Photocatalyst was polypropylene (PP) beads coated $TiO_2$ powder by CVD (chemical vapor deposition) process. Instead of natural organic matters (NOM) and fine inorganic particles in natural water source, standard NOM solution was prepared with humic acid and kaolin. Water-back-flushing of 10 sec was performed per every period of 10 min to minimize membrane fouling. Resistance of membrane fouling ($R_f$) increased and J decreased as concentration of humic acid changed from 2 mg/L to 10 mg/L, and finally the highest total permeate volume ($V_T$) could be obtained at 2 mg/L. Then, treatment efficiency of turbidity and $UV_{254}$ absorbance were above 96.4% and 78.9%, respectively. As results of treatment portions by membrane filtration, photocatalyst adsorption, and photo-oxidation in (MF), (MF + $TiO_2$), (MF + $TiO_2$ + UV) processes, turbidity was treated little by photocatalyst adsorption, and photo-oxidation. However, treatment portions of $UV_{254}$ absorbance by adsorption (MF + $TiO_2$) and photo-oxidation (MF + $TiO_2$ + UV) at humic acid of 4 mg/L and 6 mg/L were above 9.0, 9.5 and 8.1, 10.9%, respectively.

Frequency Dependent Properties of Tris(8-Hydroxyquinoline) Aluminum Thin Films

  • Lee, Yong-Soo;Park, Jae-Hoon;Choi, Jong-Sun
    • KIEE International Transactions on Electrophysics and Applications
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    • v.11C no.3
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    • pp.70-74
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    • 2001
  • Admittance or impedance spectroscopy is one of the powerful tools to study dielectric relaxation and loss processes in organic and inorganic materials. In this study, the frequency dependent properties of an indium tin oxide/tris(8-hydroxyquinoline) aluminum($Alq_3$)/aluminum structure have been studied. The conductance of the $Alq_3$ film increases with the DC applied voltage up to 4V and decreases above 4V in the low frequency region. This indicates that the resistance of the device decreases with the applied bias due to the carrier injection enhancement, thereafter the injected carriers form the space charge and the additional injection of carriers is prevented. The Cole-Cole plot of the admittance takes a one-semicircle shape, which means that the device can be modeled as a parallel resistor-capacitor network. The resistance and capacitance were estimated as 8.62k${\Omega}$ and 2.7nF, respectively, at 3V in the low frequency region. The dielectric constant ( ${\epsilon}'$ ) of the $Alq_3$ film is independent of the frequency in the low frequency region below 100kHz, while the frequency dependency was observed at above 100kHz. The dielectric loss factor ( ${\epsilon}"$ ) of the $Alq_3$ film shows the dielectric dispersion below 100kHz and dielectric absorption in higher frequency domain. The dispersion is thought to be related to the hopping process of the carriers. The ${\epsilon}"$ is proportional to the reciprocal of the frequency. The dielectric relaxation time was extracted to about 0.318${\mu}s$ from the dielectric absorption spectrum.

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Involvement of a Novel Organic Cation Transporter in Paeonol Transport Across the Blood-Brain Barrier

  • Gyawali, Asmita;Krol, Sokhoeurn;Kang, Young-Sook
    • Biomolecules & Therapeutics
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    • v.27 no.3
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    • pp.290-301
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    • 2019
  • Paeonol has neuroprotective function, which could be useful for improving central nervous system disorder. The purpose of this study was to characterize the functional mechanism involved in brain transport of paeonol through blood-brain barrier (BBB). Brain transport of paeonol was characterized by internal carotid artery perfusion (ICAP), carotid artery single injection technique (brain uptake index, BUI) and intravenous (IV) injection technique in vivo. The transport mechanism of paeonol was examined using conditionally immortalized rat brain capillary endothelial cell line (TR-BBB) as an in vitro model of BBB. Brain volume of distribution (VD) of [$^3H$]paeonol in rat brain was about 6-fold higher than that of [$^{14}C$]sucrose, the vascular space marker of BBB. The uptake of [$^3H$]paeonol was concentration-dependent. Brain volume of distribution of paeonol and BUI as in vivo and inhibition of analog as in vitro studies presented significant reduction effect in the presence of unlabeled lipophilic compounds such as paeonol, imperatorin, diphenhydramine, pyrilamine, tramadol and ALC during the uptake of [$^3H$]paeonol. In addition, the uptake significantly decreased and increased at the acidic and alkaline pH in both extracellular and intracellular study, respectively. In the presence of metabolic inhibitor, the uptake reduced significantly but not affected by sodium free or membrane potential disruption. Similarly, paeonol uptake was not affected on OCTN2 or rPMAT siRNA transfection BBB cells. Interestingly. Paeonol is actively transported from the blood to brain across the BBB by a carrier mediated transporter system.

Use of an Electric Muscle Stimulation Thigh Band and High-intensity Circuit Training to Activate the Thigh Muscle (무릎 밴드를 이용한 EMS와 High-intensity Circuit Training의 대퇴근육 활성화 효과)

  • Hanna Park;Jinhee Park;Jooyong Kim
    • Journal of Fashion Business
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    • v.27 no.2
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    • pp.39-51
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    • 2023
  • The purpose of this study was to effectively improve the thigh muscles of adult women working from home due to COVID-19. In this study, ten adult women working from home performed 1) an electromyography test, 2) a static balance test on a balance board, and a 3) dynamic balance test by squatting on a Bosu ball four times: before electric muscle stimulation (EMS), after EMS, after high-intensity circuit training (HICT), and after EMS plus HICT. For this test, EMS was attached to a medical knee support to manufacture an EMS knee band that could be easily worn regardless of the location. For the experiment, EMS(electric muscle stimulation) was attached to the medical knee protector to manufacture an EMS knee band that can be easily worn regardless of location, and was measured based on the right foot. The study results confirmed that in all tests (electromyography test, static balance test on the balance board, and dynamic balance test by squatting on a Bosu ball), thigh strength improved in the order of treatment before EMS, after EMS, after HICT, and after EMS plus HICT. The study showed that people working from home or with activity restrictions due to COVID-19 had better exercise effects when wearing the EMS knee band and performing HICT, even in a small space.

Study on the Improvement of Water Regeneration Center by Using Non-water-soluble Sanitary Products: Focusing on the case of Seoul City (비수용성 위생용품 사용에 따른 물재생센터 개선방안: 서울시를 중심으로)

  • Choong-Gon Kim;Yoon-Hwan Bae;Hyun-Gon Shin
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.2
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    • pp.39-44
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    • 2023
  • This study was conducted to analyze problems related to non-water-soluble sanitary products during the treatment of water regeneration centers in E.T.F. and S.T.F. at a time when the demand and supply of non-water-soluble sanitary products are increasing. As a result, the improvement plan of the W.R.C. should focus on pretreatment facilities. When replacing facilities in the future, various dust removers suitable for the facility's reality will be installed in the pretreatment of S.T.F., and it is proposed to link a bar-racks screen with a comprehensive treatment device or install a comprehensive treatment device for impurities alone in the pretreatment of E.T.F.. In addition, a microscreen screen must be installed on the front end of the excretory treatment unit. to separate non-water-soluble materials, and it is necessary to secure a maintenance space for the excretory treatment unit.

Effect of Several Native Moss Plants on Particulate Matter, Volatile Organic Compounds and Air Composition

  • Gong, Gyeong Yeop;Kang, Ji Su;Jeong, Kyeong Jin;Jeong, Jun Ho;Yun, Jae Gill
    • Journal of People, Plants, and Environment
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    • v.22 no.1
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    • pp.31-38
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    • 2019
  • Experiments were carried out to investigate the effects of mosses on the removal of particulate matter (PM 10) and volatile organic compounds (VOCs) in an indoor space and on the composition of air. For particulate matter removal experiments, 0.2 g mosquitto coil was burned in a glass chamber, where three kinds of mosses (Plagiomnium cuspidatum, Myuroclada maximowiczii, Etodon luridus) were placed. For VOCs removal experiments, 1 mL paint thinner was volatilized in a glass chamber, where Plagiomnium cuspidatum and Myuroclada maximowiczii were used. As a result, it was found that particulate matter was effectively removed by the three mosses, and the removal efficiency of particulate matter increased as the amount of mosses increased. The amount of VOCs was similar to the level in the control when a low amount of mosses (2 and 4 plates) was used. However, the removal efficiency of VOCs was significant when 6 plates of mosses were used. On the other hand, formaldehyde concentration was 40 times more than the control and carbon monoxide 30 times, when 0.2 g of mosquito repellent was completely burned in a glass chamber. Also formaldehyde removal effect was significant when 6 plates of mosses were placed. However, there was no change in the concentration of indoor oxygen, temperature and humidity by moss plants. In conclusion, the moss plants were effective in removing particulate matter and VOCs, and they are expected to be used for indoor decoration and landscape in order to improve indoor air quality in the future.

Development of Commercial-scaled Pervaporation Hollow Fiber Membrane System for High Pressure and High Temperature Applications (고온 고압용 상업적 규모의 중공사 투과증발 막시스템 개발)

  • Yeom, Choong Kyun;Kang, Kyeong Log;Kim, Joo Yeol;Ahn, Hyo Sung;Kwon, Konho
    • Membrane Journal
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    • v.23 no.4
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    • pp.257-266
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    • 2013
  • The main purpose of this study is to develop a commercial scale of pervaporative process equipped with hollow fiber membrane modules, being able to effectually purify organic solvent at high temperature well over its boiling point under high vapor pressure. Three constituent technologies have been developed; 1) to fabricate braid-reinforced hollow fiber membrane stable in high pressure and high temperature application, 2) to design and fabricate a commercial scale of hollow fiber membrane module, and 3) to design and fabricate a pilot scale of pervaporation equipment system. The developed hollow fiber membrane possesses a membrane performance superior to the membrane of Sulzer (Germany) which is the most-well known for pervaporation process, and the membrane module equips hollow fiber membranes of $4.6m^2$ and the pervaporation system can treat organic liquid at 200 L/h, which is based on the dehydration of 95 wt% isopropyl alcohol (IPA). Since the membrane module is designed to flow in and pass through the inside of individual hollow fiber membrane, not to involve both the formation of feed's dead volume observed in flat-sheet membrane module and the channeling of feed occurring inside hollow fiber bundle which lower membrane performance seriously, it showed excellent separation efficiency. In particular, the module is inexpensive and has less heat loss into its surrounding, in compared with flat-sheet membrane module. In addition, permeant can be removed effectively from the outer surface of hollow fiber membrane because the applied vacuum is conveyed uniformly through space between fibers into respective fiber, even into one in the middle of the hollow fiber bundle in which the space between fibers is uniform in distance. Since the hollow fiber membrane pervaporation system is the first one ever developed in the world, our own unique proprietary technology can be secured, preoccupying technical superiority in export competitive challenges.