• 한국토양비료학회지
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• 제16권1호
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• pp.20-27
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• 1983

제주도(濟州道) 화산회토양유기물(火山灰土壌有機物)의 화학성(化学性), 유기물(有機物) 성상(性狀) 및 부식산(腐植酸)의 광학적(光学的) 특성(特性)을 알고져 수종(数種)의 화산회토양(火山灰土壌)을 공시(供試)하여 실내시험(室內試験)한 결과(結果)를 요약(要約)하면 다음과 같다. 가. 토양(土壌)의 화학적(化学的) 성질(性質) 1) 화산회토양(火山灰土壌)은 비화산회토양(非火山灰土壌)에 비(比)하여 유기물(有機物)(4~27%), 유효규산(有効珪酸)(291~884ppm), 활성(活性) 알루미늄(150~478ppm) 및 활성철함량(活性鉄含量)(0.77~0.86%)이 많고 반대(反対)로 유효인산(有効燐酸)(4~15ppm) 함량(含量)이 현저(顕著)히 낮았다. 2) 가리(加里), 석화(石火), 고토등(苦土等)은 밭의 경우 화산회토양(火山灰土壌)에서 높은 편이나 삼림지(森林地) 및 유휴지토양(遊休地土壌)은 낮은 경향(傾向)을 보였다. 3) 화산회토양(火山灰土壌)은 규반비(珪礬比) 및 규산(珪酸)/유기물비(有機物比)가 낮은 반면(反面) K/Ca+Mg, Al/Fe(활성(活性)) 및 C/P비(比)가 현저(顕著)히 높았다. 나. 유기물(有機物) 및 질소분별정량(窒素分別定量) 1) 화산회토양(火山灰土壌)은 유기물(有機物)의 총탄소중(総炭素中) Humin-C의 비율(比率), 유기물중(有機物中) Humin산(酸) 그리고 Humin중(中) C/N율(率)이 비화산회토양(非火山灰土壌)보다 현저(顕著)히 높았다. 2) 화산회토양(火山灰土壌)은 비화산회토양(非火山灰土壌)에 비(比)하여 총질소(総窒素), 산(酸) 및 알카리가용성(可溶性) 질소함량(窒素含量)이 현저(顕著)히 높은 반면(反面) 총질소중(総窒素中) 무기태질소(無機態窒素)로 방출(放出)될 수 있는 무기화율(無機化率)은 높지 않았다. 다. 토양부식(土壌腐植)의 형태(形態) 1) 화산회토양(火山灰土壌)은 비화산회토양(非火山灰土壌)에 비(比)하여 광흡(光吸) 수능(收能)이 높고(K600, RF치(値), ${\delta}logK$) 부식화도(腐植化度)가 진전(進展)될수록 색농도(色濃度)가 짙은 것으로 나타났다. 2) 화산회토양(火山灰土壌)은 산화제(酸化劑)에 대(対)한 저항성(抵抗性)이 높고 산(酸) 및 알카리 가수분해성(加水分解性)이 강(强)하여 부식화도(腐植化度)가 높아 부식(腐植)의 자연분해(自然分解)가 극(極)히 어려운 것으로 나타났다. 라. Humin의 관능기조사(官能基調査) 화산회토양(火山灰土壌)의 유출부식산(油出腐植酸)의 관능기(官能基)는 phenolic-OH기(基), Alcoholic-OH기(基) 및 Carboxyl기(基)가 많고 비화산회토양(非火山灰土壌)은 Methoxyl기(基) 및 Carbonyl기(基)가 많았다. 마. 부식산(腐植酸)의 흡광도(吸光度) 1) 공시토양(供試土壌)의 가시광역(可視光域)은 200~500nm부근의 단파장영역(短波長領域)이었으며 주로 350, 420, 450 및 480nm 에서 4개(個)의 흡광곡선(吸光曲線)을 나타내었다. 2) 화산회토양(火山灰土壌)인 흑악통(黑岳統)은 362nm부근에서 단일(單一)의 높은 흡광도(吸光度)를 보였으며 비화산회토양(非火山灰土壌)인 영악통(永楽統)은 360nm와 390nm에서 2개(個)의 단순(單純)한 높은 흡광대(吸光帶)를 나타내었다. 마. 분해촉진제(分解促進剤) 처리효과(處理効果) 화산회토양(火山灰土壌)에 대(対)한 분해촉진효과(分解促進効果)는 이도통(統)은 역분해성(易分解性) 유기물(有機物) 첨가(添加)에 따른 "Priming Effect"가 증가(增加)되었으며 남원(南元)과 흑악통(黑岳統)은 Na-Pyrophosphate의 첨가효과(添加効果)가 있었다.

• 한국토양비료학회지
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• 제44권3호
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• pp.331-336
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• 2011

최근 편리함과 측정의 정확성으로 인해 Capacitance sensor가 토양수분 연구나 물관리에 국제적으로도 널리 이용되고 있다. 이 연구는 Capacitance sensor (EnviroSCAN, Sentek Ltd.)가 화산회토양이 많이 분포하는 제주도 지역에서도 활용성이 있는 지를 알아보기 위해 유기물함량이 다른 제주도의 대표적인 토양 종류를 이용하여 Calibration 시험을 수행하였다. 시험 결과 화산회토양에서는 비화산회토양과 달리 센서의 Scaled frequency와 토양의 용적수분함량 간에 Calibration식이 로그식 형태로 나타내는 것이 일반적으로 적용되는 지수식 형태로 나타내는 것보다 상관이 더 높게 나타났다. 또한 화산회토양이 많이 분포하는 지역에 서는 토양수분함량이 높아 습하거나 매우 적어 건조할 경우에는 Capacitance sensor에 의한 수분함량 측정값이 건조기를 이용한 수분함량 값보다 과소하게 측정될 수 있었다. Capacitance sensor를 이용하여 화산회토양에서 토양 수분함량을 정확하게 측정하기 위해서 Calibration식에 적용될 수 있는 현실적인 계수값을 제시하였다. 또 현재 이용되는 EnviroSCAN capacitance probes의 활용성을 제고하기 위해서 계수값을 유기물함량별로 추정하는 식을 제시 하였다. Capacitance sensor를 이용하여 토양수분함량을 정확하게 측정하기 위해서는 사전에 토양의 공극분포, 유기물함량, EC 등 측정여건을 파악하여 조절하는 것이 필요하였다.

• 한국환경복원기술학회지
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• 제4권4호
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• pp.12-18
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• 2001

This study was carried out to analyze physico-chemical properties of soils at the ground of landscape planting in reclaimed land from the sea on Kwangyang Bay, South Korea. Physico-chemical properties of soils at each planting grounds were tested by ANOVA and were significantly(P<0.01) different. The difference came from the soil properties of the covered soil, the disturbance applied to the soil with land use and the accumulation of organic matter after landscape planting. Soil hardness, pH, ECe, Na and K level were in a stable condition at high then low of ground height for landscape planting. Organic matter accumulation was greater at lower planting grounds then top and slope ground of big mounding. The planting grounds of favorable growth for landscape trees were determined as following order : the slope ground and the top ground of big mounding>the ground of medium mounding>the coved ground of improve soil>the lower ground of big mounding>the filled ground of improve soil.

• Environmental Engineering Research
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• 제11권5호
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• pp.241-249
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• 2006

A mathematical model is described for the prediction of convective upward transport of an organic solvent driven by evaporation at the surface, which is known as the major transport mechanism in the in-situ photolysis of a soil contaminated with 2,3,7,8-tetrachlorodibenzo-p-dioxin(TCDD). A finite-element model was proposed to incorporate the effects of multiphase flow on the distribution of each fluid, gravity as a driving force, and the use of hysteretic models for more accurate description of k-S-p relations. Extensive numerical calculations were performed to study fluid flow through three types of soils under different water table conditions. Predictions of relative permeability-saturation-pressure (k-S-p) relations and fluids distribution for an illustrative soil indicate that hysteresis effects may be quite substantial. This result emphasizes the need to use hysteretic models in performing flow simulations including reversals of flow paths. Results of additional calculations accounting for hysteresis on the one-dimensional unsaturated soil columns show that gravity affects significantly on the flow of each fluid during gravity drainage, solvent injection, and evaporation, especially for highly permeable soils. The rate and duration of solvent injection also have a profound influence on the fluid saturation profile and the amount of evaporated solvent. Key factors influencing water drainage and solvent evaporation in soils also include hydraulic conductivity and water table configuration.

• Applied Biological Chemistry
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• 제20권3호
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• pp.310-316
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• 1977

합리적인 제초제 사용에 필요한 기초자료를 얻기 위하여 21개 대표통의 표토에 대한 Atrazine (2-Chloro-4-ethylamino-6-isopropylamino-s-triazine)과 Alachlor (2-Chloro-2'.6'-diethyl-N-(meto xymethyl)-acetanilide)의 흡착 실험을 한 결과는 다음과 같다. 1. Atrazine의 흡착은 점토함량과 유기물 함량과는 정의 상관관계이나 치환성 가리 함량과는 부의 상관관계이었다. 2. Alachlor의 흡착은 유기물 함량, 점토함량및 CEC와는 정의 상관관계이나 모재함량과는 부의 상관관계였다. 3. Alachlor의 토양흡착은 Freundlich 정온 흡착방정식과 잘 부합되었다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2008년도 추계 학술발표회
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• pp.268-276
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• 2008

The status of contaminated soils vary widely ; therefore, the techniques and equipment applicable to the soil concerned should be selected and used after careful consideration. Hyundai Soil Washing is physical-chemical separation based on mining and mineral processing principles for removing a broad range of organic and inorganic contaminants from soil. Mobile plant(capacity 15 tons./hr) was installed for this project. The goals of this project were 1) to verify the applicability of the washing process, which showed reliable results in the pilot plant with various kind of contaminated soils and 2) to promote recycling of the washed soil as a backfill on site. The results revealed that $F^-$ and $Pb^{2+}$ in the soil were effectively washed out to a certain level which washed soil was acceptable for recyeling.

• Journal of Plant Biology
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• 제12권1호
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• pp.15-21
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• 1969

In this experiment, the litters of each five species of neadle-leaf trees and broad-leaf trees were laid on each pot soils, which had same soil conditions, is the green house and the sil fertility of each pots were determined after four years. Chemical properties among each pot soils under litters of needle-laef trees showed remarkable different values in the pH, base exchange capacity, total exchangeable base, base saturation, organic matter, available phosphorus, exchangeable potassium and calcium, and that of broad-leaf trees showed respectively significant difference. The content of chemical components, such as total exchangeable base, organic matter, total nitrogen, available phosphorus and exchanbeable potassium, between pot soils under litters of the needle-leaf trees and the broad-leaf trees were significant at the 0.01 and 0.05 levels of the statistical probability. The fertility of soil under the influence of decayed fallen leaves is the highest value in the posts of broad-leaves and next to the pots of needle-leaves and the control pots the lowest. The pH value of the soil with various kinds of fallen leaves showed little difference among themselves, but it especially approached in the broad leaves plots gradually to neutral and hte non-treated plot showed acidity. Lespedeza bicolar and Castanea crenata are supposed to contribute to the fertility of soil. Pinus rigida showed excellent exchanged properties of soi. The leaves of Robinia pseudoacacia and Pinus koraiensis did not contribute much to the promotion of fertility of soil.

• Journal of Forest and Environmental Science
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• 제36권2호
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• pp.133-142
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• 2020

Soil physical and chemical properties at three layers such as top (0-10 cm), middle (10-20 cm) and bottom (20-30 cm) layers under three different vegetation types were studied. Soil samples were collected from Acacia forest, vegetable and fallow lands of Chittagong university campus, Chittagong, Bangladesh. Results showed that sand was the dominant soil particle followed by clay and silt fractions in all soil depths under different vegetation types. Soils of fallow land showed the highest values of bulk density while forest soils had the lowest values at three depths. Acacia forest soil having lowest values of dispersion ratio (DR) is less vulnerable while fallow soil with highest DR values is more vulnerable to soil erosion. The lower pH value at all soil layers in three ecosystems represented that soils under study are acidic in nature. Contents of organic matter, total nitrogen, exchangeable cations (Ca²⁺, Mg²⁺, K⁺ and Na⁺) and cation exchange capacity (CEC) were observed higher in Acacia forest soils compared to vegetable and fallow soils. Only soils of vegetable land had higher level of available phosphorus in three layers than that of other two land covers. The study also revealed that different soil properties were observed in three different vegetation types might be due to variation in vegetation and agronomic practices.

• 한국농공학회논문집
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• 제59권5호
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• pp.41-49
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• 2017

This study was aimed to investigate the influence of cation exchange capacity (CEC) and application amounts of zeolite on the stabilization of heavy metals (As, Ni, Pb, and Zn) in upland soils. The upland soils were sampled from field near mines located in Gyeonggi Province. The CEC of zeolite was treated at three different levels, ie, low, medium, and high, while zeolite was amended with soils at the ratio of 0.1 % and 0.5 % as to soil weight. A sequential extraction was performed for the soil sampled at 1, 2 4, and 8 week after zeolite was added to the soil. The concentrations of Pb and Zn appeared to be high in the sampled soils. The mobility of heavy metals obtained from sequential experiments was as follows: Pb > Zn > Ni >As. Addition of zeolite to contaminated soils effectively reduced exchangeable and carbonate fractions but increased organic and residual fraction, indicating that zeolite is effective for immobilizing heavy metals in soils. The influence of incubation time on the metal stabilization was rather pronounced as compared to the application amount and CEC of zeolite.

• 보존과학연구
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• 통권27호
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• pp.203-214
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• 2006

The work focuses on the chemical analysis of organic residues in archaeological soils. Particularly, the detection of manuring in archaeological soils can provide important information concerning early human behavior, diet, parasites, ecological adeptation. In this study, archaeological soils excavated at bunto-ri, Haenam and kumjang-ri, Kyungju were used to assess the possibility as indicators of ancient human activity in archaeological areas. The sampled soils were analyzed soil color, pH for their physical and chemical properties and GC/MSD to detect and quantify specific compound. The results showed that the sampled soils were normal pH(6.8~7.2) and soil color of light brown to yellowish brown. Also, the result from the GC/MS analysis indicated that their compounds were hexadecanoic acid, octadecanoic acid, nonadecane, docosanoic acid, methyl ester, teracosanoic acidand methyl este from bunto-ri site and 1-heptadecene, cyclotetracosane, tetracosane, cyclotetracosane,1-docosene, n-nonadecane, tetracosanoic acid methyl ester, cyclooctacosane, 1-nonadecene, eicosane, cyclotriacontane from kumjang-ri site. These compounds are not only normal soil materials but also animal lipid compounds. And the more scientific analysis of the soils will solve a curiosity for artificially incoming.