• Title/Summary/Keyword: Organic core

Search Result 328, Processing Time 0.029 seconds

Origin of Multiple Conductance Peaks in Single-Molecule Junction Experiments

  • Park, Min Kyu;Kim, Hu Sung;Kim, Yong-Hoon
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2013.02a
    • /
    • pp.654-654
    • /
    • 2013
  • One of the most important yet unresolved problems in molecular electronics is the controversy over the number and nature of multiple conductance peaks in single-molecule junctions. Currently, there are three competing explanations of this observation: (1) manifestation of different molecule-electrode contact geometries, (2) formation of gauche defects within the molecular core, (3) involvement of different electrode surface orientations [1]. However, the exact origin of multiple conductance peaks is not yet fully understood, which indicates our incomplete understanding of the scientifically as well as techno-logically important organic-metal contacts. To theoretically resolve this problem, we previously applied a multiscale computational approach that combines force fields molecular dynamics (FF MD), density functional theory (DFT), and matrix Green's function (MGF) calculations [2] to a thermally fluctuating haxanedithiol (C6DT) molecule stretched between flat Au(111) electrodes, but could observe only a single conductance peak [3]. In this presentation, using DFT geometry optimizations and MGF calculations, we consider molecular junctions with more realistic molecule-metal contact conformations and Au(111) electrode surface directions. We also conduct DFT-based molecular dynamics for the highly stretched junction models to confirm our conclusion. We conclude that the S-Au coordination number should be the more dominant factor than the electrode surface orientation.

  • PDF

Development of Somaloy Components for a BLDC Motor in a Scroll Compressor Application

  • Persson, Mats;Nord, Goran;Pennander, Lars-Olov;Atkinson, Glynn;Jack, Alan
    • Proceedings of the Korean Powder Metallurgy Institute Conference
    • /
    • 2006.09b
    • /
    • pp.804-805
    • /
    • 2006
  • Electric scroll-compressor drives are commonly used for e.g. home appliance cooling units. The recent development of hybrid cars with internal combustion engine in combination with electrical propulsion requires new solutions to be able to cool the passenger compartment of cars at stand-still. Both application areas demand efficient motor drives to reach good economy and efficient use of limited battery power as well as competitive volume/weight for a given output. The BLDC motor is a controllable and efficient solution. A major part of the motor is the soft-magnetic core. The powder based $Somaloy^{(R)}$ material shows high resistivity and induction as the result of engineered iron particles with in-organic coating. The unique features of compacted $Somaloy^{(R)}$ components can be utilized to enhance the shape and total volume of the BLDC motor with at least maintained efficiency compared to the use of traditional laminated steel sheet cores. A careful design of the $Somaloy^{(R)}$ components can also simplify assembly and positively influence the coil configuration. This study shows a comparison between a typical laminated BLDC motor and a redesigned, $Somaloy^{(R)}$ based version adapted for a scroll-compressor application.

  • PDF

Rare earth element geochemistry of shelf sediments in the western part of Jeju Island, korea

  • Youn, Jeung-Su;Kim, Tae-Joung
    • 한국지구과학회:학술대회논문집
    • /
    • 2010.04a
    • /
    • pp.58-58
    • /
    • 2010
  • The sediment geochemistry, including REE of surface and core samples in the western part off Jeju Island have been carried out in order to understand the provenance and hydrolic sorting. The sediment in the study area were primarily composed of coarse silt with a mean grain size of $2.8{\sim}82.8{\mu}m$. The ratios of TOC over total nitrogen (TN) showed that the study area sediments contained more organic matters of marine origin than those of terrigenous origin. The total A1203, Fe203, K20, MgO, and MnO contents and REE concentration of the fine sediments are higher than those of the coarse sediments. The higher Zr/Th and Zr/Yb ratios in coarse sediments relative to fine-grained detritus indicates sedimentary sorting. Grain size influence the REE concentrations of the study area sediment significantly. The < $63{\mu}m$ fraction of the sediment has higher REE concentration and different REE patterns when compared with those in bulk samples, due to the presence of REE-enrich heavy minerals. The REE distribution patterns of the western part of Jeju Island sediments are relatively enriched in most LREEs than the Yellow River sediment and depleted in the Changjiang River, but the LaN/YbN ratios are similar to the Changjiang sediment. The Eu/Eu* ratios ranged from 0.594~0.665(0.631) is much similar to the Yellow River sediment, possibly mixture of the sediments from these two rivers.

  • PDF

Operating Characteristics of a Scroll Expander Used in Organic Rankine Cycle (유기랭킨사이클 적용 스크롤 팽창기 성능 특성 연구)

  • Shin, Dong-Gil;Kim, Young-Min;Kim, Chang-Gi
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
    • /
    • v.23 no.12
    • /
    • pp.776-781
    • /
    • 2011
  • The rapid increases in global energy demand and global warming need renewable energy sources such as solar thermal energy, biomass energy and waste heat. A ORC-based micro-CHP system(< 10 kWe) is one of the effective means to use renewable energy and solve energy problems because of its compactness, flexibilities and lower cost compared to other systems. The most important core components of the ORC is the expander which has a strong effect on the cycle efficiency. In the range of power output from 1 to 10 kW, the scroll expander is a good choice due to its performance and reliability. In this study, we have carried out an experimental study on an ORC equipped with oil-free scroll expander working with refrigerant R134a. We have measured power output and thermal efficiencies of the ORC and analyzed correlation between volumetric efficiencies of the expander and thermal efficiencies of the ORC.

Annealing Effect on $SnO_2$ Thin Films Properties ($SnO_2$ 박막 특성에 미치는 annealing 효과)

  • Park, Kyung-Hee;Seo, Yong-Jin;Lee, Woo-Sun;Park, Jin-Seong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2003.05c
    • /
    • pp.99-102
    • /
    • 2003
  • Tin dioxide thin films were deposited at $375^{\circ}C$ on alumina substrate by metal-organic chemical vapor deposition process to find the relationship between physicochemical properties and the annealing treatments. The small grains with heat treatments grew to the bunch of grains and then showed the hillocks on the film surface. The thickness decreased with annealing treatment. The measured binding energy (BE) and branching ratio of the Sn 3d spin-orbital doublet were typical of oxidized states of Sn and the BE of the O1s core level of about 530~530.65eV also confirmed the presence of O-Sn bonds. The BE of oxygen and tin with annealing treatment shifted to higher position. O/Sn atomic ratios of films deposited at $375^{\circ}C$ for 2min and 4min were 1.99 and 2.01, respectively. The value of the atomic ratio O/Sn of films deposited at $375^{\circ}C$ for 2min changed from 1.99 to 2.45 with annealing treatment. Gas sensitivity depended on annealing temperature, the sensitivity increased with increasing annealing temperature.

  • PDF

Enzyme-Conjugated CdSe/ZnS Quantum Dot Biosensors for Glucose Detection

  • Kim, Gang-Il;Sung, Yun-Mo
    • Korean Journal of Materials Research
    • /
    • v.19 no.1
    • /
    • pp.44-49
    • /
    • 2009
  • Conjugated nanocrystals using CdSe/ZnS core/shell nanocrystal quantum dots modified by organic linkers and glucose oxidase (GOx) were prepared for use as biosensors. The trioctylphophine oxide (TOPO)-capped QDs were first modified to give them water-solubility by terminal carboxyl groups that were bonded to the amino groups of GOx through an EDC/NHS coupling reaction. As the glucose concentration increased, the photoluminescence intensity was enhanced linearly due to the electron transfer during the enzymatic reaction. The UV-visible spectra of the as-prepared QDs are identical to that of QDs-MAA. This shows that these QDs do not become agglomerated during ligand exchanges. A photoluminescence (PL) spectroscopic study showed that the PL intensity of the QDs-GOx bioconjugates was increased in the presence of glucose. These glucose sensors showed linearity up to approximately 15 mM and became gradually saturated above 15 mM because the excess glucose did not affect the enzymatic oxidation reaction past that amount. These biosensors show highly sensitive variation in terms of their photoluminescence depending on the glucose concentration.

Light Efficiency Enhancement Technology of OLED: Fabrication of Random Nano External Light Extraction Composite Layer (OLED의 광 효율 향상 기술: 랜덤 나노 외부 광 추출 복합 층 제작)

  • Choi, Geun Su;Jang, Eun Bi;Seo, Ga Eun;Park, Young Wook
    • Journal of the Semiconductor & Display Technology
    • /
    • v.21 no.3
    • /
    • pp.39-44
    • /
    • 2022
  • The light extraction technology for improving the light efficiency of OLEDs is the core technology for extracting the light inside the OLEDs to the outside. This study demonstrates a simple method to generate random nanostructures (RNSs) containing high refractive index nanoparticles to improve light extraction and viewing angle characteristics. A simple dry low-temperature process makes the nanostructured scattering layer on the polymer resin widely used in the industry. The scattering layer has the shape of randomly distributed nanorods. To control optical properties, we focused on changing the shape and density of RNSs and adjusting the concentration of high refractive index nanoparticles. As a result, the film of the present invention exhibits a perpendicular transmittance of 85% at a wavelength of 550 nm. This film was used as a scattering layer to reduce substrate mode loss and improve EL efficiency in OLEDs.

A new type of multimedia content with Chinese characters as the core-Barrage

  • Pan, Yang;Kim, KiHong;Yan, JiHui
    • International journal of advanced smart convergence
    • /
    • v.11 no.2
    • /
    • pp.118-127
    • /
    • 2022
  • Barrage language is a new media language based on Internet video. It is a representative expression of the Internet environment regardless of its format and content. As a unique movie viewing characteristic provided by the barrage function, the timeliness of feedback, entertainment, and interactivity of the content are excellent. Characteristic. Barrage language itself is closely related not only to the value of linguistic research, but also to the spread of the Internet in the Internet environment. Based on the current situation of Chinese video sites, this thesis explores how Barrage is an organic cycle of culture and consumption in a specific platform and group, and analyzes its propagation methods and effects. By analyzing the characteristics of content production patterns unique to the barrage culture, implications and reference values for production activities of other cultures, the effect of popularization on viewers and the production and consumption of the 'barrage' culture of the industry is studied, and furthermore, the 'barrage' culture is It was designed to be a reference for the development of the platform, internet culture, and animation industry culture.

Nerve-Agent Selective Chemiresistors Fabricated by Oxime Decorated Polypyrrole Layer on Cellulose Paper (셀룰로오스 종이 상에 Oxime 도입된 polypyrrole 층을 제조한 신경작용제 선택적 화학저항 센서)

  • Changhoon Jeon;Taihwan Ha
    • Journal of the Korea Institute of Military Science and Technology
    • /
    • v.27 no.4
    • /
    • pp.528-534
    • /
    • 2024
  • In continuous research of detecting highly toxic chemical warfare agents to ensure preparedness for the future battlefield, flexible and wearable sensor platforms with high sensitivity are still demanding. Herein we demonstrate a facile fabrication of polypyrrole-based chemiresistors on cellulose paper for the detection of nerve gas simulants. In order to optimize electrical properties of sensor platform, conducting polymer made of polypyrrole were first synthesized on flexible cellulose paper and interdigitated electrodes were formed thereon. Following confirmation of polypyrrole and/or oxime moiety through FT-IR analyses, electrical characteristics were measured in the various ratio of monomers between simple pyrrole and oxime-modified one. Typically for the optimized chemiresistor(2:8 molar ratio of simple pyrrole and oxime-modified one), eleven species of chemical warfare agents were examined and enhanced conductivity(104~105 order) was observed for three simulants(diethyl cyanophosphonate, diisopropyl fluorophosphonate and diethyl chlorophosphonate), which was mainly attributed to intermolecular hydrogen bonding, while no significant responses was recorded against sixteen common volatile organic chemicals.

Study on VOCs Emission Characteristic of Taxidermied Mounting Techniques (박제표본 제작방법에 따른 휘발성유기화합물 방출 특성 연구)

  • OH Jungwoo;CHUNG Yongjae
    • Korean Journal of Heritage: History & Science
    • /
    • v.56 no.2
    • /
    • pp.136-146
    • /
    • 2023
  • Biological materials, such as stuffed specimens, can release various acids or volatiles. There has been no research carried out on the emission characteristics of organic compounds generated from the preservatives used in taxidermy specimens or associated manufacturing materials and methods. Therefore, in order to identify the organic compounds generated from taxidermy specimens, a degradation experiment was conducted on specimens for each material and for storage specimens. To produce Ogye chicken specimens, naphthalene and borax were used as preservatives, and planer sawdust, newspaper, and polystyrene foam were used as the core body materials. The deterioration experiment was conducted for 2 weeks in a high-temperature environment(50℃) and a high-humidity environment (95%), with an Ogye chicken specimen (year 2015) kept in an animal storage facility. Results indicated that the concentration of organic compounds generated by the specimen in the high-temperature environment tended to be greater than that in the high-humidity environment. The preservatives benzene, toluene, xylene, and p-dichlorobenzene were detected in the specimens using naphthalene, confirming that naphthalene is a major organic compound release factor, and the specimens that used sawdust, newspaper, and polystyrene foam also exhibited organic compounds. This appears to have been due to degradation of the material. In addition, ammonia was detected in the specimens for each material due to decay. In particular, the specimens using borax at high temperature were subject to approximately 9 times higher rates of ammonia-related deterioration than the specimens using naphthalene. These results can be considered to result from the prevention of biological damage through insecticidal effects by accelerating the sublimation of naphthalene in a high-temperature environment. Naphthalene is a potentially carcinogenic substance, and when used as a preservative, proper use management is required. Taxidermy specimens can release various organic compounds depending on the manufacturing techniques used, so a systematic preservation management plan is required that depends on conditions such as the applicable manufacturing materials and preservatives.