• Title/Summary/Keyword: Organic Se

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Phase-and Size-Controlled Synthesis of CdSe/ZnS Nanoparticles Using Ionic Liquid (이온성 액체에 의한 CdSe/ZnS 나노입자의 상과 크기제어 합성)

  • Song, Yun-Mi;Jang, Dong-Myung;Park, Kee-Young;Park, Jeung-Hee;Cha, Eun-Hee
    • Journal of the Korean Electrochemical Society
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    • v.14 no.1
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    • pp.1-8
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    • 2011
  • Ionic liquids are room-temperature molten salts, composed of organic mostly of organic ions that may undergo almost unlimited structural variation. We approach the new aspects of ionic liquids in applications where the semiconductor nanoparticles used as sensitizers of solar cells. We studied the effects of ionic liquids as capping ligand and/or solvent, on the morphology and phase of the CdSe/ZnS nanoparticles. Colloidal CdSe/ZnS nanoparticles were synthesized using a series of imidazolium ionic liquids; 1-R-3-methylimidazolium bis(trifluoromethylsulfonyl) imide ([RMIM][TFSI]), where R = ethyl ([EMIM]), butyl ([BMIM]), hexyl ([HMIM]), octyl ([OMIM]). The average size of nanoparticles was 8~9 nm, and both zinc-blende and wurtzite phase was produced. We also synthesized the nanoparticles using a mixture of trihexyltetradecylphosphonium bis(trifluoromethylsulfonyl)imide ([$P_{6,6,6,14}$][TFSI]) and octadecene (ODE). The CdSe/ZnS nanoparticles have a smaller size (5.5 nm) than that synthesized using imidazolium, and with a controlled phase from zinc-blende to wurtzite by increasing the volume ratio of [$P_{6,6,6,14}$][TFSI]. For the first time, the phase and size control of the CdSe/ZnS nanoparticles was successfully demonstrated using those ionic liquids.

Distribution of the Organic Contents in Reservoir Sediment (호소 퇴적물의 유기물 분포)

  • Hwang, Jong Yeon;Han, Eui Jung;Yu, Soon Ju;Yoon, Young Sam;Cheon, Se Eug;Kim, Tae Keun
    • Journal of Environmental Impact Assessment
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    • v.8 no.2
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    • pp.95-107
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    • 1999
  • The organic contents of reservoir sediment can offer a good indicator to events in history of lake life. Reservoir sediment have many information of the past and future fingerprint about development direction of life cycle in biological animals. So, in this study we made an effort to know the distribution of organic contents in Daecheong reservoir sediment. Items for this investigations are such as follows: Loss on ignition, COD, Organic carbon, TN, TP, heavy metal contents, Loss on ignitions were determined in 6.44~15.91% and COD were determined in 1.606~6.859%, organic carbon in 1,077~3.743%. Contents of TP and TN were in the range of 0.083~0.757%, and 0.645~0.926%, respectively.

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Selenium in Pig Nutrition and Reproduction: Boars and Semen Quality - A Review

  • Surai, Peter F.;Fisinin, Vladimir I.
    • Asian-Australasian Journal of Animal Sciences
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    • v.28 no.5
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    • pp.730-746
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    • 2015
  • Selenium plays an important role in boar nutrition via participating in selenoprotein synthesis. It seems likely that selenoproteins are central for antioxidant system regulation in the body. Se-dependent enzyme glutathione peroxidase (GSH-Px) is the most studied selenoprotein in swine production. However, roles of other selenoproteins in boar semen production and maintenance of semen quality also need to be studied. Boar semen is characterised by a high proportion of easily oxidized long chain polyunsaturated fatty acids and requires an effective antioxidant defense. The requirement of swine for selenium varies depending on many environmental and other conditions and, in general, is considered to be 0.15 to 0.30 mg/kg feed. It seems likely that reproducing sows and boars are especially sensitive to Se deficiency, and meeting their requirements is an important challenge for pig nutritionists. In fact, in many countries there are legal limits as to how much Se may be included into the diet and this restricts flexibility in terms of addressing the Se needs of the developing and reproducing swine. The analysis of data of various boar trials with different Se sources indicates that in some cases when background Se levels were low, there were advantages of Se dietary supplementation. It is necessary to take into account that only an optimal Se status of animals is associated with the best antioxidant protection and could have positive effects on boar semen production and its quality. However, in many cases, background Se levels were not determined and therefore, it is difficult to judge if the basic diets were deficient in Se. It can also be suggested that, because of higher efficacy of assimilation from the diet, and possibilities of building Se reserves in the body, organic selenium in the form of selenomethionine (SeMet) provided by a range of products, including Se-Yeast and SeMet preparations is an important source of Se to better meet the needs of modern pig genotypes in commercial conditions of intensive pig production.

Tailoring the Excited-State Intramolecular Proton Transfer (ESIPT) Fluorescence of 2-(2'-Hydroxyphenyl)benzoxazole Derivatives

  • Seo, Jang-Won;Kim, Se-Hoon;Park, Sang-Hyuk;Park, Soo-Young
    • Bulletin of the Korean Chemical Society
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    • v.26 no.11
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    • pp.1706-1710
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    • 2005
  • The excited-state intramolecular proton transfer (ESIPT) fluorescence in the 2-(2'-hydroxyphenyl)benzoxazole (HBO) derivatives with different electron donor and acceptor substituents was studied by spectroscopic and theoretical methods. Changes in the electronic transition, energy levels, and orbital diagrams of HBO analogues were investigated by the semi-empirical molecular orbital calculation and were correlated with the experimental spectral position of ESIPT keto emission. It was found that the presence of substituents, regardless of their nature, resulted in the red-shifted absorption relative to HBO. However, the spectral change of the ESIPT fluorescence was differently affected by the nature of substituent: hypsochromic shift with electron donor and bathochromic shift with electron acceptor.

Dehydration and RDF Production of Organic Sludge with Hydrothermal Pre-treatment Process (증기열 전처리공정을 이용한 유기성 슬러지의 건조 및 성형연료화)

  • Park, Se-Joon;Choi, Yong-Sung;Lee, Kyung-Sup
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.58 no.4
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    • pp.526-531
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    • 2009
  • This paper suggests the dehydration and RDF(Refuse Derived Fuel) production of organic sludge, livestock manure and sewerage sludge causing environmental problems, with hydrothermal pre-treatment process. The renewable technology from the organic wastes must involve short treatment time required, reusable energy source, anti-odor and viruses, low cost for the treatment, and well-fertilization. The hydrothermal pre-treatment process promotes to evaporate moisture in the sludge after being shortly treated in a reactor, which is supplied steam and heat by an external boiler, due to the pressure with steam breaks the cell walls of the sludge, so this process removes the internal moisture of the cell. Then, the treated sludge(solid-state) is mixed with waste vinyls called RDF(6,706kcal/kg).

Dehydration and RDF Production of Organic Wastes with Pressurized Hydrothermal Treatment Process (증기가압형 처리공정을 이용한 유기성 폐기물의 건조처리 및 고형연료화)

  • Park, Se-Joon;Choi, Young-Chan;Choi, In-Kyu
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.5
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    • pp.439-446
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    • 2009
  • This paper investigates the dehydration and RDF (Refuse Derived Fuel) production of organic wastes, livestock manure and sewerage sludge with pressurized hydrothermal treatment process. The renewable technology for the organic wastes must involve short treatment time required, reusable energy source, anti-odor and viruses, low cost for the treatment, and well-fertilization. The pressurized hydrothermal treatment process promotes to evaporate moisture in the waste after being shortly treated in a reactor, which uses steam and heat supplied by an external boiler. By the pressurized steam, the cell walls of the waste break and effectively release the internal moisture. Then, the dried waste can be mixed with waste vinyls to produce RDF with a higher heating value as high as 6,700 kcal/kg.

Enhancement of outcoupling efficiency of OLEDs by using nanoimprinted polymer nanostructures

  • Jeon, So-Hee;Kang, Jae-Wook;Park, Hyung-Dol;Shim, Jong-Youp;Jeong, Jun-Ho;Kim, Se-Heon;Youn, Jae-R.;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.521-522
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    • 2008
  • An etch-less simple method was developed to fabricate two-dimensional nanostructures on glass substrate directly by using UV curable polymer resin and UV nanoimprint lithography in order to improve output coupling efficiency of OLEDs. OLEDs integrated on nanoimprinted substrates enhanced electro-luminance intensity by up to 50% compared with the conventional device.

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