• Title/Summary/Keyword: Organic Se

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Sewage sludge solubilization using ultrasonic combined with calcium peroxide (초음파/과산화칼슘(US/CaO2)을 이용한 하수슬러지 가용화)

  • Han, Jun-Hyuk;Nam, Se-Yong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.29 no.4
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    • pp.41-46
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    • 2021
  • In order to investigate the degree of sewage sludge solubilizaion using ultrasonic(US) combined with calcium peroxide(CaO2), VSS reduction rate, solubilization rate, SCOD/VSS ratio, SCOD increasing rate, LB-EPS(Loosely-Bound EPS) and TB-EPS(Tightly-bound EPS) were measured. US was compared as a control. Solubilization rate increased by 23.4% under US and increased by 50.7% under US/CaO2(0.05 g CaO2/g VSS). and also, at the same conditions, VSS reduction rate increased by 7.1% and 17.7%, respectively. SCOD increasing rate from 10 to 90 minutes was 0.0151 min-1 under US/CaO2(0.02 g CaO2/g VSS). TB-EPS decreased by 36.4% under US and decreased by 59.0% under US/CaO2(0.05 g CaO2/g VSS). TB-EPS decreased during first 10 minutes and then decreased slowly until 90 minutes. There was no significant difference in TB-EPS decrease according to the dosage of calcium peroxide.

Characterization of fine particulate matter during summer at an urban site in Gwangju using chemical, optical, and spectroscopic methods (화학적·광학적·분광학적 방법을 이용한 광주 도심지역 여름철 초미세먼지의 특성)

  • Son, Se-Chang;Park, Tae-Eon;Park, Seungshik
    • Particle and aerosol research
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    • v.17 no.4
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    • pp.91-106
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    • 2021
  • Daily PM2.5 was collected during summer period in 2020 in Gwangju to investigate its chemical and light absorption properties. In addition, real-time light absorption coefficients were observed using a dual-spot 7-wavelength aethalometer. During the study period, SO42- was the most important contributor to PM2.5, accounting for on average 33% (10-64%) of PM2.5. The chemical form of SO42- was appeared to be combination of 70% (NH4)2SO4 and 30% NH4HSO4. Concentration-weighted trajectory (CWT) analysis indicated that SO42- particles were dominated by local pollution, rather than regional transport from China. A combination of aethalometer-based and water-extracted brown carbon (BrC) absorption indicated that light absorption of BrC due to aerosol particles was 1.6 times higher than that due to water-soluble BrC, but the opposite result was found in absorption Ångström exponent (AAE) values. Lower AAE value by aerosol BrC particles was due to the light absorption of aerosol BrC by both water-soluble and insoluble organic aerosols. The BrC light absorption was also influenced by both primary sources (e.g., traffic and biomass burning emissions) and secondary organic aerosol formation. Finally the ATR-FTIR analysis confirmed the presence of NH4+, C-H groups, SO42-, and HSO42-. The presence of HSO42- supports the result of the estimated composition ratio of inorganic sulfate ((NH4)2SO4) and bisulfate (NH4HSO4).

Improvement of Sewage Sludge Dewaterability using Fe(II)/Na2S2O8 (Fe(II)/Na2S2O8을 이용한 하수슬러지 탈수능 개선)

  • Han, Jun-Hyuk;Nam, Se-Yong
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.3
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    • pp.23-28
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    • 2022
  • In order to investigate the degree of sewage sludge dewaterability using Fe(II)/Na2S2O8, STTF, SCST, water content, TS, VS, TB-EPS as carbohydrate and Protein were measured. The dosage of Na2S2O8 was varied from 0.4 to 0.7 mmol/gVS and molar ratio of Fe(II)/Na2S2O8 was varied from 0.5 to 0.7 mol/mol. According to the increase of the dosage of Na2S2O8 and Fe(II)/Na2S2O8 molar ratio, STTF and SCST increased from 1.00 to 15.00 and 4.51, respectively. Water content decreased to 82.6%. TB-EPS as carbohydrate and protein decreasing rate also increased to 37.16% and 57.34%, respectively. Especially, Na2S2O8 0.6 mmol/gVS and Fe(II)/Na2S2O8 0.6 mol/mol condition, water content dercreased to 83.1%, STTF and SCST increased to 13.64 and 4.19 which showed the cost effective improvement of dewaterability. It is considered that SO4- radical generated by Fe(II)/Na2S2O8 degraded EPS and converted bound water to free water.

Effects of different inorganic: organic zinc ratios or combination of low crude protein diet and mixed feed additive in weaned piglet diets

  • Oh, Han Jin;Kim, Myung Hoo;Lee, Ji Hwan;Kim, Yong Ju;An, Jae Woo;Chang, Se Yeon;Go, Young Bin;Song, Dong Cheol;Cho, Hyun Ah;Jo, Min Seok;Kim, Dae Young;Kim, Min Ji;Cho, Sung Bo;Kim, Hyeun Bum;Cho, Jin Ho
    • Journal of Animal Science and Technology
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    • v.64 no.1
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    • pp.23-37
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    • 2022
  • Thirty-six weaned piglets with an initial body weight (BW) of 8.43 ± 0.40 kg (28 days of age, ([Landrace × Yorkshire] × Duroc) were randomly assigned to 6 treatments for a 2-week feeding trial to determine the effects of different inorganic zinc (IZ), organic zinc (OZ) or combination of low crude protein diet (LP) and Mixed feed additive (MFA) on diarrhea score, nutrient digestibility, zinc utilization, blood profiles, organ weight, and fecal microflora in weaned piglet diet. The pigs were individually placed in 45 × 55 × 45 cm stainless steel metabolism cages in an environmentally controlled room (30 ± 1℃). The dietary treatments included a negative control (NC), positive control (PC; zinc oxide, 1,000 mg/kg), T1 (IZ : OZ, 850 : 150), T2 (IZ : OZ 700 : 300), T3 (IZ : OZ, 500 : 500), and T4 (LP + MFA [0.1% Essential oils + 0.08% Protease + 0.02% Xylanase]). The daily feed allowance was adjusted to 2.7 times the maintenance requirement for digestible energy (2.7 × 110 kcal of DE/kg BW0.75). This allowance was divided into two equal parts, and the piglets were fed at 08 : 30 and 17 : 30 each day. Water was provided ad libitum through a drinking nipple. The diarrhea score was significantly increased (p < 0.05) in NC treatment compared with other treatments. The apparent total tract digestibility (ATTD) of dry matter (DM), nitrogen (N), and gross energy (GE) was significantly increased (p < 0.05) in the T2 treatment compared with the PC and NC treatments in week 1. In week 2, the ATTD of DM, N, and GE was significantly decreased (p < 0.05) in the NC treatment compared with other treatments. The T3 treatment had significantly higher (p < 0.05) ATTD and apparent ileal digestibility of zinc than the PC and T1 treatments. The Escherichia coli count in feces was significantly decreased in the T4 treatment compared with the NC and T2 treatments. The Lactobacillus count in feces was significantly increased in the T4 and T1 treatment compared with the T2 and T3 treatments. In conclusion, IZ : OZ 500 : 500 levels could improve nutrient digestibility and zinc utilization in weaned piglets, Moreover, MFA in LP diets could be used as a zinc alternative.

Synthesis and Properties of Photo-curable Biomass-based Urethane Acrylate Oligomers (광경화형 바이오매스계 우레탄 아크릴레이트 올리고머의 합성 및 물성 연구)

  • Se-Jin Kim;Lan-Ji Baek;Byungjin Koo;Jungin Choi;JungMi Cheon;Jae-Hwan Chun
    • Journal of Adhesion and Interface
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    • v.24 no.1
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    • pp.26-35
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    • 2023
  • Generally, solvent-type coatings generate a large amount of volatile organic chemicals(VOC), which are carcinogenic substances, in the manufacturing process, and their use is regulated due to environmental problems. There is also the problem of resource depletion due to limited fossil fuels. Therefore, in this study, UV-curable urethane acrylate oligomers were synthesized with different contents of isosorbide, which is a biomass material, and proceeded to evaluate the physical properties of coatings. As the isosorbide contents increased, the viscosity, glass transition temperature, tensile strength, stain resistance, and pencil hardness increased, but elongation and flexibility decreased, and BOI-3 showed the best adhesion. The isosorbide content of the oligomer fixed at 20%, UV-curable urethane acrylate oligomer was synthesized according to the content ratio of polycaprolactone diol(PCL) and Ecoprol H1000(Ecoprol). As the PCL/Ecoprol content ratio increased, the glass transition temperature, elongation, and flexibility increased, but the tensile strength and pencil hardness decreased. It was confirmed that the adhesion and stain resistance increased by improving the surface bonding strength of PCL. All films of oligomers synthesized were transparent without discoloration.

Growth Environment and Vegetation Structure of Habitats of Acer tegmentosum Maxim. (산겨릅나무(Acer tegmentosum Maxim.) 자생지의 서식환경 특성 및 식생구조)

  • Son, Ho-Jun;Kim, Se-Chang;Lee, Da-Hyun;Kwon, Soon-Jae;Park, Wan-Geun;Kim, Young-Seol
    • Journal of agriculture & life science
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    • v.50 no.3
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    • pp.69-80
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    • 2016
  • The present study was to survey the site environment, vegetation structure and soil characteristics in the wild habitats of Acer tegmentosum Maxim. and offers basic information for habitats conservation and restoration. Most of the wild habitats were located at altitudes between 605~1,413m with inclinations ranged as 8~30°. The bare rock rate were 8~50%. The vegetation structure by the PC-ORD based on the Two Way Cluster Analysis were divided into three groups Community I(Acer tegmentosum - Quercus mongolica), Community II(Acer tegmentosum - Carpinus cordata), Community III(Quercus mongolica - Tilia amurensis). The species diversity(H') was highest in Community II as 1.474, Community I was 1.471, Community III was 1.219. The soil textures were Clay loam, The average soil pH was 4.8, Soil organic matter was 15.15% and available phosphorus was 2.33ppm. Ordination analysis result by soil characteristics, community, characteristic species showed that the greatest effect factors were slope, altitude, tree and shrub's cover rate, organic matter, total-nitrogen, calcium, magnesium. Correlation analysis between environment factor result showed that O.M. - (T.N., K+, Mg2+, CEC, EC), T.N. - (K+, Mg2+, CEC, EC) were positive correlations.

Degradation Characteristics of Non-degradable Dye in Aqueous Solution by Ozonation (고도산화공정인 오존처리에 의한 난분해성 염료 수용액의 분해특성)

  • Hwang, Se-Wook;Park, Jong-Hwan;Lee, Su-Lim;Eom, Ju-Hyun;Ryu, Sung-Ki;Choi, Ik-Won;Kim, Seong-Heon;Kang, Se-Won;Cho, Ju-Sik;Seo, Dong-Cheol
    • Korean Journal of Environmental Agriculture
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    • v.39 no.1
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    • pp.58-64
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    • 2020
  • BACKGROUND: Most of the researches on the dye removal using ozonation have been focused on the removal efficiency. However, the research on their removal characteristics and mechanism according to the reaction time has been still insufficient. METHODS AND RESULTS: In this study, the effects of initial pH and dye concentration with reaction time on the degradation characteristics of methyl orange (MO) and methylene blue (MB) by ozonation were evaluated. The degradation efficiency of MB by ozonation increased with increasing pH. On the other hand, the degradation efficiency of MO by ozonation did not show a significant difference with varing pH. The both MO and MB by ozonation were decomposed within 30 min irrespective of the dye concentration, but the decomposition rates of dyes were faster at lower initial dye concentration. The decomposition efficiency of total organic carbon (TOC) in each dye solution by ozonation was low, which was found to be effective for partial decomposition such as decolorization rather than complete degradation of the dye. CONCLUSION: Overall, ozonation was an effective method for removing nondegradable dyes. However, it is necessary to study the optimization of dye degradation under various environmental conditions for ozonation.

Effects of Cultivation Season and Method on Growth and Quality of Tomato (토마토의 재배시기(栽培時期)와 재배방식(栽培方式)이 생육(生育) 및 품질(品質)에 미치는 영향(影響))

  • Park, Se Won;Lee, Ji Won;Kim, Kwang Yong;Kim, Young Cheol;Hong, Se Jin
    • Horticultural Science & Technology
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    • v.17 no.2
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    • pp.115-117
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    • 1999
  • Tomato (Lycopersicon esculentum) fruits were grown by the hydroponic cultivation system using perlite and soil cultivation system. The growth, yield, and fruit quality were compared between two growing seasons of spring and summer and two cultivation systems, respectively. In tomato, little difference was observed in growth and yield between two cultivation systems, but plant growth and total yield of fruits were much more in summer than in spring. The contents of glucose and fructose were more in spring-grown fruit than in summer-grown one, and in hydroponically cultivated fruit than in soilcultivated, respectively. The weight loss during room temperature storage was lower in hydroponically cultivated fruit than in soil-cultivated one, and in summer-grown fruit than in spring-grown one, respectively. In terms of color change, the shelf-life of tomato fruit was shorter by one day in summer-grown one fruit than in spring-grown one, and in hydroponcically cultivated one fruit than in soil-cultivated, respectively.

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Physicochemical Composition of Seaweed Fulvescens (Capsosiphon fulvescens) (매생이(Capsosiphon fulvescens)의 이화학적 성분)

  • Yang, Ho-Cheol;Jung, Kyeong-Mo;Gang, Kwang-Sung;Song, Byeong-Jun;Lim, Hyeon-Cheol;Na, Hwan-Sik;Mun, Hee;Heo, Nam-Chil
    • Korean Journal of Food Science and Technology
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    • v.37 no.6
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    • pp.912-917
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    • 2005
  • Physicochemical components of dried green algae, Seaweed fulvescens (Capsosiphon fulvescens) with $96.02{\pm}0.02%$ moisture content, were investigated. Crude protein, crude lipid, ash and carbohydrate content of C. fulvescens were $31.76{\pm}0.26,\;1.01{\pm}0.21,\;13.58{\pm}0.62\;and\;53.65{\pm}0.73$, respectively. Predominant minerals were Na, Mg, Ca, K and P. Fe $(122.83{\pm}11.19mg/%)\;and\;Se\;(0.90{\pm}0.07mg%)$ contents in were higher than those of other seaweeds. Major free sugars were identified as fructose, glucose, sucrose, maltose and galactose. Organic acid including L-malic acid, citric acid, tartaric acid and d-malic acid were detected. Most abundant amino acids were glutamic acid, aspartic acid and alanine. Main fatty acids were palmitic acid, linolenic acid and stearidonic acid, with 58.37% polyenes.

Effects of Passivation Thin Films by Spray Coatings on Properties of Flexible CIGS Solar Cells (스프레이코팅법에 의한 패시베이션 박막이 플렉시블 CIGS 태양전지의 특성에 미치는 영향)

  • Lee, Sang Hee;Park, Byung Min;Kim, Ki Hong;Chang, Young Chul;Pyee, Jaeho;Chang, Ho Jung
    • Journal of the Microelectronics and Packaging Society
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    • v.23 no.3
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    • pp.57-61
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    • 2016
  • In order to protect the solar cells from the moisture and oxygen, we evaluated the electrical and optical properties for the $Cu(In,Ga)Se_2$ (CIGS) solar cells which were prepared by the spray coating method. Generally, the EVA (ethylene-vinyl acetate) films are laminated to protect the CIGS flexible solar cells, which results in a high cost process due to complicated devices. In this study, we tried to prepare the protection layers of the flexible CIGS flexible solar cells by using spray coating method instead of conventional laminating films in order to reduce the device weight as well as the process time. The CIGS solar cells with spray coating method showed an enhanced efficiency than the before treated sample (2.77% to 2.93%) and relatively proper water vapor transmission rate of the solar cells about 62.891 gm/[$m^2-day$].