Korean Journal of Environmental Agriculture (한국환경농학회지)

The Korean Society of Environmental Agriculture (한국환경농학회)
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Degradation Characteristics of Non-degradable Dye in Aqueous Solution by Ozonation

고도산화공정인 오존처리에 의한 난분해성 염료 수용액의 분해특성

  • Hwang, Se-Wook (Division of Applied Life Science (BK21 Plus) & Institute of Agriculture and Life Science, College of Agriculture and Life Sciences, Gyeongsang National University) ;
  • Park, Jong-Hwan (Division of Applied Life Science (BK21 Plus) & Institute of Agriculture and Life Science, College of Agriculture and Life Sciences, Gyeongsang National University) ;
  • Lee, Su-Lim (Division of Applied Life Science (BK21 Plus) & Institute of Agriculture and Life Science, College of Agriculture and Life Sciences, Gyeongsang National University) ;
  • Eom, Ju-Hyun (Division of Applied Life Science (BK21 Plus) & Institute of Agriculture and Life Science, College of Agriculture and Life Sciences, Gyeongsang National University) ;
  • Ryu, Sung-Ki (Agricultural Chemistry, Graduate Schoools, Gyeongsang National University) ;
  • Choi, Ik-Won (Water Environmental Engineering Research Division, Water Environment Research Department, National Institute of Environmental Research) ;
  • Kim, Seong-Heon (Soil and Fertilizer Division, Department of Agricultural Environment, National Institute of Agricultural Sciences, Rural Development Administration) ;
  • Kang, Se-Won (Red River Research Station, Louisiana State University Agricultural Center) ;
  • Cho, Ju-Sik (Department of Bio-Environmental Sciences, College of Life Sciences Industry, Sunchon National University) ;
  • Seo, Dong-Cheol (Division of Applied Life Science (BK21 Plus) & Institute of Agriculture and Life Science, College of Agriculture and Life Sciences, Gyeongsang National University)
  • 황세욱 (경상대학교 농업생명과학대학 응용생명과학부(BK21 Plus) & 농업생명과학연구원) ;
  • 박종환 (경상대학교 농업생명과학대학 응용생명과학부(BK21 Plus) & 농업생명과학연구원) ;
  • 이수림 (경상대학교 농업생명과학대학 응용생명과학부(BK21 Plus) & 농업생명과학연구원) ;
  • 엄주현 (경상대학교 농업생명과학대학 응용생명과학부(BK21 Plus) & 농업생명과학연구원) ;
  • 류성기 (경상대학교 일반대학원 농화학과) ;
  • 최익원 (국립환경과학원 물환경연구부 물환경공학연구과) ;
  • 김성헌 (농촌진흥청 농업환경부 토양비료과) ;
  • 강세원 (루이지애나주립대학교 레드리버연구소) ;
  • 조주식 (순천대학교 생명산업과학대학 생물환경학과) ;
  • 서동철 (경상대학교 농업생명과학대학 응용생명과학부(BK21 Plus) & 농업생명과학연구원)
  • Received : 2020.03.04
  • Accepted : 2020.03.23
  • Published : 2020.03.31
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Abstract

BACKGROUND: Most of the researches on the dye removal using ozonation have been focused on the removal efficiency. However, the research on their removal characteristics and mechanism according to the reaction time has been still insufficient. METHODS AND RESULTS: In this study, the effects of initial pH and dye concentration with reaction time on the degradation characteristics of methyl orange (MO) and methylene blue (MB) by ozonation were evaluated. The degradation efficiency of MB by ozonation increased with increasing pH. On the other hand, the degradation efficiency of MO by ozonation did not show a significant difference with varing pH. The both MO and MB by ozonation were decomposed within 30 min irrespective of the dye concentration, but the decomposition rates of dyes were faster at lower initial dye concentration. The decomposition efficiency of total organic carbon (TOC) in each dye solution by ozonation was low, which was found to be effective for partial decomposition such as decolorization rather than complete degradation of the dye. CONCLUSION: Overall, ozonation was an effective method for removing nondegradable dyes. However, it is necessary to study the optimization of dye degradation under various environmental conditions for ozonation.

Keywords

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