• Title/Summary/Keyword: Organic Contaminants

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A fundamental study on ozone oxidation of humic substances (휴믹물질의 오존산화에 관한 기초연구)

  • 김은호;김영웅;손희종;장성호
    • Journal of environmental and Sanitary engineering
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    • v.14 no.3
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    • pp.10-21
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    • 1999
  • The purpose of study were to research the characteristics of water variation adding humic acids to distilled water after ozonation. Upon investigating pH variation with contact time after providing distilled water+air, distilled water+ozone and distilled water-humic acid-air in reactor, it reduced after 60 minute in inletting air and in spite of short contact time did suddenly in inletting ozone. TOC and UV-254 continued to increase with contact time of ozone and humic acids. $NH^{4+}-N$ did slowly increase or decrease after constant contact time of ozone, because $NH^{4+}-N$ was converted into $No^3-N$ by ozone. T-N did suddenly increase after 90minute, but T-P did rarely fluctuate for total experiment. Total 30 species of organic matter were detected by GS/MSD, but 14 species did really tend to increase except for matter identified in distilled water and blank test. Humic acids generated $aliphatic{\cdot}aromatic$ hydrocarbon, alcohol and amine etc., and did various matters without inflow course of contaminants.

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Study for the Preparation of Deodorizing Fiber( III ) - Preparations of Deodorizing Fibers using $TiO_2$ and Effects of $TiO_2$ sol Concentration on the Deodorant Activity- (소취 섬유의 제조에 관한 연구(III) - 산화티탄(IV)을 이용한 소취 섬유의 제조 및 $TiO_2$ sol 용액의 농도가 소취율에 미치는 영향 -)

  • 박수민;오선화;강영수
    • Textile Coloration and Finishing
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    • v.14 no.3
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    • pp.11-18
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    • 2002
  • The preparations of deodorizing fibers using $\textrm{TiO}_2$ have been investigated. $\textrm{TiO}_2$ is known to be an excellent photocatalyst for the degradation of organic and inorganic contaminants in water. $\textrm{TiO}_2$ catalyst have been supported on the glass fiber by a dip-coating procedure. The resulting materials have been characterized by XRD and SEM. The immobilized catalysts were tested in the photocatalytic degradation of $\textrm{NH}_3$, $\textrm{CH}_3\textrm{SH}$ and $\textrm{CH}_3\textrm{CHO}$. The deodorant activity(D.A.) of these deodorizing fibers was measured by chromogenic gas detector tubes. The efficient deodorant activity results have been achieved through the increase of $\textrm{TiO}_2$ sol concentration.

산업단지내 독성유기화합물 및 중금속으로 오염된 토양의 정화복원기술 상용화 연구

  • 김수곤;손규동;박지연;최희철;양지원
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.31-34
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    • 2004
  • Feasibility of electrokinetic(EK)-Fenton process and Ozone chemical oxidation were investigated for tile removal of organic contaminants and heavy metals from the contaminated soil. In EK-Fenton process, accumulated electroosmotic flow(EOF) was 80 L for 26 days. Removal efficiency of TPH, As, and Ni were 61%, 36%, and 47%, respectively. The concentration of As was high near the anode due to the transport of anionic As toward the anode, while the concentration of Ni was high near the cathode by the movement of cationic Ni to the cathode. Field scale application of in-situ ozonation was carried out for removal of TPH in 3-D test cell (3 m$\times$2 m$\times$2 m). After 25 days of ozone injection, more than 80% of removal rate was observed through the test cell.

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Exploration of retention system for papermaking system closure (제지공정의 무방류화를 위한 보류시스템 탐색)

  • 이학래;함충현;이지영;황남선;이상길;김종민
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.33 no.2
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    • pp.1-7
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    • 2001
  • Use of high yield pulp and recycled fiber as raw materials and water system closure result in higher fines content and buildup of organic and inorganic contaminants in white water. These are detrimental for the effectiveness of chemical additives including retention aids. Thus it is imperative to employ a retention systems that maintains its efficiency in closed papermaking system for reducing fresh water consumption. The performance of four different microparticle retention systems including cationic polyacrylamide (C-PAM)/bentonite, highly charged cationic starch (HCS)/silica, C-PAM/micropolymer, cationic guar gum (CGG)/silica was evaluated and compared at three different levels of papermaking system closure. Buildup of detrimental substances in a closed white water system increased cationic demand and finally reduced the performance of retention systems. Cationic starch and guar gums maintained their effectiveness in retention in closed white water systems contaminated with anionic trashes because of their structural rigidity and hydrogen bonding ability. Particularly, cationic guar gums, due its stiffness of molecular structure, appeared perform better than catinonic starch.

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Application of Response Surface Methodology for optimize the Biostimulant ball and stabilize Heavy metals pollutants in contaminated coastal sediments

  • Song, Young-chae;Subha, Bakthacachallam;Woo, Jung Hui
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2015.07a
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    • pp.179-180
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    • 2015
  • The variety of organic and inorganic pollutants are introduced to coastal sediment and making highly contaminated due to rapid development of industralization and economic development. Numerous contaminants are release into marine sediment and it significantly affect marine aquatic environment. In the present study stated the optimize the biostimulant ball (BSB) in coastal sedimentand stabilse the heavy metals present in the sediment. The effective variables like BSB size, distance and month variables on Cu stabilization was determined by using Response surface methodology(RSM). The analysis of variance (ANOVA) and coefficient determination (R2) of Cu reduction 0.9610 and maximum stabilisation was obtained in 3cm ball size and 5.5cm distance and 4 month interval time. This result revealed that the BSB in effective for Cu reduction in coastal sediment.

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Improved Calibration for the Analysis of Emerging Contaminants in Wastewater Using Ultra High Performance Liquid Chromatography and Time-of-Flight Mass Spectrometry

  • Pellinen, Jukka;Lepisto, Riikka-Juulia;Savolainen, Santeri
    • Mass Spectrometry Letters
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    • v.9 no.3
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    • pp.77-80
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    • 2018
  • The focus of this paper is to present techniques to overcome certain difficulties in quantitative analysis with a time-of-flight mass spectrometer (TOF-MS). The method is based on conventional solid-phase extraction, followed by reversed-phase ultra high performance liquid chromatography of the extract, and mass spectrometric analysis. The target compounds included atenolol, atrazine, caffeine, carbamazepine, diclofenac, estrone, ibuprofen, naproxen, simazine, sucralose, sulfamethoxazole, and triclosan. The matrix effects caused by high concentrations of organic compounds in wastewater are especially significant in electrospray ionization mass spectroscopy. Internal-standard calibration with isotopically labeled standards corrects the results for many matrix effects, but some peculiarities were observed. The problems encountered in quantitation of carbamazepine and triclosan, due to nonlinear calibration were solved by changing the internal standard and using a narrower mass window. With simazine, the use of a quadratic calibration curve was the best solution.

A Study on the Cleaning Efficiency Valuation of Alternatives Cleaning Agent for Trichloroethane & Trichlorotrifluoroethane (Trichloroethane과 Trichlorotrifluoroethane의 대체세정제에 대한 세정력 평가에 관한 연구)

  • Lee, Seok-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.13 no.3
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    • pp.111-117
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    • 1996
  • Many alternatives to Trichlorothane & Trichlorotrifluoroethane mainly used as cleaning solvent for industrial parts are developed and commercialized because the solvent is scheduled to phaseout after 1996. Considering there are many kinds of parts and contaminants in all parts cleaning, It is essential to investigating the characteristics and performance of the alternatives prior to use. For the contaminant of a standard oil, waters, hydrocarbon and halogen parts which are the comercially available and promising alternatives were experimented at the same condition of Trichlorothane & Trichlorotrifluoroethane to check the cleaning performance. Overally, the removal efficiency of halogen solvent parts was better than that of hydrocarbon or waters parts for removing the standard oil used in this experiment.

PAH regualtion of CYP1 gene in MCF-7 & ZR-75-1 human breast cancer cells

  • Min, Kyung-Nan;Kim, Ja-Young;Kang, So-Hee;Seo, Mi-Jung;Sheen, Yhun-Yhong
    • Proceedings of the PSK Conference
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    • 2003.04a
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    • pp.182.2-183
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    • 2003
  • Recent industrial society has human widely exposed to PAHs that are comming from the incomplete combustion of organic material as widerspread environmetal contaminants. Biological activities of PAHs are not known although PAHs are considered as carcinogens. The mechanism of action of PAHs has been studied extensively, however it is not clear how PAHs turn on CYP1A1 in human breast cancer. (omitted)

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창원지역 지하수의 수질특성

  • 김무진;함세영;황한석;성익환
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.191-193
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    • 2001
  • This paper presents the result of groundwater analysis in Changwon area and the characteristics of the groundwater properties. Changwon city conducted groundwater analysis at 551 sites in 1996 and 1997. The water quality is suitable as groundwater use at 466 sites (84.6 %) and exceeds maximum contaminant levels (MCLs) at 85 sites (15.4 %). Major contaminants are total bacteria, coliform and nitrate-N. DNAPLs, e.g. TCE and PCE are detected in the areas of industrial complex and residence. The detection of TCE and PCE is due to organic solvents from manufacturing companies. They are also derived from laundries, Photographer's studios, septic tanks, etc. In addition, fifty groundwater samples were analyzed. Iron, manganese, zinc, copper, lead, aluminum and fluorine are detected in nearly all the groundwater samples. The groundwaters shown on the Piper diagram mostly belong to Ca-HCO$_3$ type.

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Aeration Factor Used To Design The Container Type of Biopile Systems for Small-Scale Petroleum-Contaminated Soil Projects

  • Jung, Hyun-Gyu
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.2
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    • pp.316-319
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    • 2011
  • Biopiles which offer the potential for cost-effective treatment of contaminated soils are above-ground, engineered systems that use oxygen to stimulate the growth and reproduction of aerobic bacteria for degradation of the petroleum constituents adsorbed to soil in excavated soils. This technology involves heaping contaminated soils into piles and stimulating aerobic microbial activity within the soils through the aeration and/or addition of minerals, nutrients, and moisture. Inside the biopile, microbially mediated reactions by blowing or extracting air through the pipes can enhance degradation of the organic contaminants. The influence of a aeration system on the biopile performance was investigated. Air pressure made to compare the efficiency of suction in the pipes showed that there were slightly significant difference between the two piles in the total amount of TPH biodegradation. The normalised degradation rate was, however, considerably higher in the aeration system than in the normal system without aeration, suggesting that the vertical venting method may have improved the efficiency of the biological reactions in the pile.