• Title/Summary/Keyword: Organic Carbon

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Characteristics of Carbonaceous Aerosols Measured at Gosan - Based on Analysis of Thermal Distribution by Carbon Analyzer and Organic Compounds by GCMS (제주도 고산지역 탄소 성분의 특성 분석 - 유기탄소의 열광학적 특성 및 유기성분 중심으로)

  • Bae, Min-Suk;Park, Seung-Shik;Kim, Young Joon
    • Journal of Korean Society for Atmospheric Environment
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    • v.29 no.6
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    • pp.722-733
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    • 2013
  • Ground-based measurements were conducted from August 25 to September 8 of 2011 for understanding characteristics of carbonaceous aerosols measured at Gosan. Chemical components and their sources were discussed by analysis of organic compounds with identification of primary and secondary products in particulate matter. Thus, organic carbon (OC) and elemental carbon (EC) based on the carbonaceous thermal distribution (CTD), which provides detailed carbon signature characteristics relative to analytical temperature, was used to improve the carbon fractionation of the analytical method. In addition, organic compounds by gas chromatography technique with the backward trajectories were discussed for characteristics of carbonaceous aerosols. Different air-masses were classified related to the OC thermal signatures and the organic molecular markers such as aromatic acids and PAHs. We concluded that the aging process was influenced by the long-range transport from East Sea area.

Spatial and Temporal Variations of δ13C and C/N in Suspended Particulate Organic Matter in the Gangneung Namdae Stream, Korea (강릉 남대천 부유입자유기물의 탄소안정동위원소 비와 C/N 비의 시·공간 변동)

  • Kwak, Jung Hyun;Park, Hyun Je
    • Journal of Environmental Science International
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    • v.29 no.5
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    • pp.531-539
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    • 2020
  • To understand the composition, quantity, and quality of Suspended Particulate Organic Matter (SPOM) in the Gangneung Namdae Stream, Korea, we examined spatiotemporal variations in water temperature, salinity, chlorophlly a (Chl a), Particulate Organic Carbon (POC) and nitrogen (PON), and carbon stable isotope (δ13C) of SPOM at six stations in June (pre-monsoon), July (monsoon), and September (post-monsoon) 2017. With increasing precipitation, the average POC and C/N values increased significantly in July than in June. In September, the values decreased with decreasing precipitation. The δ13C values showed irregular spatiotemporal fluctuations among the stations and periods, thereby suggesting a greater contribution of autochthonous organic matter to the pool of SPOM than that of allochthonous organic matter derived from upstream. In addition, the large and irregular changes in POC, C/N ratio, C:Chl a, and δ13C compared to that of PON were observed for all periods among the stations, indicating a serial discontinuity of the stream. Our results suggest that the Gangneung Namdae Stream is significantly influenced by the increase in freshwater discharge caused by heavy rainfalls during the summer monsoon and post-monsoon periods.

Soil organic carbon variation in relation to land use changes: the case of Birr watershed, upper Blue Nile River Basin, Ethiopia

  • Amanuel, Wondimagegn;Yimer, Fantaw;Karltun, Erik
    • Journal of Ecology and Environment
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    • v.42 no.3
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    • pp.128-138
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    • 2018
  • Background: This study investigated the variation of soil organic carbon in four land cover types: natural and mixed forest, cultivated land, Eucalyptus plantation and open bush land. The study was conducted in the Birr watershed of the upper Blue Nile ('Abbay') river basin. Methods: The data was subjected to a two-way of ANOVA analysis using the general linear model (GLM) procedures of SAS. Pairwise comparison method was also used to assess the mean difference of the land uses and depth levels depending on soil properties. Total of 148 soil samples were collected from two depth layers: 0-10 and 10-20 cm. Results: The results showed that overall mean soil organic carbon stock was higher under natural and mixed forest land use compared with other land use types and at all depths ($29.62{\pm}1.95Mg\;C\;ha^{-1}$), which was 36.14, 28.36, and 27.63% more than in cultivated land, open bush land, and Eucalyptus plantation, respectively. This could be due to greater inputs of vegetation and reduced decomposition of organic matter. On the other hand, the lowest soil organic carbon stock under cultivated land could be due to reduced inputs of organic matter and frequent tillage which encouraged oxidation of organic matter. Conclusions: Hence, carbon concentrations and stocks under natural and mixed forest and Eucalyptus plantation were higher than other land use types suggesting that two management strategies for improving soil conditions in the watershed: to maintain and preserve the forest in order to maintain carbon storage in the future and to recover abandoned crop land and degraded lands by establishing tree plantations to avoid overharvesting in natural forests.

Downward particle flux in the eastern Bransfield Strait, Antarctica

  • Kim, Dongseon;Kim, Dong-Yup;Jeonghee Shim;Kang, Young-Chul;Kim, Taerim
    • Journal of the korean society of oceanography
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    • v.38 no.1
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    • pp.1-10
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    • 2003
  • A time-series sediment trap was deployed at a depth of 1034 m in the eastern Bransfield Strait from December 25, 1998 to December 24, 1999. Particle fluxes showed large seasonal variation; about 99% of the annual total mass flux (49 g m/sup -2/) was collected during the austral summer and fall (January-March). Settling particles consisted primarily of biogenic silica, organic carbon, calcium carbonate, and lithogenic material. Biogenic silica and lithogenic material predominated settling particles, comprising 36% and 30% of the total mass flux, respectively, followed by organic carbon, 11% and calcium carbonate, merely 0.6%. The annual organic carbon flux was 5.4 g C m/sup -2/ at 1000 m in the eastern Bransfield Strait, which is greater than the central Strait flux. The relatively lower flux of organic carbon in the central Bransfield Strait may be caused by a stronger surface current in this region. Organic carbon flux estimates in the eastern Bransfield Strait are the highest in the Southern Ocean, perhaps because of the fast sinking of fecal pellets, which leads to less decomposition of organic material in the water column. Approximately 5.8% of the organic carbon produced on the surface in the eastern Bransfield Strait is exported down to 1000 m; this percentage exceeds the maximum EF/sub 1000/ values observed in the Atlantic and Southern Oceans. The eastern Bransfield Strait appears to be the most important site of organic carbon export to the deep sea in the Southern Ocean.

Removal Characteristics of Natural Organic Matters in Activated Carbon and Biofiltration Process (활성탄 공정과 생물여과 공정에서의 자연유기물질 제거특성)

  • Son, Hee-Jong;Choi, Keun-Joo;Kim, Sang-Goo
    • Journal of Korean Society of Environmental Engineers
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    • v.29 no.2
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    • pp.205-213
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    • 2007
  • We have studied NOM(natural organic matters) adsorption and biodegradation on 3 kinds of activated carbon and a anthracite. Coal based activated carbon showed the highest DOC(dissolved organic carbon) adsorption capability and roconut(samchully), wood (pica) in the order among the 3 kinds of activated carbon(F400). The biomass amount and activity also showed on coal, wood and coconut based activated carbon in the order. Over 15 minutes EBCT(empty bed contact time) needed to achieve 10 to 17% average removal efficiency and $18\sim24%$ maximum removal efficiency of NOM biodegradation in biofilter using anthracite. Hydrophobic and below 10,000 dalton NOM was much easier to adsorb into the activated carbon than hydrophilic NOM, THMFP(trihalomethane formation potential) and BDOC (biodegradable dissolved organic carbon)$_{slow}$ were much easier than HAA5FP(haloacetic acid 5 formation potential) and $BDOC_{rapid}$ to adsorb into the activated carbon. Hydrophilic and below 1,000 dalton NOM was much easily biodegraded and HAA5FP and $BDOC_{rapid}$ was easier than THMFT and $BDOC_{slow}$ to biodegrade in the biofilter.

Formation of Assimilable Organic Carbon from Algogenic Organic Matter

  • Kim, Ji-Hoon;Chung, Soon-Hyung;Lee, Jing-Yeon;Kim, In-Hwan;Lee, Tae-Ho;Kim, Young-Ju
    • Environmental Engineering Research
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    • v.15 no.1
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    • pp.9-14
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    • 2010
  • The objective of this study was to assess the variation in the concentration of assimilable organic carbon (AOC) in a drinking water resource, and investigate the characteristics of AOC derived from algae. The seasonal change in AOC at the Kamafusa dam corresponded to changes in the algal cell number. In order to understand the relationship between AOC and algae in a water resource and water purification plant, two kinds of laboratory experiment were performed. The algal culture experiment showed that extracellular organic matter (EOM) that was released during the growth of Phormidium tenue with M-11 medium led to significant increases in the AOC concentration, but no significant variation in the AOC concentration was observed with CT medium containing a high dissolved organic carbon concentration. The chlorination experiment showed that the AOC included in EOM was not easily removed by chlorination, although the AOC included in intercellular organic matter released from the algal cells by chlorination was removed under conditions where residual chlorine was detected.

The Removal Characteristics of Organic Matter in Drinking Water Source by Coagulation and Ultrafiltration Process (응집 및 한외여과 공정에 의한 상수원수의 유기물질 제거 특성)

  • Kim, Hyun-Sik;Lim, Ji-Young;Kim, Jin-Han
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.2
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    • pp.5-10
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    • 2018
  • This study was evaluated the characteristics of organic materials in the water source and the removal characteristics of organic materials by ultrafiltration including mixing and coagulation process. As a results of the study, it was found that the total organic carbon in the water source was mostly caused by the dissolved organic materials. As the specific ultraviolet absorbance value of the raw water was low, we found the soluble organic material has a high hydrophilic and low molecular material composition ratio. As a result of ultrafiltration experiment including mixing and coagulation process, the average removal rate of total organic carbon, dissolved organic carbon and ultraviolet absorbance at 254 were 37.9%, 30.3%, and 28.2%, respectively.

Evaluation of the Possibility of Developing Organic Matter Indicators in Coastal Environments: Utilization of Dissolved Organic Carbon and Fluorescent Dissolved Organic Matter (연안환경에서 유기물 지표 개발을 위한 가능성 평가: 용존유기탄소와 형광용존유기물질 활용)

  • Lee, Min-Young;Yang, Kyungsun;Kim, Sunchan;Kim, Tae-Hoon
    • Ocean and Polar Research
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    • v.43 no.2
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    • pp.65-72
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    • 2021
  • In order to evaluate the dissolved organic carbon (DOC) and fluorescent dissolved organic matter (FDOM), as indicators of organic matter in the coastal environments, we measured the concentrations of DOC, FDOM, and chemical oxygen demand (COD) in saline groundwater (Woljeong, Pyoseon, and Hwasun beaches) and coastal seawater (Haengwon, Gwideok, Pyoseon, and Yeongnak) in Jeju, Korea. The highest concentrations of DOC and COD in groundwater were found in Woljeong and Pyoseon, and those in coastal water were observed in Haengwon and Pyoseon, indicating that the higher concentrations of DOC and COD seem to be associated with saline groundwater-driven dissolved organic matter (DOM) and/or biogeochemical processes. According to origin and optical properties of DOM using FDOM as a tracer, proportion of humic-like FDOM, more refractory DOM, was relatively greater in the groundwater than in the coastal water. With regard to this result, there was no relationship between DOC and COD in groundwater, while DOC showed a good positive correlation (r2 = 0.66) with COD in coastal water. This result indicates that COD as an indicator of assessment of DOM has a limitation in which it is difficult to quantify refractory DOM. Although DOC is a potential alternative to COD in the coastal environments, particulate organic carbon cannot be negligible due to relatively higher concentration compared to the open ocean. Therefore, the use of total organic carbon (TOC) as a replacement of COD in the coastal ocean is important, and the evaluation criterion of the TOC is necessary in order to evaluate of organic matter indicator in the various coastal environments.

Contribution of Phytoplankton and Zooplankton to Total Organic Carbon (TOC) in the Reservoir-river-Seonakdong River, Busan (서낙동강에서 동·식물플랑크톤의 총유기탄소 기여율 변동 분석)

  • Lee, You-Jung
    • Journal of Environmental Science International
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    • v.29 no.7
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    • pp.691-702
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    • 2020
  • Carbon biomass of plankton community, Total Organic Carbon (TOC) and Chlorophyll a (chl.a) concentration were examined in the SeoNakdong river from January to December in 2014, to assess composition of phyto- and zoo-plankton variation, to certify the correlation between chl.a and TOC and to determine the level of contribution of plankton carbon content to TOC in the reservoir-river ecosystem. The correlation level between TOC and chl.a was low in the year 2014 but exceptionally was highly correlated only during the period with cyanobacterial bloom. The high level of contribution of plankton carbon content to TOC was attributed to cyanobacterial carbon biomass from May to November and to Cladocera carbon biomass from March to May, November and December despite of its low abundance. These results suggest that there were inter-relationships between phytoplankton, zooplankton and TOC and also subtle consistency of their properties through the year. These patterns should be discussed in relation to the physiochemical and biological characteristics of the environment, as well as to allochthonous organic matters from non-point pollution sources.

Distribution Characteristics of Organic Carbon and Nutrient in Effluent of Land-based Aquaculture Farms around Wando in Korea (하계 완도 주변 육상 양식장 배출수 중 유기탄소 및 영양염의 분포 특성)

  • GyuRi Kim;Yujeong Choi;Tae–Hoon Kim
    • Ocean and Polar Research
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    • v.45 no.3
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    • pp.103-111
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    • 2023
  • To evaluate the impact of effluents from land-based fish farms on the coastal ocean of Wando, Korea, we analyzed inorganic nutrients, particulate organic carbon (POC), dissolved organic carbon (DOC), and colored dissolved organic matter (CDOM) in the effluent and influent of land-based fish farms during the summer (July) of 2021. The average concentrations of nutrients (Dissolved inorganic nitrogen, phosphorus, and silicate; DIN, DIP, and DSi, respectively) in the effluents of this study area were 17±3.7 μM, 1.4±0.7 μM, and 14±1.6 μM, respectively. The average concentrations of POC and DOC were 37±22 μM and 81±13 μM, respectively, with POC accounting for about 30% for total organic carbon in effluents. The Reduced Dissolved Inorganic Nitrogen/Total Dissolved Inorganic Nitrogen ratio (0.7), potential short-period index, indicates that the discharge of nutrients excreted by the fish and unconsumed feed into coastal water results in such nutrients being deposited and accumulated in the sediment. Subsequently, this continuous accumulation triggers the release of ammonium ions during organic matter decomposition, and the ammonium-enriched waters that encroach on fish farms as influent seem to be due to the diffusion of high concentrations of ammonium from bottom sediment. Furthermore, we used fluorescence indices to examine the characteristics of organic matter sources, obtaining mean values of 1.54±0.19, 1.06±0.06, and 1.56±0.06 for the humification index, biological index, and fluorescence index, respectively, in the effluent. These results indicate that the organic matters had an autochthonous origin that resulted from microbial decomposition, and such organic matters were rapidly generated and removed by biological activity, likely supplied from the sediment. Our results suggest that the effluent from land-based fish farms could be a potential source of deoxygenation occurrence in coastal areas.