• Title/Summary/Keyword: Olivine

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Mineralogical and Gechemical Studies of Titaniferous Iron Ores and Ultramafic to Mafic Rocks from the Boreundo Iron Ore Deposits, South Korea (볼음도 자철광상의 초염기성-염기성암과 티타늄자철광석의 광물 및 지구화학적 연구)

  • 김규한
    • Economic and Environmental Geology
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    • v.33 no.1
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    • pp.1-18
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    • 2000
  • Lens shaped and stratiform titanomagnetite orebodies in the Boreumdo iron mine are closely associated with amphibolite which intruded into Precambrian metasediments. Mineralogical and petrochemical analyses of amphilbolite and titanomagnetite ores were carried out in order to interpret the origin of amphilbolite and the genesis of titanomagnetite ore deposits. Amphibolites belong to orthoamphilbolite interms of Niggli value and mineralogy, and are characterized by the occurrence of relict olivine. The amphilbolites responsible for titanomagnetite mineralization have extremely high content of $TiO_2$, ranging from 2.12 to 4.59 wt.% with the average value of 3.43 wt.%. Amphibole minerals in amphibolites are consist mainly of calcic amphiboles such as hornblende, ferroan pargasitic hornblende and tremolite. Most plagioclases belong to andesine ($An_{30-50}$\ulcorner). The metamorphic temperature and geobarometric pressure which are calculated by the calcic amphibole-plagioclase geothermometer and calcic amphilbole geobarometer are estimated to be 537$^{\circ}C$~579$^{\circ}C$(avg. 555$^{\circ}C$) and 2.9~6.6 kbar (avg. 4.5 kbars), respectively. It shows a typical amphibolite facies. Based on the mineral chemistry and petrochemisty of amphibolites and iron ores which are composed mainly of titanomagnetite and ilmenite in the Boreumdo iron mine, the titaniferous oxide melts could be immiscibly separatd from the titaniferous ultrabasic magma. The genesis of the Boreumdo titanomagnetite ore deposits are analogous to the Soyeonpyeongdo and Yonchon iron ore deposits in terms of their mineralogy, mineral chemistry and geologic setting.

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A Study on Serpentinization of Serpentinites from the Ulsan Iron Mine (울산철광산 지역의 사문암의 사문석화 작용에 관한 연구)

  • Kim, Kyo Han;Park, Jae Kyong;Yang, Jong Mann;Satake, Hiroshi
    • Economic and Environmental Geology
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    • v.26 no.3
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    • pp.267-278
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    • 1993
  • Serpentinite rocks which are composed mainly of olivine, serpentine and clinopyroxene, cropped out in the anorogenic Kyongsang sedimentary basin of South Korea. The serpentinites contain high content of MgO (36.87~41.99%) and 47~67 ppm Co, 1185~2042 ppm Ni and 979~3582 ppm Cr, which are quite similar to those of ultrabasic rocks such as peridotite and dunite. Isotopic compositions of serpentinites range from -95.5 to -105.7‰ in ${\delta}D$ and +1.7 to 7.1‰ in ${\delta}^{18}O$ corresponding to the continental antigorite type. A wide variation of oxygen isotopic values and $H_2O^+$ content of serpentinites reflect the different water/rock ratios during serpentinization processes. Formation temperature of serpentine minerals are estimated to be unusually high temperature of $488{\sim}646^{\circ}C$ by serpentine-magnetite isotopic fractionation, which belong to continental antigorite type. Calculated ${\delta}^{18}O$ value of serpentinized fluid during serpentinization is suggested that the hydrothermal fluid responsible for serpentinization be originated from the magmatic fluid with a minor influx of paleo-meteoric water in this area.

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Occurrence types and mineralogical characteristics of asbestos for the Kwangcheon area, Chungnam (충남 광천지역 석면의 산출 유형 및 광물학적 특징)

  • Song, Suckhwan;Hwang, Jung Hwan;Hwang, Byum Goo;Kim, Hyunwook
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.18 no.4
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    • pp.271-281
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    • 2008
  • This study is to characterize the occurrence types and mineralogical characteristics of asbestos for the Kwangcheon areas, Chungnam. The mine areas had been exploited as asbestos mines for several decades since 1930. Host rocks of the asbestos are serpentinites and altered rocks of the ultramafic rocks. Representative samples of the host rocks and minerals were sampled and were examined with microscopes. To confirm for the existences and compositions for the asbestos, the rock samples were analysed with EPMA, XRD and EDS. Chrysotile, tremolite and actinolite were found as asbestos and non-asbestos forms in these areas. Chrysotiles, as non-asbestos forms, occur in the host rocks with mesh and hourglass textures. They, as asbestos forms, are mainly found as the veins. The tremolite and actinolite, as asbestos types, occur as alteration products of the olivine and pyroxene within the host rocks. They, as asbestos types, are also found following the cracks and fractures. Overall results suggest that three types of the asbestos are found in the Kwangcheon and Kaewol mine areas. Based on the occurrence types for the asbestos, additional studies are required for the asbestos in the top soil and air.

Lithium-Ion Batteries for Plug-In Hybrid Electric Vehicle (플러그인 하이브리드자동차용 리튬이온 이차전지)

  • Cho, Mann;Son, Young-Mok;Nah, Do-Baek;Kil, Sang-Cheol;Kim, Sang-Woo
    • Journal of Energy Engineering
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    • v.19 no.2
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    • pp.81-91
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    • 2010
  • Plug-in hybrid electric vehicles(PHEVs) are gaining attention over the world due to their abilities to reduce $CO_2$ emission and gasoline/diesel consumption by using electricity from the grid. Lithium ion battery is one of the most suitable candidates as energy storage device for PHEVs applications up to 2030. This review focuses on the present status of lithium ion battery technology, then on comparison of the performance characteristics of the promising cathode materials.

Investigation of Reflectance Distribution and Trend for the Double Ray Located in the Northwest of Tycho Crater

  • Yi, Eung Seok;Kim, Kyeong Ja;Choi, Yi Re;Kim, Yong Ha;Lee, Sung Soon;Lee, Seung Ryeol
    • Journal of Astronomy and Space Sciences
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    • v.32 no.2
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    • pp.161-166
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    • 2015
  • Analysis of lunar samples returned by the US Apollo missions revealed that the lunar highlands consist of anorthosite, plagioclase, pyroxene, and olivine; also, the lunar maria are composed of materials such as basalt and ilmenite. More recently, the remote sensing approach has enabled reduction of the time required to investigate the entire lunar surface, compared to the approach of returning samples. Moreover, remote sensing has also made it possible to determine the existence of specific minerals and to examine wide areas. In this paper, an investigation was performed on the reflectance distribution and its trend. The results were applied to the example of the double ray stretched in parallel lines from the Tycho crater to the third-quadrant of Mare Nubium. Basic research and background information for the investigation of lunar surface characteristics is also presented. For this research, resources aboard the SELenological and ENgineering Explorer (SELENE), a Japanese lunar probe, were used. These included the Multiband Imager (MI) in the Lunar Imager/Spectrometer (LISM). The data of these instruments were edited through the toolkit, an image editing and analysis tool, Exelis Visual Information Solution (ENVI).

Development of LiFePO4/FePO4 Electrode for Electro-Osmotic Pump using Li+ Migration

  • Baek, Jaewook;Kim, Kyeonghyeon;Shin, Woonsup
    • Journal of Electrochemical Science and Technology
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    • v.9 no.2
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    • pp.85-92
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    • 2018
  • Olivine structure of $LiFePO_4$ (LFP) is one of the most commonly used materials in aqueous rechargeable lithium batteries (ARLBs), and can store and release charge through the insertion/de-insertion of $Li^+$ between LFP and FP. We have fabricated LFP and LFP/FP electrodes on titanium paper and studied their electrochemical properties in 2 M $Li_2SO_4$. The LFP/FP electrode was determined to be a suitable electrode for electo-ostmotic pump (EOP) in terms of efficiency in water and 0.5 mM $Li_2SO_4$ solution. Experiments to determine the effect of cations and anions on the performance of EOP using LFP/FP electrode have shown that $Li^+$ is the best cation and that the anion does not significantly affect the performance of the EOP. As the concentration of $Li_2SO_4$ solution was increased, the current increased. The flow rate peaked at $4.8{\mu}L/30s$ in 1.0 mM $Li_2SO_4$ solution and then decreased. When the EOP was tested continuously in 1.0 mM $Li_2SO_4$ solution, the EOP transported approximately 35 mL of fluid while maintaining a stable flow rate and current for 144 h.

Genesis of Talc Ore Deposits in the Yesan Area of Chungnam, Korea (충남(忠南) 예산지구(禮山地區) 활석광상(滑石鑛床)의 성인(成因)에 관(關)한 연구(硏究))

  • Woo, Young-Kyun;Choi, Suck-Won;Park, Ki-Hwa
    • Economic and Environmental Geology
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    • v.24 no.4
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    • pp.363-378
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    • 1991
  • Field and microscopic evidence, XRD,EPMA and chemical data suggest that parent rock of talc ore deposits of Yesan district was originated from ultramafic igneous rock. Parent rock can be divided into serpentinized dunite, serpentinized peridotite, metagabbro, amphibolite and hornblende schist. The ore deposits are highly sheared, and show many evidences of hydrothermal alteration and metamorphism at the greenschist and albite-epidote amphibolite facies. The process of steatitization is variable depending upon the composition, and the degree of alteration and metamorphism of the parent rocks. Steatitization can be divided into two processes with or without serpentinization. The parent rocks with serpentinization are serpentinized dunite, serpentinized peridotite and metagabbro, showing the following alteration process; olivine ${\rightarrow}$ serpentine${\rightarrow}$ talc. The rocks without serpentinization are amphibolite and hornblende schist showing the following sequence; hornblende${\rightarrow}$ chlorite${\rightarrow}$ talc. Formation of talc deposits is summarized as following six stages; I) Intrusion of ultramafic rocks, 2) autometamorphism, 3) metamorphism at greenschist and albite-epidote-amphibolite facies, 4) brittle deformation, 5) hydrothermal alteration, 6) purification of low-grade talc by late dyke intrusion.

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Equilibrium Sorption of Heavy Metals (Pb, Cu. Zn, Cd) onto Scoria

  • Kwon, Jang-Soon;Yun, Seong-Taek
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.302-305
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    • 2002
  • Scoria is a bomb-sized, generally vesicular pyroclast that is red or black in color and light in weight. In this study, scoria from Cheju was examined for the use as a sorbent. It is composed of plagioclase, olivine, hornblende, pyroxene, and glass, with an average composition of 49.84% SiO$_2$, 14.07% A1$_2$O$_3$, End 9.14% Fe$_2$O$_3$. Studies on kinetic isotherm sorption of Zn(II) onto scoria under various parameters such as initial zinc concentration, particle size, and adsorbent/adsorbate ratio were carried out using an agitated batch. The results suggest that the smaller scoria size and the larger adsorbent/adsorbate ratio produce the higher degree of Zn(II) removal. More effective removal also appears at lower initial Zn concentration. The sorption behavior of Zn(II) onto scoria seems to be mainly controlled by cation exchange. Studies on equilibrium isotherm sorption of other heavy metals (Pb, Cu, Cd) onto scoria were also conducted and compared with those onto powdered activated carbon (PAC) and non-organic matter scoria (NOS), The results suggest that the Cheju scoria has the slightly higher sorption capability than PAC and NOS, and the order of the effective sorption onto scoria and PAC is Pb > Cu > Zn > Cd. The monometal sorption onto scoria is more stronger than the competitive sorption.

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Mg-skarn Minerals from Magnetite Deposits of the Janggun Mine, Korea (장군광산(將軍鑛山)의 자철석광상(磁鐵石鑛床)에서 산출(産出)되는 Mg-스카른광물(鑛物))

  • Lee, Chan Hee;Song, Suckhwan;Lee, Hyun Koo
    • Economic and Environmental Geology
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    • v.29 no.1
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    • pp.11-21
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    • 1996
  • The first Mg-skarn minerals are found from magnetite ore deposits of the Janggun mine, Korea. The skarn minerals are composed of mostly chondrodite, olivine, chlorite, serpentine, phlogophite, talc, apatite, magnesite, dolomite, siderite and trace amount of clinopyroxene, amphibole, garnet, wollastonite associated with magnetite, pyrrhotite and pyrite. The skarn zone is developed in the magnetite deposits at the contact of the Mg-rich Janggun Limestone Formation and the Chunyang granite. The chondrodites are columnar and radial shapes and some of them show twins. The chemical compositions of twinning-type chondrodites have high FeO (4.63 to 5.6 wt%), MnO (0.26 to 0.46 wt%) and low MgO (55.02 to 56.18 wt%) relative to the radial-type chondrodites. Twinning in chondrodite has been formed in close relation to substitution between Mg and Fe + Mn in humite solid solution. Temperature, $-logfo_2$ and $X_{CO2}$ during the skarn stage of magnetite deposits from the Janggun mine range from 395 to $430^{\circ}C$, from 30.5 to 31.2 atm and from 0.06 to 0.09, respectively.

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Petrology of the basalt in the Udo monogenetic volcano, Jeju Island (제주도 우도 단성화산의 현무암에 대한 암석학적 연구)

  • Koh Jeong Seon;Yun Sung-Hyo;Hyeon Gyeong Bong;Lee Moon Won;Gil Young-Woo
    • The Journal of the Petrological Society of Korea
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    • v.14 no.1
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    • pp.45-60
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    • 2005
  • This study was intended to elucidate the petrography and geochemical characteristics of the Someori Basalt in the Udo monogenetic volcano, eastern Jeju Island. The Someori basalts consist of plagioclase, olivine, orthopyroxene, clinopyroxene and ilmenite. The Someori basalts are plotted into subalkali rock series on the TAS diagram, and belong to tholeiitic basalts in the diagram of alkali index against to Al₂O₃ contents. The basalts belong to tholeiitic rock series, having normative quartz (less than 3.9%) + hypersthene + diopside.