• Title/Summary/Keyword: Oil industry

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Source Identification of Ambient PM-10 Using the PMF Model (PMF 모델을 이용한 대기 중 PM-10 오염원의 확인)

  • 황인조;김동술
    • Journal of Korean Society for Atmospheric Environment
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    • v.19 no.6
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    • pp.701-717
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    • 2003
  • The objective of this study was to extensively estimate the air quality trends of the study area by surveying con-centration trends in months or seasons, after analyzing the mass concentration of PM-10 samples and the inorganic lements, ion, and total carbon in PM-10. Also, the study introduced to apply the PMF (Positive Matrix Factoriza-tion) model that is useful when absence of the source profile. Thus the model was thought to be suitable in Korea that often has few information about pollution sources. After obtaining results from the PMF modeling, the existing sources at the study area were qualitatively identified The PM-10 particles collected on quartz fiber filters by a PM-10 high-vol air sampler for 3 years (Mar. 1999∼Dec.2001) in Kyung Hee University. The 25 chemical species (Al, Mn, Ti, V, Cr, Fe, Ni, Cu, Zn, As, Se, Cd, Ba, Ce, Pb, Si, N $a^{#}$, N $H_4$$^{+}$, $K^{+}$, $Mg^{2+}$, $Ca^{2+}$, C $l^{[-10]}$ , N $O_3$$^{[-10]}$ , S $O_4$$^{2-}$, TC) were analyzed by ICP-AES, IC, and EA after executing proper pre - treatments of each sample filter. The PMF model was intensively applied to estimate the quantitative contribution of air pollution sources based on the chemical information (128 samples and 25 chemical species). Through a case study of the PMF modeling for the PM-10 aerosols. the total of 11 factors were determined. The multiple linear regression analysis between the observed PM-10 mass concentration and the estimated G matrix had been performed following the FPEAK test. Finally the regression analysis provided source profiles (scaled F matrix). So, 11 sources were qualitatively identified, such as secondary aerosol related source, soil related source, waste incineration source, field burning source, fossil fuel combustion source, industry related source, motor vehicle source, oil/coal combustion source, non-ferrous metal source, and aged sea- salt source, respectively.ively.y.

Logistics Network Design of Eco-Friendly industrial estate -Focused on GILC in Busan- (친환경 산업단지의 물류네트워크 설계 - 부산 국제산업물류도시를 중심으로-)

  • Kim, Woong-Sub;Shin, Jae-Young
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2012.06a
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    • pp.273-274
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    • 2012
  • Companies are facing challenges to have high competitiveness because of continuous oil price rising and CO2 emissions regulations. Thus, companies are trying hard to construct effective logistics and operation system to achieve high customer service quality and saving cost. Also the ec-friendly idustrial complex is needed. Busan is in process to construct GILC(Global Industry Logistics City) in west Busan province to achieve high competitiveness and support lack of industrial complex. To construct this kind of logistics industrial complex, it needs logistics system through proper policy and freight transportation co-operation. Especially, efficient management through logistics hierarchy construction in industrial complex is very important for low cost and eco-friendly point of view. Therefore, this paper aims to analyze logistics system and suggest operation model to present logistics complex construction base data.

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International industrial logistics complex logistics network design (국제산업물류단지 물류네트워크 설계)

  • Shin, Jae Young;Kim, Woong-Sub
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2014.06a
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    • pp.221-222
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    • 2014
  • Companies are facing challenges to have high competitiveness because of continuous oil price rising and CO2 emissions regulations. Thus, companies are trying hard to construct effective logistics and operation system to achieve high customer service quality and saving cost. Also the ec-friendly idustrial complex is needed. Busan is in process to construct GILC(Global Industry Logistics City) in west Busan province to achieve high competitiveness and support lack of industrial complex. To construct this kind of logistics industrial complex, it needs logistics system through proper policy and freight transportation co-operation. Especially, efficient management through logistics hierarchy construction in industrial complex is very important for low cost and eco-friendly point of view. Therefore, this paper aims to analyze logistics system and suggest operation model to present logistics complex construction base data.

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Expression and Characterization of a New Esterase Cloned Directly from Agrobacterium tumefaciens Genome

  • PARK HYO-JUNG;KIM YOUNG-JUN;KIM HYUNG-KWOUN
    • Journal of Microbiology and Biotechnology
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    • v.16 no.1
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    • pp.145-148
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    • 2006
  • A new functional lipolytic enzyme (AT4) has recently been found from Agrobacterium tumefaciens C58 Cereon using a genome-wide approach. The enzyme has some sequence similarity to E. coli acetyl hydrolase, Emericella nidulans lipase, Moraxella sp. lipase, Acinetobacter lwoffii esterase, and Streptomyces hygroscopicus acetyl hydrolase. However, the sequence similarities are very low (less than $25\%$), suggesting that it is a new lipase/esterase enzyme. ill the present study, intact cell of the A. tumefaciens strain was shown to have lipolytic activity on a tributyrin-LB plate. The AT4 gene was then expressed at a high level in E. coli BL21 (DE3) cells and the enzyme was purified simply by Ni-NTA column chromatography. The purified enzyme showed hydrolytic activity toward p-nitrophenyl caproate, but not toward olive oil, suggesting that the AT4 enzyme was a typical esterase rather than lipase. AT4 esterase had a maximum hydrolytic activity at $45^{\circ}C$ and pH 8.0, when p-nitrophenyl caproate was used as a substrate. It was relatively stable up to $40^{\circ}C$ and at pH 5.0-9.0. Calcium ion and EDT A did not affect the activity and thermal stability of the enzyme. As for substrate specificity, AT4 enzyme could rapidly hydrolyze acetyl and butyl groups from p-nitrophenyl esters and 1-naphthyl esters. In addition, it also released acetyl residues from acetylated glucose and xylose substrates. Therefore, this new esterase enzyme might be used as a biocatalyst in acetylation and deacetylation reactions performed in the fine chemical industry.

Effect of Accession to OPRC-HNS Protocol on Korean Industry (OPRC-HNS 의정서 가입이 국내 산업계에 미치는 영향)

  • Choi, Jong-Wook;Lee, Seung-Hwan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.13 no.4
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    • pp.37-42
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    • 2007
  • Since the OPRC-HNS Protocol entered into forced in the June of 2007, the potential effects on industrial circles are encouraged to be analyzed according to the obligatory regulations listed in the Protocols. This study was conducted on the quantitative analysis of the possible effect on the industrial circles if Korea accedes to OPRC-HNS Protocol. In spite of any burdens caused by keeping "accident emergency program memorandum" and performing "education and any training program for the crews", potential decrease of insurance fee is in possibility provided it follows. In addition, the oil refinery and petrochemical industries may also have burdens for potential costs for acquiring any materials including equipments and fees for education and training related to HNS. However, minimizing any costs by swift response against accidents would be big advantage that comes with paying of small amounts of expense by international convention related to HNS.

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Static impedance functions for monopiles supporting offshore wind turbines in nonhomogeneous soils-emphasis on soil/monopile interface characteristics

  • Abed, Younes;Bouzid, Djillali Amar;Bhattacharya, Subhamoy;Aissa, Mohammed H.
    • Earthquakes and Structures
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    • v.10 no.5
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    • pp.1143-1179
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    • 2016
  • Offshore wind turbines are considered as a fundamental part to develop substantial, alternative energy sources. In this highly flexible structures, monopiles are usually used as support foundations. Since the monopiles are large diameter (3.5 to 7 m) deep foundations, they result in extremely stiff short monopiles where the slenderness (length to diameter) may range between 5 and 10. Consequently, their elastic deformation patterns under lateral loading differ from those of small diameter monopiles usually employed for supporting structures in offshore oil and gas industry. For this reason, design recommendations (API and DNV) are not appropriate for designing foundations for offshore wind turbine structures as they have been established on the basis of full-scale load tests on long, slender and flexible piles. Furthermore, as these facilities are very sensitive to rotations and dynamic changes in the soil-pile system, the accurate prediction of monopile head displacement and rotation constitutes a design criterion of paramount importance. In this paper, the Fourier Series Aided Finite Element Method (FSAFEM) is employed for the determination of static impedance functions of monopiles for OWT subjected to horizontal force and/or to an overturning moment, where a non-homogeneous soil profile has been considered. On the basis of an extensive parametric study, and in order to address the problem of head stiffness of short monopiles, approximate analytical formulae are obtained for lateral stiffness $K_L$, rotational stiffness $K_R$ and cross coupling stiffness $K_{LR}$ for both rough and smooth interfaces. Theses expressions which depend only on the values of the monopile slenderness $L/D_p$ rather than the relative soil/monopile rigidity $E_p/E_s$ usually found in the offshore platforms designing codes (DNV code for example) have been incorporated in the expressions of the OWT natural frequency of four wind farm sites. Excellent agreement has been found between the computed and the measured natural frequencies.

Thermo-responsive antifouling study of commercial PolyCera® membranes for POME treatment

  • Haan, Teow Yeit;Chean, Loh Wei;Mohammad, Abdul Wahab
    • Membrane and Water Treatment
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    • v.11 no.2
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    • pp.97-109
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    • 2020
  • Membrane fouling is the main drawback of membrane technology. Frequent membrane cleaning and membrane replacement are, therefore, required to reduce membrane fouling that causes permeate flux reduction, lower rejection, or higher operating pressure. Studies have proved that the alteration of membrane properties is the key controlling factor in lessening membrane fouling. Among stimuli-responsive membranes, thermo-responsive membrane is the most popular, with a drastic phase transition and swelling-shrinking behavior caused by the temperature change. In this study, the thermo-responsive ability of two commercial membranes, PolyCera® Titan membrane and PolyCera® Hydro membrane, at different temperatures was studied on the antifouling function of the membrane in palm oil mill effluent (POME) treatment. The evaluation of the membrane's thermo-responsive ability was done through three cycles of adsorption (fouling) and desorption (defouling) processes in a membrane filtration process. The experimental result depicted that PolyCera® Hydro membrane had a higher membrane permeability of 67.869 L/㎡.h.bar than PolyCera® Titan membrane at 46.011 L/㎡.h.bar. However, the high membrane permeability of PolyCera® Hydro membrane was compensated with low removal efficiency. PolyCera® Titan membrane with a smaller mean pore size had better rejection performance than PolyCera® Hydro membrane for all tested parameters. On the other hand, PolyCera® Titan membrane had a better hydrodynamic cleaning efficiency than PolyCera® Hydro membrane regardless of the hydrodynamic cleaning temperature. The best hydrodynamic cleaning performed by PolyCera® Titan membrane was at 35℃ with the flux recovery ratio (FRR) of 99.17 ± 1.43%. The excellent thermo-responsive properties of the PolyCera® Titan membrane could eventually reduce the frequency of membrane replacement and lessen the use of chemicals for membrane cleaning. This outstanding exploration helps to provide a solution to the chemical industry and membrane technology bottleneck, which is the membrane fouling, thus reducing the operating cost incurred by the membrane fouling.

Effect of Rare Earth Metal on Catalyst for Hydrogenation Reaction (희토류가 수소화 촉매에 미치는 영향)

  • An, Jae Young;Jeon, Jong-Ki
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.1
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    • pp.151-156
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    • 2018
  • As industry and medicine developed, many people became interested in the quality of life. As the concern for health became higher, vegetarian or vegetable oils became more popular than meat. With the development of processes primarily using nickel catalysts today, the shelf life of vegetable oils has increased and mobility has become more convenient. Currently nickel catalysts for the curing of oil are dominated by foreign companies in the world market. On the other hand, the mass production technology of domestic nickel catalyst is backward, and the entire amount is imported from foreign countries. Therefore, there is a need for active research and development of a catalyst that can be commercialized in korea. In this study, nickel as a main active catalyst was used as a base for hydrogen curing reaction, and the effect of rare earth on catalytic activity was investigated. A certain amount of rare earths could induce the dispersion of nickel to increase efficiency and use as co-catalyst.

Design of Naphtha Splitter Unit with Petlyuk Distillation Column Using Aspen HYSYS Simulation (Aspen HYSYS를 이용한 나프타 분리공정의 Petlyuk Distillation Column 설계)

  • Lee, Ju-Yeong
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.2
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    • pp.21-27
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    • 2018
  • FRN (Full range Naphtha) is distilled from crude oil in a Naphtha Splitter Unit and is separated into the Light Straight Naphtha, Heavy Naphtha, and kerosene according to the boiling point in sequence. This separation is conducted using a series of binary-like columns. In this separation method, the energy consumed in the reboiler is used to separate the heaviest components and most of this energy is discarded as vapor condensation in the overhead cooler. In this study, the first two columns of the separation process are replaced with the Petlyuk column. A structural design was exercised by a stage to stage computation with an ideal tray efficiency in the equilibrium condition. Compared to the performance of a conventional system of 3-column model, the design outcome indicates that the procedure is simple and efficient because the composition of the liquid component in the column tray was designed to be similar to the equilibrium distillation curve. An analysis of the performance of the new process indicated an energy saving of 12.3% under same total number of trays and with a saving of the initial investment cost.

A Systems Engineering Approach to the Design of Steam Reforming H2 Generation System based on Natural Gas: Case of Iron and Steel making Plant (천연가스 기반 스팀 리포밍 수소 생산 시스템 설계를 위한 시스템엔지니어링 접근방법: 철강생산플랜트를 중심으로)

  • Kim, Joon-Young;Hong, Dae Geun;Suh, Suk-Hwan;Sur, Hwal Won
    • Journal of the Korean Society of Systems Engineering
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    • v.11 no.1
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    • pp.81-93
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    • 2015
  • Steam Reforming H2 Generation (SRH2G) System is a chemical process to produce hydrogen through steam reforming of hydrocarbon. Largely speaking, there are two types of materials for the SRH2G: 1) Oil and coal, and 2)Natural Gas such as shale gas. From the perspective of cost, quality (purity), and environmental burden (pollution), the latter is much more desirable than the former. For this reason, research on SRH2G using natural gas is actively carried out, and implemented and operated in the various industry. In this paper, we develop a natural gas based SRH2G system via systems engineering approach. Specifically, we first derived stakeholder requirements, followed by systems requirements and finally system architecture via a tailored SE process for plant (called Plant Systems Engineering (PSE) process) based on ISO/IEC 15288. The developed method was applied to iron and steel plant as a case study. Through the case study, by the SE approach, we were convinced that a successful system satisfying stakeholders' requirements within the given constraints can be developed, verified and validated.