• Title/Summary/Keyword: O/F

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Electrical and optical properties of Al and F doped ZnO transparent conducting film by sol-gel method (Sol-gel법에 의한 Al과 F가 첨가된 ZnO 투명전도막의 전기 및 광학적 특성)

  • Lee, Seung-Yup;Lee, Min-Jae;Park, Byung-Ok
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.16 no.2
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    • pp.59-65
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    • 2006
  • Al-doped and F-doped ZnO (ZnO : Al & ZnO : F) thin films were coated onto glass substrate by sol-gel method. These films showed c-axis orientation in common, but different I(002)/[I(002) + I(101)] and FWHM (full width at half-maximum). In particular, the grain size of the ZnO : Al films decreased with the increase in the Al-doping concentration, while for the ZnO : F films the grain siae increased up to F 3 at% and then decreased. For the electrical properties, Hall effect measurement was used. The resistivity of the ZnO : Al films and the ZnO : F films were, respectively, $2.9{\times}10^{-2}{\Omega}cm$ at Al 1 at% and $3.3{\times}10^{-1}{\Omega}cm$ at F 3 at%. Moreover compared with ZnO:Al films, ZnO:F films have lower carrier concentration (ZnO : Al $4.8{\times}10^{18}cm^{-3}$, ZnO : F $3.9{\times}10^{16}cm^{-3}$) and higher mobility (ZnO : Al $45cm^2/Vs$, ZnO : F $495cm^2/Vs$). For average optical transmittances, ZnO : Al thin films have $86{\sim}90%$ and ZnO : F films have $77{\sim}85%$ comparatively low.

A Study on Spray and Mixing Characteristics of Unlike Impinging Triplet Injector (F-O-F, O-F-O) (충돌형(F-O-F, O-F-O) 실물형 분사기의 분무특성 및 혼합특성에 관한 연구)

  • 김종규;김승한;문일윤;이광진;서성현;한영민
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2003.10a
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    • pp.195-203
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    • 2003
  • Spray and Mixing characteristics of the unlike impinging triplet injectors (F-O-F, O-F-O) were investigated with the variation of the momentum ratio of oxidizer to fuel. The spray pattern was measured using a backlit stroboscopic photography technique, and mixing efficiency was measured using a mechanical patternator. Kerosene/water were used as a propellant simulant. From the experimental results, it is found that a O-F-O type injector has a good atomization. And as the momentum ratio increases, the mixing efficiency decreases rapidly.

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Variation of Band Gap Energy upon Structural Distortion for Nb-containing Oxyfluorides (Nb를 포함하는 불소산화물에서 구조적 뒤틀림에 따른 에너지 띠 간격의 변화)

  • Kim, Hyun-Jun;Kim, Seung-Joo
    • Journal of the Korean Chemical Society
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    • v.51 no.3
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    • pp.265-269
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    • 2007
  • A comparative study on crystal structures and UV-visible diffuse reflectance spectra for Nb-containing oxyfluorides was performed to probe the relationship between energy band gap and local structure. The oxyfluorides, RbSrNb2O6F, RbCaNb2O6F and RbNb2O5F are commonly composed of the corner-sharing NbO5F octahedra as structural building units. The average Nb-O(F)-Nb bond angles, which can be a measure of the structural distortion, are 158.6° for RbSrNb2O6F, 149.6° for RbCaNb2O6F and 139.5° for RbNb2O5F. As the bond angle decreases, the band gap increases: 3.48eV for RbSrNb2O6F, 3.75eV for RbCaNb2O6F and 4.03 eV for RbNb2O5F. This experimental result implies that the band gap can be controlled with a range of 0.6 eV through a variation of local structure for the Nb-containing oxyfluorides.

Recovery of $ZrO_2$ by Leaching from $LiF-BeF_2-ZrO_2$ Molten Salt in Distilled Water ($LiF-BeF_2-ZrO_2$ 용융염에서 증류수 침출에 의한 $ZrO_2$의 회수 - 증류수에서 $LiF-BeF_2-ZrF_4+ZrO_2$ 용융염의 용해현상 -)

  • Woo, Mun-Sik;Yoo, Jae-Hyung;Park, Hyun-Soo;Kang, Young-Ho;Kwon, Soo-Han
    • Analytical Science and Technology
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    • v.13 no.6
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    • pp.712-721
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    • 2000
  • $LiF-BeF_2-ZrF_4$(63-30-7 mol%) molten salt was dissolved up to 0.02g in 1ml of distilled water at room temperature. $ZrO_2$ oxide made from $ZrF_4$ through pyrohydrolysis was recovered by leaching in distilled water with $LiF-BeF_2-ZrF_4$molten salt including it at room temperature. The crystalline sharpness of recovered $ZrO_2$ oxide was not damaged.

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Free Energy of Formation of BaThO3 from E.M.F. Measurement

  • Park, S. H.;H. D. Baek;J. S. Hwang;Park, C. O.
    • The Korean Journal of Ceramics
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    • v.4 no.3
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    • pp.204-206
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    • 1998
  • The Gibbs free energy of formation of $BaThO_3$ from elemental oxides has been measured at temperatures between 853 and 903 K using a $CaF_2$ solid electrolyte galvanic cell. The galvanic cell consisted of Pt, $O_2, CaO+CaF_2 \parallel CaF_2 \parallelBaThO_3+ThO_2+BaF_2, O_2$, Pt EMF gave the standard Gibbs free energy for the reaction $CaF_2+BaThO_3=CaO+BaF_2+ThO_3$ as $\DeltaG^o$,/TEX>=124111.031-117.597 T(J/mol).

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Stability of Water-in-Oil Emulsion by Gelation;Application of Sun-Block Cream containing Titanium Dioxide($TiO_{2}$) (겔화에 의한 Water-in-Oil에멀젼의 안정성;이산화티타늄($TiO_{2}$)이 함유된 Sun-block Cream의 응용)

  • Kim, In-Young
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.2
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    • pp.67-75
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    • 2000
  • Cosmetic industries have recently developed sun-block products, which are composed of W/O or O/W emulsion system. It was very difficult for waterproofing product to show the stability in W/O emulsion with $TiO_{2}$. To enhance the stability of W/O emulsion, it needs to be combined with the water and oil soluble components as the gelling agents. The emulsifiers used in W/O were 3.0% of cetyl dimethicone copolyol, 2.0% of sorbitan sesquioleate as the basic emulsifiers, and 0.6% of quaternium-18 bentonite and 1.5% of dextrin palmitate as stabilizer were used. The content of titanium dioxide was optimized up to 8.0%. Titanium dioxide was used as the UV scattering powder coated with $Al_{2}O_{3}$(UV-sperse T40/TN). The sunscreen cream prepared with W/O emulsion system by using QB and DP showed higher stability than that of W/O emulsion system by using each QB and DP. W/O emulsion from Formula 3 for passing one year was very durable more than F1 and F2. Within W/O emulsion by observing F1, F2 and F3 for one year, F3 was more excellent than F2 and F3 when they were observed at RT, $4^{\circ}C$, $40^{\circ}C$, because F3 used the mixed QB and DP in W/O emulsion. The zeta potential for F1, F2, and F3 after one year were 21, 30 and 43, respectively. From these result F3 was found best stable emulsion. The in-vitro SPF value for F3 was 35 for the initial product at room temperature and also, the in-vitro SPF values of F3 was 32 for after one year. Finally, the mean in-vivo SPF value of 10 volunteers for F3 was 27.3 by the Korea cosmetic association made the rules of SPF.

The mixing characteristics of Unlike Split Triplet(F-O-O-F) Impinging-Jet Injector Elements (F-O-O-F 인젝터의 혼합 특성)

  • Lim Byoungjik;Jung Kihoon;Yoon Youngbin
    • Proceedings of the KSME Conference
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    • 2002.08a
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    • pp.283-286
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    • 2002
  • The mixing of fuel and oxidizer and each mass distribution of unlike split triplet(F-O-O-F) injector for liquid rocket which are known to affect the combustion efficiency significantly, has been investigated using PLLIF technique. Experiment is conducted to investigate the effect of mixture ratio(MiR), momentum ratio(MoR) and impinging angle on mixing efficiency. The mixing efficiency, which is introduced by Rupe, gives the global chracteristic of spray mixing. Experiment far comparison with triplet injector(F-O-F), which has same momentum ratio and impinging angle with split triplet injector is conducted.

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SOME REMARKS ON CENTERED-LINDELÖF SPACES

  • Song, Yan-Kui
    • Communications of the Korean Mathematical Society
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    • v.24 no.2
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    • pp.277-280
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    • 2009
  • In this paper, we prove the following two statements: (1) There exists a Hausdorff locally $Lindel{\ddot{o}}f$ centered-$Lindel{\ddot{o}}f$ space that is not star-$Lindel{\ddot{o}}f$. (2) There exists a $T_1$ locally compact centered-$Lindel{\ddot{o}}f$ space that is not star-$Lindel{\ddot{o}}f$. The two statements give a partial answer to Bonanzinga and Matveev [2, Question 1].

Improvement of Current Path by Using Ferroelectric Material in 3D NAND Flash Memory (3D NAND Flash Memory에 Ferroelectric Material을 사용한 Current Path 개선)

  • Jihwan Lee;Jaewoo Lee;Myounggon Kang
    • Journal of IKEEE
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    • v.27 no.4
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    • pp.399-404
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    • 2023
  • In this paper, we analyzed the current path in the O/N/O (Oxide/Nitride/Oxide) structure of 3D NAND Flash memory and in the O/N/F (Oxide/Nitride/Ferroelectric) structure where the blocking oxide is replaced by a ferroelectric. In the O/N/O structure, when Vread is applied, a current path is formed on the backside of the channel due to the E-fields of neighboring cells. In contrast, the O/N/F structure exhibits a current path formed on the front side due to the polarization of the ferroelectric material, causing electrons to move toward the channel front. Additionally, we performed an examination of device characteristics considering channel thickness and channel length. The analysis results showed that the front electron current density in the O/N/F structure increased by 2.8 times compared to the O/N/O structure, and the front electron current density ratio of the O/N/F structure was 17.7% higher. Therefore, the front current path is formed more effectively in the O/N/F structure than in the O/N/O structure.

Production of $[^{18}F]F_2$ Gas for Electrophilic Substitution Reaction (친전자성 치환반응을 위한 $[^{18}F]F_2$ Gas의 생산 연구)

  • Moon, Byung-Seok;Kim, Jae-Hong;Lee, Kyo-Chul;An, Gwang-Il;Cheon, Gi-Jeong;Chun, Kwon-Soo
    • Nuclear Medicine and Molecular Imaging
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    • v.40 no.4
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    • pp.228-232
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    • 2006
  • Purpose: electrophilic $^{18}F(T_{1/2}=110\;min)$ radionuclide in the form of $[^{18}F]F_2$ gas is of great significance for labeling radiopharmaceuticals for positron omission tomography (PET). However, its production In high yield and with high specific radioactivity is still a challenge to overcome several problems on targetry. The aim of the present study was to develop a method suitable for the routine production of $[^{18}F]F_2$ for the electrophilic substitution reaction. Materials and Methods: The target was designed water-cooled aluminum target chamber system with a conical bore shape. Production of the elemental fluorine was carried out via the $^{18}O(p,n)^{18}F$ reaction using a two-step irradiation protocol. In the first irradiation, the target filled with highly enriched $^{18}O_2$ was irradiated with protons for $^{18}F$ production, which were adsorbed on the inner surface of target body. In the second irradiation, the mixed gas ($1%[^{19}F]F_2/Ar$) was leaded into the target chamber, fellowing a short irradiation of proton for isotopic exchange between the carrier-fluorine and the radiofluorine absorbed in the target chamber. Optimization of production was performed as the function of irradiation time, the beam current and $^{18}O_2$ loading pressure. Results: Production runs was performed under the following optimum conditions: The 1st irradiation for the nuclear reaction (15.0 bar of 97% enriched $^{18}O_2$, 13.2 MeV protons, 30 ${\mu}A$, 60-90 min irradiation), the recovery of enriched oxygen via cryogenic pumping; The 2nd irradiation for the recovery of absorbed radiofluorine (12.0 bar of 1% $[^{19}F]fluorine/argon$ gas, 13.2 MeV protons, 30 ${\mu}A$, 20-30 min irradiation) the recovery of $[^{18}F]fluorine$ for synthesis. The yield of $[^{18}F]fluorine$ at EOB (end of bombardment) was achieved around $34{\pm}6.0$ GBq (n>10). Conclusion: The production of $^{18}F$ electrophilic agent via $^{18}O(p,n)^{18}F$ reaction was much under investigation. Especially, an aluminum gas target was very advantageous for routine production of $[^{18}F]fluorine$. These results suggest the possibility to use $[^{18}F]F_2$ gas as a electrophilic substitution agent.