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Simulation of thermal distribution with the effect of groundwater flow in an aquifer thermal energy storage (ATES) system model (대수층 축열 에너지(ATES) 시스템 모델에서 지하수 유동 영향에 의한 지반내 온도 분포 예측 시뮬레이션)

  • Shim, Byoung-Ohan
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.1 no.1
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    • pp.1-8
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    • 2005
  • Aquifer Thermal Energy Storage (ATES) can be a cost-effective and renewable geothermal energy source, depending on site-specific and thermohydraulic conditions. To design an effective ATES system having the effect of groundwater movement, understanding of thermohydraulic processes is necessary. The heat transfer phenomena for an aquifer heat storage are simulated by using FEFLOW with the scenario of heat pump operation with pumping and waste water reinjection in a two layered confined aquifer model. Temperature distribution of the aquifer model is generated, and hydraulic heads and temperature variations are monitored at the both wells during 365 days. The average groundwater velocities are determined with two hydraulic gradient sets according to boundary conditions, and the effect of groundwater flow are shown at the generated thermal distributions of three different depth slices. The generated temperature contour lines at the hydraulic gradient of 0.001 are shaped circular, and the center is moved less than 5 m to the direction of groundwater flow in 365 days simulation period. However at the hydraulic gradient of 0.01, the contour center of the temperature are moved to the end of east boundary at each slice and the largest movement is at bottom slice. By the analysis of thermal interference data between two wells the efficiency of the heat pump system model is validated, and the variation of heads is monitored at injection, pumping and no operation mode.

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이산화티타늄($TiO_2$)의 Anatase상에 따른 가스감응 특성의 영향

  • O, Sang-Jin;Heo, Jeung-Su;Lee, Han-Yong;Jo, Bong-Han
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.05a
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    • pp.30.2-30.2
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    • 2009
  • TiO2는 3가지의 결정구조를 가지고 있으며 결정 입자, 구조, 상의 형태에 따라서 성질 및 기능에 영향을 주고 있다. anatase상의 애너지 밴드갭과 전자와의 재결합 확률이 크기 때문에 Rutile상 보다 우수한 성질을 갖고 있어 산화물 반도체로 이용하는 것이 적합하다. 본 실험에서는 나노로드의 TiO2를 수열처리법에 의해 합성한 후 박막을 제조하여 감응특성을 조사하였다. X선 회절분석기(X-Ray Diffraction)로 분석결과 ph=1의 루타일상을 제외하고, pH=2~7의 더 넓은 구간에서 뚜렷한 회절피크의 anatase 상이 나타났으며 다른 비정질상이 발생되지 않는 결정성이 좋은 단결정임이 나타났다. NaOH solution 을 이용하여 수열처리후 $180^{\circ}C$이상의 특정 온도 구간에서 수십 나노 로드 형태로의 2차 성장된 모습을 TEM과 EDS로 결정구조와 화학조성을 분석하였다. 그리고 BET 측정을 통해 $180^{\circ}C$의 소성온도에서 TiO2 입자의 비표면적이 가장 우수한 것으로 나타났다. 나노로드의 수용액을 Al2O3기판의 감지막 위에 떨어뜨려 네트워크된 막을 형성한후에 센서를 제작하였다. 히터 전압이 $400^{\circ}C$에서 나노 파우더센서에서는 반응이 일어나지 않은 반면, 나노 로드센서는 CH3SH에서 28% 의 높은 감도를 얻었고, Toluene의 반응에서는 15%의 감도가 나타났다. 그 외 NO, CO, H2등의 측정에서 아무런 반응이 일어나지 않았다. 이는 비교적 기공이 큰분자(Size)를 가진 CH3SH=76nm, Toluene=60nm에서 반응이 일어난 반면, H2=28nm, CO=22nm에서 감도가 나타나지 않은 것을 보아 흡착분자크기에 의한 영향이 큰 것으로 나타났다.

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Low Complexity PTS Scheme for Reducing PAPR in OFDM Systems (직교 주파수 분할 다중화 시스템에서 최대 전력 대 평균전력의 비 감소를 위한 저 복잡도 부분 전송 수열 방법)

  • Cho, Young-Jeon;No, Jong-Seon;Shin, Dong-Joon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.38A no.2
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    • pp.201-208
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    • 2013
  • In this paper, the PTS scheme generate alternative orthogonal frequency frequency division multiplexing (OFDM) signal sequences by multiplying all the time domain samples with phase rotating vectors to find an OFDM signal having the minimum peak-to-average power ratio (PAPR). However, it needs an exhaustive search which causes large computational complexity. In order to solve this problem, we propose two efficient methods based on the crest factor. The first proposed scheme is to select time domain sample with large magnitude to calculate PAPR, and the next scheme is to calculate the absolute value of real and imaginary part of the sample at each subblock. The simulation results show that the proposed schemes achieve better PAPR reduction performance than existing PTS schemes.

A Study on Thermal Satisfaction of Domestic Heat Wave Reduction Facilities (국내 폭염 저감 시설의 온열 만족도에 대한 연구)

  • Jun, Yong-Joon;Park, Lyool;Park, Kyung-Soon
    • Journal of the Korean Society for Geothermal and Hydrothermal Energy
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    • v.18 no.1
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    • pp.1-11
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    • 2022
  • As abnormal climates occur due to the increase in greenhouse gases at home and abroad, various problems such as human casualties, crop damage, energy depletion, and economic loss due to heat diseases, which are one of the extreme climate phenomena, are following one after another. In response, the government has established the 'Climate Crisis Response Special Committee' since 2018, when it recorded the greatest damage in history due to heat waves, and has been carrying out budget formation and reform of laws and systems every year to respond to heat waves. However, in relation to the heat wave damage reduction facility that is being expanded with a large budget, there is no prior research related to the degree of heat loss due to the use of the facility, the difference in effects between specific groups, and the economic effect that comes back compared to the invested budget. Therefore, from a midto long-term perspective, it is expected that it will be difficult to establish a clear direction for policy making. Therefore, in this study, representative facilities were selected according to the principle of heat reduction among the currently expanded heat damage reduction facilities, and a questionnaire survey was conducted for users of each reduction facility (waterfall, awning, pond, and elastic pavement). Accordingly, the change in the sense of heat according to the use of the heat damage reduction facility was checked, and the change in the sense of heat according to the group characteristics (gender, age, metabolic rate) was analyzed to examine the characteristics of the relationship between the facility and the users.

A Comparative Study on Morphologies and Characteristics of Silica Nanoparticles Recycled from Silicon Sludge Waste of Semiconductor Process Based on Synthesis Methods (반도체 공정에서 발생하는 폐실리콘 슬러지의 재활용을 통한 실리카 나노입자의 제조 및 합성법에 따른 형상 및 특성 비교 연구)

  • Jiwon Kim;Minki Sa;Yeon-Ryong Chu;Suk Jekal;Ha-Yeong Kim;Chan-Gyo Kim;Hyung Sub Sim;Chang-Min Yoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.31 no.3
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    • pp.5-13
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    • 2023
  • In this study, a comparative study is conducted on the synthesis methods for silica nanoparticle employing the silicon sludge waste generated from the semiconductor manufacturing processes. Specifically, acid-washed silicon sludge wastes with no impurities are employed as the precursors of sol-gel and hydrothermal methods for silica nanoparticles preparation. The morphologies and properties of silica nanoparticles synthesized via two synthetic methods are examined by various analysis methods. As a result, silica nanoparticles from the sol-gel method are fabricated with high purity and uniform shape, while the hydrothermal method exhibits advantages in yield and ease of synthetic process. This comparative study offers detailed experimental results on the two synthetic methods for silica nanoparticle synthesis, which may contribute to the establishment of manufacturing high-value materials using the by-products generated in the semiconductor process.

$NH_3$ Gas Sensor Based on ZnO Nanowires as Sensing Material

  • No, Im-Jun;Sin, Baek-Gyun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.378-379
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    • 2012
  • ITO 만큼 높은 전도성과 광학적 투과성을 갖는 Al-doped ZnO (AZO) 박막을 DC-Pulse magnetron sputtering을 이용하여 40 nm 두께로 증착 후 리소그라피 공정을 통해 $30{\mu}m$ 간격으로 패터닝 하였다. 간격 30 ${\mu}m$로 배열된 AZO를 촉매층으로 하는 수열합성법을 리사이클 공정을 반복하여 수행하여 ZnO 나노선을 성장시켰다. 이와 같이 AZO 전극 사이에 길이 $30{\mu}m$의 ZnO 나노선이 래터럴 구조로 연결된 소자의 $NH_3$ 가스감지 특성을 조사하였다. 합성된 나노선의 전기적, 광학적, 구조적인 특성을 분석하여 높은 가스 감지도를 예상할 수 있는 특성을 확인하였다. 제작된 가스센서를 진공 챔버에 설치 후 양 전극간에 동작전압(Operating voltage)을 1 V로 인가하여 고정한 후에 $NH_3$를 주입(Injection)과 퍼지(Purge)를 반복하며 그 주입량(10 ppm, 20 ppm, 40 ppm, 60 ppm)에 변화를 주었고, 그에 따른 전류변화를 관찰하여 $NH_3$ 가스감지특성을 평가하였다.

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Property of film heater using ZnO nanowires (ZnO 나노선을 이용한 면 발열 특성)

  • No, I.J.;Kim, S.H.;Lee, K.I.;Shin, P.K.;Cho, J.W.
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1517-1518
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    • 2011
  • 수열합성법을 이용하여 ZnO 나노선을 합성 하였다. 리사이클 공정을 통해 얻은 양질의 길고 수직한 나노선은 기판과 분리공정을 통해 분리된 후 유전체 층이 올라간 실리콘 웨이퍼 위에 스프레이 공정을 통해 고르게 분사 되었고 열처리 공정을 통해 면 발열 소자로서 제작 되었다. 소자 양단 전극에 전계를 인가한 후 열화상카메라를 통해 발열상태를 확인 하였다.

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A Study of Hydroxyapatite Synthesis by Wet-direct and Hydrothermal Synthesis (습식 및 수열합성법에 의한 Hydroxyapatite의 합성에 관한 연구)

  • 전성용;김홍기;이경희;이병하
    • Journal of the Korean Ceramic Society
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    • v.30 no.3
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    • pp.215-221
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    • 1993
  • The Hydroxyapatite powders were prepared by Wet-direct and Hydrothermal synthesis using Ca(NO3)2.4H2O and (NH4)2.HPO4.Stoichiometric and good cristalline HAp powders were obtained 9$0^{\circ}C$ by wet-direct process. The aspect ratio of HAp powders prepared by hydrothermal synthesis was increased with increasing synthetic temperature. The HAp particles obtained at 20$0^{\circ}C$ for 10hr were needle shaped ultra fine crystals, about 100nm in size. Small amount of TCP was obtained above 80$0^{\circ}C$ after heat-treatment of hydrothermally synthesized HAp but good crystalline HAp phase was maintained up to 120$0^{\circ}C$ as the primary phase.

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Hydrothermal Synthesis of $CeO_2$ Powder (수열법에 의한 $CeO_2$ 분말 합성)

  • Lee, K.J.;Park, B.K.;Lee, T.K.;Hwang, Y.;Kim, C.J.;Choi, S.C.
    • Korean Journal of Crystallography
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    • v.11 no.1
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    • pp.52-57
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    • 2000
  • Hydrothermal synthesis of find CeO₂ powder has been investigated. Synthesis was performed with Ce(NO₃)₃·6H₂O, in ethanol and water solution. Mineralizer were NH₄OH and KOH and reaction for the powder synthesis has performed at 130℃. The morphology of CeO₂ was nearly spherical in using NH₄OH and cubic form in KOH. Particle size increased with addition of NH₄OH. Ethanol solution was effective to reduced the agglomeration.

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The growth of ZnO nanorods by hydrothermal method on organic substrates (유기 기판 위에 수열 합성법으로 성장된 ZnO 나노 막대의 특성 연구)

  • Kim, Ah-Ra;Lee, Ji-Yeon;Lee, Ju-Young;Kim, Hong-Seung;Park, Hyun-Kook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2010.06a
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    • pp.281-281
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    • 2010
  • In this study, ZnO nanorod arrays are grown on organic substrates by hydrothermal method which requires a low temperature, simple process, and no vacuum. The structure properties of ZnO nanorods were examined by field emission scanning electron microscopy and X-ray diffraction. To detect the optical transmission, ultraviolet visible spectrophotometer was also used. From results, the ZnO nanorods were grown the horizontal growth on the organic substrates had the length of over $10\;{\mu}m$. After deposition of ZnO seed layer, the ZnO nanorod arrays had uniformity orientation and length.

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