• Title/Summary/Keyword: Nitrate pollution

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COMPOSTING AND LAND APPLICATION OF ANIMAL WASTES

  • Harada, Y.
    • Asian-Australasian Journal of Animal Sciences
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    • v.5 no.1
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    • pp.113-121
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    • 1992
  • An the livestock production in Japan is industrialized, a tremendous amount of animal wastes is being produced annually, resulting in serious environmental pollution problems. Animal wastes could be pollutants, but they are also important sources of fertilizer nutrients and organic matter. Composting is an effective way of promoting the increased utilization of animal wastes. The characterization of maturing process during composting is important in order to improve the composting technology and to develop and efficient method to estimate the degree of maturity. The rise and fall in temperature, and changes in the constituents of the compost, reflect the maturing process and may serve as indicators for maturation. In addition, the detection of nitrate by diphenylamine, the determination of cation-exchange capacity (CEC), and the germination test, are also recommended as the methods of estimating the degree of maturity. The heavy applications of animal manure and compost may cause an adverse effect on soils and crops. When excess manure is applied, the nitrogen will be accumulated in soil, resulting in accumulation of nitrate in crops and pollution of the groundwater. Guidelines for application rates are recommended, to maintain soil productivity and quality of crops, and to prevent the environmental pollution.

A Study on Pollution Conditions and Management of Sand Flooring Related to Animal Feces - Nitrogen Analysis Method Development - (동물 분변으로 인한 모래 바닥재의 오염실태 및 관리 방안에 관한 연구 - 질소분석방법개발 -)

  • Jeong, Won-Gu;Ha, Ji-Young;Oh, Geun-Chan;Huh, In-Ryang;Choi, Seung-Bong
    • Journal of Environmental Health Sciences
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    • v.46 no.6
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    • pp.646-654
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    • 2020
  • Objectives: Users of parks or children's play facilities have pointed to pets' bowel movements as the most serious problem when using them. In prior studies, a very low detection rate of parasites (eggs) in sand flooring materials has been found. Even though feces have been identified, no parasites (eggs) have been detected. Method: A standard solution of nitrate nitrogen was used to verify the reliability of a new nitrogen analysis method. The linearity, precision, and accuracy of the nitrate nitrogen analysis method were verified. Using this method, the pollution distribution of the sand flooring material and the degree of pollution at each point were investigated. Results: As a result of the verification of the nitrogen analysis method, the linearity was found to be good at r2=0.999 when distilled water is mixed in a standard substance solution. The standard substance additive solution r2=0.968 was found to be good. Precision represented 0.01 to 0.06% RSD for peak height. The recovery rate was 92.4 to 104.0 percent, indicating high accuracy. According to the same method of analysis, the flooring material sand at a general amusement facility with the largest number of concealed spaces was nitrate nitrogen 6.1 times higher than at the entrance of the playground. Also, in a comparison between clean sand and sandy flooring, the average nitrogen concentration of the sand flooring material was 24.4-167 times higher than pure sand. Conclusions: As such, no parasites (eggs) were detected at all points under investigation, but the sand flooring was exposed to animal fecal contamination. Therefore, the management of nitrogenous components should allow accurate identification of animal fecal contamination so that the timing of sand replacement can be managed hygienically and safely.

Groundwater vulnerability assessment in the southern coastal sedimentary basin of Benin using DRASTIC, modified DRASTIC, Entropy Weight DRASTIC and AVI

  • Agossou, Amos;Yang, Jeong-Seok
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.152-152
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    • 2021
  • The importance of groundwater has long been recognized, but the ground water potential to become contaminated as a result of human activities has only been recognized in recently. Before 1980 it was thought that soils served as filters, preventing harmful substances deposited at the surface from migrating into groundwater. Today it is known that soils have a finite capacity to protect groundwater. It can be contaminated from divers sources. Therefore, Assessment of aquifer vulnerability to pollution is essential for the protection and management of groundwater and land use planning. In this study, we used DRASTIC and AVI for groundwater vulnerability to contamination assessment. the different methods were applied to the southern coastal sedimentary basin of Benin and DRASTIC method was modified in two different steps. First, we modified DRASTIC by adding land use parameter to include the actual pollution sources (DRASTICLcLu) and second, classic DRASTIC weights was modified using Shannon's entropy (Entropy weight DRASTIC). The reliability of the applied approaches was verified using nitrate (NO3-) concentration and by comparing the overall vulnerability maps to the previous researches in the study area and in the world. The results from validation showed that the addition of landcover/land use parameter to the classic DRASTIC helps to improve the method for better definition of the vulnerable areas in the basin and also, the weight modification using entropy improved better the method because Entropy weight DRASTICLcLu showed the highest correlation with nitrate concentration in the study basin. In summary the weight modification using entropy approach reduced the uncertainty of the human subjectivity in assigning weights and ratings in the standard DRASTIC.

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Simultaneous Removal of Ammonium and Nitrate by Natural Zeolite and Bacteria (천연 zeolite와 미생물을 이용한 NH4+ 및 NO3-의 동시 제거)

  • Lee, Seon-hee;Lee, Ji-Hye;Kim, Duk gyum;Lee, Chang-Soo;Kang, Kyung Suk;Kim, In Ho
    • Korean Chemical Engineering Research
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    • v.46 no.5
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    • pp.971-976
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    • 2008
  • Water pollution by ammonium ion and nitrate is a common and growing problem in the ecosystem. Process of biological removal consists of nitrification and denitrification by bacteria. Ammonium is oxidized generally to nitrate by nitrification and nitrate is reduced to dinitrogen gas in the subsequent denitrification process. Although natural zeolite is well known for its ability to preferentially remove ammonium, it is not sufficiently removing ammonium ion and nitrate by adsorption. In order to overcome this problem, a method of biological removal with zeolite is used for simultaneous removal of ammonium and nitrate. As a result, in case of shaking culture with 1% seed and passing through zeolite column, the process revealed that ammonium ion could be removed completely after 14 hours. The removal of nitrate using columns with naturally adsorbed bacteria onto zeolite reached approximately 100% after 4 hours.

Reactive Transport of Nitrate in Surface-Groundwater Interactions (지표수-지하수 상호작용에서 질산성질소의 반응성 이동 연구)

  • Chang, Sun Woo;Woo, Soyoung;Chung, Il-Moon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.44 no.5
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    • pp.663-672
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    • 2024
  • Nitrate contamination primarily results from agricultural activities and wastewater inputs, potentially leading to groundwater pollution. This study analyzed the reactive transport of nitrate in surface-groundwater interactions in the Gadeok-myeon, Cheongwon-gun, using integrated SWAT, MODFLOW, and RT3D models. The study used SWAT to simulate hydrological cycles, MODFLOW for groundwater flow analysis, and RT3D to model the reactive transport of nitrate. SWAT was used to estimate daily groundwater recharge and nitrate concentrations, which were then input into MODFLOW and RT3D models. The results showed that groundwater flow and reactive transport of nitrate were effectively simulated, providing insights into improving predictive models for groundwater and surface water interactions.

Identification of the Sources of Nitrate using Stable Isotope Mass Ratio in Rural Watersheds (안정 동위원소비를 이용한 농촌하천유역 질산성 질소의 오염원 추정)

  • 홍영진;권순국;홍성구
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.43 no.4
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    • pp.120-128
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    • 2001
  • Pollution sources and their environmental contributions were investigated to select the best management practices for the effective control of water quality. The nitrogen isotope mass ratio was determined to estimate the nitrate sources and their contribution. Sampling sites were chosen by calculating effluent loads at each watershed. Two liters each of the surface water samples were collected from four sites at Bokha river and two sites and Gwanri river. They were sequentially prepared through distillation method and analyzed using an isotope ratio mass spectrometer(IsoPrime EA). As revealed by the experimental values obtained the mass ratio values ($\delta$$^{5}$ N) of watersheds with a large amount of nonpoint sources were less than +5 an indication that the samples were influenced by chemical fertilizers. However watersheds with large amount of point sources were influenced not only by chemical fertilizers but also by animal and municipal wastes. The mass ratio values of samples generally decreased during rainy days. But during dry days the mass ratio values well-reflected the nitrate sources and the condition of watersheds. Through this study the nitrogen isotope mass ratio has been found to be useful for estimating nitrate sources and their contribution to the rural watersheds.

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A Study on Equilibrium of $NH_4NO_{3(s, aq)}-HNO_{3(g)}-NH_{3(g)}$ in Urban Atmosphere (도시 대기중에서 $NH_4NO_{3(s, aq)}-HNO_{3(g)}-NH_{3(g)}$의 평형에 관한 연구(II))

  • 천만영;이영재;김희강
    • Journal of Korean Society for Atmospheric Environment
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    • v.9 no.2
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    • pp.154-159
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    • 1993
  • Theoretical prediction of the equilibrium of temperature and relative humidity dependance involving $HNO_{3(g)}-NH_{3(g)}$ and $NH_4NH_{3(s, aq)}$ was compared with atmospheric measurement of particulate nitrate$(NO_3^-)$, Ammonia-Nitric Acid partial pressure product $([$NH_{3(g)}][HNO_{3(g)}]ppb^2$) by a triple filter pack sampler from Oct 1991 to July 1992. The measured $HNO_3NH_3$ concentration product K was greater than equilibrium constant $K_p$ calculated from thermodynamic data of $NH_4NO_{3(s, aq)}-HNO_{3(g)}-NH_{3(g)}$ during fall, winter and spring. But K was lower than $K_p$ in summer. K was greater than $K_p$ as the result of supersaturation by air pollution, particularly anthropogenic $NH_3$.The reason of $K < K_p$ was due to removal of particulate nitrate$(NO_3^-)$ by rainout and washout. $NH_4NO_3$ which consists mainly of particulate nitrate is formed by reaction between $HNO_3$ and $NH_3$. As a result of the removal of particulate nitrate$(NO_3^-)$ by rainout and washout, concentrations of $HNO_3$ and $NH_3$ are decreased by equilibrium transfer(Le Chatelier's Law) in atmosphere.

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Modeling of the Nitrate Adsorption Kinetics onto $ZnCl_2$ Treated Granular Activated Carbon (염화아연으로 표면개질된 입상활성탄의 질산성질소 흡착속도의 모델링 연구)

  • Ji, Min-Kyu;Jung, Woo-Sik;Bhatnagar, Amit;Jeon, Byong-Hun
    • Journal of Soil and Groundwater Environment
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    • v.13 no.3
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    • pp.21-26
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    • 2008
  • Nitrate adsorption from aqueous solutions onto zinc chloride ($ZnCl_2$) treated coconut Granular Activated Carbon (GAC) was studied in a batch mode at two different initial nitrate concentrations (25 and 50 mg/L). The rate of nitrate uptake on prepared media was fast in the beginning, and 50% of adsorption was occurred within 10 min. The adsorption equilibrium was achieved within one hour. The mechanism of adsorption of nitrate on $ZnCl_2$ treated coconut GAC was investigated using four simplified kinetic models : the rate parameters were calculated for each model. The kinetic analysis indicated that pseudo-second-order kinetic with pore-diffusion-controlled was the best correlation of the experimental kinetic data in the present adsorption study.