Identification of the Sources of Nitrate using Stable Isotope Mass Ratio in Rural Watersheds

안정 동위원소비를 이용한 농촌하천유역 질산성 질소의 오염원 추정

  • 홍영진 (서울대학교 대학원) ;
  • 권순국 (서울대학교 농업생명과학대학) ;
  • 홍성구 (한경대학교 농업생명과학부)
  • Published : 2001.07.01

Abstract

Pollution sources and their environmental contributions were investigated to select the best management practices for the effective control of water quality. The nitrogen isotope mass ratio was determined to estimate the nitrate sources and their contribution. Sampling sites were chosen by calculating effluent loads at each watershed. Two liters each of the surface water samples were collected from four sites at Bokha river and two sites and Gwanri river. They were sequentially prepared through distillation method and analyzed using an isotope ratio mass spectrometer(IsoPrime EA). As revealed by the experimental values obtained the mass ratio values ($\delta$$^{5}$ N) of watersheds with a large amount of nonpoint sources were less than +5 an indication that the samples were influenced by chemical fertilizers. However watersheds with large amount of point sources were influenced not only by chemical fertilizers but also by animal and municipal wastes. The mass ratio values of samples generally decreased during rainy days. But during dry days the mass ratio values well-reflected the nitrate sources and the condition of watersheds. Through this study the nitrogen isotope mass ratio has been found to be useful for estimating nitrate sources and their contribution to the rural watersheds.

Keywords

References

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