• Title/Summary/Keyword: Ni201

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Electrochemical Catalytic Behavior of Cu2O Catalyst for Oxygen Reduction Reaction in Molten Carbonate Fuel Cells

  • Song, Shin Ae;Kim, Kiyoung;Lim, Sung Nam;Han, Jonghee;Yoon, Sung Pil;Kang, Min-Goo;Jang, Seong-Cheol
    • Journal of Electrochemical Science and Technology
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    • v.9 no.3
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    • pp.195-201
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    • 2018
  • To enhance the performance of cathodes at low temperatures, a Cu-coated cathode is prepared, and its electrochemical performance is examined by testing its use in a single cell. At $620^{\circ}C$ and a current density of $150mAcm^{-2}$, a single cell containing the Cu-coated cathode has a significantly higher voltage (0.87 V) during the initial operation than does that with an uncoated cathode (0.79 V). According to EIS analysis, the high voltage of the cell with the Cu-coated cathode is due to the dramatic decrease in the high-frequency resistance related to electrochemical reactions. From XPS analysis, it is confirmed that the Cu is initially in the form of $Cu_2O$ and is converted into CuO after 150 h of operation, without any change in the state of the Ni or Li. Therefore, the high initial cell voltage is confirmed to be due to $Cu_2O$. Because $Cu_2O$ is catalytically active toward $O_2$ adsorption and dissociation, $Cu_2O$ on a NiO cathode enhances cell performance and reduces cathode polarization. However, the cell with the Cu-coated cathode does not maintain its high voltage because $Cu_2O$ is oxidized to CuO, which demonstrates similar catalytic activity toward $O_2$ as NiO.

Implementation of virtual laboratory for automation and complex process control systems using Web-based tool (Web 기반 도구를 이용한 자동화 복합 공정 제어 시스템의 가상실험실 구현)

  • Han, Earl;Park, Sung-Moo;Heo, Ji-Woong;Hong, Sang-Eun
    • Proceedings of the KAIS Fall Conference
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    • 2008.05a
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    • pp.198-201
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    • 2008
  • 인터넷의 비약적인 발달은 제어시스템의 설계 및 운영에도 많은 영향을 미치게 되어 지금까지와는 전혀 다른 시스템 구현이 가능한 환경으로 만들어 가고 있다. 이와 같은 배경에서 본 연구에서는 LabVIEW를 이용한 복합 공정의 제어 및 모니터링을 Web을 기반으로 한 새로운 방법의 원격제어 시스템을 사용하여 가상실험실을 구현하였다. LS산전의 GLOFA-GM3와 미쓰비시의 MELSEC-Q PLC를 각각 TCP/IP와 RS-232C통신을 사용하여 복합공정 제어 시스템을 구현하였다. NI사의 LabVIEW 프로그램에서 지원하는 Web 출판 기능을 사용하여 웹상에서 50대의 Clint PC의 접속을 가능하게 하여 원격으로 접속, 학습이 가능하도록 가상실험실을 구현하였으며 학습자들은 원격으로 복합 제어공정을 실시간으로 학습할 수 있게 되었다. 나아가 Web 상에서 원격제어의 가능성을 활용하여 산업체에서의 활용범위를 넓히고, 가상 교육환경의 가능성을 열었다.

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Size Control of Nickel Powders from Nickel Chloride Solution Containing Ammonia in DEA Solutions (DEA 용액에서 암모니아를 함유한 염화니켈 수용액으로부터 니켈 분말의 입경 제어)

  • Choi Eun Young;Lee Yoon Bok;Yoon Suk Young;Kim Kwang Ho;Kim Jin Chun;Rhyim Young Mok;Kim Hyong Kuk;Kim Yang Do
    • Journal of Powder Materials
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    • v.12 no.3
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    • pp.201-207
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    • 2005
  • Nickel powders were synthesized by the hydrazine reduction of nickel chloride solution containing ammonia in DEA solutions. The size distribution of nickel powders were investigated as a function of ammonia concentration, hydrazine concentration and the mixed composition ratio of diethanolammine (DEA) and triethanolammine (TEA). Nickel powders with the size in submicron range were obtained at $185^{\circ}C$ for 45 minutes by hydrazine reduction of nickel chloride solution in DEA solutions. The hydrazine concentrations showed significant effects on the particle size and shape distribution of nickel powders under $NH_3/Ni^{2+}$ molar ratio of 2.0 condition. As the mixed volume ratio of TEA and DEA increased, nickel powders with relatively larger particle size and low agglomeration were obtained. Nickel powders with particle size in the ranged from 0.4 to $0.9\;{\mu}m$ were obtained at the 50 $vol.%$ of TEA.

Effect of Bonding Condition on the Tensile Properties of Diffusion Bonded Haynes230 (고상확산접합된 Haynes230의 인장성질에 미치는 접합조건의 영향)

  • Kang, Gil-Mo;Jeon, Ae-Jeong;Kim, Hong-Kyu;Hong, Sung-Suk;Kang, Chung-Yun
    • Journal of Welding and Joining
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    • v.31 no.3
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    • pp.76-83
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    • 2013
  • This study investigated the effect of bonding temperature and holding time on microstructures and mechanical properties of diffusion bonded joint of Haynes230. The diffusion bonds were performed at the temperature of 950, 1050, and $1150^{\circ}C$ for holding times of 30, 60, 120 and 240 minutes at a pressure of 4MPa under high vacuum condition. The amount of non-bonded area and void observed in the bonded interface decreased with increasing bonding temperature and holding time. Cr-rich precipitates at the linear interface region restrained grain migration at $950^{\circ}C$ and $1050^{\circ}C$. However, the grain migration was observed in spite of short holding time due to the dissolution of precipitates to base metal in the interface region at $1150^{\circ}C$. Three types of the fracture surface were observed after tensile test. The region where the coalesce and migration of grain occurred much showed high fracture load because of base metal fracture whereas the region where those did less due to the precipitates demonstrated low fracture load because of interface fracture. The expected fracture load could be derived with the value of fracture area of base metal ($A_{BF}$) and interface ($A_{IF}$), $Load=201A_{BF}+153A_{IF}$. Based on this equation, strength of base metal and interface fracture were calculated as 201MPa and 153MPa, respectively.

Investigation on Size Distribution of Tungsten-based Alloy Particles with Solvent Viscosity During Ultrasonic Ball Milling Process (초음파 볼밀링 공정에 의한 용매 점도 특성에 따른 텅스텐계 합금 분쇄 거동)

  • Ryu, KeunHyuk;So, HyeongSub;Yun, JiSeok;Kim, InHo;Lee, Kun-Jae
    • Journal of Powder Materials
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    • v.26 no.3
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    • pp.201-207
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    • 2019
  • Tungsten heavy alloys (W-Ni-Fe) play an important role in various industries because of their excellent mechanical properties, such as the excellent hardness of tungsten, low thermal expansion, corrosion resistance of nickel, and ductility of iron. In tungsten heavy alloys, tungsten nanoparticles allow the relatively low-temperature molding of high-melting-point tungsten and can improve densification. In this study, to improve the densification of tungsten heavy alloy, nanoparticles are manufactured by ultrasonic milling of metal oxide. The physical properties of the metal oxide and the solvent viscosity are selected as the main parameters. When the density is low and the Mohs hardness is high, the particle size distribution is relatively high. When the density is high and the Mohs hardness is low, the particle size distribution is relatively low. Additionally, the average particle size tends to decrease with increasing viscosity. Metal oxides prepared by ultrasonic milling in high-viscosity solvent show an average particle size of less than 300 nm based on the dynamic light scattering and scanning electron microscopy analysis. The effects of the physical properties of the metal oxide and the solvent viscosity on the pulverization are analyzed experimentally.

Distribution Characteristics of the Naturalized Plants in the Stream of Downtown and Urban Forest of Chuncheon City (춘천시 도심하천(태백천)과 도시림에 있어서 귀화식물의 분포특성)

  • Son, Ho-Jun;Ahn, Chi-Ho;Ahn, Seung-Il;Kim, Nam-Young;Kim, Young-Sol;Park, Wan-Geun
    • Journal of Korean Society of Forest Science
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    • v.100 no.2
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    • pp.184-201
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    • 2011
  • This study was carried out to investigate the distribution status and invasional characteristics of the naturalized plants. The vascular plants in these areas were consisted of total 381 taxa: 81 families, 234 genera, 295 species, 2 subspecies, 66 verieties, 18 forms. Among the investigated vascular plants, naturalized plants (Sicyos angulatus, Barbarea vulgaris, Thlaspi arvense, Amorpha fruticosa, Trifolium pratense, Ambrosia artemisiifolia, Ambrosia trifida, Aster pilosus, Rumex acetosella etc.) were 41 taxa. The Naturalization Index (NI) was 10.70% and the Urbanization Index (UI) was 15.30% at Chuncheon city. The Invasion Index was 63.41% at urban river and 97.56% at stream high, 19.51% at urban forest area.

The Manufacture of Digital X-ray Devices and Implementation of Image Processing Algorithm (디지털 X-ray 장치 제작 및 영상 처리 알고리즘 구현)

  • Kim, So-young;Park, Seung-woo;Lee, Dong-hoon
    • Journal of the Institute of Convergence Signal Processing
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    • v.21 no.4
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    • pp.195-201
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    • 2020
  • This study studied scoliosis, one of the most common modern diseases caused by lifestyle patterns of office workers sitting in front of computers all day and modern people who use smart phones frequently. Scoliosis is a typical complication that takes more than 80% of the nation's total population at least once. X-ray are used to test for these complications. X-ray, a non-destructive testing method that allows scoliosis to be easily performed and filmed in various areas such as the chest, abdomen and bone without contrast agents or other instruments. We uses NI DAQ to miniaturize digital X-ray imaging devices and image intensifier in self-shielding housing with Vision Assistant for drawing lines to the top and the bottom of the spine to acquire angles, i.e. curvature in real-time. In this way, the research was conducted to see scoliosis patients and their condition easily and to help rapid treatment for solving the problem of posture correction in modern people.

Effects of Isocitrate Lyase Inhibitors on Spore Germination and Appressorium Development in Magnaporthe grisea

  • Kim Seung-Young;Park Jin-Soo;Oh Ki-Bong
    • Journal of Microbiology and Biotechnology
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    • v.16 no.7
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    • pp.1158-1162
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    • 2006
  • The glyoxylate cycle can conserve carbons and adequately supply tricarboxylic acid (TCA) cycle intermediates for biosynthesis when microorganisms grow on $C_{2}$ carbon sources. It has been reported that isocitrate lyase (ICL1), a key enzyme of the glyoxylate cycle, is highly induced when Magnaporthe grisea, the causal agent of rice blast, infects its host. Therefore, the glyoxylate cycle is considered as a new target for antifungal agents. A 1.6-kb DNA fragment encoding the ICL1 from M. grisea KJ201 was amplified by PCR, cloned into a vector providing His-tag at the N-terminus, expressed in Escherichia coli, and purified using Ni-NTA affinity chromatography. The molecular mass of the purified ICL1 was approximately 60 kDa, as determined by SDS-PAGE. The ICL1 inhibitory effects of TCA cycle intermediates and their analogs were investigated. Among them, 3-nitropropionate was found to be the strongest inhibitor with an $IC_{50}$ value of $11.0{\mu}g/ml$. 3-Nitropropionate inhibited the appressorium development in M. grisea at the ${\mu}M$ level, whereas conidia germination remained unaffected. This compound also inhibited the mycelial growth of the fungus on minimal medium containing acetate as a $C_{2}$ carbon source. These results suggest that ICL1 plays a crucial role in appressorium formation of M. grisea and is a new target for the control of phytopathogenic fungal infection.

Shear Strength of the ${Cu_6}{Sn_5}$-dispersed Sn-Pb Solder Bumps Fabricated by Screen Printing Process (${Cu_6}{Sn_5}$를 분산시켜 스크린 프린팅법으로 제조한 Sn-Pb 솔더범프의 전단강도)

  • Choe, Jin-Won;Lee, Gwang-Eung;Cha, Ho-Seop;O, Tae-Seong
    • Korean Journal of Materials Research
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    • v.10 no.12
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    • pp.799-806
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    • 2000
  • Cu$_{6}$Sn$_{5}$-dispersed 63Sn-37Pb solder bumps of 760$\mu\textrm{m}$ size were fabricated on Au(0.5$\mu\textrm{m}$)/Ni(5$\mu\textrm{m}$)/Cu(27$\pm$20$\mu\textrm{m}$) BGA substrates by screen printing process, and their shear strength were characterized with variations of dwell time at reflow peak temperature and aging time at 15$0^{\circ}C$ . With dwell time of 30 seconds at reflow peak temperature, the solder bumps with Cu$_{6}$Sn$_{5}$ dispersion exhibited higher shear strength than the value of the 63Sn-37Pb solder bump. With increasing the dwell time longer than 60 seconds, however the shear strength of the Cu$_{6}$Sn$_{5}$-dispersed solder bumps became lower than that the 63Sn-37Pb solder bumps. The failure surface of the solder bumps could be divided into two legions of slow crack propagation and critical crack propagation. The shear strength of the solder bumps was inversely proportional to the slow crack propagation length, regardless of the dwell time at peak temperature, aging time at 150 $^{\circ}C$ and the volume fraction of Cu$_{6}$Sn$_{5}$ dispersion.> 5/ dispersion.

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The Horse Manure Fertilizers and Pollutants Characteristics Analysis Research (말 분뇨의 비료성분 및 오염물질 특성 조사 연구)

  • Kwag, J.H.;Jeong, M.W.;Choi, D.Y.;Kim, J.H.;Kim, Y.H.;Park, J.C.;Kim, I.C.;Yang, C.B.;La, C.C.
    • Journal of Animal Environmental Science
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    • v.18 no.3
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    • pp.201-206
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    • 2012
  • Horse manure general composition and contaminants, heavy metals content analysis was investigated as follows. The moisture content of horse feces was 76.1% and 96% for horse urine. The average T-N, T-P, T-K concentrations of the racing horse were 0.18%, 0.10%, 0.22% respectively and 2.88%, 0.0015%, 0.84% for urine. And the average BODs, COD, SS concentrations were 26,906 $mg/{\ell}$, 36,642 $mg/{\ell}$, 89,375 $mg/{\ell}$ respectively and 14,298 $mg/{\ell}$, 7,484 $mg/{\ell}$, 6,987 $mg/{\ell}$ for urine. In addition, the Cr, Cu, Ni, Cd, Pb, Zn concentrations of feces were 2.65 mg/kg, 7.05 mg/kg, 1.24 mg/kg, 0.07 mg/kg, 0.01 mg/kg, 45.11 mg/kg respectively and 1.52 mg/kg, 1.62 mg/kg, 0.00 mg/kg, 0.03 mg/kg, 0.03 mg/kg, 4.49 mg/kg for urine on the fresh matter basis. The end of the survey was that the quality of the compost can be used as a raw material, and manure is necessary to constantly driven forward horse manure composting research.