• 한국수소및신에너지학회논문집
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• 제15권4호
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• pp.257-265
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• 2004

Numerical analysis, as EAM(Embedded Atom Method), in the atomic level is necessary to analyze the relation between the hydrogen and hydrogen absorption metals. EAM established on density functional theory was developed as a new means for calculating various properties and phenomena of realistic metal systems. In this study, we had constructed the EAM program from constitutive formulae and parameters of the hydrogen, nickel and palladium for the purpose of predicting the expansion behavior on hydrogen absorbing. In result, not only the ground state properties of metals but also lattice constants and the volume expansion ratio of metal hydrides show good agreement with Daw's data and experiment data.

• Journal of Magnetics
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• 제5권3호
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• pp.90-98
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• 2000

The change in the magnetic properties of a spin-valve multilayer with the structure IrMn (9 m)/CoFe (4 nm)/Cu (2.6 nm)/CoFe (2 nm)/NiEe (6 nm) is investigated as a function of the size and the aspect ratio. At a fixed aspect ratio (the length/width ratio) of 2, the magnetostatic interactions begin to affect the magnetic properties substantially at a spin-valve length of 5 $\mum$, and, at a length of 1 $\mum$, they become even more dominant. In the case of a fixed multilayer size (2.4 $\mum$) which is indicated by the sum of the length and the width, magnetization change occurs by continuous spin-reversal and M-H loops are characterized by no or very small hysteresis at aspect ratios smaller than unity, At aspect ratios greater than unity, magnetization change occurs by spin-flip resulting in squared hysteresis loops. A very large changes in the coercivity and the bias field is observed, and these results are explained by two separate contributions to the total magnetostatic interactions: the coercivity by the self-demagnetizing field and the bias field by the interlayer magnetostatic interaction field.

• 자원환경지질
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• 제29권3호
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• pp.281-291
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• 1996

위스컨신주 북동부 지역에 분포하는 Badwater녹암의 암석학적인 특정과 그들이 생성될 당시의 지구조적인 환경을 유추하기 위하여 채취한 암석을 분석하여 지화학적 연구가 행하여 졌다. 암석들의 화학조성은 전형적인 대륙성 쏠레아이트이며, Mg값이나 Ni, Cr과 같은 호정적인 원소의 함량에 미루어 분출되기전에 많은 분별정출 작용을 받았음을 시사한다. 암석들의 불호정적원소의 변화를 살펴보면 이들은 지각과의 동화작용에 많은 영향을 받았다고 사료된다. 이 암석들은 다양한 화학조성을 보이고 있으나, 모마그마의 성분과 유사한 가장 덜 분화된 암석은 전이형 해양현무암과 유사한 화학조성을 가지고 있다. 이러한 점으로 미루어 전이형 해양현무암과 화학조성이 유사한 모마그마가 지각과의 동화작용으로 그들의 화학조성이 현재의 대륙성 쏠레아이트와 같이 변하였음을 시사한다. 암석들의 지화학적 특성을 살펴보면 분기지역과 같은 인장력을 받는 지구조적 환경에서 생성된 현무암과 유사한 화학적 특징을 나타낸다.

• 한국콘텐츠학회논문지
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• 제16권3호
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• pp.198-209
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• 2016

영화 <늑대소년>은 여성관객의 숨겨진 본래적 욕망을 늑대를 통해 은유적으로 묘사하고 있다. 대부분의 늑대이야기는 인류 역사에서 체득된 늑대에 대한 공포와 두려움을 그리고 문화적으로 악의 상징으로서의 늑대에 대한 심적 응징의 보상 등을 담고 있다. 본 연구는 물리적 공포와 처벌대상의 늑대가 아닌 내면 깊숙이 자리하고 있는 원형적 야성의 은유로서의 늑대에 주목했다. 사춘기 순이의 괴기스런 늑대인간에 대한 경험과 노년의 순이가 이를 회상하는 가운데 여성의 본래적 (성적) 욕망이 모습을 드러낸다. <늑대소년>에 성적 묘사는 없다. 하지만 주인공 순이의 늑대소년과의 교감을 통한 자아성장과정 속에서 프로이의 성이론, 성적 욕망의 억압과 해소 그리고 승화의 메커니즘을 읽어본다. 브뤼노 베틀하임의 전래동화 "빨간모자"의 분석을 통해 사춘기 순이의 본래적 욕망을 분석하고 크리스티바 에스테스의 늑대이야기를 통해서는 노년의 순이가 잊고 있었던 여성의 야생성을 역 추적한다. 본 연구는 <늑대소년>이 생물학적 존재에서 사회적 존재로 거듭나는 가운데 억압되고 제거된 아니면 숨겨져 있던 여성의 본래적 욕망을 재 각성시키고 있음을 분석하였다. 표면적으로 <늑대소년>이 잔잔한 로맨스의 달콤함을 보여주지만 내면적으로는 환타지한 늑대인간과의 사랑을 통해 억압과 금기에 대한 저항의 쾌락과 연계된다.

• 한국자기학회지
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• 제10권2호
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• pp.67-73
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• 2000

6개의 타겟을 가진 직류 마그네트론 방식을 이용하여 스파터링 전력 및 압력을 변화시켜 Si/Ta(50 $\AA$)NiFe(60 $\AA$)/CoFe(20 $\AA$)/Cu(26 $\AA$)/CoFe(40 $\AA$)/FeMn(150 $\AA$)Ta(50 $\AA$) 스핀 밸브 박막을 제조하여 교환자기이방성 및 자기적 특성을 조사하였다. FeMn 층의 증착시 스파터링 전력을 증가시킴으로써 교환이방성을 증가시킬 수 있었으며, X-선 회절 실험결과 스파터링 전력 증가에 따른 교환이방성의 증가는 FeMn (111)면의 우선성장 발달에 기인하는 것으로 판단되었다. 강자성상을 사이에 두고 있는 Cu의 스파터링 압력을 1-5 mTorr 증가시 교환이방성이 급격히 감소하며, 자기저항비 및 자장민감도도 감소하였다. Si/Ta/NiFe/CoFe/Cu(t), 30 W/CoFe, 100 W/FeMn, 100 W/Ta 스핀 밸브에서 Cu 두께를 22-38 $\AA$까지 변화시켜 자기저항비를 조사한 결과 Cu의 두께가 22 $\AA$일 때 자기저항비 6.5%까지 얻을 수 있었으며, Cu 두께를 감소시켜 교환이방성을 증가시킬 수 있었다. 이와 같은 Cu 두께 감소에 따른 교환이방성의 증가는 FM-AFM 스핀-스핀 상호작용에 의하여 설명하였다.

• Journal of Microbiology and Biotechnology
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• 제25권7호
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• pp.1119-1128
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• 2015

1-Aminocyclopropane-1-carboxylate (ACC) deaminase, which is encoded by some bacteria, can reduce the amount of ethylene, a root elongation inhibitor, and stimulate the growth of plants under various environmental stresses. The presence of ACC deaminase activity and the regulation of ACC in several rhizospheric bacteria have been reported. The nitrogen-fixing Pseudomonas stutzeri A1501 is capable of endophytic association with rice plants and promotes the growth of rice. However, the functional identification of ACC deaminase has not been performed. In this study, the proposed effect of ACC deaminase in P. stutzeri A1501 was investigated. Genome mining showed that P. stutzeri A1501 carries a single gene encoding ACC deaminase, designated acdS. The acdS mutant was devoid of ACC deaminase activity and was less resistant to NaCl and NiCl₂ compared with the wild-type. Furthermore, inactivation of acdS greatly impaired its nitrogenase activity under salt stress conditions. It was also observed that mutation of the acdS gene led to loss of the ability to promote the growth of rice under salt or heavy metal stress. Taken together, this study illustrates the essential role of ACC deaminase, not only in enhancing the salt or heavy metal tolerance of bacteria but also in improving the growth of plants, and provides a theoretical basis for studying the interaction between plant growth-promoting rhizobacteria and plants.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2011년도 제40회 동계학술대회 초록집
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• pp.482-483
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• 2011

Graphene is a good candidate for the future nano-electronic materials because it has excellent conductivity, mobility, transparency, flexibility and others. Until now, most graphene researches are focused on the nano electronic device applications, however, biological application of graphene has been relatively less reported. We have fabricated a deoxyribonucleic acid (DNA) conjugated graphene field-effect transistor (FET) and measured the electrical transport characteristics. We have used graphene sheets grown on Ni substrates by chemical vapour deposition. The Raman spectra of graphene sheets indicate high quality and only a few number of layers. The synthesized graphene is transferred on top of the substrate with pre-patterned electrodes by the floating-and-scooping method [1]. Then we applied adhesive tapes on the surface of the graphene to define graphene flakes of a few micron sizes near the electrodes. The current-voltage characteristic of the graphene layer before stripping shows linear zero gate bias conductance and no gate operation. After stripping, the zero gate bias conductance of the device is reduced and clear gate operation is observed. The change of FET characteristics before and after stripping is due to the formation of a micron size graphene flake. After combined with 30 base pairs single-stranded poly(dT) DNA molecules, the conductance and gate operation of the graphene flake FETs become slightly smaller than that of the pristine ones. It is considered that DNA is to be stably binding to the graphene layer due to the ${\pi}-{\pi}$ stacking interaction between nucleic bases and the surface of graphene. And this binding can modulate the electrical transport properties of graphene FETs. We also calculate the field-effect mobility of pristine and DNA conjugated graphene FET devices.

• 한국세라믹학회지
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• 제47권1호
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• pp.26-38
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• 2010

Degradation in Solid Oxide Fuel Cell performance can be ascribed to the following fundamental processes from the materials chemical point of view; that is, diffusion in solids and reaction with gaseous impurities. For SOFC materials, diffusion in solids is usually slow in operation temperatures $800\sim1000^{\circ}C$. Even at $800^{\circ}C$, however, a few processes are rapid enough to lead to some degradations; namely, Sr diffusion in doped ceria, cation diffusion in cathode materials, diffusion related with metal corrosion, and sintering of nickel anodes. For gaseous impurities, chromium containing vapors are important to know how the chemical stability of cathode materials is related with degradation of performance. For LSM as the most stable cathode among the perovskite-type cathodes, electrochemical reduction reaction of $CrO_3$(g) at the electrochemically active sites is crucial, whereas the rest of the cathodes have the $SrCrO_4$ formation at the point where cathodes meet with the gases, leading to rather complicated processes to the degradations, depending on the amount and distribution of reacted Cr component. These features can be easily generalized to other impurities in air or to the reaction of nickel anodes with gaseous impurities in anode atmosphere.

• Bulletin of the Korean Chemical Society
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• 제12권5호
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• pp.474-477
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• 1991

The preferential transport phenomena of neutral cation-anion moieties in neutral macrocycle-facilitated emulsion liquid membrane were described in this study. Emulsion membrane systems consisting of (1) aqueous source phase containing 0.001 M M($NO_3$)$_2(M=Mn^{2+},\;Co^{2+},\;Ni^{2+},\;Cu^{2+},\;Zn^{2+},\;Sr^{2+},\;Cd^{2+},\;and\;Pb^{2+})$ (2) a toluene membrane containing 0.01 M ligand $(DBN_3O_2$, DA18C6, DT18C6, TT18C6, HT18C6) and the surfactant span 80 (sorbitan monooleate) (3% v/v) and (3) an aqueous receiving phase containing $Na_2S_2O_3$ or $NaNO_3$ were studied with respect to the disappearence of transition metal ions from the source phase as a function of time. Cation transports for various two component or three component equimolar mixture of transition metal and $Cu^{2+}$ in a emulsion membrane system incorporating macrocyclic ligand (HT18C6) as carrier were determinded. $Cu^{2+}$ was transported higher rates than the other $M^{2+}$ in the mixture solution. Equilibrium constants for cation-source phase co-anion, cation macrocycle and cation-receiving phase reagent interaction are examined as parameters for the prediction of cation transport selectivities.

• Journal of Electrochemical Science and Technology
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• 제13권2호
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• pp.269-278
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• 2022

Utilization of high-voltage electrolyte additive(s) at a small fraction is a cost-effective strategy for a good solid electrolyte interphase (SEI) formation and performance improvement of a lithium-rich layered oxide-based high-energy lithium-ion cell by avoiding the occurrence of metal-dissolution that is one of the failure modes. To mitigate metal-dissolution, we explored fluorinated dual-additives of fluoroethylene carbonate (FEC) and di(2,2,2-trifluoroethyl)carbonate (DFDEC) for building-up of a good SEI in a 4.7 V full-cell that consists of high-capacity silicon-graphite composite (15 wt% Si/C/CF/C-graphite) anode and Li_1.13Mn_0.463Ni_0.203Co_0.203O₂ (LMNC) cathode. The full-cell including optimum fractions of dual-additives shows increased capacity to 228 mAhg^-1 at 0.2C and improved performance from the one in the base electrolyte. Surface analysis results find that the SEI stabilization of LMNC cathode induced by dual-additives leads to a suppression of soluble Mn²⁺-O formation at cathode surface, mitigating metal-dissolution event and crack formation as well as structural degradation. The SEI and structure of Si/C/CF/C-graphite anode is also stabilized by the effects of dual-additives, contributing to performance improvement. The data give insight into a basic understanding of cathode-electrolyte and anode-electrolyte interfacial processes and cathode-anode interaction that are critical factors affecting full-cell performance.