• Title/Summary/Keyword: Ni-Mo

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The influence of spraying conditions to the coating layer properties of Fe-Cr-Ni-Mo-Si-B alloy using the HVOF (HVOF를 이용한 Fe-Cr-Ni-Mo-Si-B계 고성능 합금 용사층의 특성에 미치는 용사조건의 영향)

  • 권기봉;조대형;장영권;백영남
    • Journal of the Korean institute of surface engineering
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    • v.35 no.1
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    • pp.5-10
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    • 2002
  • This study was performed to investigate the influence of spraying condition to the coating layer properties of Fe-Cr-Ni-Mo-Si-B alloy using the HVOF. The investigations, such as thickness measurement, surface roughness, hardness, friction coefficient, resistance of corrosion were carried out. Matrix is prepared by gritting and coating layer is made of Fe-Cr-Ni-Mo-Si-B alloy powder using HVOF. Alumina gritting layers are superior to steel gritting layers. The less spaying distance, the more coating layer properties confirmed. The optimum spraying condition, in this study, was proved as 13inch spraying distance with feed rate 350rpm (78g/min).

A Study on the Low Temperature Fracture Toughness of Ion-nitrided Ni-Cr-Mo Steel (이온 실화처리한 Ni-Cr-Mo강의 저온파괴인성에 관한 연구)

  • 오세욱;윤한기;문인철
    • Journal of Ocean Engineering and Technology
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    • v.1 no.2
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    • pp.101-112
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    • 1987
  • Fracture toughness characterization in the transition region is examined for heat-treated and ionnitrided Ni-Cr-Mo steel. After heat treatment for the specimens of Ni-Cr-Mo steel, organizations of specimens-specimens which are heat-treated and ion-nitrided for 4 hours at 500 .deg. C and 5 torr in 25%N/dub 2/-75%H/sub 2/mixed gas-, hardness variety, and X-ray diffraction pattern of the ion-nitriding compound layer are observed. Fracture toughenss test of unloading compliance method were conducted over the regions from room trmperature to -70.deg. C. The compound layer was consisted of r'=Fe/sub 4/N phase and ion-nitrided layer's depth was 200mm from surface. The transition regions of heat-treated and ion-nitrided specimens were about -30.deg. C and -50.deg. C, respectively. The transition region of ion-nitrided specimens is estimated less than that of heat-treated one, and this is the effect of ion-nitriding.

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Extraction of Valuable Metals from Spent Desulfurizing Catalyst (탈황(脫黃) 폐촉매(廢觸媒)로부터 유가금속(有價金屬) 추출(抽出))

  • Pradhan, Debabrata;Kim, Dong-Jin;Baik, Seung-Bai;Lee, Seoung-Won
    • Resources Recycling
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    • v.20 no.3
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    • pp.48-54
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    • 2011
  • Sulphuric acid leaching was conducted to extract the metal values from spent refinery catalyst. More than 95% of Ni and V and 30% of Mo could be leached out in 1 M sulphuric acid and 1 hr of leaching time. The decrease in Mo leaching was due to typical characteristic of Mo matrix. The activation energies of the leaching reactions showed the dissolution process follows a diffusion control mechanism. In order to leach out all Mo, further the leaching experiments were conducted with sulfur free spent refinery catalyst. For sulfur free spent refinery catalyst, a two step process of leaching with 1 M sulphuric acid followed by sodium carbonate washing showed better leaching than a two step leaching process with sodium carbonate followed by sulphuric acid washing, with almost 99% leaching of Ni, Mo and V. Solvent extraction using LIX 841 were conducted for a leach liquor containing Ni, 2 g/L; V, 9 g/L, Mo, 0.6 g/L. More than 98% of Mo was extracted from the leach liquor at A:O ratio of 5:2 in a 2 stage process. Similarly V was extracted at A:O ratio of 5:3 in a 2 stage process with 82% of total V extraction.

Improved Cycle Life and Storage Performance in High-Voltage Operated Li2MnO3-LiMO2(M=Ni, Co, Mn)/Graphite Cell System by Fluorine Compounds as Main Electrolyte Solvent (고전압 구동 Li2MnO3-LiMO2(M=Ni, Co, Mn)/graphite 시스템에서의 전지 수명 및 고온 방치 특성 향상에 효과적인 플루오로 화합물계 전해액에 대한 연구)

  • Yu, Jung-Yi;Shin, Woocheol;Lee, Byong-Gon
    • Journal of the Korean Electrochemical Society
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    • v.16 no.3
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    • pp.162-168
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    • 2013
  • $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn) nano-composite is a promising cathode material for xEV application due to its high theoretic capacity. However high voltage operating system of $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn) has worked as a hurdle in its application because of the inherent demerits, such as cycle life degradation and gas evolution. In order to enhance cell performance of $Li_2MnO_3-LiMO_2$(M=Ni, Co, Mn)/graphite cell, we examined electrolyte mainly composed of FEC, fluroalkyl ether and $LiPF_6$ (F-based EL). F-based EL showed much better discharging retention ratio than 1.3 M $LiPF_6$ EC/EMC/DMC (3/4/3, v/v/v) (STD). Furthermore gas evolution, especially CO and $CO_2$ during $60^{\circ}C$ storage for 30 days was dramatically reduced owing to thermal stable SEI formation effect of F-based EL.

Defects evolution and element segregation of Ni-Mo-Cr alloy irradiated by 30 keV Ar ions

  • Liu, Min;Liu, Wenguan;He, Xiujie;Gao, Yantao;Liu, Renduo;Zhou, Xingtai
    • Nuclear Engineering and Technology
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    • v.52 no.8
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    • pp.1749-1755
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    • 2020
  • In present study, TEM foils of Ni-Mo-Cr alloy were directly irradiated with 30 keV Ar ions to allow direct characterization. The defects evolution and element segregation after irradiation were investigated by TEM and HAADF-EDS linear scanning. At low irradiation doses (1.38 and 2.76 dpa), black dots were formed and grew with increasing dose. Complicated defects including peas-shaped dislocation loops, polygon dislocation networks and large loops were visible in samples irradiated to high doses (13.8 and 27.6 dpa). Meanwhile, dislocation channels appeared, in which defects were swept out. Significant Mo depletions at dislocation lines and grain boundaries were induced by irradiation due to large misfits between Mo-Ni atoms and high content of Mo.