• Title/Summary/Keyword: Ni loss

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Electrodeposited Nano-flakes of Manganese Oxide on Macroporous Ni Electrode Exhibiting High Pseudocapacitance

  • Gobal, F.;Jafarzadeh, S.
    • Journal of Electrochemical Science and Technology
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    • 제3권4호
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    • pp.178-184
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    • 2012
  • A porous nickel (P-Ni) substrate was prepared by selective leaching of zinc from pressed pellets containing powders of Ni & Zn in 4 M NaOH solution. Anodic deposition of manganese oxide onto the porous Ni substrate ($MnO_x$/P-Ni) formed nano-flakes of manganese oxide layers as revealed in SEM studies. Pseudocapacitance of this oxide electrode was evaluated by cyclic voltammetry (CV) and chronopotentiometry (CHP) in 2 M NaOH solution. The specific capacitance of the Mn oxide electrode was as high as 1515 F $g^{-1}$, which was ten times higher than Mn oxide deposited on a flat Ni-ribbon. 80% of capacity was retained after 200 charge/discharge cycles. The system showed no loss of activity in dry form over period of days. The impedance studies indicated highly conducting $MnO_x$/P-Ni substance and the obtained specific capacitance from impedance data showed good agreement with the charge/discharge measurements.

PLC용 자심재료의 협가제에 따른 자기적 특성의 변화 (Magnetic Properties of Magnetic Core Materials for PLC as a Funtion to Additives)

  • 안용운;김종령;오영우
    • 한국자기학회지
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    • 제13권6호
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    • pp.246-250
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    • 2003
  • 고주파 대역에서 전자기적 특성이 안정적으로 유지되는 Ni-Zn 페라이트를 제조하기 위해 Ni$_{0.8}$Zn$_{0.2}$Fe$_2$O$_4$를 기본조성으로 Bi$_2$O$_3$와 CaO를 첨가하였다. Bi$_2$O$_3$의 첨가량이 0.3 wt%까지는 손실이 증가하였고 그 이상의 첨가량에서는 감소하였으며, 투자율은 Bi$_2$O$_3$ 첨가량이 증가할수록 증가하였다. Bi$_2$O$_3$와 CaO는 고용체를 형성하여 입계에 편석 됨으로서 비저항층을 형성하여 각각 0.7 wt%, CaO 0.3 wt% 첨가할 경우 가장 낮은 손실과 높은 공명주파수를 나타내었다.

Mn2O3가 LiNiBi Ferrite의 물리적 특성에 미치는 영향 (Physical Properties of Polycrystalline Mn2O3-Substituted LiNiBi Ferrite)

  • 고재귀
    • 한국재료학회지
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    • 제14권9호
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    • pp.655-658
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    • 2004
  • Lithium ferrites are a low-cost material which have been prominent in the high frequency core industry because of their excellent temperature performance and high squareness ratio. In order to develope the lithium ferrites with the high squareness and low coercive force, the ferrites of $Li_{0.48}Bi_{0.02}Ni_{0.04}Fe_{2.46-x}O_4$ were investigated the by varying composition, temperature and frequency. Electric loss of the Li-ferrite was lowered with the substitution of $Mn_{2}O_3$. The addition of $Mn_{2}O_3$ increased the magnetic induction (Bm&Br) but decreased the coercive force (Hc) and the squareness ratio (R=Br/Bm). Also, the Br value was stable at environmental temperature variation.

Ni-Cr 박막으로 제작한 attenuator에 대한 주파수 특성연구 (The study on frequency characteristics of attenuator fabricated by Ni-Cr thin films)

  • 김동진;류제천;구본급;강병돈;김규태;송양섭;유광민;김장환
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2000년도 하계학술대회 논문집 C
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    • pp.1637-1639
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    • 2000
  • Resister networks are used widely in many, high frequency applications for attenuators. In this paper we studied the frequency characteristics of attenuator using network analyzer and compared Ni-Cr thin film resistor with thick film resistor attenuator. Also from return loss, insertion loss and VSWR we obtained the maximum available frequency of these attenuators.

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Energy Band Structure, Electronic and Optical properties of Transparent Conducting Nickel Oxide Thin Films on $SiO_2$/Si substrate

  • Denny, Yus Rama;Lee, Sang-Su;Lee, Kang-Il;Lee, Sun-Young;Kang, Hee-Jae;Heo, Sung;Chung, Jae-Gwan;Lee, Jae-Cheol
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.347-347
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    • 2012
  • Nickel Oxide (NiO) is a transition metal oxide of the rock salt structure that has a wide band gap of 3.5 eV. It has a variety of specialized applications due to its excellent chemical stability, optical, electrical and magnetic properties. In this study, we concentrated on the application of NiO thin film for transparent conducting oxide. The energy band structure, electronic and optical properties of Nickel Oxide (NiO) thin films grown on Si by using electron beam evaporation were investigated by X-Ray Photoelectron Spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), and UV-Spectrometer. The band gap of NiO thin films determined by REELS spectra was 3.53 eV for the primary energies of 1.5 keV. The valence-band offset (VBO) of NiO thin films investigated by XPS was 3.88 eV and the conduction-band offset (CBO) was 1.59 eV. The UV-spectra analysis showed that the optical transmittance of the NiO thin film was 84% in the visible light region within an error of ${\pm}1%$ and the optical band gap for indirect band gap was 3.53 eV which is well agreement with estimated by REELS. The dielectric function was determined using the REELS spectra in conjunction with the Quantitative Analysis of Electron Energy Loss Spectra (QUEELS)-${\varepsilon}({\kappa},{\omega})$-REELS software. The Energy Loss Function (ELF) appeared at 4.8, 8.2, 22.5, 38.6, and 67.0 eV. The results are in good agreement with the previous study [1]. The transmission coefficient of NiO thin films calculated by QUEELS-REELS was 85% in the visible region, we confirmed that the optical transmittance values obtained with UV-Spectrometer is the same as that of estimated from QUEELS-${\varepsilon}({\kappa},{\omega})$-REELS within uncertainty. The inelastic mean free path (IMFP) estimated from QUEELS-${\varepsilon}({\kappa},{\omega})$-REELS is consistent with the IMFP values determined by the Tanuma-Powell Penn (TPP2M) formula [2]. Our results showed that the IMFP of NiO thin films was increased with increasing primary energies. The quantitative analysis of REELS provides us with a straightforward way to determine the electronic and optical properties of transparent thin film materials.

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$Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$(X=Cu, Mg, Mn)-Rubber Composite의 전파흡수특성에 관한 연구 (Electromagetic Wave Absorbing Properties of $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$(X=Cu, Mg, Mn)-Rubber Composite)

  • 임희대;윤국태;이찬규
    • 한국재료학회지
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    • 제9권12호
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    • pp.1234-1239
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    • 1999
  • $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$의 조성에서 X를 각각 Cu, Mg, Mn으로 치환시켜 치환원소에 따른 결정구조와 형상, 입도 및 자기적 성질을 비교 분석하여고, Network Analyzer을 이용하여 $Ni_{0.5}-Zn_{0.4}-X_{0.1}{\cdot}Fe_2O_4$-Rubber Composite의 재료정수 및 전파흡수특성에 대하여 비교 조사하였다. 치환원소에 관계없이 동일한 결정구조와 형상 및 입도를 나타냈고, VSM 분석결과 치환원소에 관계없이 동일한 자화값을 가지며, Mg로 치환된 경우 가장 큰 보자력과 자기이력손실을 나타냈다. 또한 Mn으로 치환된 경우 가장 높은 유전손실(${\varepsilon}_r"/{\varepsilon}_r'$)을, Cu로 치환된 경우에는 가장 큰 자기손실(${\mu}_r"/{\mu}_r'$)을 나타냈다. 4mm의 두께로 제조한 Compos-Composite에서는 Mg로 치환된 시료가 2GHz에서 -40dB이상의 가장 우수한 전파흡수특성을 나타내었다.

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Effects of Sheet Thickness on the Electromagnetic Wave Absorbing Characterization of Li0.375Ni0.375Zn0.25-Ferrite Composite as a Radiation Absorbent Material

  • Kim, Dong-Young;Yoon, Young-Ho;Jo, Kwan-Jun;Jung, Gil-Bong;An, Chong-Chul
    • Journal of electromagnetic engineering and science
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    • 제16권3호
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    • pp.150-158
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    • 2016
  • This paper reports on a study of LiNiZn-ferrite composite as a radiation absorbent material (RAM). The electromagnetic (EM) wave absorbers are composed of an EM wave absorbing material and a polymeric binder. The surface morphology, chemical composition, weight percent of the ferrite composite of the toroid sample, magnetic properties, and return loss are investigated using field emission scanning electron microscopy (FE-SEM), energy dispersive X-ray spectroscopy (EDX), X-ray photoelectron spectroscopy (XPS), thermogravimetric analysis (TGA), vibrating sample magnetometer (VSM), and network analyzer. For preparing the absorbing sheet, chlorinated polyethylene (CPE) is used as a polymeric binder. The EM wave absorption properties of the prepared samples were studied at 4 - 8 GHz. We can confirm the effects of the thickness of the samples for absorption properties. An absorption bandwidth of more than a 10-dB return loss shifts toward a lower frequency range along with an increase in the thickness of the absorber.

$Bi_2O_3$와 CaO 첨가에 따른 PLC용 자심 재료의 물성 (Dependence of the physical properties for magnetic core materials on the concentrations of $Bi_2O_3$ and CaO)

  • 안용운;이해연;김종령;김현식;오영우
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 초전도 자성체
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    • pp.64-67
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    • 2002
  • The Physical and magnetic properties such as microstructure, permeability and power loss of Ni-Zn ferrite with composition of $Ni_{0.8}Zn_{0.2}Fe_2O_4$, were investigated as the function of $Bi_2O_3$ and CaO contents. The power loss increased in proportion to the amount of $Bi_2O_3$ up to 0.3 wt% but it decreased over than 0.3 wt% addition. The highest permeability of 134 was obtained to the specimen added 1.0 wt% $Bi_2O_3$ since $Bi_2O_3$ contents were strongly dominant to grain growth and size than that of CaO. $Bi_2O_3$ liquid phase created during sintering process promoted sintering and grain growth so that grain size and permeability increased compared to that of the specimens which were sintered with free-additive and CaO. Also, lots of pores existed in the specimen which was added $Bi_2O_3$ wt% with the biggest grain size.

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THE INVESTIGATION OF PSEUDOELASTIC NITI WIRES FOR DAMPING USES

  • Pan, Qiang;Cho, Chong-Du;Lu, Sheng
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2007년도 춘계학술대회A
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    • pp.154-159
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    • 2007
  • Some shape memory alloys like NiTi show noticeable high damping property in pseudoelastic range. Due to its instinct characteristics, a NiTi alloy is commonly used for passive damping applications, in which the energy may be dissipated by the conversion from mechanical to thermal energy. Previous researches found the NiTi wires own higher damping property than the bars; therefore the wire form is adopted in this study. A loss factor is introduced for measuring the damping property of the NiTi wires. The experimental observation shows the mechanical behaviors of NiTi wires are dependent on temperature, strain rate and strain amplitude. Moreover, it is found the first several decades of loading-unloading cycles can obviously influence the property of NiTi wires under the same working conditions.

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Ni/MH 2차전지용 TiFe1-xNix 합금전극의 방전특성에 대한 열처리의 영향 (Effects of Heat-treatments on Discharge Characteristics of TiFe1-xNix Alloy Electrodes for Ni/MH Secondary Battery)

  • 정순돌;정상식;안효준;김기원
    • 한국수소및신에너지학회논문집
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    • 제9권4호
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    • pp.135-141
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    • 1998
  • Fe-Ti계 수소저장합금 전극의 방전특성을 개선하기 위하여 Ni을 첨가한 $TiFe_{1-x}Ni_x$ 합금을 제조하여 방전특성과 열처리 온도에 따른 변화를 조사하였다. 합금의 조성은 x = 0.1에서 0.6까지 0.1 단위씩 변화시킨 6가지 조성을 선택하여 각각에 대한 초기방전용량과 충방전사이클에 따른 용량변화를 조사하였다. 초기방전용량은 Ni의 조성이 클수록 증가하다가 x = 0.6 에서 다시 감소하였으며 Ni의 조성이 증가함에 따라 사이클특성은 전반적으로 매우 악화되었다. 열처리온도가 사이클 특성에 미치는 영향을 조사하기 위하여 초기용량이 가장 우수한 $TiFe_{0.5}Ni_{0.5}$ 합금에 대하여 $700{\sim}900^{\circ}C$ 의 온도범위에서 열처리를 시행한 후 방전특성을 조사하였다. 열처리에 의해서 초기용량은 감소되지만 사이클 특성은 현저히 개선되었다. $700{\sim}850^{\circ}C$의 온도범위에서 1시간 열처리한 전극의 경우에 사이클이 진행되면서 방전용량이 크게 회복되었으며, 열처리한 표면조직을 SEM 으로 관찰해 본 결과 이는 충분한 전극강도 및 기공율에 기인한 것으로 생각되었다. $900^{\circ}C$에서 1시간 열처리한 전극은 충분한 기공율을 갖지 못하여 방전특성이 좋지 않음을 알 수 있었다.

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