• 제목/요약/키워드: Ni buffer layer

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세라믹 선재의 전기 구조적 특성

  • 이상헌;이영희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 춘계학술대회 논문집
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    • pp.54-56
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    • 2005
  • Fabrication of c-axis oriented $(Hg_{0.75}Rc_{0.25})Ba_2Ca_2Cu_3O_y$ thick fabricated has been attempted using Ni substrates with the buffer layer of Cr or NiO. Coexistence of $(Hg_{0.75}Rc_{0.25})Ba_2Ca_3Cu_4O_y$ pellets wad found to stabilize $(Hg_{0.75}Rc_{0.25})Ba_2Ca_2Cu_3O_y$ phase of the tape. The c-axis oriented tapes were reproducibly obtained on the NiO/Ni substerate and they recorded high $B_{irr}$ at 77K.$(Hg_{0.75}Rc_{0.25})Ba_2Ca_2Cu_3O_y$ 1223.

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YBCO coated conductor with a single buffer layer of Yttrium Oxide

  • Park, Chan;Dongqi Shi;Kyujeong Song;Rokkil Ko;Park, Soojeong;Yoo, Sang-Im
    • 한국초전도ㆍ저온공학회논문지
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    • 제5권3호
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    • pp.20-22
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    • 2003
  • Y$_2$O$_3$ films were pulsed laser deposited on cube textured Ni and Ni-W substrates to be used as a single buffer layer of YBCO coated conductor. Initial deposition of $Y_2$O$_3$ films was performed in a reducing atmosphere, and subsequent deposition was done in the base pressure of the chamber and oxygen atmosphere. The $Y_2$O$_3$ films have a strong cube texture (The full width at half maximum of the ø-scan of $Y_2$O$_3$ was 8.4 which was the same as that of metal substrate) and smooth crack-free microstructure. The biaxially textured YBCO films (The full width at half maximum of the ø-scan was 10.2) pulsed laser deposited on the $Y_2$O$_3$/metal exhibited Tc(R=0) of 86.5K and Jc of 0.7 MA/cm2 at 77K in self field, representing that the $Y_2$O$_3$ single buffer layer is an efficient diffusion barrier of Ni and thus very promising for the achievement of high-Jc YBCO coated conductor.

NiCr 박막 저항계의 열적 안정성에 관한 연구 (The Study on Thermal Stability of NiCr Thin-films Resistor)

  • 김인성;정순종;김도한;송재성
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2001년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.168-170
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    • 2001
  • The NiCr is an important material for present thin-film resistor application owing to its low TCR and thermal stability. In this work, the NiCr thin films were deposited on corning glass substrate by reactive magnetron sputtering and the annealing at temperatures range from 300 to $500^{\circ}C$ for 20 min in vacuum. X-ray, AFM, $R_s$(surface leakage current) have been used to study the structural and electrical properties of the NiCr thin films. The high precision NiCr thin films resistor with TCR(temperature coefficient of resistance) of less then 10 ppm/$^{\circ}C$ was obtained under in in-situ annealing at $300^{\circ}C$ on Cr buffer layer substrate. It is clear that the NiCr thin-films resistor electrical properties are low TCR related with it's annealing and buffer layer condition. NiCr thin film resistor having a good thermal stability and low TCR properties are expected for the application to the dielectric material of passive component.

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NiCr 박막의 어닐링과 열적안정성에 관한 연구 (The Study on Thermal Stability of NiCr Thin-films)

  • 김인성;민복기;송재성
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 추계학술대회 논문집 Vol.17
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    • pp.81-84
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    • 2004
  • The NiCr is an important material for present thin-film resistor application owing to its low TCR and thermal stability. In this work, the NiCr thin films were deposited on coming glass substrate by reactive magnetron sputtering and the annealing at temperatures range from 300 to $500^{\circ}C$ for 20 min in vacuum. X-ray, AFM, $R_s$(surface leakage current) have been used to study the structural and electrical properties of the NiCr thin films. The high precision NiCr thin films resistor with TCR(temperature coefficient of resistance) of less then $10\;ppm/^{\circ}C$ was obtained under in in-situ annealing at $300^{\circ}C$ on Cr buffer layer substrate. It is clear that the NiCr thin-films resistor electrical properties are low TCR related with it's annealing and buffer layer condition. NiCr thin film resistor having a good thermal stability and low TCR properties are expected for the application to the dielectric material of passive component.

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Effect of the thickness of CeO$_2$ buffer layer on the YBCO coated conductor

  • Dongqi Shi;Ping Ma;Ko, Rock-Kil;Kim, Ho-Sup;Ha, Hong-Soo;Chung, Jun-Ki;Kyu-Jeong, Song;Park, Chan;Moon, Seung-Hyun
    • 한국초전도ㆍ저온공학회논문지
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    • 제6권4호
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    • pp.1-4
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    • 2004
  • Three group samples with difference thickness of $CeO_2$ capping layer deposited by PLD were studied. Among them, one group $CeO_2$ films were deposited on stainless steel tape coated with IBAD- YSZ and $CeO_2$ buffer layer ($CeO_2$/IBAD-YSZ/SS); other two groups of $CeO_2 YSZ Y_2O_3$multi-layer were deposited on NiW substrates for fabrication of YBCO coated conductor through RABiTS approach. The pulsed laser deposition (PLD) and DC magnetron sputtering were employed to deposit these buffer layers. On the top of buffer layer, YBCO film was deposited by PLD. The effect of thickness of $CeO_2$ film on the texture of $CeO_2$ film and critical current density ($J_c$) of YBCO film were analyzed. For the case $CeO_2$ on $CeO_2$/IBAD-YSZ/SS, there was a self-epitaxy effect with the increase of $CeO_2$ film. For $YSZ/Y_2O_3$ NiW which was deposited by PLD or DC magnetron sputtering, there is not self-epitaxy effect. However, the capping layer of $CeO_2$ film deposited by PLD improved the quality of buffer layer for $YSZ/Y_2O_3$ which was deposited by DC magnetron sputtering, therefore increased the $J_c$ of YBCO film.

양축 정렬된 Ni기판 위에 MOCVD법에 의한 YBCO 초전도 선재용 $CeO_2$ 완충층의 증착 (Deposition of $CeO_2$ buffer layer for YBCO coated conductors on biaxially textured Ni substrate by MOCVD technique)

  • 김호진;주진호;전병혁;정충환;박순동;박해웅;홍계원;김찬중
    • 한국초전도ㆍ저온공학회논문지
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    • 제4권2호
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    • pp.21-26
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    • 2002
  • Textured CeO2 buffer layers for YBCO coated conductors were deposited on biaxially textured Ni substrate by metalorganic chemical vapor deposition (MOCVD). The degree of texture of deposited $CeO_2$ films was strong1y dependent on the deposition temperature (Td) and oxygen Partial Pressure(PO2). ($\ell$00) textured $CeO_2$ films were well deposited at T=500~52$0^{\circ}C$. PO2=0.90~3.33 Torr. The surface morphology showed that the films consisted of columnar CeO2 films grown from the Ni substrates. The root mean square roughness of CeO$_2$ films estimated by atomic force microscopy(AFM) increased as the deposition temperature(Td) increa- sed. The growth rate of the $CeO_2$ films deposited at T=52$0^{\circ}C$ and PO2=2.30 Torr was 150~200 nm/min that was much faster than that of other Physical deposition methods.

MOCVD법에 의한 YBCO coated conductor용 YSZ 완충층 제작 (Fabrication of YSZ buffer layer for YBCO coated conductor by MOCVD method)

  • 선종원;김형섭;정충환;전병혁;김찬중
    • 한국초전도저온공학회:학술대회논문집
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    • 한국초전도저온공학회 2003년도 학술대회 논문집
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    • pp.129-132
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    • 2003
  • Yttria stabilized zirconia (YSZ) buffer layers were deposited by a metal organic chemical vapor deposition (MOCVD) technique using single liquid source for the application of YBa$_2$Cu$_3$$O_{7-x}$ (YBCO) coated conductor. Y:Zr mole ratio was 0.2:0.8, and tetrahydrofuran (THF) was used as a solvent. The (100) single crystal MgO substrate was used for searching deposition condition. Bi-axially oriented CeO$_2$ and NiO films were fabricated on {100}〈001〉 Ni substrate by the same method and used as templates. At a constant working pressure of 10 Torr, the deposition temperatures (660~80$0^{\circ}C$) and oxygen flow rates (100~500 sccm) were changed to find the optimum deposition condition. The best (100) oriented YSZ film on MgO was obtained at 74$0^{\circ}C$ and $O_2$ flow rate of 300 sccm. For YSZ buffer layer with this deposition condition on CeO$_2$/Ni template, full width half maximum (FWHM) values of the in-plane and out-of-plane alignments were 10.6$^{\circ}$ and 9.8$^{\circ}$, respectively. The SEM image of YSZ film on CeO$_2$/Ni showed surface morphologies without microcrack.k.

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Buffer 층을 갖는 CoFe/ Cu/ Co 샌드위치 박막의 자기저항 특성 (Magnetoresistance of Buffer/CoFe/Cu/Co Sandwiches)

  • 송은영;오미영;김경민;이장로;김미양;김희중;박창만;이상석;황도근
    • 한국자기학회지
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    • 제7권3호
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    • pp.146-151
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    • 1997
  • DC magnetron sputtering 방법으로 Corning glass 기판 위에 버퍼층을 Fe와 N $i_{81}$$Fe_{19}$로 바꾸어가면서 보자력이 다른 $Co_{90}$ F $e_{10}$와 Co를 이용하여 buffer/CoFe(35 .angs. )/Cu(t .angs. )/Co(35 .angs. )의 형태로 샌드위치 박막을 제작하고 버퍼층 두께 및 바자성층 Cu층 두께, 자성층 두께 변화에 따른 자기저항비 의존성을 조사하였다. 자기저항비와 포화 자기장( $H_{s}$ )은 버퍼층의 두께가 두꺼워짐에 따라 증가하다가 극대치 3%를 보인 후 완만하게 감소하였다. NiFe, Fe 버퍼층을 갖는 시료를 비교한 경우, 각각 CoFe층과 Co층 사이의 결합 자기장( $H_{int}$)은 큰 차이가 없었으나 NiFe 버퍼층을 갖는 시료가 minor 자기저항 곡선의 반가폭 $H_{w}$ 는 감소하고 자기저항(MR) 기울기(slope)와 관련된 field sensitivity(%/Oe)는 향상되었다.다.

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Mn-Ir의 조성과 두께 및 초기진공도에 따른 Mn-Ir/Ni-Fe/Zr 다층막의 자기적특성과 미세구조 연구 (A Study on the Magnetic Properties and Microstructures of Mn-Ir/Ni-Fe/Zr Muti layers with Various Compositions, Thicknesses and Base Pressures)

  • 노재철;최영석;이경섭;김용성;서수정
    • 한국자기학회지
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    • 제9권3호
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    • pp.166-172
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    • 1999
  • 본 연구에서는 마그네트론 스퍼터링 법으로 제작한 Mn-Ir/Ni-Fe/Zr/Si 다층막에서 Mn-Ir의 조성과 증착조건을 변화시키고 또한 Mn-Ir층의 두께를 조절한 후 자기적 특성과 미세구조에 대하여 고찰하였다. Mn-22at% Ir의 조성에서 219Oe의 가장 높은 Hex와 30Oe의 낮은 Hc를 얻을 수 있었다. 초기진공도가 3.0$\times$10-6Torr 이상 일때는 교환이방성이 사라지게 되었으며 이것은 Mn-Ir의 비정질화와 결정립미세화에 의한 것으로 판단된다.

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초전도 테이프 제작을 위한 니켈기판 상의 산화물 박막 증찰 (Study on Depositing Oxide Films on Ni Substrate for Superconducting Tape)

  • 김호섭;;고락길;정준기;하홍수;송규정;박찬
    • 한국전기전자재료학회논문지
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    • 제17권12호
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    • pp.1356-1361
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    • 2004
  • High temperature superconducting coated conductor has a structure of ///. The buffer layer consists of multi-layer, this study reports the deposition method and optimal deposition conditions of YSZ(Yttria-stabilized zirconia) layer which plays a important part in preventing the elements of substrate from diffusing into the superconducting layer. YSZ layer was deposited by DC reactive sputtering technique using water vapor for oxidizing deposited elements on substrate. To investigate optimal thickness of YSZ film, four YSZ/CeO$_2$/Ni samples with different YSZ thickness(130 nm, 260 nm, 390 nm, and 650 nm) were prepared. The SEM image showed that the surface of YSZ layer was getting to be rougher as YSZ layer was getting thicker and the growth mode of YSZ layer was columnar grain growth. After CeO$_2$ layer was deposited with the same thickness of 18.3 nm on each four samples, YBCO layer was deposited by PLD method with the thickness of 300 nm. The critical currents of four samples were 0, 6 A, 7.5 A, and 5 A respectively. This shows that as YSZ layer is getting thicker, YSZ layer plays a good role as a diffusion barrier but the surface of YSZ layer is getting rougher.